CN104606077A - Nanometer ultraviolet-resistant ginseng whitening hand sanitizer and preparation method thereof - Google Patents
Nanometer ultraviolet-resistant ginseng whitening hand sanitizer and preparation method thereof Download PDFInfo
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- CN104606077A CN104606077A CN201510053523.7A CN201510053523A CN104606077A CN 104606077 A CN104606077 A CN 104606077A CN 201510053523 A CN201510053523 A CN 201510053523A CN 104606077 A CN104606077 A CN 104606077A
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Abstract
The invention relates to a nanometer ultraviolet-resistant ginseng whitening hand sanitizer and a preparation method thereof. The hand sanitizer is prepared from the following components in parts by mass: 1-20 parts of aqueous solution of sodium dodecyl benzene sulfonate, 0.1-5 parts of glycerin, 0.1-5 parts of 2-methyl-4-isothiazolin-3-one, 1-40 parts of aqueous solution of cocamidopropyl betaine, 0.1-20 parts of panaxoside, 0.5-2 parts of nanometer titania, 0.1-5 parts of spices, 0.1-5 parts of pigments, 0.01-2 parts of citric acid, 0.1-5 parts of sodium chloride and the balance of distilled water. Compared with the prior art, the hand sanitizer prepared by the invention can achieve the bacteria resisting and inhibiting effects, and the effects of whitening, moistening skin and preventing ultraviolet radiation can be achieved.
Description
Technical field
The invention belongs to detergent technical field, especially relate to a kind of nano anti-ultraviolet ginseng skin-whitening liquid soap and preparation method thereof.
Background technology
Along with the pollution of environment, the destruction of ozone layer, damaging faint ultraviolet to the mankind also becomes more severe originally.Be subject to the impact of ultraviolet radiation, human skin cancer, will improve greatly etc. the sickness rate of disease.But existing handwashing liquid, major function still rests on decontamination aspect, although portioned product has sterilizing function, can damage hand skin after long-time use, moreover, the Disinfection Effect of many handwashing liquid also allows of no optimist.
Chinese patent CN101711726A discloses a kind of ginseng skin-whitening liquid soap and preparation method thereof.With the addition of natural ginseng saponin component in this ginseng skin-whitening liquid soap, enhance skin anti-aging effect, improve skin microcirculation, have anti-coarse and crease-resistantly split effect, and then play beauty treatment and health care dual function.Handwashing liquid is by polyoxyethylenated alcohol sodium sulfate, alkyl polyglucoside, cocamido propyl betaine, glycerol, EDTA-2Na, MIT, 2, the raw material such as the chloro-2-hydroxy-diphenylether of 4,4-tri-, spice, pigment, citric acid, ginsenoside, distilled water is made.Preparation method extracts the effective ingredient such as ginsenoside by from plant Radix Ginseng stem, leaf and root, by adding various raw material, through dissolving, heating, emulsifying, stirring, leave standstill etc. technique make ginseng skin-whitening liquid soap.But, in this patent, adopt 2,4, the chloro-2-hydroxy-diphenylether of 4-tri-, as antibacterial, now studies have found that, 2,4,4-tri-chloro-2-hydroxy-diphenylether has certain controversial, because it can cause white mouse hepatocarcinoma and hepatic fibrosis, thus has carcinogenic probability, therefore the compound system of handwashing liquid is not suitable for, therefore need the antibacterial adopting other, thus need the entirety to compound system, comprise other component added and all will adjust accordingly.
Summary of the invention
Object of the present invention is exactly provide a kind of natural ginsenoside's composition and nano-titanium oxide composition of with the addition of to overcome defect that above-mentioned prior art exists, enhances skin anti-aging ability, improves skin circulation, sterilize more thorough, and nontoxic.Except retaining decontamination, the antibacterial and bacteriostasis of handwashing liquid, life-time service nano anti-ultraviolet ginseng skin-whitening liquid soap that can also reach whitening and moistening skin effect and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
Nano anti-ultraviolet ginseng skin-whitening liquid soap, adopts the component of following mass percentage content to prepare:
Sodium dodecyl benzene sulfonate aqueous solution 1 ~ 20, glycerol 0.1 ~ 5, MIT 0.1 ~ 5, cocamido propyl betaine aqueous solution 1 ~ 40, ginsenoside 0.1 ~ 20, nano-titanium oxide 0.5 ~ 2, spice 0.1 ~ 5, pigment 0.1 ~ 5, citric acid 0.01 ~ 2, sodium chloride 0.1 ~ 5, all the other are distilled water, and gross mass percentage ratio meets 100%.
Preferably, the mass fraction of sodium dodecyl benzene sulfonate aqueous solution is 4.8%.
Preferably, the mass fraction of cocamido propyl betaine aqueous solution is 30%.
Preferably, ginsenoside can extract and obtain from plant Radix Ginseng stem, leaf and root.
Preferably, nano-titanium oxide is Powdered rutile type nano titanic oxide, and diameter is 20 ~ 50nm, and Mohs' hardness is 6.0 ~ 6.5.
The preparation method of nano anti-ultraviolet ginseng skin-whitening liquid soap adopts following steps:
(1) add the distilled water of total amount 20 ~ 30wt% in a kettle., and be heated to 60 ~ 80 DEG C;
(2) keep system temperature at 60 ~ 80 DEG C, add sodium dodecyl benzene sulfonate aqueous solution, glycerol, MIT successively under stirring, fully stir 3 ~ 8h;
(3) be cooled to 20 ~ 30 DEG C, add ginsenoside, nano-titanium oxide, spice, pigment, cocamido propyl betaine aqueous solution, sodium chloride and remaining distilled water under stirring successively, fully stir 3 ~ 5h;
(4) regulate stock solution pH value straight 5.5 ~ 6.5 with citric acid, then leave standstill 5 ~ 9h, the foam in system is disappeared completely, and transparent, the uniform state of solution, namely prepares nano anti-ultraviolet ginseng skin-whitening liquid soap.
Compared with prior art, the present invention has the following advantages:
Nano-titanium oxide has following character:
1, the ultraviolet in air can be absorbed.
2, ultravioletly there is chemical reaction in absorption simultaneously, as follows:
TiO
2+hνe——+h
H
2O+h——·OH+H
O
2+e——O
2·
O
2·+H——HO
2·
2HO
2·——O
2+H
2O
2
H
2O
2+O
2·——·OH+OH+O
2
The Superoxide anion free radical produced can be oxidized a lot of antibacterial to play the effect of sterilization.
Study discovery by experiment, in the Common Pathogenic Micro-Organism Culture Dish adding a small amount of nano-titanium oxide, staphylococcus aureus and the survival rate of escherichia coli in 1 hour are 0.03%, exceed chemical drugs handwashing liquid as: drip dew disinfection hand cleanser 99% sterilizing rate.
3, cleaning function: we find that nano-titanium oxide is due to Superhydrophilic, organic contamination image " burning " generally can be decomposed into CO2 and H2O, carbon dioxide enters in the middle of air immediately, and water can rest on skin and keeps the skin wet in time, increases humidity.
4, water-fastness due to Superhydrophilic, skin surface can be rested on for a long time and play bactericidal action, can reduce and wash one's hands number of times and do not reduce clean-up performance.
4, to human non-toxic, non-stimulated, also odorlessness.
The effect of ginsenoside is as follows:
1, it can Cell protection film prevent cell senescence.Its anti-cell oxidability is 5 times that do not use any antioxidant,
2, ginsenoside experimental results demonstrate and effectively can have been resisted tumor cell.Residual by after washing one's hands, ginsenoside can reduce the incidence rate of skin carcinoma, can play the effect of prevention to a certain extent.
If 3, ginsenoside is added in handwashing liquid, can whitening be played, antioxidative effect, even can replace some conventional Skin whitening care cosmeticses.
Detailed description of the invention
Nano anti-ultraviolet ginseng skin-whitening liquid soap, adopts the component of following mass percentage content to prepare:
Mass fraction is the sodium dodecyl benzene sulfonate aqueous solution 1 ~ 20 of 4.8%, glycerol 0.1 ~ 5, MIT 0.1 ~ 5, mass fraction is the cocamido propyl betaine aqueous solution 1 ~ 40 of 30%, ginsenoside 0.1 ~ 20, nano-titanium oxide 0.5 ~ 2, spice 0.1 ~ 5, pigment 0.1 ~ 5, citric acid 0.01 ~ 2, sodium chloride 0.1 ~ 5, all the other are distilled water, gross mass percentage ratio meets 100%, wherein, the nano-titanium oxide added is Powdered rutile type nano titanic oxide, diameter is 20 ~ 50nm, Mohs' hardness is 6.0 ~ 6.5.
The preparation method of nano anti-ultraviolet ginseng skin-whitening liquid soap adopts following steps:
(1) add the distilled water of total amount 20 ~ 30wt% in a kettle., and be heated to 60 ~ 80 DEG C;
(2) keep system temperature at 60 ~ 80 DEG C, add sodium dodecyl benzene sulfonate aqueous solution, glycerol, MIT successively under stirring, fully stir 3 ~ 8h;
(3) be cooled to 20 ~ 30 DEG C, add ginsenoside, nano-titanium oxide, spice, pigment, cocamido propyl betaine aqueous solution, sodium chloride and remaining distilled water under stirring successively, fully stir 3 ~ 5h;
(4) regulate stock solution pH value straight 5.5 ~ 6.5 with citric acid, then leave standstill 5 ~ 9h, the foam in system is disappeared completely, and transparent, the uniform state of solution, namely prepares nano anti-ultraviolet ginseng skin-whitening liquid soap.
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Nano anti-ultraviolet ginseng skin-whitening liquid soap, adopts the component of following mass percentage content to prepare:
Cocamido propyl betaine aqueous solution 1%, ginsenoside 20 %, nano-titanium oxide 0.5%, spice 0.1%, pigment 0.1%, citric acid 0.01%, sodium chloride 0.1% that the sodium dodecyl benzene sulfonate aqueous solution 1% that mass fraction is 4.8%, glycerol 0.1%, MIT 0.1%, mass fraction are 30%, all the other are distilled water, gross mass percentage ratio meets 100%, the nano-titanium oxide added is Powdered rutile type nano titanic oxide, diameter is 20nm, and Mohs' hardness is 6.0.
The preparation method of nano anti-ultraviolet ginseng skin-whitening liquid soap adopts following steps:
(1) add the distilled water of total amount 20wt% in a kettle., and be heated to 60 DEG C;
(2) keep system temperature at 60 DEG C, add sodium dodecyl benzene sulfonate aqueous solution, glycerol, MIT successively under stirring, fully stir 3h;
(3) be cooled to 20 DEG C, add ginsenoside, nano-titanium oxide, spice, pigment, cocamido propyl betaine aqueous solution, sodium chloride and remaining distilled water under stirring successively, fully stir 3h;
(4) regulate stock solution pH value straight 5.5 with citric acid, then leave standstill 5h, the foam in system is disappeared completely, and transparent, the uniform state of solution, namely prepares nano anti-ultraviolet ginseng skin-whitening liquid soap.
Embodiment 2
Nano anti-ultraviolet ginseng skin-whitening liquid soap, adopts the component of following mass percentage content to prepare:
The cocamido propyl betaine aqueous solution 20% that the sodium dodecyl benzene sulfonate aqueous solution 10% that mass fraction is 4.8%, glycerol 2%, MIT 3%, mass fraction are 30%, ginsenoside 10%, nano-titanium oxide 1%, spice 3%, pigment 3%, citric acid 1%, sodium chloride 2%, all the other are distilled water, gross mass percentage ratio meets 100%, the nano-titanium oxide added is Powdered rutile type nano titanic oxide, diameter is 40nm, and Mohs' hardness is 6.3.
The preparation method of nano anti-ultraviolet ginseng skin-whitening liquid soap adopts following steps:
(1) add the distilled water of total amount 20wt% in a kettle., and be heated to 70 DEG C;
(2) keep system temperature at 70 DEG C, add sodium dodecyl benzene sulfonate aqueous solution, glycerol, MIT successively under stirring, fully stir 3 ~ 8h;
(3) be cooled to 25 DEG C, add ginsenoside, nano-titanium oxide, spice, pigment, cocamido propyl betaine aqueous solution, sodium chloride and remaining distilled water under stirring successively, fully stir 4h;
(4) regulate stock solution pH value straight 6 with citric acid, then leave standstill 8h, the foam in system is disappeared completely, and transparent, the uniform state of solution, namely prepares nano anti-ultraviolet ginseng skin-whitening liquid soap.
Embodiment 3
Nano anti-ultraviolet ginseng skin-whitening liquid soap, adopts the component of following mass percentage content to prepare:
The cocamido propyl betaine aqueous solution 40% that the sodium dodecyl benzene sulfonate aqueous solution 20% that mass fraction is 4.8%, glycerol 5%, MIT 5%, mass fraction are 30%, ginsenoside 0.1%, nano-titanium oxide 2%, spice 5%, pigment 5%, citric acid 2%, sodium chloride 5%, all the other are distilled water, gross mass percentage ratio meets 100%, the nano-titanium oxide added is Powdered rutile type nano titanic oxide, diameter is 50nm, and Mohs' hardness is 6.5.
The preparation method of nano anti-ultraviolet ginseng skin-whitening liquid soap adopts following steps:
(1) add the distilled water of total amount 30wt% in a kettle., and be heated to 80 DEG C;
(2) keep system temperature at 80 DEG C, add sodium dodecyl benzene sulfonate aqueous solution, glycerol, MIT successively under stirring, fully stir 8h;
(3) be cooled to 30 DEG C, add ginsenoside, nano-titanium oxide, spice, pigment, cocamido propyl betaine aqueous solution, sodium chloride and remaining distilled water under stirring successively, fully stir 5h;
(4) regulate stock solution pH value straight 6.5 with citric acid, then leave standstill 9h, the foam in system is disappeared completely, and transparent, the uniform state of solution, namely prepares nano anti-ultraviolet ginseng skin-whitening liquid soap.
The product that embodiment 2 prepares, according to People's Republic of China (PRC) light industry standard QB2654-2004, following index all reaches requirement:
Gross activity thing is 9.73%
PH value is 6.11
Methanol is 552mg/kg
Formaldehyde is 85mg/kg
Arsenic (in As) is 0.53mg/kg
Heavy metal (in Pb) is for 7.2mg/kg hydrargyrum (in Hg) for 0.08mg/kg bacterium colony group number is 158, and above data may have error, but in allowed band.In addition, without colibacillus of excrement.
Claims (5)
1. nano anti-ultraviolet ginseng skin-whitening liquid soap, is characterized in that, this handwashing liquid adopts the component of following mass percentage content to prepare:
Sodium dodecyl benzene sulfonate aqueous solution 1 ~ 20, glycerol 0.1 ~ 5, MIT 0.1 ~ 5, cocamido propyl betaine aqueous solution 1 ~ 40, ginsenoside 0.1 ~ 20, nano-titanium oxide 0.5 ~ 2, spice 0.1 ~ 5, pigment 0.1 ~ 5, citric acid 0.01 ~ 2, sodium chloride 0.1 ~ 5, all the other are distilled water, and gross mass percentage ratio meets 100%.
2. nano anti-ultraviolet ginseng skin-whitening liquid soap according to claim 1, is characterized in that, the mass fraction of described sodium dodecyl benzene sulfonate aqueous solution is 4.8%.
3. nano anti-ultraviolet ginseng skin-whitening liquid soap according to claim 1, is characterized in that, the mass fraction of described cocamido propyl betaine aqueous solution is 30%.
4. nano anti-ultraviolet ginseng skin-whitening liquid soap according to claim 1, is characterized in that, described nano-titanium oxide is Powdered rutile type nano titanic oxide, and diameter is 20 ~ 50nm, and Mohs' hardness is 6.0 ~ 6.5.
5. the preparation method of the nano anti-ultraviolet ginseng skin-whitening liquid soap according to any one of claim 1-4, is characterized in that, the method adopts following steps:
(1) add the distilled water of total amount 20 ~ 30wt% in a kettle., and be heated to 60 ~ 80 DEG C;
(2) keep system temperature at 60 ~ 80 DEG C, add sodium dodecyl benzene sulfonate aqueous solution, glycerol, MIT successively under stirring, fully stir 3 ~ 8h;
(3) be cooled to 20 ~ 30 DEG C, add ginsenoside, nano-titanium oxide, spice, pigment, cocamido propyl betaine aqueous solution, sodium chloride and remaining distilled water under stirring successively, fully stir 3 ~ 5h;
(4) regulate stock solution pH value straight 5.5 ~ 6.5 with citric acid, then leave standstill 5 ~ 9h, the foam in system is disappeared completely, and transparent, the uniform state of solution, namely prepares nano anti-ultraviolet ginseng skin-whitening liquid soap.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105534731A (en) * | 2015-12-22 | 2016-05-04 | 上海心动能科技有限公司 | Multi-ion water-based foamless odor-removing liquid soap and a preparing method thereof |
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| CN101402844A (en) * | 2008-03-14 | 2009-04-08 | 东莞拓扑实业有限公司 | UV proof, antimicrobial nano-function powder and method of producing the same |
| CN101711726A (en) * | 2009-11-19 | 2010-05-26 | 同济大学 | Ginseng skin-whitening liquid soap and preparation method thereof |
| CN102078273A (en) * | 2011-01-10 | 2011-06-01 | 王飞 | Antibiosis plant extract spray |
| CN103893019A (en) * | 2012-12-26 | 2014-07-02 | 大连林桥科技有限公司 | Photocatalyst hand cleanser |
| CN104027293A (en) * | 2014-06-27 | 2014-09-10 | 王忠良 | Whitening cosmetic and preparation method thereof |
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2015
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402844A (en) * | 2008-03-14 | 2009-04-08 | 东莞拓扑实业有限公司 | UV proof, antimicrobial nano-function powder and method of producing the same |
| CN101711726A (en) * | 2009-11-19 | 2010-05-26 | 同济大学 | Ginseng skin-whitening liquid soap and preparation method thereof |
| CN102078273A (en) * | 2011-01-10 | 2011-06-01 | 王飞 | Antibiosis plant extract spray |
| CN103893019A (en) * | 2012-12-26 | 2014-07-02 | 大连林桥科技有限公司 | Photocatalyst hand cleanser |
| CN104027293A (en) * | 2014-06-27 | 2014-09-10 | 王忠良 | Whitening cosmetic and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105534731A (en) * | 2015-12-22 | 2016-05-04 | 上海心动能科技有限公司 | Multi-ion water-based foamless odor-removing liquid soap and a preparing method thereof |
| CN105534731B (en) * | 2015-12-22 | 2018-06-19 | 上海心动能科技有限公司 | A kind of still based on polyion water removes peculiar smell hand cleanser and preparation method thereof |
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Application publication date: 20150513 |