CN104387662A - 一种低成本耐刮擦pp/pet合金材料及其制备方法 - Google Patents
一种低成本耐刮擦pp/pet合金材料及其制备方法 Download PDFInfo
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- CN104387662A CN104387662A CN201410605777.0A CN201410605777A CN104387662A CN 104387662 A CN104387662 A CN 104387662A CN 201410605777 A CN201410605777 A CN 201410605777A CN 104387662 A CN104387662 A CN 104387662A
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- pet
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- pet alloy
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- 239000005020 polyethylene terephthalate Substances 0.000 title abstract 8
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- 239000000463 material Substances 0.000 claims abstract description 23
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- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
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- 239000004743 Polypropylene Substances 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 13
- 239000000865 liniment Substances 0.000 claims description 7
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- 150000001408 amides Chemical class 0.000 claims description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N 10294-56-1 Chemical class 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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products 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OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- SMYKVLBUSSNXMV-UHFFFAOYSA-J aluminum;tetrahydroxide Chemical compound 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[OH-].[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-J 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000005712 crystallization Effects 0.000 claims description 2
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 claims description 2
- 239000008188 pellet Substances 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-M stearate Chemical compound 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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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Abstract
本发明公开了一种低成本耐刮擦PP/PET合金材料及其制备方法，它包括以下重量百分比计的原料：PP 50-70％；PET 10-30％；相容剂1-5％；SR-100 0.5-1％；硅灰石5-20％；滑石粉5-20％；润滑剂0.1-0.5％；抗氧剂0.2-0.6％；偶联剂0.2-0.5％。按重量百分比称取原料；加入高速搅拌机中充分混合均匀；混合完全后通过计量的送料装置将物料送入双螺杆挤出机中，各区温度为170-240℃，物料在螺杆的剪切、混炼和输送下充分熔合，最后经过挤出、拉条、冷却后制成粒料。本发明通过PET的刚性分子链结构来提高PP的表面硬度，相容剂的加入使得PET与PP良好的相容，均匀的分布在PP分子链之间提高材料的耐刮擦性能，同时PET树脂价格低廉，大幅度的降低了成本；通过新型耐刮擦剂SR-100提高了材料表面的爽滑性，提高材料的耐刮擦性。
Description
技术领域
[0001] 本发明涉及一种低成本耐刮擦PP/PET合金材料，以及这种合金材料的制备方法， 属于改性塑料技术领域。
背景技术
[0002] 聚丙烯类树脂不仅质量轻、价格相对低廉，并且还具有良好的耐化学腐蚀性、耐热 性，及均衡的机械力学性能和优良的可加工性，因此被广泛应用于家电、汽车、电子电器等 领域，在日益激烈的市场竞争中，PP类树脂正逐步取代一些价格较高的通用塑料。然而，随 着社会的发展和人们生活品质的提高，对使用的材料也提出了越来越高的要求，PP类树脂 由于分子链较为柔软，表面硬度低、耐刮擦性差，在一定程度上限制了其应用的范围。
[0003] 目前，提高PP类树脂耐刮擦性的最常用的方法，就是在其中填充无机填料和一些 小分子的耐刮擦剂（如酰胺类，改性硅氧烷类助剂），但这种方法在提高PP类树脂的耐刮擦 性后，，会使注塑件表面会因助剂迁移产生油纹，老化测试后表面发粘，且添加量较大。现有 助剂价格较贵，成本高，换而言之，这类方法无法提高PP类树脂的耐刮擦性、。因此，目前市 场急需开发一种加工方便、操作简单且性能均衡的低成本耐刮擦PP类树脂。
发明内容
[0004] 本发明的目的是为了提供一种加工方便、操作简单且性能均衡的低成本耐刮擦 PP/PET合金材料，以解决现有技术的上述问题。
[0005] 本发明的另一个目的是提供上述树脂的制备方法。
[0006] 本发明的目的是通过以下技术方案来实现。
[0007] -种低成本耐刮擦PP/PET合金材料，包括以下重量百分比计的原料：
[0008]
[0009] 上述PP/PET合金材料体系中，
[0010] 所述的PP树脂为均聚PP、共聚PP和高结晶PP中的一种或两种以上的混合物。
[0011] 所述的PET树脂的粘度0• 6-0. 8dl/g，优选为仪征化纤的SB-500。
[0012] 所述相容剂为马来酸酐接枝聚丙烯材料，优选为沈阳科通KT-1或上海日之升 9801 ；
[0013] 所述的SR-100为新型汽巴耐刮擦剂。
[0014] 所述的硅灰石为具有长径比在1:6-1:20之间，目数为3000-5000目。
[0015] 所述的滑石粉为目数1250-2000目之间。
[0016] 所述的润滑剂为硬脂酸盐和酰胺类润滑剂的一种或几种的混合物；
[0017] 所述的抗氧剂为受阻酚类主抗氧剂和亚磷酸酯类辅抗氧剂的混合物。
[0018] 所述偶联剂为硅烷偶联剂、铝酸酯偶联剂和钛酸酯偶联剂中的一种或几种的混合 物。
[0019] 上述低成本耐刮擦PP/PET合金材料的制备方法，包括如下步骤：
[0020] 1)按重量百分比称取原料；
[0021] 2)加入高速搅拌机中充分混合均匀；混合完全后通过计量的送料装置将物料送 入双螺杆挤出机中，各区温度为170-240°C，物料在螺杆的剪切、混炼和输送下充分熔合，最 后经过挤出、拉条、冷却后制成粒料。
[0022] 本发明通过PET与PP合金，PET的刚性分子链结构来提高PP的表面硬度，相容剂 的加入使得PET与PP良好的相容，均匀的分布在PP分子链之间提高材料的耐刮擦性能，同 时PET树脂价格低廉，大幅度的降低了成本；本发明通过新型耐刮擦剂SR-100提高了材料 表面的爽滑性，提高材料的耐刮擦性，而且相比于现有的刮擦剂不迁移至材料表面；本发明 通过长径比为1:6-1:20,目数为3000-5000的硅灰石和目数1250-2000目的滑石粉这种粗 细不一的填充体系，不但提高材料表面硬度，而且减小了刮擦时抬肩的程度，减小了光的散 射，使得△ L值明显减小，提高材料的耐刮擦性，同时硅灰石与滑石粉价格低廉，大幅度降
低了材料的成本。
具体实施方式
[0023] 下面结合具体实施例进一步阐述本发明的技术方案。
[0024] 实施例 1-5 :
[0025] 先将PET树脂烘干，再将PP、相容剂、耐刮擦剂、硅灰石、滑石粉、润滑剂、抗氧剂、 偶联剂加入高速混合机中混合5-10min，后将烘干的PET倒入高速混合机中，同PP、相容剂、 耐刮擦剂、硅灰石、滑石粉、润滑剂、抗氧剂、偶联剂一起混合5-10min，混料机采用中低速混 合，混料机的转速为150rpm，搅拌叶与桶壁间隙小于0. 5厘米，在混料机中混合均匀得到混 合物料，混合均匀的效果为目视各种粒子和粉末基本均匀，没有明显的团块和集聚；
[0026] 将混合物料从主喂料口加入到双螺杆挤出机中，双螺杆挤出机中螺杆长径比 为40 :1，主机螺杆转速450rpm，双螺杆挤出机中从进料段到机头的各反应段温度分别为 200°C、220°C、230°C、220°C、210°C、210°C、200°C、190°C，模头温度为 220°C，经双螺杆挤出 机熔融挤出，然后采用水冷拉条切粒方式，再经过筛分脱水即制得低成本耐刮擦PP/PET合 金材料。
[0027] 将实施例1-7制备的一种低成本耐刮擦PP/PET合金材料在220°C〜240°C注塑成 型温度下注塑得到测试样条，测试样条的相关性能测试和测试方法详见下表。
[0028] 表1 PET含量对体系耐刮性的影响
[0029]
[0030] 表2试验测试数据
[0031]
[0032] A L数值为现刮擦性能测试中体现的白度变化的数值，A L越小说明刮擦性能越 好。
[0033] 数据显示，当PET含量从0升至30时，材料的A L值也从0. 9降至0. 6,耐刮擦性 显著提高，表明体系中PET刚性链的引入的确对材料的耐刮擦性有显著改善。同时材料成 本降低。
[0034] 表3助剂及填充对体系耐刮性的影响
[0035]
[0036] 表4各组的试验数据
[0037]
[0038] A L数值为现刮擦性能测试中体现的白度变化的数值，A L越小说明刮擦性能越 好。
[0039] 数据表明，实施例3和5通过改变SR-100的用量来比较体系的耐摩擦性，当 SR-100含量为1%时，体系的耐刮擦性较为优异。实施例6和7通过进行单一填充组分试 验与实施例3作对比，试验数据表明，单一的填充组分并不利于体系的耐刮性，同时对体系 的机械性能也有不利影响。不同的长径比和细度的TALC和硅灰石填充体系，能显著改善材 料的表面硬度，减小A L值。
Claims (11)
1. 一种低成本耐刮擦PP/PET合金材料，其特征在于：包括以下重量百分比计的原料：
2. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述的PP树 脂为均聚PP、共聚PP和高结晶PP中的一种或两种以上的混合物。
3. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述的PET树 脂的粘度〇.6-〇.8dl/g。
4. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述相容剂为 马来酸酐接枝聚丙烯材料。
5. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述的SR-IOO 为新型汽巴耐刮擦剂。
6. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述的硅灰石 的长径比在1:6-1:20之间，目数为3000-5000目。
7. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述的滑石粉 为目数1250-2000目之间。
8. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述的润滑剂 为硬脂酸盐和酰胺类润滑剂的一种或几种的混合物；
9. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述的抗氧剂 为受阻酚类主抗氧剂和亚磷酸酯类辅抗氧剂的混合物。
10. 根据权利要求1所述的低成本耐刮擦PP/PET合金材料，其特征在于：所述偶联剂 为硅烷偶联剂、铝酸酯偶联剂和钛酸酯偶联剂中的一种或几种的混合物。
11. 权利要求1-10中任意之一所述低成本耐刮擦PP/PET合金材料的制备方法，其特征 在于：包括如下步骤： 1) 按重量百分比称取原料； 2) 加入高速搅拌机中充分混合均匀；混合完全后通过计量的送料装置将物料送入双 螺杆挤出机中，各区温度为170-240°C，物料在螺杆的剪切、混炼和输送下充分熔合，最后经 过挤出、拉条、冷却后制成粒料。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647012A (zh) * | 2016-03-09 | 2016-06-08 | 苏州莱特复合材料有限公司 | 一种pp和pet合金及其制备方法 |
| CN108641198A (zh) * | 2018-05-25 | 2018-10-12 | 宁波星陆汽车部件有限公司 | 改性高熔融流动轮罩的制备工艺 |
| CN110527263A (zh) * | 2019-09-18 | 2019-12-03 | 合肥市和裕达塑业有限公司 | 一种高耐刮擦物理发泡挤出pet与pp复合材料及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181093A (zh) * | 2011-03-31 | 2011-09-14 | 江苏金发科技新材料有限公司 | 一种抗刮伤聚丙烯复合材料及其制备方法 |
| CN102382362A (zh) * | 2010-08-30 | 2012-03-21 | 比亚迪股份有限公司 | 一种耐刮擦材料组合物和耐刮擦材料及其制备方法 |
| CN102532697A (zh) * | 2010-12-30 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | 一种高韧性低气味耐刮擦聚丙烯组合物及其制备方法 |
| CN103387710A (zh) * | 2012-05-08 | 2013-11-13 | 合肥杰事杰新材料股份有限公司 | 一种聚丙烯/聚酯合金材料及其制备方法和应用 |
| CN103524976A (zh) * | 2013-10-29 | 2014-01-22 | 上海延锋江森座椅有限公司 | 高强度耐刮擦聚丙烯改性树脂 |
| CN103709674A (zh) * | 2012-09-30 | 2014-04-09 | 青岛欣展塑胶有限公司 | 一种pet/pp合金材料及其制备方法 |
-
2014
- 2014-10-31 CN CN201410605777.0A patent/CN104387662A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382362A (zh) * | 2010-08-30 | 2012-03-21 | 比亚迪股份有限公司 | 一种耐刮擦材料组合物和耐刮擦材料及其制备方法 |
| CN102532697A (zh) * | 2010-12-30 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | 一种高韧性低气味耐刮擦聚丙烯组合物及其制备方法 |
| CN102181093A (zh) * | 2011-03-31 | 2011-09-14 | 江苏金发科技新材料有限公司 | 一种抗刮伤聚丙烯复合材料及其制备方法 |
| CN103387710A (zh) * | 2012-05-08 | 2013-11-13 | 合肥杰事杰新材料股份有限公司 | 一种聚丙烯/聚酯合金材料及其制备方法和应用 |
| CN103709674A (zh) * | 2012-09-30 | 2014-04-09 | 青岛欣展塑胶有限公司 | 一种pet/pp合金材料及其制备方法 |
| CN103524976A (zh) * | 2013-10-29 | 2014-01-22 | 上海延锋江森座椅有限公司 | 高强度耐刮擦聚丙烯改性树脂 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647012A (zh) * | 2016-03-09 | 2016-06-08 | 苏州莱特复合材料有限公司 | 一种pp和pet合金及其制备方法 |
| CN108641198A (zh) * | 2018-05-25 | 2018-10-12 | 宁波星陆汽车部件有限公司 | 改性高熔融流动轮罩的制备工艺 |
| CN110527263A (zh) * | 2019-09-18 | 2019-12-03 | 合肥市和裕达塑业有限公司 | 一种高耐刮擦物理发泡挤出pet与pp复合材料及其制备方法 |
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