CN104587954A - 一种活性吸附剂的制备方法及其制备的活性吸附剂的应用 - Google Patents
一种活性吸附剂的制备方法及其制备的活性吸附剂的应用 Download PDFInfo
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- CN104587954A CN104587954A CN201410823198.3A CN201410823198A CN104587954A CN 104587954 A CN104587954 A CN 104587954A CN 201410823198 A CN201410823198 A CN 201410823198A CN 104587954 A CN104587954 A CN 104587954A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000003463 adsorbent Substances 0.000 title abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002351 wastewater Substances 0.000 claims abstract description 20
- 238000009713 electroplating Methods 0.000 claims abstract description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000004913 activation Effects 0.000 claims abstract description 11
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- 239000011651 chromium Substances 0.000 claims abstract description 11
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 239000010949 copper Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 239000010881 fly ash Substances 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 18
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 9
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 4
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 11
- 238000001179 sorption measurement Methods 0.000 abstract description 11
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005067 remediation Methods 0.000 abstract description 3
- 239000002689 soil Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 238000005342 ion exchange Methods 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 239000010883 coal ash Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 238000001354 calcination Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Geology (AREA)
- Water Supply & Treatment (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN201410823198.3A CN104587954B (zh) | 2014-12-25 | 2014-12-25 | 一种活性吸附剂的制备方法及其制备的活性吸附剂的应用 |
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CN201410823198.3A CN104587954B (zh) | 2014-12-25 | 2014-12-25 | 一种活性吸附剂的制备方法及其制备的活性吸附剂的应用 |
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CN104587954A true CN104587954A (zh) | 2015-05-06 |
CN104587954B CN104587954B (zh) | 2018-05-04 |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104874370A (zh) * | 2015-05-11 | 2015-09-02 | 安徽省中日农业环保科技有限公司 | 一种桃核重金属吸附颗粒剂及其制备方法 |
CN104888731A (zh) * | 2015-05-21 | 2015-09-09 | 安徽凤凰滤清器股份有限公司 | 一种吸附性能好的复合吸附剂 |
CN105126746A (zh) * | 2015-07-31 | 2015-12-09 | 北京东泰富博新材料科技股份有限公司 | 基于硅藻土的多功能材料及其制备方法和应用 |
CN106495303A (zh) * | 2016-09-08 | 2017-03-15 | 北京神雾环境能源科技集团股份有限公司 | 一种利用电石炉气粉尘制备水体油污去除剂的方法 |
CN106732455A (zh) * | 2016-12-14 | 2017-05-31 | 严帝 | 一种陶瓷纤维改性的凹凸棒土吸附剂及其制备方法 |
CN106747257A (zh) * | 2016-12-05 | 2017-05-31 | 郑州诚合信息技术有限公司 | 一种吸附尾气的道路涂层及其制备方法和应用 |
CN107159091A (zh) * | 2017-07-27 | 2017-09-15 | 同济大学 | 一种含钙硅的高性能重金属吸附材料及其制备方法 |
WO2017162013A1 (zh) * | 2016-03-25 | 2017-09-28 | 大连理工大学 | 一种离子阻控吸附剂制备与应用方法 |
CN107487812A (zh) * | 2017-09-02 | 2017-12-19 | 长沙埃比林环保科技有限公司 | 一种含镍电镀废水交换膜处理方法 |
CN109679683A (zh) * | 2017-10-18 | 2019-04-26 | 中国石油化工股份有限公司 | 一种脱硫吸附剂活性测量方法 |
CN109967030A (zh) * | 2017-12-27 | 2019-07-05 | 上海绅涪生物科技有限公司 | 一种氨氮吸附材料及其制备方法 |
CN111760328A (zh) * | 2020-07-08 | 2020-10-13 | 山东西奥生物科技有限公司 | 一种老旧变压器油性能恢复工艺与复合吸附柱及其装填和再生方法 |
CN112266098A (zh) * | 2020-10-12 | 2021-01-26 | 东华理工大学 | 一种利用助剂提升吸咐剂吸附性能的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103880113A (zh) * | 2014-04-14 | 2014-06-25 | 北京矿冶研究总院 | 利用改性粉煤灰循环处理重金属离子废水的方法 |
-
2014
- 2014-12-25 CN CN201410823198.3A patent/CN104587954B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103880113A (zh) * | 2014-04-14 | 2014-06-25 | 北京矿冶研究总院 | 利用改性粉煤灰循环处理重金属离子废水的方法 |
Non-Patent Citations (3)
Title |
---|
王悦等: "硅藻土磁性吸附剂对酚类废水处理方法研究", 《2014中国环境科学学会学术年会论文集》 * |
郭海康: "微珠粉煤灰改性及其吸附/催化性能研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
高耀文等: "硅藻土复合除磷材料的吸附动力学及热力学研究", 《工业安全与环保》 * |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104874370A (zh) * | 2015-05-11 | 2015-09-02 | 安徽省中日农业环保科技有限公司 | 一种桃核重金属吸附颗粒剂及其制备方法 |
CN104888731A (zh) * | 2015-05-21 | 2015-09-09 | 安徽凤凰滤清器股份有限公司 | 一种吸附性能好的复合吸附剂 |
CN105126746A (zh) * | 2015-07-31 | 2015-12-09 | 北京东泰富博新材料科技股份有限公司 | 基于硅藻土的多功能材料及其制备方法和应用 |
CN105126746B (zh) * | 2015-07-31 | 2016-03-23 | 北京东泰富博新材料科技股份有限公司 | 基于硅藻土的多功能材料及其制备方法和应用 |
WO2017162013A1 (zh) * | 2016-03-25 | 2017-09-28 | 大连理工大学 | 一种离子阻控吸附剂制备与应用方法 |
CN106495303A (zh) * | 2016-09-08 | 2017-03-15 | 北京神雾环境能源科技集团股份有限公司 | 一种利用电石炉气粉尘制备水体油污去除剂的方法 |
CN106747257A (zh) * | 2016-12-05 | 2017-05-31 | 郑州诚合信息技术有限公司 | 一种吸附尾气的道路涂层及其制备方法和应用 |
CN106732455A (zh) * | 2016-12-14 | 2017-05-31 | 严帝 | 一种陶瓷纤维改性的凹凸棒土吸附剂及其制备方法 |
CN107159091A (zh) * | 2017-07-27 | 2017-09-15 | 同济大学 | 一种含钙硅的高性能重金属吸附材料及其制备方法 |
CN107487812A (zh) * | 2017-09-02 | 2017-12-19 | 长沙埃比林环保科技有限公司 | 一种含镍电镀废水交换膜处理方法 |
CN109679683A (zh) * | 2017-10-18 | 2019-04-26 | 中国石油化工股份有限公司 | 一种脱硫吸附剂活性测量方法 |
CN109679683B (zh) * | 2017-10-18 | 2021-02-09 | 中国石油化工股份有限公司 | 一种脱硫吸附剂活性测量方法 |
CN109967030A (zh) * | 2017-12-27 | 2019-07-05 | 上海绅涪生物科技有限公司 | 一种氨氮吸附材料及其制备方法 |
CN111760328A (zh) * | 2020-07-08 | 2020-10-13 | 山东西奥生物科技有限公司 | 一种老旧变压器油性能恢复工艺与复合吸附柱及其装填和再生方法 |
CN112266098A (zh) * | 2020-10-12 | 2021-01-26 | 东华理工大学 | 一种利用助剂提升吸咐剂吸附性能的方法 |
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