CN104521967B - Agriculturally useful compositions and application containing fipronil bisamide and botanical components - Google Patents
Agriculturally useful compositions and application containing fipronil bisamide and botanical components Download PDFInfo
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- CN104521967B CN104521967B CN201410743482.XA CN201410743482A CN104521967B CN 104521967 B CN104521967 B CN 104521967B CN 201410743482 A CN201410743482 A CN 201410743482A CN 104521967 B CN104521967 B CN 104521967B
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- fipronil bisamide
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- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 description 1
- MKXKFYHWDHIYRV-UHFFFAOYSA-N flutamide Chemical compound CC(C)C(=O)NC1=CC=C([N+]([O-])=O)C(C(F)(F)F)=C1 MKXKFYHWDHIYRV-UHFFFAOYSA-N 0.000 description 1
- OCDGBSUVYYVKQZ-UHFFFAOYSA-N gramine Chemical compound C1=CC=C2C(CN(C)C)=CNC2=C1 OCDGBSUVYYVKQZ-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- HDVAWXXJVMJBAR-VHSXEESVSA-N lupinine Chemical compound C1CCC[C@@H]2[C@H](CO)CCCN21 HDVAWXXJVMJBAR-VHSXEESVSA-N 0.000 description 1
- 229930014016 lupinine Natural products 0.000 description 1
- 229930014456 matrine Natural products 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229960005181 morphine Drugs 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 229960001789 papaverine Drugs 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 description 1
- 229940084560 sanguinarine Drugs 0.000 description 1
- YZRQUTZNTDAYPJ-UHFFFAOYSA-N sanguinarine pseudobase Natural products C1=C2OCOC2=CC2=C3N(C)C(O)C4=C(OCO5)C5=CC=C4C3=CC=C21 YZRQUTZNTDAYPJ-UHFFFAOYSA-N 0.000 description 1
- SLRCCWJSBJZJBV-AJNGGQMLSA-N sparteine Chemical compound C1N2CCCC[C@H]2[C@@H]2CN3CCCC[C@H]3[C@H]1C2 SLRCCWJSBJZJBV-AJNGGQMLSA-N 0.000 description 1
- 229960001945 sparteine Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- UINUUSQOLRQGNF-UHFFFAOYSA-N stemonine Chemical compound O1C2(C=C(C)C(=O)O2)C(CC)C(C2CC3)C1CCCN2C3C1CC(C)C(=O)O1 UINUUSQOLRQGNF-UHFFFAOYSA-N 0.000 description 1
- HTLBMAZNGBFLEY-UHFFFAOYSA-N stemonine-C17 Natural products O1C(=O)C(C)CC1C1N2CCCC3OC(=O)C(C)C3C2CC1 HTLBMAZNGBFLEY-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- REJLGAUYTKNVJM-SGXCCWNXSA-N tomatine Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@H]1[C@@H](CO)O[C@H]([C@@H]([C@H]1O)O)O[C@@H]1C[C@@H]2CC[C@H]3[C@@H]4C[C@H]5[C@@H]([C@]4(CC[C@@H]3[C@@]2(C)CC1)C)[C@@H]([C@@]1(NC[C@@H](C)CC1)O5)C)[C@@H]1OC[C@@H](O)[C@H](O)[C@H]1O REJLGAUYTKNVJM-SGXCCWNXSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
Agriculturally useful compositions containing fipronil bisamide Yu botanical components of the invention, belong to plant protection art.Botanical components are the active component of one or more in alkaloids, terpenes, flavonoids, the plant photoactivation endotoxin of plant, and the quality parts ratio of A and B is 30:1‑1:30, composition is to the obvious preventive effect to crop disease and insect.
Description
Technical field
The invention belongs to plant protection art, more particularly to combined with the agricultural of botanical components containing fipronil bisamide
Thing can effectively prevent and treat diseases and pests of agronomic crop with application, the present composition.
Background technology
In recent years, due to single and not Scientific Usage of Drugs, pest and disease damage has produced the different degrees of resistance to the action of a drug, and agriculture and forestry are produced
Still with chemical pesticide as mainly kind is prevented and treated, environmental pollution and the serious of ecological environment is caused to destroy increasingly.As people live
The raising of level and the enhancing of health perception, development and the exploitation of biological pesticide are progressively paid close attention to by agricultural chemical R＆D,
Focus as agriculture and forestry sustainable development, is the effective way for improving environment, reduction or delaying drug resistance and improving drug effect.Its
In, botanical components turn into one of focus of biological pesticide research.
It is reported that the main of tool plant source agricultural Development volue has Meliaceae, composite family, pulse family, Rutaceae, aster section, lip
The certain plants of section, Annonaceae, Ranunculaceae, Euphorbiaceae, Araeceae, Myrsinacea, Papilionaceae etc., research is more to be had
Trifoliate jewelvine, thunder godvine, tobacco, Dalmatian chrysanthemum, marigold, the tuber of stemona, capsicum, macleaya cordata, kuh-seng, chinaberry, Chinese tallow tree, black nightshade, Rhododendron molle, horse
Mulberry, garlic, the fruit of a cubeb litsea tree, Rhododendron molle flowers, winter daphne, the root of langdu, Lysimachia foenum-graecum, peppermint, calamus, Chinese cassia tree, black pepper, Artemisia scoparia, galangal,
Argy wormwood, Chinese prickly ash, Cynanchum Komarovii, gleditsia sinensis, datura, ginkgo, camphor tree, reticulate millettia, elscholtiza, asarum, India red sandalwood, erythrina indica, plant
Iron son or frutus cnidii etc..The botanical components with desinsection that can be made into, including can directly using the root of plant, stem, leaf, flower,
The active component of the crushed materials such as fruit, seed, crude extract or extraction plant.Plant source active component is divided into biology by chemical constitution
Bases, terpenes, flavonoids, light-activated toxin class and other class active components.
Fipronil bisamide (flubendiamide), belongs to new phthalic amide insecticides, and the mechanism of action is activation
Ryanodine receptor intracellular calcium release channel, causes the runaway release of calcium ion of storage, ultimately results in insect death.Should
Medical instrument has work fast, lasting period long, is produced with existing insecticide no interactions resistance, is mainly used in the anti-of lepidoptera pest
Control.
Research on fipronil bisamide and the agriculturally useful compositions of botanical components is unmanned at present to be reported, applicant carried out
Substantial amounts of exploration, it was found that some unexpected effects.
The content of the invention
The purpose of the present invention is to reduce or delaying drug resistance, raising drug effect, there is provided one kind contains fipronil bisamide and plant source
The agriculturally useful compositions of material and application.
The present invention is achieved through the following technical solutions：
Agriculturally useful compositions containing fipronil bisamide Yu botanical components, component A and component of the said composition containing effective dose
B, component A are fipronil bisamides, and component B is botanical components, and botanical components are trifoliate jewelvine, thunder godvine, tobacco, Dalmatian chrysanthemum, ten thousand
Shou Ju, Eupatorium adenophorum, the tuber of stemona, capsicum, macleaya cordata, kuh-seng, Dalmatian chrysanthemum, chinaberry, Chinese tallow tree, black nightshade, Rhododendron molle, Coriaria sinica, garlic, mountain
Grey son, Rhododendron molle flowers, winter daphne, the root of langdu, Lysimachia foenum-graecum, peppermint, calamus, Chinese cassia tree, black pepper, Artemisia scoparia, galangal, argy wormwood, Chinese prickly ash,
Cynanchum Komarovii, gleditsia sinensis, datura, ginkgo, camphor tree, reticulate millettia, elscholtiza, asarum, India red sandalwood, erythrina indica, iron are young or frutus cnidii is planted
The active component of one or more in alkaloids, terpenes, flavonoids, essential oil class, the plant photoactivation endotoxin of thing, A
It is 30 with the quality parts ratio of B:1-1:30.Preferably, the quality parts ratio of A and B is 20:1-1:20.
In above-mentioned composition, alkaloids is total thunder godvine alkaloid, oxymatrine, nicotine, datura total alkali, black false hellebore
Alkali, capsaicine, the total alkaloids, camptothecine, stemonine, oxymatrine, matrine, sanguinarine, jamaicin, Sophora alopecuroide are always given birth to
Alkaloids, papaverine, quinoline are peaceful, tomatin, lupinine, sparteine, numb rope, donaxine, morphine, kind art soft-shelled turtle alkali, gelsemium henbane amine,
Strychnia, mufangchine, magnoflorine, Chelidonine, aconitine, eulexine, atropine, black nightshade alkaloid, dandelion life
One or more in alkaloids etc..Preferably, alkaloids is total thunder godvine alkaloid, oxymatrine, nicotine, datura
One or more alkaloids in alkali, black false hellebore total alkali, capsaicine, the total alkaloids, camptothecine.
In above-mentioned composition, terpenes are Chinese azalea extract, the coriamyrtin of Coriariaceae plant, the Celastraceae in Ericaceae
The Diterpenes in Deoxypodophyllotoxin, Euphorbiaceae and Isolated From Thymelaeaceae Species in Celastrus angulatus, Cupressaceae, the Berberidaceae plant of plant
One or more in triterpene compound in compound and Meliaceae etc..Preferred terpenes are Chinese azalea extract, coriamyrtin, hardship
Skin rattan element and Deoxypodophyllotoxin in one kind or two kinds.
In above-mentioned composition, flavonoids be rotenone, pterocarpoid, chamaejasmine, kuh-seng flavones and plant iron son flavones in
One or more.Preferred flavonoids is one kind or two kinds in rotenone, pterocarpoid and chamaejasmine.
In above-mentioned composition, the percentage that fipronil bisamide and botanical components quality sum account for composition gross mass is
0.1-90%.
Above-mentioned composition of the invention can be processed to wettable powder, water dispersible granules, aqueous emulsion, microemulsion or outstanding
Floating agent etc..
Present invention also offers the application process of above-mentioned composition, it is characterised in that by composition with base manure, spraying, filling
Root, seed dressing, impregnating are applied to crop.
It is used to prevent and treat the purposes of plant pest present invention also offers above-mentioned composition.Preferably, the present invention is carried
The purposes of preventing and treating lepidoptera pest is supplied.Preferably, the use of composition for preventing and controlling beet armyworm, rice leaf roller, apple skin worm
On the way.
Alkaloids, terpenes, flavonoids, essential oil class, plant photoactivation poison in present composition botanical components
Plain class, both can come from tissue, organ, plant of plant etc., it is also possible to each growth phase from Plant Tissue Breeding.
Composition of the invention compared with prior art, produces following beneficial effect：
1st, use cost is reduced：Preventive effect, preventing and treating spectrum increase are improved because composition has, Pesticide use number of times is reduced, dropped
Low use cost.
2nd, the resistance to the action of a drug is delayed：Fipronil bisamide is compounded from the component of the different mechanism of action of botanical components, and pest and disease damage is not
It is also easy to produce the resistance to the action of a drug.
Specific embodiment
Be only used for explaining the present invention described in example below, for made without departing from spirit of the invention and principle modification,
Replace or improve, belong to the scope of protection of present invention.
Effect of composition of the embodiment 1 containing fipronil bisamide and botanical components to beet armyworm
Experiment is used to test using the beet armyworm of field collection after raising for 2 generations.Specific method is as follows：
Leaf dish prepares：The luxuriant dish of cleaning is chosen, is cleaned and is dried, it is standby to make leaf dish with card punch.
Before medicament test preparation, different concentration gradients are configured to according to different ratio scheme, often match 6 concentration.
Dipping：Leaf dish is gripped with tweezers soak in liquid 5 seconds, take out and dry in the air on blotting paper, after being put in 24 after natural air drying
In orifice plate, per 2, hole.Per concentration, 3 plates are put in treatment altogether.
Connect worm：24 orifice plates put 1 instar larvae of beet armyworm 3 per hole, and insectary (25 ± 1 DEG C, 12H/ are put into after covering
In 12H).
Investigation statisticses：Treatment checks dead borer population after 48 hours, and corrected mortality is calculated with Abbott formula.Appliance computer
Program obtains each lethal concentration of 50 LC for trying single dose and variant proportioning50, the toxicity index of medicament is calculated according to the abundant methods of Sun Yun
And mixed co-toxicity coefficient (CTC values), it is synergistic effect that CTC values are more than 120, and specific method is as follows.
It is standard single dose to set a kind of single dose (A), and it is 100 to specify its toxicity index (TI), then：
Percentage of the TI × single dose of the theoretical toxicity index (TTI) of mixture=each single doses of Σ in mixture
Specific test result is shown in Table 1.
Effect of composition of the table 1 containing fipronil bisamide and botanical components to beet armyworm
Table 1 shows, fipronil bisamide and thunder godvine total alkali, oxymatrine, nicotine, datura total alkali, black false hellebore total alkali,
Capsaicine, the total alkaloids, camplotheca acuminata total alkali composition it is different to the effect of beet armyworm, the actual preventive effect of composition is obvious
Higher than theoretical preventive effect, the co-toxicity coefficient (CTC) of composition is all higher than 120, so composition has significant increasing to beet armyworm
Effect effect.
Effect of composition of the embodiment 2 containing fipronil bisamide and botanical components to rice leaf roller
According to scheme, built agent and single dose are prepared, and carry out activity preliminary experiment.According to trial test result, preparation is prepared
Into the concentration for needing.Before experiment, cell, listed, the radix of investigation rice leaf roller are set, and set corresponding single dose and blank pair
According to using manual sprayer routine conventional spray.Effect of the 7d investigation medicaments to rice leaf roller after medicine.Using Abbot formula,
Percentage is converted into preventive effect.
In theoretical effect, x is the effect of substance A when concentration is a, and y is the effect of substance B when concentration is b, compares reason
By effect and actual effect, the synergy of composition is evaluated.The results are shown in Table 2.
Effect of composition of the table 2 containing fipronil bisamide and botanical components to rice leaf roller
Find out from table 2, fipronil bisamide Chinese azalea extract, coriamyrtin, Celastrus angulatus, deoxidation ghost respectively with terpenes
The rotenone of mortar toxin and flavonoids, chamaejasmine, the composition of pterocarpin, the actual effect to rice leaf roller are above theory
Effect, shows obvious synergistic function.
Effect of composition of the embodiment 3 containing fipronil bisamide and botanical components to Apple Pests
According to scheme, built agent and single dose are prepared, and carry out activity preliminary experiment.According to activity test determination trial, by preparation
It is configured to the concentration for needing.Before experiment, cell, listed, investigation apple skin worm radix are set, and set corresponding single dose and blank pair
According to using manual sprayer routine conventional spray.Effect of the 3d investigation medicaments to apple skin worm after medicine.It is public according to embodiment 2
Formula is calculated and counted, and the results are shown in Table 3.
Field efficacy of composition of the table 3 containing fipronil bisamide to Apple Pests
Find out from table 3, the fish of fipronil bisamide Chinese azalea extract, Deoxypodophyllotoxin and flavonoids respectively with terpenes
Rattan ketone, chamaejasmine, the composition of pterocarpin, to the preventive effect of apple skin worm significantly, and actual effect to insect is above reason
By effect, composition shows obvious synergistic function.
Claims (4)
1. agriculturally useful compositions containing fipronil bisamide Yu botanical components, component A and component B of the said composition containing effective dose,
Component A is fipronil bisamide, and component B is botanical components, and botanical components are trifoliate jewelvine, thunder godvine, tobacco, Dalmatian chrysanthemum, Wan Shou
Chrysanthemum, Eupatorium adenophorum, the tuber of stemona, capsicum, macleaya cordata, kuh-seng, Dalmatian chrysanthemum, chinaberry, Chinese tallow tree, black nightshade, Rhododendron molle, Coriaria sinica, garlic, mountain are grey
Son, Rhododendron molle flowers, winter daphne, the root of langdu, Lysimachia foenum-graecum, peppermint, calamus, Chinese cassia tree, black pepper, Artemisia scoparia, galangal, argy wormwood, Chinese prickly ash, ox
Heart Piao Zi, gleditsia sinensis, datura, ginkgo, camphor tree, reticulate millettia, elscholtiza, asarum, India red sandalwood, erythrina indica, iron son or frutus cnidii plant
Alkaloids in the active component of one or more, alkaloids be thunder godvine total alkali, oxymatrine, nicotine, Man Tuo
The quality of the one kind in sieve total alkali, black false hellebore total alkali, capsaicine, the total alkaloids, camptothecine, fipronil bisamide and thunder godvine total alkali
Portion rate is 10:1-1:5；Fipronil bisamide is 10 with the quality parts ratio of oxymatrine:1-1:5；Fipronil bisamide and cigarette
The quality parts ratio of alkali is 20:1-1:5；Fipronil bisamide is 10 with the quality parts ratio of datura total alkali:1-1:10；Fluorine worm is double
Acid amides is 10 with the quality parts ratio of black false hellebore total alkali:1-1:5；Fipronil bisamide is 20 with the quality parts ratio of capsaicine:1-1:
1；Fipronil bisamide is 20 with the quality parts ratio of the total alkaloids:1-1:10；The mass fraction of fipronil bisamide and camptothecine
Than being 10:1-1:5.
2. it is total that agriculturally useful compositions according to claim 1, fipronil bisamide and botanical components quality sum account for composition
The percentage of quality is 0.05-90%, and composition is processed to wettable powder, water dispersible granules, aqueous emulsion, microemulsion or outstanding
Floating agent.
3. the application method of the composition described in claim 2, composition is applied to base manure, spraying, pouring root, seed dressing, dipping
Crop.
4. the composition described in claim 2 is used to prevent and treat the purposes of plant pest.
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| CN201410743482.XA CN104521967B (en) | 2014-12-08 | 2014-12-08 | Agriculturally useful compositions and application containing fipronil bisamide and botanical components |
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| CN105104441A (en) * | 2015-09-17 | 2015-12-02 | 广西天峨五福种业有限公司 | Botanical pesticide composition with matrine and eupatorium adenophorum spreng |
| CN105340994A (en) * | 2015-10-09 | 2016-02-24 | 南宁源广农业科技有限公司 | Vegetable pesticide and preparation method thereof |
| CN105410078A (en) * | 2015-11-18 | 2016-03-23 | 无锡市稼宝药业有限公司 | Botanical fungicide for basal stem rot |
| CN105340924A (en) * | 2015-12-16 | 2016-02-24 | 济南昊泽环保科技有限公司 | Insecticide composition containing o-phenylenediamine pesticide and sophocarpidine |
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| CN106417306B (en) * | 2016-09-12 | 2019-04-19 | 广西南宁乐蕊生物科技有限责任公司 | A kind of Pesticidal combination containing Celastrus angulatus and Tolfenpyrad |
| CN106857153A (en) * | 2017-02-27 | 2017-06-20 | 昆明浙东农业种植有限公司 | Prevent the implantation methods of apple tree root rot |
| CN107372686A (en) * | 2017-06-01 | 2017-11-24 | 磐安县派普特生物科技有限公司 | A kind of natural insecticide for preventing ginkgo insect pest and its application |
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| CN102578117A (en) * | 2012-01-19 | 2012-07-18 | 华南理工大学 | Flubendiamide-rotenone compound suspending agent and preparation method thereof |
| CN104602520A (en) * | 2012-07-31 | 2015-05-06 | 拜尔农作物科学股份公司 | Compositions comprising a pesticidal terpene mixture and an insecticide |
| CN103190451B (en) * | 2013-04-07 | 2015-04-15 | 海南正业中农高科股份有限公司 | Oligochitosan and plant source substance-containing agricultural composition and applications |
| CN103548852B (en) * | 2013-10-31 | 2016-04-13 | 浙江农林大学天目学院 | A kind of containing alkaloidal insecticides and uses thereof |
-
2014
- 2014-12-08 CN CN201510915543.0A patent/CN105594772B/en active Active
- 2014-12-08 CN CN201410743482.XA patent/CN104521967B/en active Active
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| Publication number | Publication date |
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| CN105594772B (en) | 2018-01-02 |
| CN104521967A (en) | 2015-04-22 |
| CN105594772A (en) | 2016-05-25 |
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Denomination of invention: Agricultural composition containing flubendiamide and plant-derived substances, and applications thereof Effective date of registration: 20190215 Granted publication date: 20170630 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2019460000001 |
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