CN104592017B - 制备2-异亚丙基-5-甲基-4-己烯基丁酸酯的方法 - Google Patents

制备2-异亚丙基-5-甲基-4-己烯基丁酸酯的方法 Download PDF

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Publication number
CN104592017B
CN104592017B CN201410601659.2A CN201410601659A CN104592017B CN 104592017 B CN104592017 B CN 104592017B CN 201410601659 A CN201410601659 A CN 201410601659A CN 104592017 B CN104592017 B CN 104592017B
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Prior art keywords
methyl
isopropylidene
acid
reaction
alcohol
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Chinese (zh)
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CN104592017A (zh
Inventor
金生刚
石桥尚树
山下美与志
三宅裕树
马场启弘
长江祐辅
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Shin-Etsu Chemical Co Ltd
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Shin-Etsu Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Plant Pathology (AREA)
  • Insects & Arthropods (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201410601659.2A 2013-10-30 2014-10-30 制备2-异亚丙基-5-甲基-4-己烯基丁酸酯的方法 Active CN104592017B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013-225424 2013-10-30
JP2013225424 2013-10-30

Publications (2)

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CN104592017A CN104592017A (zh) 2015-05-06
CN104592017B true CN104592017B (zh) 2019-02-22

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US (1) US9126920B2 (enExample)
EP (1) EP2868651B1 (enExample)
JP (1) JP6254925B2 (enExample)
CN (1) CN104592017B (enExample)
IN (1) IN2014DE03067A (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7210501B2 (ja) * 2020-04-21 2023-01-23 信越化学工業株式会社 ２－イソプロペニル－５－メチル－４－ヘキセン酸、２－イソプロペニル－５－メチル－４－ヘキセン－１－オール及びそのカルボン酸エステルの製造方法
JP7216043B2 (ja) 2020-04-21 2023-01-31 信越化学工業株式会社 ６－イソプロペニル－３－メチル－９－デセニル＝アセテートの製造方法及びその中間体
CN115215725A (zh) * 2021-04-15 2022-10-21 宋晓瑜 一种制备乙酸薰衣草酯及薰衣草醇的方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3781333A (en) * 1968-12-23 1973-12-25 Givaudan Corp Beta,beta-dimethyl acrylates
JPS5867635A (ja) * 1981-10-16 1983-04-22 Sumitomo Chem Co Ltd 置換ジエンアルコールの製造法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
A convenient route for synthesis of 2-isopropyliden-5-methyl-4-hexen-1-yl butyrate, the sex pheromone of Planococcus kraunhiae (Hemiptera: Pseudococcidae), by use of β,γ to α,β double-bond migration in an unsaturated aldehyde;Jun Tabata;《Applied Entomology and Zoology》;20130317;第48卷(第2期);第229-232页
A New Synthetic Method of Lavandulols;Masanao MATSUI et al.;《Agr. Biol. Chem.》;19621231;第26卷(第10期);第705-708页
New Attempt at the Synthesis of Lavandulol by a Claisen Type Rearrangement;Masanao MATSUI et al.;《Agr. Biol. Chem.》;19681231;第32卷(第10期);第1246-1249页

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Publication number Publication date
JP6254925B2 (ja) 2017-12-27
IN2014DE03067A (enExample) 2015-09-25
EP2868651B1 (en) 2017-08-09
CN104592017A (zh) 2015-05-06
US20150119597A1 (en) 2015-04-30
US9126920B2 (en) 2015-09-08
JP2015110553A (ja) 2015-06-18
EP2868651A1 (en) 2015-05-06

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