CN1043568C - 铱为基的溶液的制备方法、所得到的溶液以及该溶液作为催化剂的用途 - Google Patents
铱为基的溶液的制备方法、所得到的溶液以及该溶液作为催化剂的用途 Download PDFInfo
- Publication number
- CN1043568C CN1043568C CN94114097A CN94114097A CN1043568C CN 1043568 C CN1043568 C CN 1043568C CN 94114097 A CN94114097 A CN 94114097A CN 94114097 A CN94114097 A CN 94114097A CN 1043568 C CN1043568 C CN 1043568C
- Authority
- CN
- China
- Prior art keywords
- iridium
- solution
- catalyzer
- reaction
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052741 iridium Inorganic materials 0.000 title claims abstract description 57
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003054 catalyst Substances 0.000 title abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 38
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000007791 liquid phase Substances 0.000 claims abstract description 7
- 229940071870 hydroiodic acid Drugs 0.000 claims description 26
- 239000000376 reactant Substances 0.000 claims description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 12
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 12
- 238000005810 carbonylation reaction Methods 0.000 claims description 11
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 claims description 10
- 229910000457 iridium oxide Inorganic materials 0.000 claims description 10
- 230000036571 hydration Effects 0.000 claims description 9
- 238000006703 hydration reaction Methods 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 150000004820 halides Chemical class 0.000 claims description 5
- IUJMNDNTFMJNEL-UHFFFAOYSA-K iridium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Ir+3] IUJMNDNTFMJNEL-UHFFFAOYSA-K 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000001307 helium Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 51
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 12
- 239000012429 reaction media Substances 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000006698 induction Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- 238000000862 absorption spectrum Methods 0.000 description 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000006315 carbonylation Effects 0.000 description 3
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- -1 carboxylic acid ester compound Chemical class 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000026030 halogenation Effects 0.000 description 2
- 238000005658 halogenation reaction Methods 0.000 description 2
- 238000007037 hydroformylation reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- YIYBQIKDCADOSF-UHFFFAOYSA-N alpha-Butylen-alpha-carbonsaeure Natural products CCC=CC(O)=O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- NICDRCVJGXLKSF-UHFFFAOYSA-N nitric acid;trihydrochloride Chemical compound Cl.Cl.Cl.O[N+]([O-])=O NICDRCVJGXLKSF-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YIYBQIKDCADOSF-ONEGZZNKSA-N trans-pent-2-enoic acid Chemical compound CC\C=C\C(O)=O YIYBQIKDCADOSF-ONEGZZNKSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/468—Iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9314844A FR2713620B1 (fr) | 1993-12-10 | 1993-12-10 | Procédé de préparation d'une solution à base d'iridium, solution obtenue et utilisation de celle-ci en tant que catalyseur. |
| FR9314844 | 1993-12-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1112458A CN1112458A (zh) | 1995-11-29 |
| CN1043568C true CN1043568C (zh) | 1999-06-09 |
Family
ID=9453785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94114097A Expired - Lifetime CN1043568C (zh) | 1993-12-10 | 1994-12-09 | 铱为基的溶液的制备方法、所得到的溶液以及该溶液作为催化剂的用途 |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP0657386B1 (enExample) |
| JP (1) | JP2915309B2 (enExample) |
| KR (1) | KR100348202B1 (enExample) |
| CN (1) | CN1043568C (enExample) |
| BR (1) | BR9404917A (enExample) |
| CA (1) | CA2137537C (enExample) |
| CZ (1) | CZ311794A3 (enExample) |
| DE (1) | DE69410954T2 (enExample) |
| ES (1) | ES2121169T3 (enExample) |
| FR (1) | FR2713620B1 (enExample) |
| PL (1) | PL306197A1 (enExample) |
| RU (1) | RU2137543C1 (enExample) |
| SK (1) | SK152794A3 (enExample) |
| TW (1) | TW272144B (enExample) |
| UA (1) | UA40595C2 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9816385D0 (en) | 1998-07-29 | 1998-09-23 | Bp Chem Int Ltd | Process |
| GB9819079D0 (en) * | 1998-09-03 | 1998-10-28 | Bp Chem Int Ltd | Carbonylation process |
| GB9819606D0 (en) | 1998-09-08 | 1998-11-04 | Bp Chem Int Ltd | Carbonylation process |
| CN106170467B (zh) | 2013-12-24 | 2020-05-12 | 英国石油有限公司 | 通过乙酸甲酯的氢化来生产乙醇的方法 |
| CN112439437B (zh) * | 2019-08-28 | 2023-08-15 | 中国石油化工股份有限公司 | 作为合成醋酸的催化剂的含铱溶液及其制备方法、应用 |
| CN118439666B (zh) * | 2024-03-29 | 2025-11-14 | 华东理工大学 | 一种二维羰基铱材料的制备方法及其应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4918226A (en) * | 1980-08-04 | 1990-04-17 | Exxon Research And Engineering Company | Process for converting formate esters to carboxylic acids |
| CA1239937A (en) * | 1982-04-12 | 1988-08-02 | Exxon Research And Engineering Company | Process for converting olefins to carboxylic acids or esters using soluble iridium compounds |
| FR2675797B1 (fr) * | 1991-04-26 | 1994-10-28 | Rhone Poulenc Chimie | Procede de preparation de l'acide adipique par hydrocarboxylation d'acides penteniques. |
| UA29414C2 (uk) * | 1993-03-31 | 2000-11-15 | Пардіс Асетік | Спосіб одержання карбонових кислот або відповідних складних ефірів |
-
1993
- 1993-12-10 FR FR9314844A patent/FR2713620B1/fr not_active Expired - Fee Related
-
1994
- 1994-12-07 CA CA002137537A patent/CA2137537C/fr not_active Expired - Fee Related
- 1994-12-09 TW TW083111490A patent/TW272144B/zh not_active IP Right Cessation
- 1994-12-09 UA UA94129162A patent/UA40595C2/uk unknown
- 1994-12-09 DE DE69410954T patent/DE69410954T2/de not_active Expired - Lifetime
- 1994-12-09 EP EP94402834A patent/EP0657386B1/fr not_active Expired - Lifetime
- 1994-12-09 ES ES94402834T patent/ES2121169T3/es not_active Expired - Lifetime
- 1994-12-09 SK SK1527-94A patent/SK152794A3/sk unknown
- 1994-12-09 RU RU94043803A patent/RU2137543C1/ru not_active IP Right Cessation
- 1994-12-09 PL PL94306197A patent/PL306197A1/xx unknown
- 1994-12-09 CN CN94114097A patent/CN1043568C/zh not_active Expired - Lifetime
- 1994-12-09 BR BR9404917A patent/BR9404917A/pt not_active Application Discontinuation
- 1994-12-09 CZ CZ943117A patent/CZ311794A3/cs unknown
- 1994-12-10 KR KR1019940033607A patent/KR100348202B1/ko not_active Expired - Lifetime
- 1994-12-12 JP JP6331411A patent/JP2915309B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR9404917A (pt) | 1995-08-08 |
| RU94043803A (ru) | 1996-10-10 |
| CA2137537A1 (fr) | 1995-06-11 |
| UA40595C2 (uk) | 2001-08-15 |
| FR2713620A1 (fr) | 1995-06-16 |
| CZ311794A3 (en) | 1995-11-15 |
| CN1112458A (zh) | 1995-11-29 |
| PL306197A1 (en) | 1995-06-12 |
| EP0657386A1 (fr) | 1995-06-14 |
| RU2137543C1 (ru) | 1999-09-20 |
| TW272144B (enExample) | 1996-03-11 |
| CA2137537C (fr) | 2000-04-25 |
| FR2713620B1 (fr) | 1996-03-01 |
| EP0657386B1 (fr) | 1998-06-10 |
| DE69410954D1 (de) | 1998-07-16 |
| DE69410954T2 (de) | 1999-01-14 |
| JP2915309B2 (ja) | 1999-07-05 |
| JPH07206450A (ja) | 1995-08-08 |
| KR100348202B1 (ko) | 2002-12-11 |
| ES2121169T3 (es) | 1998-11-16 |
| SK152794A3 (en) | 1995-07-11 |
| KR950016869A (ko) | 1995-07-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Applicant after: Hydisaichitic Co. Applicant before: Rhone-Poulenc Chimie |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: RHONE-POULENC CHIMIE TO: HAMILTON WILLIAM J |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CX01 | Expiry of patent term |
Expiration termination date: 20141209 Granted publication date: 19990609 |