CN104559472B - Water-based evaporation drying type gravure ink composition applicable to multiple base materials - Google Patents

Water-based evaporation drying type gravure ink composition applicable to multiple base materials Download PDF

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Publication number
CN104559472B
CN104559472B CN201510033899.1A CN201510033899A CN104559472B CN 104559472 B CN104559472 B CN 104559472B CN 201510033899 A CN201510033899 A CN 201510033899A CN 104559472 B CN104559472 B CN 104559472B
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multiple base
water
applicable
aqueous
ink composition
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CN104559472A (en
Inventor
李伟
袁国林
张世范
黄维维
陈夏萌
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China Banknote Ink Co ltd
China Banknote Printing and Minting Group Co Ltd
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ZHONGCHAO INK CO Ltd
China Banknote Printing and Minting Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a water-based evaporation drying type gravure ink composition applicable to multiple base materials. The water-based evaporation drying type gravure ink composition applicable to multiple base materials comprises the following components in percentage by weight: 20-60% of an ink linking material, 1-30% of a flaky functional material, 0-30% of an alcohol solvent, 0-10% of auxiliaries, 0-0% of a curing agent and the balance of water. The water-based evaporation drying type gravure ink composition applicable to multiple base materials contains no phenyl ketone and no ester solvent, has the characteristics of safety, no toxicity, no harm, noninflammability, non-explosiveness, nearly zero VOC and the like and is beneficial to human health and environmental safety, and defects of water-based ink composition in onboard stability and ink drying property are overcome; and by selecting resin of a specific structure, the problems of the water-based ink composition in the aspects of binding strength on a base material and printing product materialization tolerance are solved, and the ink composition can be applicable to multiple base materials such as paper and plastic.

Description

It is applicable to the aqueous volatile dry type base gravure ink compositions of multiple base material
Technical field
The present invention relates to a kind of aqueous volatile dry type base gravure ink compositions.
Background technology
In recent years, printing technology development, the kind of photogravure ink was still in increase, quality Still in the stage risen.Along with constantly perfecting of Environmental Protection in China laws and rules, volatile solvent A large amount of use is also subject to the strictest control, and State Environmental Protection Administration of China in 2007 formulates to be sent out Cloth " environmental labelling product technology requires gravure ink and flexo ink ", to all kinds of in base gravure ink The content of solvent, content of beary metal, in printing, solvent residual amount etc. make explicit provisions, and this indicates China's ink industry enter one based on brand-new epoch of environmental protection construction, this also makes to have excellent The environment-friendlyink ink of opposite sex energy becomes the inexorable trend of photogravure ink development from now on.
Solvent-based intaglio ink is manufacturing, is printing and in dry run, due to benzophenone class or esters solvent A large amount of volatilizations, not only to environment, also can endanger the healthy of operator；Ultraviolet Photocuring silk-screen ink energy consumption is higher, and is in the printing environment of strong ultraviolet radiation for a long time, to behaviour Make personnel and also have certain injury.
Summary of the invention
It is an object of the invention to provide a kind of aqueous volatile dry type base gravure ink being applicable to multiple base material Compositions and preparation method thereof, with the defect overcoming prior art to exist.
The described high adhesion force aqueous volatile dry base gravure ink compositions being applicable to multiple base material, bag Include the component of following percentage by weight:
Preferably, described for water-base gravure photochromatic printing ink, including the component of following percentage by weight:
Described ink vehicle is the water-base resin of aqueous volatile dry, selected from water-borne acrylic resin In emulsion, modified acrylic resin emulsion, ester-polyurethane resin emulsion or modified polyurethane resin emulsion One or more；
Preferably, described ink vehicle is the mixture of aqueous acrylic emulsion and polyaminoester emulsion, Weight ratio is:
Aqueous acrylic emulsion: polyaminoester emulsion=1.75～5: 1；Described aqueous acrylic emulsion is hydroxyl The water-borne acrylic resin emulsion of the polyhydric alcohol/hydroxyl functional of content 5.0-9.5% or its modified resin, weight Amount solid content is 30～55%, and pH value is 7.0～8.5, and optional BASF AG trade mark is FLX 617-A、FLX 5040、The product of FLX 5002, Opel enlightening company The trade mark isAC2597、AC2598、 The product of AC2713VP, the DSM company trade mark is NeoCryl TM A1125, NeoCryl TM The product of A1127, Beyer Co., Ltd's trade mark is Bayhydrol A 2601, Bayhydrol A 145, The product of BayhydrolA2058.
Described polyaminoester emulsion is polyester-polyol type polyurethane emulsion or its modified resin, and weight contains admittedly Amount is 30～55%, and pH value is 7.0～8.0, and the optional Opel enlightening company trade mark is U3251,941VP、The product of 901VP, Bayer is public Department's trade mark is Bayhydrol U 355, Bayhydrol U 241, Bayhydrol U 475, Bayhydrol U 2755, the product of Bayhydrol U 2757.
Described lamellar functional material be the one in pearlescent pigment, optic metachromatic material or liquid crystal material or Several combinations, pearlescent pigment may select BASF AG's trade mark be Magnapearl, Mearlin, Lumina, Dynacolor Yu Santa Fe series pearlescent pigment product, Merck & Co., Inc.'s trade mark be Iriodin, The pearlescent pigment that Xirallic, Colorstream, Lustrepak II, Securalic are serial with Colorcrypt Product, optically variable pigments may select good fortune Simon Rex, Huayang optics, the light of Chengdu Jing Hedeng company sell of one's property product, Liquid crystal material may select Yangzhou divine boat, Chengdu crystalline substance closes and the material of good fortune Simon Rex company.
Described alcohols solvent, optional ethanol, isopropanol, n-butyl alcohol or isooctanol, preferably ethanol Or isopropanol.
Described defoamer, optional organosilicon/fluorine class surfactant, high molecular polymerization species, mineral One or more in oils or plant oil, the optional BASF AG trade mark be Dehydran SE2, Dehydran 2293, Foamaster 111, the product of Foamaster 8034, the Sheng Nuopuke company trade mark For SN-DEFOAMER 1311, SN-DEFOAMER 318, SN-DEFOAMER 2000 Product, the Ying Chuan company trade mark is Foamex 800, the product of Foamex 830；
Described thickening agent, optional association type, alkali swelling type acrylic copolymer, polyurethanes, fibre Dimension element class, the optional Hai Mingsi company trade mark is the product of DeuRheo WT-201, BASF AG's board Number be Rheovis HS 1212, Rheovis HS 1152, DSX 3100, the product of DSX 3256, The Sheng Nuopuke company trade mark is the product such as SN-THICKENER 623N, SN-THICKENER 615.
Described dispersant, optional polycarboxylic acid, acrylic block copolymers, polycarboxylic acids ammonium salt class, Company of the optional China trade mark is HX 5300, HX 5310, HX 5820, and BASF AG's trade mark is The product of EFKA-7701, EFKA-6230, Hydropalat 1080, the Di Gao company trade mark is TEGO Dispers 715W、Dispers 735W、Dispers 740W、Dispers 745W、Dispers 752W、 The product of LM Colorol E, Lubrizol Corp.'s trade mark be SOLSPERSE 12000, SOLSPERSE20000、SOLSPERSE27000、SOLSPERSE43000、 The product of SOLSPERSE47000.
Described levelling agent, optional organic modified polyorganosiloxane class, polyacrylate, optional BYK (Bi Ke) company's trade mark be BYK 332, the product of BYK333, BYK345, BYK 346, Company of China trade mark is HX 5600, the product of HX 5630, and the Di Gao company trade mark is TEGO Glide 100, Glide 410, Glide 440, the product of Glide 450, BASF AG's trade mark be EFKA-3030, The product of EFKA-3034, EFKA-3570.
Described firming agent, optional aqueous aliphatic polymeric isocyanate, alicyclic polyamine, aromatic series are many Amine, phenolic aldehyde, anhydrides, the optional Beyer Co., Ltd trade mark is Bayhydur 304, Bayhydur 305, The product of BayhydurXP 2487, BASF AG's trade mark is Basonat HW 100, Basonat HA The product of 300, Basonat HW 180PC.
The system of the aqueous volatile dry type base gravure ink compositions being applicable to multiple base material of the present invention Preparation Method, comprises the steps:
Each component in addition to firming agent is mixed dispersion, adds firming agent before printing, stirring Dispersion, can obtain the described aqueous volatile dry type base gravure ink compositions being applicable to multiple base material.
The invention have the advantages that without benzophenone class, the ink composite of esters solvent, have safely, Nontoxic, do not fire the most quick-fried, close to distinguishing features such as Diamond Search, beneficially health and environment peace Entirely, aqueous ink composition is solved in machine stability and the deficiency of ink setting aspect of performance；Logical Cross and special construction resin selected, solve aqueous ink composition binding strength on base material and Problem in terms of printing materialization patience, it is multiple with plastics etc. that this ink composite can be simultaneously suitable for paper Base material.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further discussed below:
Embodiment 1
Formula see table, and amounts of components is all weight percentage.
Preparation method: first by acrylic emulsion and polyaminoester emulsion, thickening agent and defoamer stirring point Dissipate and make pre-emulsion, add pearlescent pigment, dispersant, levelling agent, solvent, water, dispersed with stirring, Add firming agent Bayhydur 304, dispersed with stirring before using, can use.
The water-soluble pearlescent base gravure ink prepared, viscosity is 21s (25 DEG C, 2# Chai Shi cup).
Using this ink with art post paperboard as base material, ten color intaglio printing press are the most of the same colour to be printed, printing speed Degree is 60m/min, and ink machine stability is good, and ink setting is fast, and printing figure stricture of vagina is clear, and printing is adopted Carrying out layer of ink fastness detection by GB GBT7707-2008 " intaglio plate decoration leaflet ", result is as follows:
Binding strength: layer of ink comes off area less than 1.0%；
Materialization resistance test and evaluation use International Police Organization to recommend method, and result is as follows:
Grading: 5=is not any change；
4=minor variations；
3=large change, destroys less than 50%；
2=great changes, destroy more than 50%；
1=feature disappears.
Rt-room temperature (20-25 DEG C)；Min-minute.
Embodiment 2
Formula see table, and amounts of components is all weight percentage.
Preparation method: first by acrylic emulsion and polyaminoester emulsion, thickening agent and defoamer stirring point Dissipate and make pre-emulsion, add pearlescent pigment, dispersant, levelling agent, solvent, water, dispersed with stirring, Add firming agent Basonat HW 180PC, dispersed with stirring before using, can use.
The water-soluble pearlescent base gravure ink prepared, viscosity is 22s (25 DEG C, 2# Chai Shi cup).
Using this ink with PET as base material, monochromatic intaglio printing press prints, and print speed printing speed is 60m/min, Ink machine stability is good, and ink setting is fast, and printing figure stricture of vagina is clear, and printing uses GB GBT7707-2008 " intaglio plate decoration leaflet " carries out layer of ink fastness detection, and result is as follows:
Binding strength: layer of ink comes off area less than 1.0%.
Materialization resistance test and evaluation use International Police Organization to recommend method, and result is as follows:
Grading: 5=is not any change；
4=minor variations；
3=large change, destroys less than 50%；
2=great changes, destroy more than 50%；
1=feature disappears.
Rt-room temperature (20-25 DEG C)；Min-minute.

Claims (5)

1. it is applicable to the aqueous volatile dry type base gravure ink compositions of multiple base material, it is characterised in that Component including following percentage by weight:
Described ink vehicle is the mixture of aqueous acrylic emulsion and polyaminoester emulsion, weight ratio For: aqueous acrylic emulsion: polyaminoester emulsion=1.75～5: 1；
Described aqueous acrylic emulsion is the aqueous third of the polyhydric alcohol/hydroxyl functional of hydroxy radical content 5.0-9.5% Olefin(e) acid resin emulsion or its modified resin, weight solid content is 30～55%, and pH value is 7.0～8.5；
Described polyaminoester emulsion is polyester-polyol type polyurethane emulsion or its modified resin, and weight contains admittedly Amount is 30～55%, and pH value is 7.0～8.0.
The aqueous volatile dry type base gravure ink being applicable to multiple base material the most according to claim 1 Compositions, it is characterised in that described lamellar functional material is pearlescent pigment, optic metachromatic material or liquid One or more combination in brilliant material.
The aqueous volatile dry type intaglio plate being applicable to multiple base material the most according to claim 1 and 2 Ink composite, it is characterised in that described alcohols solvent, for ethanol, isopropanol, n-butyl alcohol or different Capryl alcohol.
The aqueous volatile dry type intaglio plate being applicable to multiple base material the most according to claim 1 and 2 Ink composite, it is characterised in that described defoamer, for organosilicon/fluorine class surfactant, high score One or more in son polymerization species, mineral oils or plant oil；
Described thickening agent, optional association type, alkali swelling type acrylic copolymer, polyurethanes, fibre Dimension element class；
Described dispersant, for polycarboxylic acid, acrylic block copolymers or polycarboxylic acids ammonium salt class；
Described levelling agent is organic modified polyorganosiloxane class, polyacrylate.
The aqueous volatile dry type intaglio plate being applicable to multiple base material the most according to claim 1 and 2 Ink composite, it is characterised in that described firming agent, for aqueous aliphatic polymeric isocyanate, alicyclic ring Race's polyamines, aromatic polyamine, phenolic aldehyde or anhydrides.
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CN105131709A (en) * 2015-08-31 2015-12-09 厦门欧化实业有限公司 Water-soluble gravure ink and preparation method thereof
CN106590162B (en) * 2016-11-07 2020-08-21 成都普瑞斯特新材料有限公司 Water-based gravure plastic film surface printing ink and preparation method thereof
CN106700723A (en) * 2016-11-18 2017-05-24 惠州市至上新材料有限公司 Gravure environment-friendly water-based gold-sand printing ink as well as preparation method and application of gravure environment-friendly water-based gold-sand printing ink
CN106916487A (en) * 2017-03-18 2017-07-04 珠海经济特区诚成印务有限公司 A kind of package typography with pearly-lustre texture and its printing-ink for calling
CN107841194B (en) * 2017-11-02 2020-12-25 苏州太平洋印务有限公司 Black aromatic ink for toilet paper printing
CN108948866A (en) * 2018-08-07 2018-12-07 长春吉星印务有限责任公司 One kind becoming special printing inks and preparation method thereof for the aqueous light of intaglio plate green
CN109486275A (en) * 2018-11-06 2019-03-19 长沙浩然医疗科技有限公司 A kind of water-based ink and preparation method thereof for film printing
CN109517437A (en) * 2018-12-20 2019-03-26 江苏劲嘉新型包装材料有限公司 Water-base gravure ink and preparation method thereof
CN109796808B (en) * 2019-03-04 2022-01-28 上海秉印玻璃科技有限公司 Water-based ink and preparation method thereof
CN110452572B (en) * 2019-08-27 2022-02-22 昆山大世界油墨涂料有限公司 Water-based pearlescent medium for water-based decorative paper printing ink and preparation method thereof
CN110951322A (en) * 2019-12-13 2020-04-03 深圳劲嘉集团股份有限公司 Gravure water-based optically variable flocking ink and preparation method and printing method thereof

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CN103923524A (en) * 2013-01-15 2014-07-16 永发印务(东莞)有限公司 Aqueous pearlescent printing ink for web gravure printing

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Address after: 288 Xiuyan Road, Pudong New Area, Shanghai, 201315

Patentee after: CHINA BANKNOTE INK Co.,Ltd.

Patentee after: China Banknote Printing and Minting Group Co.,Ltd.

Address before: 288 Xiuyan Road, Pudong New Area, Shanghai, 201315

Patentee before: CHINA BANKNOTE INK Co.,Ltd.

Patentee before: CHINA BANKNOTE PRINTING AND MINTING Corp.

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