CN104558492A - 一种低气味高阻燃的车用聚氨酯内饰泡沫及其制备方法 - Google Patents
一种低气味高阻燃的车用聚氨酯内饰泡沫及其制备方法 Download PDFInfo
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- CN104558492A CN104558492A CN201410855589.3A CN201410855589A CN104558492A CN 104558492 A CN104558492 A CN 104558492A CN 201410855589 A CN201410855589 A CN 201410855589A CN 104558492 A CN104558492 A CN 104558492A
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- 239000006260 foam Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920002635 polyurethane Polymers 0.000 title abstract description 7
- 239000004814 polyurethane Substances 0.000 title abstract description 7
- 239000003063 flame retardant Substances 0.000 claims abstract description 29
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 9
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 239000006071 cream Substances 0.000 claims description 3
- 210000002615 epidermis Anatomy 0.000 claims description 3
- 238000005562 fading Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229920002545 silicone oil Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 3
- 230000036541 health Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- -1 as TEP Chemical compound 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- IWYDHOAUDWTVEP-UHFFFAOYSA-N mandelic acid Chemical compound OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 description 1
- 229960002510 mandelic acid Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/145—Halogen containing compounds containing carbon, halogen and hydrogen only only chlorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
原25密度性能测试 | 结构阻燃型海绵性能测试 | |
密度 | 22.6 | 23.3 |
表面硬度 | 38 | 39 |
压陷硬度25% | 74 | 74 |
拉伸强度KPa | 80 | 84 |
断裂伸长率% | 101 | 102 |
阻燃性(mm/min) | 84 | 55 |
透气率 | 1680 | 1590 |
气味测试 | 4.0+ | 3.5 |
Claims (8)
Priority Applications (1)
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CN201410855589.3A CN104558492B (zh) | 2014-12-31 | 2014-12-31 | 一种低气味高阻燃的车用聚氨酯内饰泡沫及其制备方法 |
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CN201410855589.3A CN104558492B (zh) | 2014-12-31 | 2014-12-31 | 一种低气味高阻燃的车用聚氨酯内饰泡沫及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104558492A true CN104558492A (zh) | 2015-04-29 |
CN104558492B CN104558492B (zh) | 2017-06-16 |
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CN201410855589.3A Active CN104558492B (zh) | 2014-12-31 | 2014-12-31 | 一种低气味高阻燃的车用聚氨酯内饰泡沫及其制备方法 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106543405A (zh) * | 2016-10-31 | 2017-03-29 | 江苏昊晟塑业科技有限公司 | 阻燃型汽车内饰发泡材料 |
CN108017769A (zh) * | 2017-10-26 | 2018-05-11 | 浙江川洋新材料股份有限公司 | 一种阻燃型聚氨酯软泡及其制备方法 |
CN108610463A (zh) * | 2018-05-06 | 2018-10-02 | 张家港长泰汽车饰件材料有限公司 | 低voc耐水解性聚氨酯泡沫及其制备方法 |
CN109851845A (zh) * | 2019-01-19 | 2019-06-07 | 恩龙实业(嘉兴)有限公司 | 一种泡棉及其制备方法 |
CN110431165A (zh) * | 2017-03-28 | 2019-11-08 | 科思创德国股份有限公司 | 半透明聚氨酯泡沫材料 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101250320A (zh) * | 2008-04-06 | 2008-08-27 | 陈春潮 | 一种阻燃绵 |
CN102167791A (zh) * | 2011-02-25 | 2011-08-31 | 北京万博汇佳科贸有限公司 | 一种用于软质聚氨酯泡沫的反应型阻燃剂及应用 |
CN103865025A (zh) * | 2014-03-14 | 2014-06-18 | 厦门大学 | 一种本质阻燃硬质聚氨酯泡沫塑料 |
-
2014
- 2014-12-31 CN CN201410855589.3A patent/CN104558492B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101250320A (zh) * | 2008-04-06 | 2008-08-27 | 陈春潮 | 一种阻燃绵 |
CN102167791A (zh) * | 2011-02-25 | 2011-08-31 | 北京万博汇佳科贸有限公司 | 一种用于软质聚氨酯泡沫的反应型阻燃剂及应用 |
CN103865025A (zh) * | 2014-03-14 | 2014-06-18 | 厦门大学 | 一种本质阻燃硬质聚氨酯泡沫塑料 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106543405A (zh) * | 2016-10-31 | 2017-03-29 | 江苏昊晟塑业科技有限公司 | 阻燃型汽车内饰发泡材料 |
CN110431165A (zh) * | 2017-03-28 | 2019-11-08 | 科思创德国股份有限公司 | 半透明聚氨酯泡沫材料 |
CN108017769A (zh) * | 2017-10-26 | 2018-05-11 | 浙江川洋新材料股份有限公司 | 一种阻燃型聚氨酯软泡及其制备方法 |
CN108610463A (zh) * | 2018-05-06 | 2018-10-02 | 张家港长泰汽车饰件材料有限公司 | 低voc耐水解性聚氨酯泡沫及其制备方法 |
CN108610463B (zh) * | 2018-05-06 | 2020-11-03 | 张家港长泰汽车饰件材料有限公司 | 低voc耐水解性聚氨酯泡沫及其制备方法 |
CN109851845A (zh) * | 2019-01-19 | 2019-06-07 | 恩龙实业(嘉兴)有限公司 | 一种泡棉及其制备方法 |
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Publication number | Publication date |
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CN104558492B (zh) | 2017-06-16 |
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Denomination of invention: Low air smell and high flame retardant polyurethane interior foam for vehicle and preparation method thereof Effective date of registration: 20211202 Granted publication date: 20170616 Pledgee: Industrial Bank Co.,Ltd. Shanghai Jiading sub branch Pledgor: SHANGHAI XINYUAN NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2021310000115 |
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Date of cancellation: 20231120 Granted publication date: 20170616 Pledgee: Industrial Bank Co.,Ltd. Shanghai Jiading sub branch Pledgor: SHANGHAI XINYUAN NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2021310000115 |
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Denomination of invention: A low odor and high flame retardant polyurethane interior foam for vehicles and its preparation method Effective date of registration: 20231122 Granted publication date: 20170616 Pledgee: Industrial Bank Co.,Ltd. Shanghai Nanxiang sub branch Pledgor: SHANGHAI XINYUAN NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2023310000761 |
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Address after: No. 2200 Huiwang Road, Waigang Industrial Park, Jiading District, Shanghai, 200072 Patentee after: Shanghai Xinyuan New Materials Technology (Group) Co.,Ltd. Country or region after: China Address before: No. 2200 Huiwang Road, Waigang Industrial Park, Jiading District, Shanghai, 200072 Patentee before: SHANGHAI XINYUAN NEW MATERIAL TECHNOLOGY CO.,LTD. Country or region before: China |
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