CN104403249A - 一种抗菌性高吸水树脂的制备方法 - Google Patents
一种抗菌性高吸水树脂的制备方法 Download PDFInfo
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- CN104403249A CN104403249A CN201410658347.5A CN201410658347A CN104403249A CN 104403249 A CN104403249 A CN 104403249A CN 201410658347 A CN201410658347 A CN 201410658347A CN 104403249 A CN104403249 A CN 104403249A
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- antibacterial
- germ resistance
- silicon dioxide
- high hydrophilous
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- 239000011347 resin Substances 0.000 title claims abstract description 37
- 229920005989 resin Polymers 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 12
- 239000002250 absorbent Substances 0.000 title abstract 5
- 230000002745 absorbent Effects 0.000 title abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 42
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000002245 particle Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003999 initiator Substances 0.000 claims abstract description 19
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 18
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 18
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 14
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 7
- 239000004599 antimicrobial Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000084 colloidal system Substances 0.000 claims description 6
- 238000006392 deoxygenation reaction Methods 0.000 claims description 6
- 238000013467 fragmentation Methods 0.000 claims description 6
- 238000006062 fragmentation reaction Methods 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 6
- 230000003179 granulation Effects 0.000 claims description 6
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- 229960005070 ascorbic acid Drugs 0.000 claims description 3
- -1 poly(oxyethylene glycol) Polymers 0.000 claims description 3
- 239000000178 monomer Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 230000001954 sterilising effect Effects 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 239000012467 final product Substances 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002504 physiological saline solution Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN201410658347.5A CN104403249B (zh) | 2014-11-19 | 2014-11-19 | 一种抗菌性高吸水树脂的制备方法 |
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CN201410658347.5A CN104403249B (zh) | 2014-11-19 | 2014-11-19 | 一种抗菌性高吸水树脂的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104403249A true CN104403249A (zh) | 2015-03-11 |
CN104403249B CN104403249B (zh) | 2016-11-23 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105348552A (zh) * | 2015-11-16 | 2016-02-24 | 公安部第一研究所 | 抗菌防霉高分子蓄冷材料及其制备方法 |
CN105924567A (zh) * | 2016-07-07 | 2016-09-07 | 中国地质科学院郑州矿产综合利用研究所 | 一种纸尿裤用吸收树脂及其制备方法 |
CN113929166A (zh) * | 2021-09-08 | 2022-01-14 | 五池(珠海)日化科技有限公司 | 一种可凝固废液的抑菌除臭剂及其制备方法和应用 |
CN114080426A (zh) * | 2019-07-05 | 2022-02-22 | 住友精化株式会社 | 颗粒状吸水性树脂组合物 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1587289A (zh) * | 2004-07-09 | 2005-03-02 | 浙江大学 | 一种高吸水树脂的制备方法 |
CN102516443A (zh) * | 2011-12-15 | 2012-06-27 | 东营市诺尔化工有限责任公司 | 一种高吸水树脂的制备方法 |
CN102702656A (zh) * | 2012-07-05 | 2012-10-03 | 东营市诺尔化工有限责任公司 | 一种高通液性吸水树脂的制备方法 |
-
2014
- 2014-11-19 CN CN201410658347.5A patent/CN104403249B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1587289A (zh) * | 2004-07-09 | 2005-03-02 | 浙江大学 | 一种高吸水树脂的制备方法 |
CN102516443A (zh) * | 2011-12-15 | 2012-06-27 | 东营市诺尔化工有限责任公司 | 一种高吸水树脂的制备方法 |
CN102702656A (zh) * | 2012-07-05 | 2012-10-03 | 东营市诺尔化工有限责任公司 | 一种高通液性吸水树脂的制备方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105348552A (zh) * | 2015-11-16 | 2016-02-24 | 公安部第一研究所 | 抗菌防霉高分子蓄冷材料及其制备方法 |
CN105348552B (zh) * | 2015-11-16 | 2018-07-24 | 公安部第一研究所 | 抗菌防霉高分子蓄冷材料及其制备方法 |
CN105924567A (zh) * | 2016-07-07 | 2016-09-07 | 中国地质科学院郑州矿产综合利用研究所 | 一种纸尿裤用吸收树脂及其制备方法 |
CN114080426A (zh) * | 2019-07-05 | 2022-02-22 | 住友精化株式会社 | 颗粒状吸水性树脂组合物 |
CN113929166A (zh) * | 2021-09-08 | 2022-01-14 | 五池(珠海)日化科技有限公司 | 一种可凝固废液的抑菌除臭剂及其制备方法和应用 |
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CN104403249B (zh) | 2016-11-23 |
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