CN105594772B - Agriculturally useful compositions and application containing fipronil bisamide and terpenes botanical components - Google Patents
Agriculturally useful compositions and application containing fipronil bisamide and terpenes botanical components Download PDFInfo
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- CN105594772B CN105594772B CN201510915543.0A CN201510915543A CN105594772B CN 105594772 B CN105594772 B CN 105594772B CN 201510915543 A CN201510915543 A CN 201510915543A CN 105594772 B CN105594772 B CN 105594772B
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- fipronil bisamide
- botanical components
- terpenes
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- 231100000636 lethal dose Toxicity 0.000 description 1
- HDVAWXXJVMJBAR-VHSXEESVSA-N lupinine Chemical compound C1CCC[C@@H]2[C@H](CO)CCCN21 HDVAWXXJVMJBAR-VHSXEESVSA-N 0.000 description 1
- 229930014016 lupinine Natural products 0.000 description 1
- 229930014456 matrine Natural products 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229960005181 morphine Drugs 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 229960001789 papaverine Drugs 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 244000145591 rattan cane Species 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 description 1
- 229940084560 sanguinarine Drugs 0.000 description 1
- YZRQUTZNTDAYPJ-UHFFFAOYSA-N sanguinarine pseudobase Natural products C1=C2OCOC2=CC2=C3N(C)C(O)C4=C(OCO5)C5=CC=C4C3=CC=C21 YZRQUTZNTDAYPJ-UHFFFAOYSA-N 0.000 description 1
- SLRCCWJSBJZJBV-AJNGGQMLSA-N sparteine Chemical compound C1N2CCCC[C@H]2[C@@H]2CN3CCCC[C@H]3[C@H]1C2 SLRCCWJSBJZJBV-AJNGGQMLSA-N 0.000 description 1
- 229960001945 sparteine Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- UINUUSQOLRQGNF-UHFFFAOYSA-N stemonine Chemical compound O1C2(C=C(C)C(=O)O2)C(CC)C(C2CC3)C1CCCN2C3C1CC(C)C(=O)O1 UINUUSQOLRQGNF-UHFFFAOYSA-N 0.000 description 1
- HTLBMAZNGBFLEY-UHFFFAOYSA-N stemonine-C17 Natural products O1C(=O)C(C)CC1C1N2CCCC3OC(=O)C(C)C3C2CC1 HTLBMAZNGBFLEY-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- REJLGAUYTKNVJM-SGXCCWNXSA-N tomatine Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@H]1[C@@H](CO)O[C@H]([C@@H]([C@H]1O)O)O[C@@H]1C[C@@H]2CC[C@H]3[C@@H]4C[C@H]5[C@@H]([C@]4(CC[C@@H]3[C@@]2(C)CC1)C)[C@@H]([C@@]1(NC[C@@H](C)CC1)O5)C)[C@@H]1OC[C@@H](O)[C@H](O)[C@H]1O REJLGAUYTKNVJM-SGXCCWNXSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to the agriculturally useful compositions containing fipronil bisamide and botanical components, belong to plant protection art.Botanical components are the active component of the terpenes of plant, and the quality parts ratio of fipronil bisamide and botanical components is 30:1‑1:30, obvious preventive effect of the composition to crop disease and insect.
Description
The application is point of " agriculturally useful compositions and application containing fipronil bisamide botanical components " application for a patent for invention
Case application, original application day：On December 8th, 2014, application number：201410743482X.
Technical field
The invention belongs to plant protection art, more particularly to the agricultural combination containing fipronil bisamide and botanical components
Thing can effectively prevent and treat diseases and pests of agronomic crop with application, the present composition.
Background technology
In recent years, due to single and not Scientific Usage of Drugs, pest and disease damage has produced the different degrees of resistance to the action of a drug, and agriculture and forestry produce
Still using chemical pesticide as main preventing and treating kind, environmental pollution and the serious of ecological environment is caused to destroy increasingly.As people live
Horizontal raising and the enhancing of health perception, development and the exploitation of biological pesticide are progressively paid close attention to by agricultural chemical R＆D,
It is the effective way for improving environment, reduction or delaying drug resistance and improving drug effect as the focus of agriculture and forestry sustainable development.Its
In, botanical components turn into one of focus of biological pesticide research.
It is reported that tool plant source agricultural Development volue mainly has Meliaceae, composite family, pulse family, Rutaceae, aster section, lip
The certain plants of section, Annonaceae, Ranunculaceae, Euphorbiaceae, Araeceae, Myrsinacea, Papilionaceae etc., studying more has
Trifoliate jewelvine, tripterygium wilfordii, tobacco, Dalmatian chrysanthemum, marigold, the tuber of stemona, capsicum, macleaya cordata, kuh-seng, chinaberry, Chinese tallow tree, black nightshade, Rhododendron molle, horse
Mulberry, garlic, the fruit of a cubeb litsea tree, Rhododendron molle flowers, winter daphne, the root of langdu, Lysimachia foenum-graecum, peppermint, calamus, Chinese cassia tree, black pepper, Artemisia scoparia, galangal,
Argy wormwood, Chinese prickly ash, Cynanchum Komarovii, gleditsia sinensis, datura, ginkgo, camphor tree, reticulate millettia, elscholtiza, asarum, India red sandalwood, erythrina indica, plant
Iron son or frutus cnidii etc..The botanical components with desinsection that can be made into, including can directly using the root of plant, stem, leaf, flower,
The crushed materials such as fruit, seed, crude extract or the active component for extracting plant.Plant source active component is divided into biology by chemical constitution
Bases, terpenes, flavonoids, light-activated toxin class and other class active components.
Fipronil bisamide (flubendiamide), belongs to new phthalic amide insecticides, and the mechanism of action is activation
Ryanodine receptor intracellular calcium release channel, cause the runaway release of calcium ion of storage, ultimately result in insect death.Should
Medical instrument has work fast, lasting period length, is produced with existing insecticide no interactions resistance, is mainly used in the anti-of lepidoptera pest
Control.
The current unmanned report of research on fipronil bisamide and the agriculturally useful compositions of botanical components, applicant carried out
It is substantial amounts of to explore, it was found that some unexpected effects.
The content of the invention
The purpose of the present invention is reduction or delaying drug resistance, improves drug effect, there is provided one kind contains fipronil bisamide and plant source
The agriculturally useful compositions of material and application.
The present invention is achieved through the following technical solutions：
Agriculturally useful compositions containing fipronil bisamide and botanical components, component A and component of the said composition containing effective dose
B, component A are fipronil bisamides, and component B is botanical components, and botanical components are trifoliate jewelvine, tripterygium wilfordii, tobacco, Dalmatian chrysanthemum, ten thousand
Shou Ju, Eupatorium adenophorum, the tuber of stemona, capsicum, macleaya cordata, kuh-seng, Dalmatian chrysanthemum, chinaberry, Chinese tallow tree, black nightshade, Rhododendron molle, Coriaria sinica, garlic, mountain
Grey son, Rhododendron molle flowers, winter daphne, the root of langdu, Lysimachia foenum-graecum, peppermint, calamus, Chinese cassia tree, black pepper, Artemisia scoparia, galangal, argy wormwood, Chinese prickly ash,
Cynanchum Komarovii, gleditsia sinensis, datura, ginkgo, camphor tree, reticulate millettia, elscholtiza, asarum, India red sandalwood, erythrina indica, iron are young or frutus cnidii is planted
One or more of active components in the alkaloids of thing, terpenes, flavonoids, essential oil class, plant photoactivation endotoxin, A
Quality parts ratio with B is 30:1-1:30.Preferably, A and B quality parts ratio is 20:1-1:20.
In above-mentioned composition, alkaloids is that thunder godvine alkaloid, oxymatrine, nicotine, datura total alkali, black false hellebore are total
Alkali, capsaicine, the total alkaloids, camptothecine, stemonine, oxymatrine, matrine, sanguinarine, jamaicin, Sophora alopecuroide are always given birth to
Alkaloids, papaverine, quinoline are peaceful, tomatin, lupinine, sparteine, numb rope, donaxine, morphine, kind art soft-shelled turtle alkali, gelsemium henbane amine,
Strychnia, mufangchine, magnoflorine, Chelidonine, aconitine, eulexine, atropine, black nightshade alkaloid, dandelion life
One or more in alkaloids etc..Preferably, alkaloids is that thunder godvine alkaloid, oxymatrine, nicotine, datura are total
One or more of alkaloids in alkali, black false hellebore total alkali, capsaicine, the total alkaloids, camptothecine.
In above-mentioned composition, terpenes are Chinese azalea extract, coriamyrtin, the Celastraceae of Coriariaceae plant in Ericaceae
Diterpenes in the Celastrus angulatus of plant, Cupressaceae, the Deoxypodophyllotoxin in Berberidaceae plant, Euphorbiaceae and Isolated From Thymelaeaceae Species
One or more in triterpene compound in compound and Meliaceae etc..Preferable terpenes are Chinese azalea extract, coriamyrtin, hardship
Skin rattan element and one kind in Deoxypodophyllotoxin or two kinds.
In above-mentioned composition, flavonoids is in rotenone, pterocarpoid, chamaejasmine, kuh-seng flavones and plant iron son's flavones
One or more.Preferable flavonoids is one kind or two kinds in rotenone, pterocarpoid and chamaejasmine.
In above-mentioned composition, the percentage that fipronil bisamide and botanical components quality sum account for composition gross mass is
0.1-90%.
The above-mentioned composition of the present invention can be processed to wettable powder, water dispersible granules, aqueous emulsion, microemulsion or outstanding
Floating agent etc..
Present invention also offers the application process of above-mentioned composition, it is characterised in that by composition with base manure, spraying, filling
Root, seed dressing, impregnating are applied to crop.
It is used for the purposes for preventing and treating plant pest present invention also offers above-mentioned composition.Preferably, the present invention carries
The purposes of preventing and treating lepidoptera pest is supplied.Preferably, the use of composition for preventing and controlling beet armyworm, rice leaf roller, apple skin worm
On the way.
Alkaloids, terpenes, flavonoids, essential oil class, plant photoactivation poison in present composition botanical components
Plain class, tissue, organ, plant of plant etc. were both can come from, and can be from each growth phase of Plant Tissue Breeding.
The composition of the present invention compared with prior art, produces following beneficial effect：
1st, use cost is reduced：Preventive effect, preventing and treating spectrum increase are improved because composition has, reduces Pesticide use number, drops
Low use cost.
2nd, the resistance to the action of a drug is delayed：The component compounding of fipronil bisamide mechanism of action different from botanical components, pest and disease damage is not
It is also easy to produce the resistance to the action of a drug.
Embodiment
Be only used for explaining the present invention described in example below, for made without departing from spirit of the invention and principle modification,
Replace or improve, belong to the scope of protection of present invention.
Effect of composition of the embodiment 1 containing fipronil bisamide and botanical components to beet armyworm
Experiment is used to test using the beet armyworm of field collection after raising for 2 generations.Specific method is as follows：
Leaf dish prepares：Choose and clean luxuriant dish, clean and dry, it is standby to make leaf dish with card punch.
Before medicament test preparation, different concentration gradients is configured to according to different ratio scheme, often matches 6 concentration.
Dipping：Soaked with tweezers gripping leaf dish in decoction 5 seconds, taking-up is dried in the air on blotting paper, and 24 are put in after natural air drying
In orifice plate, per 2, hole.Per concentration, 3 plates are put in processing altogether.
Connect worm：24 orifice plates put 1 instar larvae of beet armyworm 3 per hole, be put into after covering insectary (25 ± 1 DEG C, 12H/
In 12H).
Investigation statisticses：Processing checks dead borer population after 48 hours, and corrected mortality is calculated with Abbott formula.Appliance computer
Program obtains each lethal concentration of 50 LC for examination single dose and variant proportioning50, according to the toxicity index of the abundant method calculating medicaments of Sun Yun
And mixed co-toxicity coefficient (CTC values), CTC values be more than 120 for synergistic effect, specific method it is as follows.
A kind of single dose (A) is set as standard single dose, it is 100 to specify its toxicity index (TI), then：
Percentage of the TI × single dose of the theoretical toxicity index (TTI) of mixture=each single doses of Σ in mixture
Specific test result is shown in Table 1.
Effect of composition of the table 1 containing fipronil bisamide and botanical components to beet armyworm
Table 1 shows, fipronil bisamide and tripterygium wilfordii total alkali, oxymatrine, nicotine, datura total alkali, black false hellebore total alkali, peppery
Green pepper alkali, the total alkaloids, the composition of camplotheca acuminata total alkali are different to the effect of beet armyworm, and the actual preventive effect of composition is obvious high
In theoretical preventive effect, the co-toxicity coefficient (CTC) of composition is all higher than 120, so composition has significant synergy to beet armyworm
Effect.
Effect of composition of the embodiment 2 containing fipronil bisamide and botanical components to rice leaf roller
According to scheme, built agent and single dose are prepared, and carry out activity preliminary experiment.According to trial test result, preparation is prepared
Into the concentration of needs.Before experiment, cell is set, is listed, investigates the radix of rice leaf roller, and set corresponding single dose and blank pair
According to using manual sprayer routine conventional spray.7d investigates effect of the medicament to rice leaf roller after medicine.Using Abbot formula,
Percentage is converted into preventive effect.
In theoretical effect, x is the effect of substance A when concentration is a, and y is the effect of substance B when concentration is b, compares reason
By effect and actual effect, the synergy of composition is evaluated.It the results are shown in Table 2.
Effect of composition of the table 2 containing fipronil bisamide and botanical components to rice leaf roller
As seen from Table 2, the fipronil bisamide Chinese azalea extract with terpenes, coriamyrtin, Celastrus angulatus, Deoxypodophyllotoxin respectively
The rotenone of toxin and flavonoids, chamaejasmine, the composition of pterocarpin, theoretical effect is above to the actual effect of rice leaf roller
Fruit, show obvious synergistic function.
Effect of composition of the embodiment 3 containing fipronil bisamide and botanical components to Apple Pests
According to scheme, built agent and single dose are prepared, and carry out activity preliminary experiment.According to activity test determination trial, by preparation
It is configured to the concentration needed.Before experiment, cell, listed, investigation apple skin worm radix are set, and set corresponding single dose and blank pair
According to using manual sprayer routine conventional spray.3d investigates effect of the medicament to apple skin worm after medicine.It is public according to embodiment 2
Formula is calculated and counted, and the results are shown in Table 3.
Field efficacy of composition of the table 3 containing fipronil bisamide to Apple Pests
As seen from Table 3, the trifoliate jewelvine of the fipronil bisamide Chinese azalea extract with terpenes, Deoxypodophyllotoxin and flavonoids respectively
Ketone, chamaejasmine, the composition of pterocarpin, it is notable to the preventive effect of apple skin worm, and theory is above to the actual effect of insect
Effect, composition show obvious synergistic function.
Claims (4)
1. the agriculturally useful compositions containing fipronil bisamide and botanical components, component A and component B of the said composition containing effective dose,
Component A is fipronil bisamide, and component B is botanical components, and botanical components are one kind or two kinds of active components in terpenes,
Terpenes are Chinese azalea extract, coriamyrtin, the Celastrus angulatus of Celastraceae plant of Coriariaceae plant in Ericaceae, and fluorine worm is double
The quality parts ratio 8 of acid amides and Chinese azalea extract or coriamyrtin:1-1:10, the quality parts ratio of fipronil bisamide and Celastrus angulatus
8:1-1:5。
It is total that 2. agriculturally useful compositions according to claim 1, fipronil bisamide and botanical components quality sum account for composition
The percentage of quality is 0.05-90%, and composition is processed to wettable powder, water dispersible granules, aqueous emulsion, microemulsion or outstanding
Floating agent.
3. the application method of the composition described in claim 2, composition is applied to base manure, spraying, pouring root, seed dressing, dipping
Crop.
4. the composition described in claim 3 is used for the purposes for preventing and treating plant pest.
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| CN201410743482.XA CN104521967B (en) | 2014-12-08 | 2014-12-08 | Agriculturally useful compositions and application containing fipronil bisamide and botanical components |
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| CN105104441A (en) * | 2015-09-17 | 2015-12-02 | 广西天峨五福种业有限公司 | Botanical pesticide composition with matrine and eupatorium adenophorum spreng |
| CN105340994A (en) * | 2015-10-09 | 2016-02-24 | 南宁源广农业科技有限公司 | Vegetable pesticide and preparation method thereof |
| CN105410078A (en) * | 2015-11-18 | 2016-03-23 | 无锡市稼宝药业有限公司 | Botanical fungicide for basal stem rot |
| CN105340924A (en) * | 2015-12-16 | 2016-02-24 | 济南昊泽环保科技有限公司 | Insecticide composition containing o-phenylenediamine pesticide and sophocarpidine |
| CN105994423A (en) * | 2016-05-23 | 2016-10-12 | 河南红东方化工股份有限公司 | Preparation process of organic pesticide |
| CN106172384A (en) * | 2016-06-08 | 2016-12-07 | 韩立 | A kind of podophyllotoxin micro-emulsion insecticide |
| CN106417306B (en) * | 2016-09-12 | 2019-04-19 | 广西南宁乐蕊生物科技有限责任公司 | A kind of Pesticidal combination containing Celastrus angulatus and Tolfenpyrad |
| CN106857153A (en) * | 2017-02-27 | 2017-06-20 | 昆明浙东农业种植有限公司 | Prevent the implantation methods of apple tree root rot |
| CN107372686A (en) * | 2017-06-01 | 2017-11-24 | 磐安县派普特生物科技有限公司 | A kind of natural insecticide for preventing ginkgo insect pest and its application |
| CN107306976A (en) * | 2017-06-22 | 2017-11-03 | 北京清源保生物科技有限公司 | A kind of Pesticidal combination containing matrine and bromine worm fluorobenzene bisamide and its application |
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| "植物源杀虫剂的研究开发进展";卢继荣 等;《西北林学院学报》;20040830;第19卷(第3期);第109-112页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104521967B (en) | 2017-06-30 |
| CN104521967A (en) | 2015-04-22 |
| CN105594772A (en) | 2016-05-25 |
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Denomination of invention: Agricultural composition containing flubendiamide and terpene botanical component and application thereof Effective date of registration: 20190215 Granted publication date: 20180102 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2019460000001 |
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Address after: Fuchang Village, Laocheng Development Zone, Chengmai County, Hainan Province, 571923 Patentee after: Hainan Zhengye Biotechnology Co.,Ltd. Address before: 571924 Fuchang village, Laocheng Development Zone, Chengmai County, Hainan Province Patentee before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |
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