CN104395365B - 一种制备不对称型的、星形‑支链乙烯基芳香族‑二烯嵌段共聚物的方法 - Google Patents

一种制备不对称型的、星形‑支链乙烯基芳香族‑二烯嵌段共聚物的方法 Download PDF

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Publication number
CN104395365B
CN104395365B CN201380034521.2A CN201380034521A CN104395365B CN 104395365 B CN104395365 B CN 104395365B CN 201380034521 A CN201380034521 A CN 201380034521A CN 104395365 B CN104395365 B CN 104395365B
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China
Prior art keywords
block
vinyl aromatic
diene
copolymer
mol
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Expired - Fee Related
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CN201380034521.2A
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English (en)
Chinese (zh)
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CN104395365A (zh
Inventor
康拉德·诺尔
乌尔瑞克·但丁
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Ineos Styrolution Ludwigshafen GmbH
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Styrolution GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201380034521.2A 2012-06-29 2013-06-24 一种制备不对称型的、星形‑支链乙烯基芳香族‑二烯嵌段共聚物的方法 Expired - Fee Related CN104395365B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12174394.2 2012-06-29
EP12174394 2012-06-29
PCT/EP2013/063096 WO2014001233A1 (de) 2012-06-29 2013-06-24 Verfahren zur herstellung von unsymmetrisch aufgebauten, sternförmig verzweigten vinylaromat - dien- blockcopolymeren

Publications (2)

Publication Number Publication Date
CN104395365A CN104395365A (zh) 2015-03-04
CN104395365B true CN104395365B (zh) 2017-01-18

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CN201380034521.2A Expired - Fee Related CN104395365B (zh) 2012-06-29 2013-06-24 一种制备不对称型的、星形‑支链乙烯基芳香族‑二烯嵌段共聚物的方法

Country Status (7)

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US (1) US9650464B2 (enExample)
EP (1) EP2867267B1 (enExample)
JP (1) JP6228974B2 (enExample)
KR (1) KR102062938B1 (enExample)
CN (1) CN104395365B (enExample)
SG (1) SG11201408572PA (enExample)
WO (1) WO2014001233A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3068837B1 (en) 2013-11-11 2019-06-26 INEOS Styrolution Group GmbH Blends of styrene butadiene copolymers with poly(lactic acid)
US10072144B2 (en) 2014-02-10 2018-09-11 Ineos Styrolution Group Gmbh Use of styrene methyl methacrylate copolymers (SMMA) as compatibilizing agents
MX2019006344A (es) * 2016-12-23 2019-11-07 Ineos Styrolution Group Gmbh Composiciones de polimeros para peliculas de envoltura retractil.
US11326014B2 (en) 2017-06-19 2022-05-10 Ineos Styrolution Group Gmbh Vinyl aromatic/diene-block copolymers having good organoleptic properties

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091053A (en) * 1976-06-24 1978-05-23 Phillips Petroleum Company Coupled resinous diene copolymer with good integral hinge flex life and high hardness
EP0718330A1 (en) * 1994-12-23 1996-06-26 Shell Internationale Researchmaatschappij B.V. Process for manufacturing multiarmed asymmetrical radial block copolymers
US5554690A (en) * 1994-11-09 1996-09-10 Shell Oil Company Low viscosity adhesive compositions containing asymmetric radial polymers

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3639517A (en) 1969-09-22 1972-02-01 Phillips Petroleum Co Resinous branched block copolymers
DE3738748A1 (de) 1987-11-14 1989-05-24 Basf Ag Verfahren zur diskontinuierlichen herstellung von unsymmetrisch aufgebauten, sternfoermig verzweigten blockcopolymerisaten und ihre verwendung
MX9505304A (es) * 1994-12-23 1997-01-31 Shell Int Research Proceso para la fabricacion de copolimeros de bloque, radiales, asimetricos, de varios brazos.
DE19914075A1 (de) * 1999-03-27 2000-09-28 Basf Ag Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren
AU2003250340A1 (en) * 2002-06-04 2003-12-19 Kraton Polymers Research B.V. Process for making a coupled block copolymer composition and the resulting composition
KR20150022872A (ko) * 2012-06-26 2015-03-04 스티롤루션 유럽 게엠베하 비닐 방향족 중합체, 및 비닐 방향족-디엔 블록 공중합체의 제조 방법

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091053A (en) * 1976-06-24 1978-05-23 Phillips Petroleum Company Coupled resinous diene copolymer with good integral hinge flex life and high hardness
US5554690A (en) * 1994-11-09 1996-09-10 Shell Oil Company Low viscosity adhesive compositions containing asymmetric radial polymers
EP0718330A1 (en) * 1994-12-23 1996-06-26 Shell Internationale Researchmaatschappij B.V. Process for manufacturing multiarmed asymmetrical radial block copolymers

Also Published As

Publication number Publication date
US9650464B2 (en) 2017-05-16
JP6228974B2 (ja) 2017-11-08
SG11201408572PA (en) 2015-02-27
EP2867267A1 (de) 2015-05-06
US20150183917A1 (en) 2015-07-02
WO2014001233A1 (de) 2014-01-03
JP2015521680A (ja) 2015-07-30
KR20150035755A (ko) 2015-04-07
CN104395365A (zh) 2015-03-04
KR102062938B1 (ko) 2020-01-06
EP2867267B1 (de) 2016-08-31

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