CN104641500B - 包含石墨烯的电极配制物 - Google Patents

包含石墨烯的电极配制物 Download PDF

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Publication number
CN104641500B
CN104641500B CN201380032532.7A CN201380032532A CN104641500B CN 104641500 B CN104641500 B CN 104641500B CN 201380032532 A CN201380032532 A CN 201380032532A CN 104641500 B CN104641500 B CN 104641500B
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graphene
negative electrode
range
domain
electroactive material
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Chinese (zh)
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CN104641500A (zh
Inventor
N.J.哈德曼
B.布利扎纳克
A.L.杜帕斯奎尔
M.奥尔贾卡
A.基尔利迪斯
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Cabot Corp
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Cabot Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0404Methods of deposition of the material by coating on electrode collectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1391Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1393Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • H01M4/623Binders being polymers fluorinated polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/021Physical characteristics, e.g. porosity, surface area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
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    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Carbon And Carbon Compounds (AREA)
CN201380032532.7A 2012-06-20 2013-06-19 包含石墨烯的电极配制物 Expired - Fee Related CN104641500B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261661999P 2012-06-20 2012-06-20
US61/661,999 2012-06-20
PCT/US2013/046456 WO2013192258A1 (en) 2012-06-20 2013-06-19 Electrode formulations comprising graphenes

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CN104641500A CN104641500A (zh) 2015-05-20
CN104641500B true CN104641500B (zh) 2017-10-13

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US (1) US9722248B2 (https=)
JP (1) JP6250043B2 (https=)
KR (1) KR101769219B1 (https=)
CN (1) CN104641500B (https=)
WO (1) WO2013192258A1 (https=)

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AU2015249295B2 (en) * 2014-04-25 2018-07-05 South Dakota Board Of Regents High capacity electrodes
EP4521505A3 (en) * 2014-10-31 2025-04-16 PPG Industries Ohio, Inc. Lithium ion battery electrodes including graphenic carbon particles
CN104383578B (zh) * 2014-12-01 2016-05-11 哈尔滨工业大学 一种氧化石墨烯接枝改性氧化再生纤维素止血材料及其制备方法
DE102014226396B4 (de) * 2014-12-18 2025-12-18 Bayerische Motoren Werke Aktiengesellschaft Herstellung einer Kompositkathode
EP3363066A4 (en) 2015-10-14 2019-03-27 Northwestern University GRAPH-COATED METAL OXIDE SPINEL CATHODES
JP6760097B2 (ja) * 2016-01-27 2020-09-23 東レ株式会社 リチウム二次電池用正極およびその製造方法
CN105977047A (zh) * 2016-05-24 2016-09-28 宁波墨西科技有限公司 一种石墨烯/活性炭复合电极材料及其制备方法
JP6982788B2 (ja) * 2017-03-30 2021-12-17 東レ株式会社 二次電池用電極およびその製造方法
US10468674B2 (en) 2018-01-09 2019-11-05 South Dakota Board Of Regents Layered high capacity electrodes
JP7102831B2 (ja) * 2018-03-23 2022-07-20 Tdk株式会社 正極及びリチウムイオン二次電池
WO2020040713A2 (en) * 2018-06-27 2020-02-27 Anadolu Universitesi Graphene synthesis method by microfluidization
DE102018219472A1 (de) * 2018-11-15 2020-05-20 Robert Bosch Gmbh Verfahren zur Herstellung einer positiven Elektrode für eine Batteriezelle
CN120112480A (zh) * 2022-08-30 2025-06-06 株式会社3Dc 碳材料和使用了该碳材料的蓄电设备用正极、负极以及蓄电设备

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US6770226B2 (en) 1998-02-24 2004-08-03 Superior Micropowders Fine powders for use in primary and secondary batteries
WO2001091211A1 (en) * 2000-05-24 2001-11-29 Mitsubishi Cable Industries, Ltd. Lithium secondary cell and positive electrode active material, positive plate, and method for manufacturing them
CN101479866B (zh) 2006-06-27 2011-11-30 花王株式会社 锂电池正极用复合材料的制造方法
US8493711B2 (en) * 2008-01-17 2013-07-23 Fraser W. SEYMOUR Monolithic electrode, related material, process for production, and use thereof
US8450014B2 (en) * 2008-07-28 2013-05-28 Battelle Memorial Institute Lithium ion batteries with titania/graphene anodes
US8652687B2 (en) 2009-12-24 2014-02-18 Nanotek Instruments, Inc. Conductive graphene polymer binder for electrochemical cell electrodes
US20110227001A1 (en) 2010-03-19 2011-09-22 Basf Se Electrode material and use thereof for production of electrochemical cells
KR101181851B1 (ko) * 2010-08-09 2012-09-11 삼성에스디아이 주식회사 리튬 이차 전지용 활물질 및 이를 포함하는 리튬 이차 전지
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WO2013192258A8 (en) 2015-03-26
JP2015524154A (ja) 2015-08-20
US20150194674A1 (en) 2015-07-09
WO2013192258A1 (en) 2013-12-27
KR101769219B1 (ko) 2017-08-17
JP6250043B2 (ja) 2017-12-20
KR20150032865A (ko) 2015-03-30
CN104641500A (zh) 2015-05-20
US9722248B2 (en) 2017-08-01

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