CN107722221A - 一种氧化铝纤维‑poss改性聚氨酯复合发泡保温隔热建筑材料及其制备方法 - Google Patents

一种氧化铝纤维‑poss改性聚氨酯复合发泡保温隔热建筑材料及其制备方法 Download PDF

Info

Publication number
CN107722221A
CN107722221A CN201711053384.3A CN201711053384A CN107722221A CN 107722221 A CN107722221 A CN 107722221A CN 201711053384 A CN201711053384 A CN 201711053384A CN 107722221 A CN107722221 A CN 107722221A
Authority
CN
China
Prior art keywords
parts
alumina fibre
thermal insulation
preparation
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711053384.3A
Other languages
English (en)
Inventor
朱佳媚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Chenli New Material Co Ltd
Original Assignee
Hunan Chenli New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Chenli New Material Co Ltd filed Critical Hunan Chenli New Material Co Ltd
Priority to CN201711053384.3A priority Critical patent/CN107722221A/zh
Publication of CN107722221A publication Critical patent/CN107722221A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/61—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6511—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6523—Compounds of group C08G18/3225 or C08G18/3271 or polyamines of C08G18/38
    • C08G18/6529—Compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/142—Compounds containing oxygen but no halogen atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/08—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/004—Additives being defined by their length

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

本发明涉及一种氧化铝纤维‑POSS改性聚氨酯复合发泡保温隔热建筑材料及其制备方法，以重量份计组成如下，A组分：多异氰酸酯单体100～140份，增韧剂15～25份；B组分：发泡剂5～15份、聚醚多元醇40～80份、氨基取代的笼型聚倍半硅氧烷8～15份、催化剂0.2～0.5份、扩链剂6～12份、泡沫稳定剂4～8份、氧化铝纤维30～60份、阻燃剂1～3份。本发明具有以下优点：采用氨基取代的笼型聚倍半硅氧烷改性聚氨酯，增加了聚氨酯树脂的硬度与交联密度；采用导热率和加热收缩率都较低的氧化铝纤维作为增强填料，隔热性更好；氧化铝纤维具有高耐高温性，减少了阻燃剂的添加量，并同阻燃剂协同发挥阻燃效果。

Description

一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材 料及其制备方法
技术领域
本发明属于高分子材料合成领域，具体涉及一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料。
技术背景
聚氨酯是一种广泛应用的高分子材料，具有优异的物理机械性能及良好的耐水性。聚氨酯泡沫体是以树脂为基础，采用化学或物理方法在其内部产生无数小气孔而制成，孔孔相连的多孔聚氨酯海绵状泡沫材料体积密度小、比表面积大、吸附效率高，已经在催化剂载体、建筑、装饰、污水净化、血浆的过滤等方面得到了应用，但传统聚氨酯泡沫由于其内部反应温度高、强度低、阻燃差等问题，导致我国每年都会发生数起因房屋倒塌或自燃而造成的安全事故。
目前，生产聚氨酯发泡材料的方法主要是化学发泡法，即将各种原料如异氰酸酯、多元醇、催化剂、外发泡剂、交联剂等按一定比例混合均匀后注入模具中，在发生化学反应的同时进行发泡，发泡成型后从模具中取出即可得到一定形状和尺寸的发泡材料。这种方法的优点是可以大量、快速、方便地生产不同规格和形状的产品。
中国专利CN201310463539.6涉及一种无卤阻燃聚氨酯发泡塑料，按质量百分比计，它是由以下原料制备而成：水40-80％；1,4-环己烷二异氰酸酯10-20％；聚己二酸乙二醇酯二醇5-35％；扩链剂1,4-丁二醇2-5％；无卤阻燃剂1-5％；催化剂0.001-0.1％；泡沫稳定剂0.1-1％；抗氧剂0.2-0.8％。相对于现有技术，该发明采用水作为发泡剂，有效地避免了使用HCFC-141b等含氟发泡剂所带来的对环境造成的危害；通过加入无卤阻燃剂，提高了TPU发泡塑料的阻燃性能，并且由于使用的阻燃剂不含卤素，也不含铅、镉、汞和铬等重金属元素，符合欧盟VDE要求，是一种绿色环保的材料。但是该发明所述聚氨酯发泡塑料存在阻燃剂添加量大、强度低的缺点。
发明内容
为克服现有技术的缺点和不足，本发明的首要目的在于提供一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料。
本发明所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料，为采用导热率、加热收缩率都较低的氧化铝纤维作为增强材料、同时采用氨基取代的笼型聚倍半硅氧烷(含氨基POSS)增强改性聚氨酯，通过室温合成所述复合发泡材料。所述复合发泡材料主要成分由A组分和B组分按照质量比1：0.9～1：1.5经常温混合搅拌制备而得；以质量份计组成如下，A组分：多异氰酸酯单体100～140份，增韧剂15～25份；B组分：发泡剂5～15份、聚醚多元醇40～80份、氨基取代的笼型聚倍半硅氧烷8～15份、催化剂0.2～0.5份、扩链剂6～12份、泡沫稳定剂4～8份、氧化铝纤维30～60份、阻燃剂1～3份。
所述氧化铝纤维的主晶结构呈γ-氧化铝、δ-氧化铝、θ-氧化铝、α-氧化铝中的至少一种，其单丝长度为10～150mm。
所述的氨基取代的笼型聚倍半硅氧烷为八氨基苯基POSS、八-3-氨基丙基POSS中的至少一种。
所述多异氰酸酯单体为二异氰酸甲苯酯、4，4′-二异氰酸二苯甲烷酯、二异氰酸异佛尔酮酯、二异氰酸六亚甲基酯中的至少一种。
所述增韧剂为磷酸酯、柠檬酸酯、醋酸酯、邻苯二甲酸酯中的至少一种。
所述发泡剂为碳酸氢钾、碳酸氢钙、偶氮二甲酰胺、丙酮、碳酸氢钠、异戊烷、正戊烷、石油醚发泡剂中的至少一种。
所述聚醚多元醇为聚氧化丙烯多元醇、聚四氢呋喃多元醇、四氢呋喃-氧化丙烯共聚多元醇或特种聚醚多元醇中的至少一种。
所述催化剂为二月桂酸二丁基锡、三乙烯二胺、三乙烯四胺、辛酸亚锡、环烷酸锡、环烷酸铅或环烷酸钴、马来酸二丁基锡、二乙酸二丁基锡、三乙胺、乙二胺、苯甲基缩水甘油醚中的至少一种。
所述扩链剂为乙二醇、1,4-丁二醇、1,4-丁二胺、1,6-己二醇、1,6-己二胺中的至少一种。
所述泡沫稳定剂为有机硅泡沫稳定剂、磺酸基类泡沫稳定剂中的至少一种。
所述阻燃剂为聚磷酸。
所述的氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法如下：
(1)、A组分的制备：将多异氰酸酯单体、增韧剂加入反应釜，室温条件下混合搅拌0.5～1h，即制得A组分；
(2)、B组分的制备：将发泡剂、聚醚多元醇、氨基取代的笼型聚倍半硅氧烷、泡沫稳定剂、催化剂、氧化铝纤维、阻燃剂，加入反应釜，室温下混合搅拌1～2h，即制得B组分；
(3)、将A组分和B组分混合，充分搅拌均匀后，倒入模具中经发泡、熟化，脱模后，得所述的氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料。
相对现有技术，本发明一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料具有以下优点：(1)采用氨基取代的笼型聚倍半硅氧烷改性聚氨酯，增加了聚氨酯树脂的硬度与交联密度；(2)采用导热率和加热收缩率都较低的氧化铝纤维作为增强填料，所述复合材料相对于玻璃纤维-聚氨酯复合材料隔热性更好；(3)氧化铝纤维具有高耐高温性，减少了阻燃剂的添加量，并同阻燃剂协同发挥阻燃效果。
具体实施方式
实施例1
一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料，为采用导热率、加热收缩率都较低的氧化铝纤维作为增强材料、同时采用氨基取代的笼型聚倍半硅氧烷(含氨基POSS)增强改性聚氨酯，通过室温合成所述复合发泡材料；以质量份计组成如下，A组分：二异氰酸甲苯酯100份，醋酸酯15份；B组分：异戊烷15份、聚四氢呋喃多元醇70份、八氨基苯基POSS8份、三乙烯四胺0.5份、1,6-己二醇6份、有机硅泡沫稳定剂8份、氧化铝纤维60份、聚磷酸1份。
实施例2
一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料，为采用导热率、加热收缩率都较低的氧化铝纤维作为增强材料、同时采用氨基取代的笼型聚倍半硅氧烷(含氨基POSS)增强改性聚氨酯，通过室温合成所述复合发泡材料；以质量份计组成如下，A组分：4，4′-二异氰酸二苯甲烷酯140份，邻苯二甲酸酯25份；B组分：石油醚发泡剂9份、四氢呋喃-氧化丙烯共聚多元醇80份、八-3-氨基丙基POSS15份、二月桂酸二丁基锡0.2份、1,4-丁二胺12份、有机硅泡沫稳定剂4份、氧化铝纤维50份、聚磷酸3份。
实施例3
一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料，为采用导热率、加热收缩率都较低的氧化铝纤维作为增强材料、同时采用氨基取代的笼型聚倍半硅氧烷(含氨基POSS)增强改性聚氨酯，通过室温合成所述复合发泡材料；以质量份计组成如下，A组分：二异氰酸六亚甲基酯115份，柠檬酸酯22份；B组分：正戊烷12份、聚氧化丙烯多元醇40份、氨基取代的笼型聚倍半硅氧烷10份、二乙酸二丁基锡0.4份、1,4-丁二醇9份、磺酸基类泡沫稳定剂7份、氧化铝纤维30份、聚磷酸1.5份。
一种实施例1、实施例2、实施例3中所述的氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料制备方法如下：
(1)、A组分的制备：将多异氰酸酯单体、增韧剂加入反应釜，室温条件下混合搅拌0.5～1h，即制得A组分；
(2)、B组分的制备：将发泡剂、聚醚多元醇、氨基取代的笼型聚倍半硅氧烷、泡沫稳定剂、催化剂、氧化铝纤维、阻燃剂，加入反应釜，室温下混合搅拌1～2h，即制得B组分；
(3)、将A组分和B组分混合，充分搅拌均匀后，倒入模具中经发泡、熟化，脱模后，得所述的氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料。
实施例1、实施例2、实施例3与市售发泡材料一些检测数据如下表：
Shore A硬度 拉伸强度(MPa) 阻燃等级
实施例1 79 19.2 V0
实施例2 81 19.7 V0
实施例3 74 16.6 V0
市售发泡材料 62 12.8 V-1

Claims (10)

1.一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料，其特征在于：采用氧化铝纤维作为增强材料，采用氨基取代的笼型聚倍半硅氧烷来增强改性聚氨酯，通过室温合成所得，其中氧化铝纤维的主晶结构呈γ-氧化铝、δ-氧化铝、θ-氧化铝、α-氧化铝中的至少一种，氨基取代的笼型聚倍半硅氧烷为八氨基苯基POSS、八-3-氨基丙基POSS中的至少一种。
2.一种根据权利要求1所述的氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于，包括如下步骤：
(1)、A组分的制备：将多异氰酸酯单体、增韧剂加入反应釜，室温条件下混合搅拌0.5～1h，即制得A组分；
(2)、B组分的制备：将发泡剂、聚醚多元醇、氨基取代的笼型聚倍半硅氧烷、泡沫稳定剂、催化剂、氧化铝纤维、阻燃剂，加入反应釜，室温下混合搅拌1～2h，即制得B组分；
(3)、将A组分和B组分混合，充分搅拌均匀后，倒入模具中经发泡、熟化，脱模后，得所述的氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料。
3.根据权利要求2所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于，上述组分以质量份计如下，A组分：多异氰酸酯单体100～140份，增韧剂15～25份；B组分：发泡剂5～15份、聚醚多元醇40～80份、氨基取代的笼型聚倍半硅氧烷8～15份、催化剂0.2～0.5份、扩链剂6～12份、泡沫稳定剂4～8份、氧化铝纤维30～60份、阻燃剂1～3份。
4.根据权利要求3所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于，所述氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料由A组分和B组分按照质量比1：0.9～1：1.5经常温混合搅拌制备而得。
5.根据权利要求3所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于：所述氧化铝纤维的主晶结构呈γ-氧化铝、δ-氧化铝、θ-氧化铝、α-氧化铝中的至少一种，其单丝长度为10～150mm；所述的氨基取代的笼型聚倍半硅氧烷为八氨基苯基POSS、八-3-氨基丙基POSS中的至少一种。
6.根据权利要求3所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于：所述多异氰酸酯单体为二异氰酸甲苯酯、4，4′-二异氰酸二苯甲烷酯、二异氰酸异佛尔酮酯、二异氰酸六亚甲基酯至少一种；所述增韧剂为磷酸酯、柠檬酸酯、醋酸酯、邻苯二甲酸酯中的至少一种。
7.根据权利要求3所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于：所述发泡剂为碳酸氢钾、碳酸氢钙、偶氮二甲酰胺、丙酮、碳酸氢钠、异戊烷、正戊烷、石油醚发泡剂中的至少一种。
8.根据权利要求3所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于：所述聚醚多元醇为聚氧化丙烯多元醇、聚四氢呋喃多元醇、四氢呋喃-氧化丙烯共聚多元醇或特种聚醚多元醇中的至少一种。
9.根据权利要求3所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于：所述催化剂为二月桂酸二丁基锡、三乙烯二胺、三乙烯四胺、辛酸亚锡、环烷酸锡、环烷酸铅或环烷酸钴、马来酸二丁基锡、二乙酸二丁基锡、三乙胺、乙二胺、苯甲基缩水甘油醚中的至少一种。
10.根据权利要求2或3所述的一种氧化铝纤维-POSS改性聚氨酯复合发泡保温隔热建筑材料的制备方法，其特征在于：所述扩链剂为乙二醇、1,4-丁二醇、1,4-丁二胺、1,6-己二醇、1,6-己二胺中的至少一种；所述泡沫稳定剂为有机硅泡沫稳定剂、磺酸基类泡沫稳定剂中的至少一种；所述阻燃剂为聚磷酸。
CN201711053384.3A 2017-10-31 2017-10-31 一种氧化铝纤维‑poss改性聚氨酯复合发泡保温隔热建筑材料及其制备方法 Pending CN107722221A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711053384.3A CN107722221A (zh) 2017-10-31 2017-10-31 一种氧化铝纤维‑poss改性聚氨酯复合发泡保温隔热建筑材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711053384.3A CN107722221A (zh) 2017-10-31 2017-10-31 一种氧化铝纤维‑poss改性聚氨酯复合发泡保温隔热建筑材料及其制备方法

Publications (1)

Publication Number Publication Date
CN107722221A true CN107722221A (zh) 2018-02-23

Family

ID=61202106

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711053384.3A Pending CN107722221A (zh) 2017-10-31 2017-10-31 一种氧化铝纤维‑poss改性聚氨酯复合发泡保温隔热建筑材料及其制备方法

Country Status (1)

Country Link
CN (1) CN107722221A (zh)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109232846A (zh) * 2018-09-21 2019-01-18 嘉善中嘉化工有限公司 一种泡沫塑料及其合成方法
CN110183205A (zh) * 2019-04-17 2019-08-30 苏州鑫蔚谷环保产业有限公司 一种利用污泥生产多孔保温砌块的方法
CN110452523A (zh) * 2019-08-01 2019-11-15 无锡市井上海绵有限公司 一种吸音海绵以及制备方法
CN110951382A (zh) * 2019-12-20 2020-04-03 刘艳蕊 一种环保型三防漆及其制备方法
CN114773861A (zh) * 2022-05-24 2022-07-22 昆山力普电子橡胶有限公司 一种移动存储硬盘硅胶保护套及其制备方法
CN116732637A (zh) * 2023-08-14 2023-09-12 烟台舜康生物科技有限公司 高弹性氨纶的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080233164A1 (en) * 2004-01-20 2008-09-25 Ucl Biomedical Plc Polymer for Use in Conduits, Medical Devices and Biomedical Surface Modification
CN102391303A (zh) * 2011-10-24 2012-03-28 北京理工大学 一种笼型低聚八氨基苯基硅倍半氧烷的制备方法
CN102585153A (zh) * 2012-03-07 2012-07-18 厦门大学 一种无卤阻燃型硬质聚氨酯泡沫塑料及其制备方法
CN103467693A (zh) * 2013-09-25 2013-12-25 江苏华夏制漆科技有限公司 一种具有良好冻融稳定性的水性聚氨酯的制备方法
CN104592473A (zh) * 2013-10-31 2015-05-06 嘉兴禾欣化学工业有限公司 Poss改性聚氨酯树脂的制备方法
CN105384902A (zh) * 2015-12-17 2016-03-09 刘爱华 一种建筑保温用新型环保阻燃聚氨酯材料

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080233164A1 (en) * 2004-01-20 2008-09-25 Ucl Biomedical Plc Polymer for Use in Conduits, Medical Devices and Biomedical Surface Modification
CN102391303A (zh) * 2011-10-24 2012-03-28 北京理工大学 一种笼型低聚八氨基苯基硅倍半氧烷的制备方法
CN102585153A (zh) * 2012-03-07 2012-07-18 厦门大学 一种无卤阻燃型硬质聚氨酯泡沫塑料及其制备方法
CN103467693A (zh) * 2013-09-25 2013-12-25 江苏华夏制漆科技有限公司 一种具有良好冻融稳定性的水性聚氨酯的制备方法
CN104592473A (zh) * 2013-10-31 2015-05-06 嘉兴禾欣化学工业有限公司 Poss改性聚氨酯树脂的制备方法
CN105384902A (zh) * 2015-12-17 2016-03-09 刘爱华 一种建筑保温用新型环保阻燃聚氨酯材料

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
PAGACZ JOANNA,等: ""Polyurethane foams chemically reinforced with POSS—Thermal degradation studies"", 《THERMOCHIMICA ACTA》 *
张东兴: "《聚合物基复合材料科学与工程》", 30 June 2017, 哈尔滨工业大学出版社 *
田春蓉，等: ""八氨苯基POSS 交联改性聚氨酯弹性体的制备与性能"", 《化工新型材料》 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109232846A (zh) * 2018-09-21 2019-01-18 嘉善中嘉化工有限公司 一种泡沫塑料及其合成方法
CN110183205A (zh) * 2019-04-17 2019-08-30 苏州鑫蔚谷环保产业有限公司 一种利用污泥生产多孔保温砌块的方法
CN110452523A (zh) * 2019-08-01 2019-11-15 无锡市井上海绵有限公司 一种吸音海绵以及制备方法
CN110951382A (zh) * 2019-12-20 2020-04-03 刘艳蕊 一种环保型三防漆及其制备方法
CN110951382B (zh) * 2019-12-20 2021-06-04 刘艳蕊 一种环保型三防漆及其制备方法
CN114773861A (zh) * 2022-05-24 2022-07-22 昆山力普电子橡胶有限公司 一种移动存储硬盘硅胶保护套及其制备方法
CN114773861B (zh) * 2022-05-24 2022-12-27 昆山力普电子橡胶有限公司 一种移动存储硬盘硅胶保护套及其制备方法
CN116732637A (zh) * 2023-08-14 2023-09-12 烟台舜康生物科技有限公司 高弹性氨纶的制备方法

Similar Documents

Publication Publication Date Title
CN107722221A (zh) 一种氧化铝纤维‑poss改性聚氨酯复合发泡保温隔热建筑材料及其制备方法
CN103183806B (zh) 一种高阻燃硬质聚氨酯泡沫材料及其制备方法
CN102585153B (zh) 一种无卤阻燃型硬质聚氨酯泡沫塑料及其制备方法
CN101205288B (zh) 一种聚氨酯泡沫组合物
CN104151523B (zh) 硬质聚氨酯泡沫组合物、制备该泡沫的方法及保温组件
CN105131580A (zh) 一种无卤阻燃聚氨酯软泡及其制备方法
CN106189192B (zh) 一种凯夫拉纤维-聚氨酯复合发泡材料及其制备方法
CN107459620B (zh) 阻燃多元醇的制法及其制备的聚氨酯泡沫和聚氨酯密封胶
CN103865025A (zh) 一种本质阻燃硬质聚氨酯泡沫塑料
CN106632953B (zh) 一种聚氨酯仿木用组合聚醚、原料组合物及其使用方法
CN111647266A (zh) 一种聚氨酯发泡材料及制备方法
CN114835872A (zh) 一种高阻燃低导热聚氨酯泡沫材料及其制备方法
CN109824860A (zh) 一种聚氨酯聚酰亚胺泡沫材料及其制备方法
CN101392047A (zh) 用回收油脂多元醇制备聚氨酯泡沫材料的方法
CN105384902B (zh) 一种建筑保温用新型环保阻燃聚氨酯材料
CN101580576A (zh) 高阻燃低产烟率柔性聚氨酯泡沫塑料的制备方法
TW201307418A (zh) 聚胺酯發泡板及其製造方法
CN106146783A (zh) 一种用于太阳能热水器保温的无氟阻燃聚氨酯硬泡组合物
KR100809667B1 (ko) 초저밀도 수발포 폴리우레탄 조성물 및 그 제조 방법
US3061556A (en) Preparation of cellular polyurethane plastics
CN107033327A (zh) 一种冷库地面用高抗压聚氨酯组合料及其制备方法
CN106167541B (zh) 连续式生产pir大块泡用组合聚醚及其制备方法和应用
CN106832212B (zh) 储水式电热水器用聚氨酯硬泡材料及其制备方法
KR102055666B1 (ko) 준불연 경질 폴리우레탄 발포체의 제조방법
CN113817213A (zh) 一种聚氨酯硬质泡沫的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180223