CN104351202B - A kind of aqueous emulsion for chrysanthemum - Google Patents

A kind of aqueous emulsion for chrysanthemum Download PDF

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Publication number
CN104351202B
CN104351202B CN201410630498.XA CN201410630498A CN104351202B CN 104351202 B CN104351202 B CN 104351202B CN 201410630498 A CN201410630498 A CN 201410630498A CN 104351202 B CN104351202 B CN 104351202B
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China
Prior art keywords
chrysanthemum
aqueous emulsion
allicin
difenoconazole
effect
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CN201410630498.XA
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Chinese (zh)
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CN104351202A (en
Inventor
孙波
孙倩
穆柯晓
郝爱华
王蒙蒙
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Cui Junhui
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Qingdao Qingzhi Enterprise Management Consulting Co Ltd
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Abstract

The present invention relates to a kind of aqueous emulsion for chrysanthemum, described aqueous emulsion is used for preventing and treating chrysanthemum anthracnose, and active ingredient is Difenoconazole and allicin, and auxiliary agent is white dextrin, polyethylene glycol, silicone oil, styrene polyoxyethylene ether ammonium sulfate salt, ethanol.The present invention has extraordinary prevention effect to chrysanthemum anthracnose, what the present invention utilized Difenoconazole and allicin has preferable synergistic effect to chrysanthemum anthracnose, effectively enhances the prevention to chrysanthemum anthracnose and the effect for the treatment of, instant effect, lasting period is long, on non-Target crops without impact.

Description

A kind of aqueous emulsion for chrysanthemum
Technical field
The present invention relates to a kind of aqueous emulsion for chrysanthemum, be specifically related to a kind of water and milk for preventing and treating chrysanthemum anthracnose Agent, its active ingredient is Difenoconazole and allicin, belongs to technical field of pesticide.
Background technology
Chrysanthemum have diseases prevention, cure the disease, keep healthy, the function such as appreciation, chrysanthemum is used as medicine with a long history in China, have dispelling wind, Heat-clearing, improving eyesight, detoxicating functions, chrysanthemum and preparation thereof can treat headache, dizziness, hot eyes, treatment sore, pyogenic infections, virus flu, high blood The diseases such as pressure, high fat of blood, coronary heart disease, are the health food liked of people and preferable medicine.Meanwhile, chrysanthemum is again that China is large One of medicinal material, is also one of important outlet medicinal material kind.Chrysanthemum morifolium artificial cultivation is the trend of the times of Producing medicinal herbs, The raw-material high-quality of Chinese medicine, safety in production are the premises of the modernization of Chinese medicine.External only Japan, the U.S., Korea S and Southeast Asia Etc. some traditional Chinese medicinal materials assortment of a few countries artificial cultivation, but China's current artificial cultivation traditional Chinese medicinal materials assortment reaches kind more than 300, accounts for me About the 2/3 of more than the 500 kind of parts of generic medicinal plants circulated on state's medicinal material market.Existing more than 600 the Chinese medicine planting base of China, plants Plant area and reach more than 600 ten thousand mu.But in recent years, China mainland Chinese medicine export volume only accounts for about the 10% of global trade amount, mainly Reason is that raw material active ingredient is understable to exceed standard with medicinal material Pesticide Residues or content of beary metal.
Difenoconazole is a kind of pathogen ergosterol biosynthesis inhibitor, acts on wheat in phytopathogen thalline The interruption of angle sterol synthesis, and then show as strong bacteriostasis.This medicament disinfecting spectrum is wide, lasting period length, to sac fungus, half Know that the fungi of bacterium and Basidiomycetes has excellent bacteriostatic activity, go out prevention, treatment and the eradicant action of excellence at variable rate technology; To crop and Environmental security.
Allicin (Allicin) is from the bulb (garlic) of Liliaceae allium garlic (Allium Sativum) A kind of organosulfur compound extracted, exists in onion and other alliums.Formal name used at school GIUCOSinoate. Pale yellow oily liquid body.Boiling point 80-85 DEG C (0.2kPa), relative density 1.112(20/4 DEG C), index of refraction 1.561.It is dissolved in second Alcohol, chloroform or ether.Solubility 2.5% (quality) (10 DEG C) in water, its pH value of water solution is 6.5, has grease to precipitate during standing Thing is formed.Can dissolve each other with ethanol, ether and benzene.Unstable to thermokalite, stable to acid.By the squama being present in liliaceous plant garlic In stem, the garlic aminoacid existed under big allinase effect, convert generation.Exist in the bulb of green onion.There is strong garlic Smelly, taste is peppery.
In the real process of agricultural production, pest control is easiest to generate the problem that the generation of pest resistance to insecticide.No Compound with kind composition, be to prevent and treat the method that resistant insect is the most common.Heterogeneity compounds, according to reality application effect Fruit judge certain compounding be synergy, add and or antagonism.
Summary of the invention
For the problems referred to above, the invention provides a kind of aqueous emulsion for chrysanthemum, the present invention is that one is used for preventing and treating chrysanthemum The aqueous emulsion of flower anthracnose, its active ingredient is Difenoconazole and allicin, and instant effect of the present invention, holding effect are long, to non-target Crop safety.
Technical scheme is as follows:
A kind of aqueous emulsion for chrysanthemum, described aqueous emulsion is used for preventing and treating chrysanthemum anthracnose, and active ingredient is phenyl ether methyl cyclic Azoles and allicin, auxiliary agent is white dextrin, polyethylene glycol, silicone oil, styrene polyoxyethylene ether ammonium sulfate salt, ethanol.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 15%-40%, allicin 0.1%-1%, white dextrin 0.01%-0.1%, polyethylene glycol 3%-8%, silicone oil 0.1%-0.5%, styrene polyoxyethylene ether ammonium sulfate salt 5%-10%, ethanol 2%-7%, deionized water supply 100%.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 20%-35%, allicin 0.1%-1%, white dextrin 0.02%-0.1%, polyethylene glycol 4%-7%, silicone oil 0.2%-0.4%, styrene polyoxyethylene ether ammonium sulfate salt 6%-9%, ethanol 3%-6%, deionized water supply 100%.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 19.5%, allicin 0.5%, white dextrin 0.06%, polyethylene glycol 5%, silicone oil 0.4%, styrene polyoxy Vinethene ammonium sulfate 9%, ethanol 5%, deionized water supply 100%.
Aqueous emulsion of the present invention is morbidity early stage for preventing and treating dispenser period of chrysanthemum anthracnose;Annual spraying times is 1 or 2 Secondary;Active ingredient dosage is 10 grams/ha-50 grams/ha, it is preferred that dosage is 15 grams/ha.
The present invention has the advantage that compared to existing technology
(1) having synergistic effect, sterilization adds protective effect, and its effect is not the simple superposition of each composition activity, but tool There is synergistic effect significantly;
(2) times for spraying is few, and drug cost is low;
(3) generation of resistance is slowed down, good to crop safety, meet the security requirement of pesticidal preparations;
(4) present invention effectively enhances the prevention to chrysanthemum anthracnose and the effect for the treatment of, instant effect, and the lasting period is long, right Non-Target crops is without impact.
Detailed description of the invention
Below in conjunction with specific embodiment further describe the present invention, advantages of the present invention and feature will be with describe and Apparent.But embodiment is only exemplary, the scope of the present invention is not constituted any restriction.Those skilled in the art should It should be appreciated that, the details of technical solution of the present invention and form can be repaiied lower without departing from the spirit and scope of the present invention Change or replace, but these amendments and replacement each fall within protection scope of the present invention.
Embodiment 1
20% Difenoconazole and allicin aqueous emulsion
Each raw material components is by weight percentage:
Difenoconazole 19.5%
Allicin 0.5%
White dextrin 0.06%
Polyethylene glycol 5%
Silicone oil 0.4%
Styrene polyoxyethylene ether ammonium sulfate salt 9%
Ethanol 5%
Deionized water supplies 100%.
By above-mentioned each composition application conventional pesticide process technology, the aqueous emulsion goods being suitable for agriculturally using made.This In embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 286.58.
The aqueous emulsion that the embodiment of the present invention 1 obtains is used for preventing and treating chrysanthemum anthracnose, chrysanthemum anthracnose early stage dispenser, Active ingredient dosage is 15 grams/ha, sprays 2 times, and after secondary medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 87.6%、89.5%、92.4%.25% Difenoconazole missible oil by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, 14 days and The prevention effect of 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua presses 2000 times of spray pesticides 2 times, secondary After medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.After Difenoconazole and allicin compound Synergistic effect is obvious, and the preventive effect of anthracnose is significantly better than single dose.
Embodiment 2
30% Difenoconazole and allicin aqueous emulsion
Each raw material components is by weight percentage:
Difenoconazole 29.9%
Allicin 0.1%
White dextrin 0.03%
Polyethylene glycol 7%
Silicone oil 0.3%
Styrene polyoxyethylene ether ammonium sulfate salt 6%
Ethanol 3%
Deionized water supplies 100%.
By above-mentioned each composition application conventional pesticide process technology, the aqueous emulsion preparation being suitable for agriculturally using made.This In embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 243.54.
The aqueous emulsion that the embodiment of the present invention 2 obtains is used for preventing and treating chrysanthemum anthracnose, chrysanthemum anthracnose early stage dispenser, Active ingredient dosage is 20 grams/ha, sprays 2 times, and after secondary medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 85.1%、86.8%、89.3%.25% Difenoconazole missible oil by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, 14 days and The prevention effect of 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua presses 2000 times of spray pesticides 2 times, secondary After medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.After Difenoconazole and allicin compound Synergistic effect is obvious, and the preventive effect of anthracnose is significantly better than single dose.
Embodiment 3
16% Difenoconazole and allicin aqueous emulsion
Each raw material components is by weight percentage:
Difenoconazole 15%
Allicin 1%
White dextrin 0.1%
Polyethylene glycol 8%
Silicone oil 0.2%
Styrene polyoxyethylene ether ammonium sulfate salt 8%
Ethanol 6%
Deionized water supplies 100%.
By above-mentioned each composition application conventional pesticide process technology, the aqueous emulsion goods being suitable for agriculturally using made.This In embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 187.54.
The aqueous emulsion that the embodiment of the present invention 3 obtains is used for preventing and treating chrysanthemum anthracnose, chrysanthemum anthracnose early stage dispenser, Active ingredient dosage is 10 grams/ha, sprays 2 times, and after secondary medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 83.4%、85.1%、87.2%.25% Difenoconazole missible oil by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, 14 days and The prevention effect of 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua presses 2000 times of spray pesticides 2 times, secondary After medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.After Difenoconazole and allicin compound Synergistic effect is obvious, and the preventive effect of anthracnose is significantly better than single dose.

Claims (1)

1. the aqueous emulsion for chrysanthemum, it is characterised in that in described aqueous emulsion, each raw material components is by weight percentage:
Difenoconazole 19.5%, allicin 0.5%, white dextrin 0.06%, polyethylene glycol 5%, silicone oil 0.4%, styrene are poly- Oxygen vinethene ammonium sulfate 9%, ethanol 5%, deionized water supply 100%;
Described aqueous emulsion is morbidity early stage for preventing and treating dispenser period of chrysanthemum anthracnose;Annual spraying times is 2 times;Dosage It it is 15 grams/ha.
CN201410630498.XA 2014-11-11 2014-11-11 A kind of aqueous emulsion for chrysanthemum Expired - Fee Related CN104351202B (en)

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CN104351202B true CN104351202B (en) 2016-08-24

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102726415A (en) * 2012-06-19 2012-10-17 河南省大地农化有限责任公司 Allicin-containing prevention and treatment pesticide for crop plant diseases
CN102986710A (en) * 2012-12-18 2013-03-27 江苏龙灯化学有限公司 Bactericidal composition containing bellkute and difenoconazole and application of composition
CN103814902A (en) * 2014-01-27 2014-05-28 南京农业大学 Composition containing fludioxonil and difenoconazole and capable of preventing and controlling chrysanthemum disease

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102726415A (en) * 2012-06-19 2012-10-17 河南省大地农化有限责任公司 Allicin-containing prevention and treatment pesticide for crop plant diseases
CN102986710A (en) * 2012-12-18 2013-03-27 江苏龙灯化学有限公司 Bactericidal composition containing bellkute and difenoconazole and application of composition
CN103814902A (en) * 2014-01-27 2014-05-28 南京农业大学 Composition containing fludioxonil and difenoconazole and capable of preventing and controlling chrysanthemum disease

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Inventor after: Cui Junhui

Inventor before: Sun Bo

Inventor before: Sun Qian

Inventor before: Mu Kexiao

Inventor before: Hao Aihua

Inventor before: Wang Mengmeng

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Address after: 300000, Hongqiao District, Tianjin style building No. 4, 3 door 203

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Patentee before: Qingdao Qingzhi Enterprise Management Consulting Co., Ltd.

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Granted publication date: 20160824

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