CN105534731A - Multi-ion water-based foamless odor-removing liquid soap and a preparing method thereof - Google Patents
Multi-ion water-based foamless odor-removing liquid soap and a preparing method thereof Download PDFInfo
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- CN105534731A CN105534731A CN201510971933.XA CN201510971933A CN105534731A CN 105534731 A CN105534731 A CN 105534731A CN 201510971933 A CN201510971933 A CN 201510971933A CN 105534731 A CN105534731 A CN 105534731A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/16—Phosphates including polyphosphates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
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Abstract
Multi-ion water-based foamless odor-removing liquid soap and a preparing method thereof are disclosed. The liquid soap comprises a titanium-containing compound, an alkaline chelating agent, an inorganic alkaline compound and purified water. The method includes weighing the titanium-containing compound according to a titanium ion concentration, dissolving the titanium-containing compound into the purified water, stirring at 20-50 DEG C for 5-60 min, adding dropwise a solution of the alkaline chelating agent under stirring with the mole ratio of the titanium-containing compound to the alkaline chelating agent being 1:1-1:10, and adding dropwise a solution of the inorganic alkaline compound under stirring to allow the sodium ion concentration and/or the potassium ion concentration in a final product to reach a preset valve so as to prepare the liquid soap. The liquid soap is capable of rapidly removing odor, effectively cleaning various types of greasy dirt and stains after a meal and effectively inhibiting bacteria, is natural, environmental friendly, free of organic solvents, free of surfactants, free of foams, easy to wash, warm, non-irritating to noses, hand-protecting and free of irritation, and is advantaged by being efficient, safe and environmental friendly.
Description
Technical field
The present invention relates to cleaning product, particularly relate to and a kind ofly remove abnormal flavour handwashing liquid and preparation method thereof based on the still of polyion water.
Background technology
Dish is in our daily life the conventional cuisine such as seafood, river are fresh, very popular.But remain in the corners of the mouth, all kinds of oil stains of hand, spot after meal, and the residual seafood of hand and river is fresh waits food abnormal flavour, bring inconvenience and embarrassment to life.
CN103948528A discloses a kind of Fructus Fortunellae Margaritae handwashing liquid and preparation method thereof, described handwashing liquid is made up of following component: Fructus Fortunellae Margaritae extract 10-25,3-Hydroxyretinol-6 parts, tea tree ethereal oil 2-5 part, glycerol 5-8 part, polyoxyethylene lauryl ether 3-5 part, sodium chloride 3-5 part, all the other are deionized water.
CN103040665A discloses a kind of protective hand sanitizer, it is characterized in that, by weight, formed by following material mixed preparing: Punica granatum L. quintessence oil 10-15, lanoline 1-5, glycerol 2-6, Herba Menthae 0.5-1.0, Radix Angelicae Dahuricae 1-3, pure plant perfume 0.5-1.0, balance deionized water, handwashing liquid base material 10-15.
CN104224580A discloses a kind of green tea draft and cleans moisturizing foam handwashing liquid and compound method thereof.It is characterized in that, select pure natural draft cleansing, be mixed with the fine and smooth handwashing liquid of foam through special process.The active ingredient of formula is tea saponin, cocoyl betanin, polyoxyethylated coconut oil alcohol sodium sulfate, AEO-9, glycerol, EDTA-Na
2, tea tree ethereal oil.
Handwashing liquid in the market has removes greasy ability preferably, but has certain damage and stimulation to subcutaneous fat layer, and foam is also more, needs just can rinse well with a large amount of water after using, and the fresh abnormal flavour of seafood and river is difficult to remove; Mostly more or less add organic solvent, hostile environment in addition.
Therefore, those skilled in the art is devoted to develop a kind of more environmental protection, the still of safety removes abnormal flavour handwashing liquid.
Summary of the invention
Because the above-mentioned defect of prior art, technical problem to be solved by this invention is to provide a kind ofly removes abnormal flavour handwashing liquid and preparation method thereof based on the still of polyion water, this handwashing liquid can remove abnormal flavour rapidly, all kinds of oil stains, spot that effective removing is residual after meal, not containing any organic solvent, simultaneously effectively antibacterial; Natural environmental-protective, not containing any surfactant, non-foam, easily rinses, and gentleness is not pungent, and does not hinder hands, without any zest, has the advantage of efficient, safety, environmental protection; Add glycerol and aloe moisture-keeping agent, soft comfortable, does not hinder skin.
For achieving the above object, the invention provides and a kind ofly remove abnormal flavour handwashing liquid based on the still of polyion water, described handwashing liquid comprises following component: titanium-containing compound, alkaline chelator, inorganic base substance and pure water, and the oxidation-reduction potential of described handwashing liquid is negative value.
Preferably, described titanium-containing compound is selected from one or more in the organic or inorganic titanium-containing compounds such as titanate esters, Titanium alkoxides, titanium halide.
Wherein, described titanate esters is tetrabutyl titanate, tetraisopropyl titanate, tetraethyl titanate, butyl titanate, acetylacetone,2,4-pentanedione oxygen titanium or two (acetylacetone based) metatitanic acid diisopropyl ester, most preferably is butyl titanate.
Wherein, described Titanium alkoxides is compound Ti (OR)
4, wherein, R is C1-C6 alkyl; As tetramethoxy titanium, purity titanium tetraethoxide, four positive propoxy titaniums, tetraisopropoxy titanium, four titanium n-butoxide and four isobutoxy titaniums, be particularly preferably tetraisopropoxy titanium.
Wherein, described titanium halide is titanium tetrachloride.
Preferably, described alkaline chelator is selected from one or more in ethylenediaminetetraacetic acid, phosphoric acid, pyrophosphoric acid, gluconic acid, citric acid, the sodium salt of metatitanic acid or potassium salt.
Preferably, described inorganic base substance is selected from one or more in sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate.
Preferably, under the oxidation-reduction potential room temperature (20 ± 10 DEG C) of described handwashing liquid below-100mV.
Preferably, described handwashing liquid is containing, for example each ion of lower concentration:
Containing titanium ion 0.036-0.285mM;
Sodium ion 34.80-65.25mM;
Potassium ion 1.79-2.81mM.
Further preferably, described handwashing liquid is containing, for example each ion of lower concentration:
Containing titanium ion 0.142mM;
Sodium ion 52.20mM;
Potassium ion 2.30mM.
Present invention also offers a kind of still preparation method of removing abnormal flavour handwashing liquid based on polyion water, comprise step: take titanium-containing compound according to containing titanium ion concentration, be dissolved in a certain amount of pure water, 5-60min is stirred at 20-50 DEG C, dropwise add the aqueous solution of a certain amount of alkaline chelator while stirring, titanium-containing compound wherein and the mol ratio of alkaline chelator are 1:1-1:10, then the aqueous solution of inorganic base substance is dropwise added while stirring, make the sodium ion in final products and/or potassium concentration reach predetermined value, obtained stillly remove abnormal flavour handwashing liquid.
As required, of the present invention based on polyion water go can also contain the additive such as one or more spice, pigment or dyestuff, antiseptic, antioxidant in abnormal flavour handwashing liquid, and well known to a person skilled in the art the additive that may be used in abnormal flavour handwashing liquid compositions.The consumption of these additives is generally no more than the 2wt% of abnormal flavour handwashing liquid gross weight.
The present invention can remove abnormal flavour rapidly, and effective removing remains in all kinds of oil stains, spot on the corners of the mouth, hand, clothes after meal, and can remove rapidly have meal after the hand seafood that may remain and river is fresh waits food abnormal flavour, while effectively antibacterial, natural environmental-protective; Not containing any organic solvent, simultaneously effectively antibacterial; Natural environmental-protective, not containing any surfactant, non-foam, easily rinses, and gentleness is not pungent, and does not hinder hands, without any zest, has the advantage of efficient, safety, environmental protection; Add glycerol and aloe moisture-keeping agent, soft comfortable, does not hinder skin.
Detailed description of the invention
Embodiment 1
Remove an abnormal flavour handwashing liquid based on the still of polyion water, wherein containing titanium ion concentration is 0.036mM, and Na ion concentration is 34.80mM, and potassium concentration is 1.79mM.
Preparation method is: take tetraethyl titanate according to containing titanium ion concentration, be dissolved in a certain amount of pure water, 40min is stirred at 40 DEG C, dropwise add sodium citrate solution while stirring, wherein the mol ratio of titanium-containing compound and sodium citrate is 1:8, dropwise adds sodium hydroxide and potassium hydroxide solution while stirring, makes the concentration of sodium ion and potassium ion in final products reach predetermined value, its oxidation-reduction potential is at normal temperatures below-100mV after measured, obtained stillly removes abnormal flavour handwashing liquid.
Embodiment 2
Remove an abnormal flavour handwashing liquid based on the still of polyion water, wherein containing titanium ion concentration is 0.071mM, and Na ion concentration is 43.50mM, and potassium concentration is 2.05mM.
Preparation method is: take titanium tetrachloride according to containing titanium ion concentration, be dissolved in a certain amount of pure water, 10min is stirred at 20 DEG C, dropwise add potassium pyrophosphate solution while stirring, wherein the mol ratio of titanium-containing compound and potassium pyrophosphate is 1:5, then dropwise adds sodium hydroxide and potassium hydroxide solution while stirring, makes the concentration of sodium ion and potassium ion in final products reach predetermined value, its oxidation-reduction potential is at normal temperatures below-100mV after measured, obtained stillly removes abnormal flavour handwashing liquid.
Embodiment 3
Remove an abnormal flavour handwashing liquid based on the still of polyion water, wherein containing titanium ion concentration is 0.142mM, and Na ion concentration is 52.20mM, and potassium concentration is 2.30mM.
Preparation method is: take butyl titanate according to containing titanium ion concentration, be dissolved in a certain amount of pure water, 50min is stirred at 45 DEG C, dropwise add ethylenediaminetetraacetic acid potassium solution while stirring, wherein the mol ratio of titanium-containing compound and ethylenediaminetetraacetic acid potassium is 1:7, then sodium bicarbonate and potassium bicarbonate solution is dropwise added while stirring, the concentration of sodium ion and potassium ion in final products is made to reach predetermined value, its oxidation-reduction potential is at normal temperatures below-100mV after measured, obtained stillly removes abnormal flavour handwashing liquid.
Embodiment 4
Remove an abnormal flavour handwashing liquid based on the still of polyion water, wherein containing titanium ion concentration is 0.214mM, and Na ion concentration is 56.55mM, and potassium concentration is 2.56mM.
Preparation method is: take tetraisopropoxy titanium according to containing titanium ion concentration, be dissolved in a certain amount of pure water, 60min is stirred at 35 DEG C, dropwise add sodium ethylene diamine tetracetate solution while stirring, wherein the mol ratio of titanium-containing compound and sodium ethylene diamine tetracetate is 1:10, then sodium carbonate and solution of potassium carbonate is dropwise added while stirring, the concentration of sodium ion and potassium ion in final products is made to reach predetermined value, its oxidation-reduction potential is at normal temperatures below-100mV after measured, obtained stillly removes abnormal flavour handwashing liquid.
Embodiment 5
Remove an abnormal flavour handwashing liquid based on the still of polyion water, wherein containing titanium ion concentration is 0.285mM, and Na ion concentration is 65.25mM, and potassium concentration is 2.81mM.
Preparation method is: take tetramethoxy titanium according to containing titanium ion concentration, be dissolved in a certain amount of pure water, 15min is stirred at 25 DEG C, dropwise add sodium gluconate solution while stirring, wherein the mol ratio of titanium-containing compound and gluconic acid sodium salt is 1:9, then sodium hydroxide and potassium hydroxide solution is dropwise added while stirring, the concentration of sodium ion and potassium ion in final products is made to reach predetermined value, its oxidation-reduction potential is at normal temperatures below-100mV after measured, obtained stillly removes abnormal flavour handwashing liquid.
Comparative example
The handwashing liquid that market is sold
Use the both hands of the handled seafood of cleaning composition in the handwashing liquid in each embodiment and comparative example, result of use is more as shown in table 1:
The result of use of the various handwashing liquid of table 1 compares
| Project | Result of use |
| Embodiment 1 | Abnormal flavour is eliminated substantially |
| Embodiment 2 | Abnormal flavour is all eliminated |
| Embodiment 3 | Abnormal flavour is all eliminated |
| Embodiment 4 | Abnormal flavour is all eliminated |
| Embodiment 5 | Abnormal flavour is all eliminated |
| Comparative example | Leave obvious abnormal flavour |
More than describe preferred embodiment of the present invention in detail.Should be appreciated that those of ordinary skill in the art just design according to the present invention can make many modifications and variations without the need to creative work.Therefore, all technical staff in the art, all should by the determined protection domain of claims under this invention's idea on the basis of existing technology by the available technical scheme of logical analysis, reasoning, or a limited experiment.
Claims (10)
1. remove an abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that: described handwashing liquid comprises following component: titanium-containing compound, alkaline chelator, inorganic base substance and pure water, the oxidation-reduction potential of described handwashing liquid is negative value.
2. a kind ofly as claimed in claim 1 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, described titanium-containing compound is selected from one or more in titanate esters, Titanium alkoxides, titanium halide.
3. a kind ofly as claimed in claim 1 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, described alkaline chelator is selected from one or more in ethylenediaminetetraacetic acid, phosphoric acid, pyrophosphoric acid, gluconic acid, citric acid, the sodium salt of metatitanic acid or potassium salt.
4. a kind ofly as claimed in claim 1 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, described inorganic base substance is selected from one or more in sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate.
5. a kind ofly as claimed in claim 1 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, under the oxidation-reduction potential room temperature of described handwashing liquid below-100mV.
6. a kind ofly as claimed in claim 1 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, described handwashing liquid is containing, for example each ion of lower concentration:
Containing titanium ion 0.036-0.285mM;
Sodium ion 34.80-65.25mM;
Potassium ion 1.79-2.81mM.
7. a kind ofly as claimed in claim 1 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, described handwashing liquid is containing, for example each ion of lower concentration:
Containing titanium ion 0.14mM;
Sodium ion 52.20mM;
Potassium ion 2.30mM.
8. a kind ofly as claimed in claim 1 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, described handwashing liquid also comprises one or more additives in spice, pigment or dyestuff, antiseptic, antioxidant.
9. a kind ofly as claimed in claim 8 remove abnormal flavour handwashing liquid based on the still of polyion water, it is characterized in that, the addition of described additive is the 0-2% of handwashing liquid gross weight.
10. the still preparation method of removing abnormal flavour handwashing liquid based on polyion water, comprise step: take titanium-containing compound according to containing titanium ion concentration, be dissolved in a certain amount of pure water, 5-60min is stirred at 20-50 DEG C, dropwise add the aqueous solution of a certain amount of alkaline chelator while stirring, titanium-containing compound wherein and the mol ratio of alkaline chelator are 1:1-1:10, then the aqueous solution of inorganic base substance is dropwise added while stirring, make the sodium ion in final products and/or potassium concentration reach predetermined value, obtained stillly remove abnormal flavour handwashing liquid.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108130228A (en) * | 2018-02-09 | 2018-06-08 | 上海心动能科技有限公司 | A kind of clothing decontamination wet tissue based on polyion water and preparation method thereof |
| CN108309820A (en) * | 2018-04-04 | 2018-07-24 | 上海心动能科技有限公司 | A kind of secret conditioning liquid and method based on polyion water |
| CN109750500A (en) * | 2019-02-18 | 2019-05-14 | 上海心动能科技有限公司 | A kind of sound-proof material deodorant and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108130228A (en) * | 2018-02-09 | 2018-06-08 | 上海心动能科技有限公司 | A kind of clothing decontamination wet tissue based on polyion water and preparation method thereof |
| CN108309820A (en) * | 2018-04-04 | 2018-07-24 | 上海心动能科技有限公司 | A kind of secret conditioning liquid and method based on polyion water |
| CN109750500A (en) * | 2019-02-18 | 2019-05-14 | 上海心动能科技有限公司 | A kind of sound-proof material deodorant and preparation method thereof |
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| CN105534731B (en) | 2018-06-19 |
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