CN104480455A - 一种通过多巴胺制备各向异性导电胶膜用聚合物导电微球的方法 - Google Patents
一种通过多巴胺制备各向异性导电胶膜用聚合物导电微球的方法 Download PDFInfo
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- CN104480455A CN104480455A CN201410584733.4A CN201410584733A CN104480455A CN 104480455 A CN104480455 A CN 104480455A CN 201410584733 A CN201410584733 A CN 201410584733A CN 104480455 A CN104480455 A CN 104480455A
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- gold
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- dopamine
- plated
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Links
- VYFYYTLLBUKUHU-UHFFFAOYSA-N dopamine Chemical compound NCCC1=CC=C(O)C(O)=C1 VYFYYTLLBUKUHU-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 32
- 229960003638 dopamine Drugs 0.000 title claims abstract description 16
- 239000004005 microsphere Substances 0.000 title abstract description 61
- 229920000642 polymer Polymers 0.000 title abstract description 9
- 239000002313 adhesive film Substances 0.000 title abstract 3
- 239000010931 gold Substances 0.000 claims abstract description 70
- 229910052737 gold Inorganic materials 0.000 claims abstract description 69
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000011159 matrix material Substances 0.000 claims abstract description 49
- 238000007747 plating Methods 0.000 claims abstract description 41
- 239000007788 liquid Substances 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920001690 polydopamine Polymers 0.000 claims abstract description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004793 Polystyrene Substances 0.000 claims description 72
- 229920002223 polystyrene Polymers 0.000 claims description 69
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000004593 Epoxy Substances 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 150000002148 esters Chemical class 0.000 claims description 21
- 238000013019 agitation Methods 0.000 claims description 20
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000003822 epoxy resin Substances 0.000 claims description 16
- 229920000647 polyepoxide Polymers 0.000 claims description 16
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 claims description 15
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 238000009413 insulation Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- 230000008021 deposition Effects 0.000 claims description 12
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 229910021505 gold(III) hydroxide Inorganic materials 0.000 claims description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 6
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 6
- 235000019800 disodium phosphate Nutrition 0.000 claims description 6
- 239000008280 blood Substances 0.000 claims description 5
- 210000004369 blood Anatomy 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 5
- 150000002343 gold Chemical class 0.000 claims description 5
- 229910001112 rose gold Inorganic materials 0.000 claims description 5
- 239000007769 metal material Substances 0.000 claims description 4
- 239000002322 conducting polymer Substances 0.000 claims description 3
- 229920001940 conductive polymer Polymers 0.000 claims description 3
- 239000002861 polymer material Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 abstract description 18
- 230000008569 process Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 6
- 238000007731 hot pressing Methods 0.000 abstract description 6
- 125000003700 epoxy group Chemical group 0.000 abstract description 4
- 238000005886 esterification reaction Methods 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 238000000151 deposition Methods 0.000 description 14
- 239000012153 distilled water Substances 0.000 description 12
- 238000001291 vacuum drying Methods 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 10
- 239000002184 metal Substances 0.000 description 9
- 238000000967 suction filtration Methods 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000011859 microparticle Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 229960004502 levodopa Drugs 0.000 description 2
- -1 poly-DOPA amine Chemical class 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 230000002110 toxicologic effect Effects 0.000 description 2
- 231100000027 toxicology Toxicity 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 208000036142 Viral infection Diseases 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000011246 composite particle Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229920006334 epoxy coating Polymers 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/42—Coating with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
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CN201410584733.4A CN104480455B (zh) | 2014-10-26 | 2014-10-26 | 一种通过多巴胺制备各向异性导电胶膜用聚合物导电微球的方法 |
Applications Claiming Priority (1)
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CN201410584733.4A CN104480455B (zh) | 2014-10-26 | 2014-10-26 | 一种通过多巴胺制备各向异性导电胶膜用聚合物导电微球的方法 |
Publications (2)
Publication Number | Publication Date |
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CN104480455A true CN104480455A (zh) | 2015-04-01 |
CN104480455B CN104480455B (zh) | 2017-04-05 |
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CN201410584733.4A Active CN104480455B (zh) | 2014-10-26 | 2014-10-26 | 一种通过多巴胺制备各向异性导电胶膜用聚合物导电微球的方法 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105671525A (zh) * | 2016-01-27 | 2016-06-15 | 西南大学 | 一种基于聚多巴胺的制备图案化金属薄膜的方法及其产品 |
CN106011809A (zh) * | 2016-04-25 | 2016-10-12 | 北京化工大学 | 一种通过邻苯二酚-多胺制备表面包覆银的复合材料的方法 |
CN107227120A (zh) * | 2017-07-20 | 2017-10-03 | 海宁卓泰电子材料有限公司 | 一种电磁屏蔽膜及其制备方法 |
CN108461172A (zh) * | 2018-02-22 | 2018-08-28 | 南方科技大学 | 一种导电粒子及其制备方法和用途 |
CN108962438A (zh) * | 2018-07-26 | 2018-12-07 | 深圳市华星光电技术有限公司 | 一种导电球及其制作方法、液晶显示装置 |
CN117551273A (zh) * | 2024-01-12 | 2024-02-13 | 深圳先进电子材料国际创新研究院 | 一种用于底部填充胶的功能助剂及其制备方法和应用 |
Citations (6)
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---|---|---|---|---|
CN101724841A (zh) * | 2008-10-10 | 2010-06-09 | 北京化工大学 | 一种通过多巴胺沉积制备聚合物/银复合膜的方法 |
CN101812678A (zh) * | 2010-03-05 | 2010-08-25 | 北京化工大学 | 一种通过多巴胺制备表面包覆银的复合材料的方法 |
CN102352495A (zh) * | 2011-06-16 | 2012-02-15 | 东华大学 | 一种单分散性高性能导电金球的制备方法 |
CN102658071A (zh) * | 2012-05-16 | 2012-09-12 | 东华大学 | 一种用于各向异性导电胶膜的导电金球的制备方法 |
CN103276379A (zh) * | 2013-05-29 | 2013-09-04 | 北京化工大学 | 一种通过多巴胺制备表面镀银电纺纤维的方法 |
CN103665770A (zh) * | 2013-12-11 | 2014-03-26 | 复旦大学 | 金属聚合物复合材料的制备方法 |
-
2014
- 2014-10-26 CN CN201410584733.4A patent/CN104480455B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101724841A (zh) * | 2008-10-10 | 2010-06-09 | 北京化工大学 | 一种通过多巴胺沉积制备聚合物/银复合膜的方法 |
CN101812678A (zh) * | 2010-03-05 | 2010-08-25 | 北京化工大学 | 一种通过多巴胺制备表面包覆银的复合材料的方法 |
CN102352495A (zh) * | 2011-06-16 | 2012-02-15 | 东华大学 | 一种单分散性高性能导电金球的制备方法 |
CN102658071A (zh) * | 2012-05-16 | 2012-09-12 | 东华大学 | 一种用于各向异性导电胶膜的导电金球的制备方法 |
CN103276379A (zh) * | 2013-05-29 | 2013-09-04 | 北京化工大学 | 一种通过多巴胺制备表面镀银电纺纤维的方法 |
CN103665770A (zh) * | 2013-12-11 | 2014-03-26 | 复旦大学 | 金属聚合物复合材料的制备方法 |
Non-Patent Citations (1)
Title |
---|
Y.C.LIN ET.AL.: "A review of the influencing factors on anisotropic conductive adhesives joining technology in electrical applications", 《JOURNAL OF MATERIALS SCIENCE》 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105671525A (zh) * | 2016-01-27 | 2016-06-15 | 西南大学 | 一种基于聚多巴胺的制备图案化金属薄膜的方法及其产品 |
CN105671525B (zh) * | 2016-01-27 | 2018-08-10 | 西南大学 | 一种基于聚多巴胺的制备图案化金属薄膜的方法及其产品 |
CN106011809A (zh) * | 2016-04-25 | 2016-10-12 | 北京化工大学 | 一种通过邻苯二酚-多胺制备表面包覆银的复合材料的方法 |
CN107227120A (zh) * | 2017-07-20 | 2017-10-03 | 海宁卓泰电子材料有限公司 | 一种电磁屏蔽膜及其制备方法 |
CN108461172A (zh) * | 2018-02-22 | 2018-08-28 | 南方科技大学 | 一种导电粒子及其制备方法和用途 |
CN108461172B (zh) * | 2018-02-22 | 2020-06-30 | 南方科技大学 | 一种导电粒子及其制备方法和用途 |
CN108962438A (zh) * | 2018-07-26 | 2018-12-07 | 深圳市华星光电技术有限公司 | 一种导电球及其制作方法、液晶显示装置 |
CN117551273A (zh) * | 2024-01-12 | 2024-02-13 | 深圳先进电子材料国际创新研究院 | 一种用于底部填充胶的功能助剂及其制备方法和应用 |
CN117551273B (zh) * | 2024-01-12 | 2024-04-05 | 深圳先进电子材料国际创新研究院 | 一种用于底部填充胶的功能助剂及其制备方法和应用 |
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