CN104351196B - A kind of microemulsion for chrysanthemum - Google Patents
A kind of microemulsion for chrysanthemum Download PDFInfo
- Publication number
- CN104351196B CN104351196B CN201410630333.2A CN201410630333A CN104351196B CN 104351196 B CN104351196 B CN 104351196B CN 201410630333 A CN201410630333 A CN 201410630333A CN 104351196 B CN104351196 B CN 104351196B
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- CN
- China
- Prior art keywords
- chrysanthemum
- microemulsion
- allicin
- difenoconazole
- effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000007516 Chrysanthemum Nutrition 0.000 title claims abstract description 27
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 23
- 244000189548 Chrysanthemum x morifolium Species 0.000 title description 20
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 claims abstract description 26
- 235000010081 allicin Nutrition 0.000 claims abstract description 26
- 239000005760 Difenoconazole Substances 0.000 claims abstract description 24
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical group O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims abstract description 24
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical compound C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 claims abstract description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 9
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 9
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 9
- 150000001298 alcohols Chemical class 0.000 claims abstract description 9
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007859 condensation product Substances 0.000 claims abstract description 9
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical group O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 9
- 239000010452 phosphate Substances 0.000 claims abstract description 9
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 9
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 claims abstract description 9
- 241000723353 Chrysanthemum Species 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract description 16
- 230000002265 prevention Effects 0.000 abstract description 14
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract description 10
- 239000004480 active ingredient Substances 0.000 abstract description 9
- 235000011187 glycerol Nutrition 0.000 abstract description 8
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 235000019441 ethanol Nutrition 0.000 abstract description 2
- 239000003814 drug Substances 0.000 description 17
- 239000000575 pesticide Substances 0.000 description 10
- 239000007921 spray Substances 0.000 description 9
- 240000002234 Allium sativum Species 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- -1 phenyl ether methyl cyclic Azoles Chemical class 0.000 description 5
- 235000004611 garlic Nutrition 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 241000234282 Allium Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 235000009604 Chrysanthemum X morifolium Nutrition 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000234280 Liliaceae Species 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 208000029078 coronary artery disease Diseases 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000008686 ergosterol biosynthesis Effects 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Abstract
The present invention relates to a kind of microemulsion for chrysanthemum, described microemulsion is used for preventing and treating chrysanthemum anthracnose, active ingredient is Difenoconazole and allicin, and auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product sodium salt, Nekal BX, N, N dimethylformamide, phenyl phenol polyoxyethanyl ether phosphate, C8‑10Aliphatic alcohols, Arabic gum, glycerine.The present invention has extraordinary prevention effect to chrysanthemum anthracnose, what the present invention utilized Difenoconazole and allicin has preferable synergistic effect to chrysanthemum anthracnose, effectively enhances the prevention to chrysanthemum anthracnose and the effect for the treatment of, instant effect, lasting period is long, on non-Target crops without impact.
Description
Technical field
The present invention relates to a kind of microemulsion for chrysanthemum, be specifically related to a kind of micro emulsion for preventing and treating chrysanthemum anthracnose
Agent, its active ingredient is Difenoconazole and allicin, belongs to technical field of pesticide.
Background technology
Chrysanthemum have diseases prevention, cure the disease, keep healthy, the function such as appreciation, chrysanthemum is used as medicine with a long history in China, have dispelling wind,
Heat-clearing, improving eyesight, detoxicating functions, chrysanthemum and preparation thereof can treat headache, dizziness, hot eyes, treatment sore, pyogenic infections, virus flu, high blood
The diseases such as pressure, high fat of blood, coronary heart disease, are the health food liked of people and preferable medicine.Meanwhile, chrysanthemum is again that China is large
One of medicinal material, is also one of important outlet medicinal material kind.Chrysanthemum morifolium artificial cultivation is the trend of the times of Producing medicinal herbs,
The raw-material high-quality of Chinese medicine, safety in production are the premises of the modernization of Chinese medicine.External only Japan, the U.S., Korea S and Southeast Asia
Etc. some traditional Chinese medicinal materials assortment of a few countries artificial cultivation, but China's current artificial cultivation traditional Chinese medicinal materials assortment reaches kind more than 300, accounts for me
About the 2/3 of more than the 500 kind of parts of generic medicinal plants circulated on state's medicinal material market.Existing more than 600 the Chinese medicine planting base of China, plants
Plant area and reach more than 600 ten thousand mu.But in recent years, China mainland Chinese medicine export volume only accounts for about the 10% of global trade amount, mainly
Reason is that raw material active ingredient is understable to exceed standard with medicinal material Pesticide Residues or content of beary metal.
Difenoconazole is a kind of pathogen ergosterol biosynthesis inhibitor, acts on wheat in phytopathogen thalline
The interruption of angle sterol synthesis, and then show as strong bacteriostasis.This medicament disinfecting spectrum is wide, lasting period length, to sac fungus, half
Know that the fungi of bacterium and Basidiomycetes has excellent bacteriostatic activity, go out prevention, treatment and the eradicant action of excellence at variable rate technology；
To crop and Environmental security.
Allicin (Allicin) is from the bulb (garlic) of Liliaceae allium garlic (Allium Sativum)
A kind of organosulfur compound extracted, exists in onion and other alliums.Formal name used at school GIUCOSinoate.
Pale yellow oily liquid body.Boiling point 80-85 DEG C (0.2kPa), relative density 1.112(20/4 DEG C), index of refraction 1.561.It is dissolved in second
Alcohol, chloroform or ether.Solubility 2.5% (quality) (10 DEG C) in water, its pH value of water solution is 6.5, has grease to precipitate during standing
Thing is formed.Can dissolve each other with ethanol, ether and benzene.Unstable to thermokalite, stable to acid.By the squama being present in liliaceous plant garlic
In stem, the garlic aminoacid existed under big allinase effect, convert generation.Exist in the bulb of green onion.There is strong garlic
Smelly, taste is peppery.
In the real process of agricultural production, pest control is easiest to generate the problem that the generation of pest resistance to insecticide.No
Compound with kind composition, be to prevent and treat the method that resistant insect is the most common.Heterogeneity compounds, according to reality application effect
Fruit judge certain compounding be synergy, add and or antagonism.
Summary of the invention
For the problems referred to above, the invention provides a kind of microemulsion for chrysanthemum, the present invention is that one is used for preventing and treating chrysanthemum
The microemulsion of flower anthracnose, its active ingredient is Difenoconazole and allicin, and instant effect of the present invention, holding effect are long, to non-target
Crop safety.
Technical scheme is as follows:
A kind of microemulsion for chrysanthemum, described microemulsion is used for preventing and treating chrysanthemum anthracnose, and active ingredient is phenyl ether methyl cyclic
Azoles and allicin, auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product sodium salt, Nekal BX, DMF, phenyl phenol polyoxy second
Base ether phosphate, C8-10Aliphatic alcohols, Arabic gum, glycerine.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 15%-40%, allicin 0.1%-1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%-10%, Nekal BX
5%-10%, DMF 5%-10%, phenyl phenol polyoxyethanyl ether phosphate 3%-8%, C8-10Aliphatic alcohols 0.1%-
0.5%, Arabic gum 0.01%-0.1%, glycerine 1%-3%, deionized water add to 100%.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 20%-35%, allicin 0.1%-1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%-9%, Nekal BX
6%-9%, DMF 6%-9%, phenyl phenol polyoxyethanyl ether phosphate 4%-7%, C8-10Aliphatic alcohols 0.2%-
0.4%, Arabic gum 0.03%-0.07%, glycerine 1.5%-2.5%, deionized water add to 100%.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 19.5%, allicin 0.5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, Nekal BX 6%, N, N-bis-
NMF 8%, phenyl phenol polyoxyethanyl ether phosphate 5%, C8-10Aliphatic alcohols 0.2%, Arabic gum 0.05%, glycerine
1.8%, deionized water adds to 100%.
Microemulsion of the present invention is morbidity early stage for preventing and treating dispenser period of chrysanthemum anthracnose；Annual spraying times is 1 or 2
Secondary；Active ingredient dosage is 10 grams/ha-50 grams/ha, it is preferred that dosage is 15 grams/ha.
The present invention has the advantage that compared to existing technology
(1) having synergistic effect, sterilization adds protective effect, and its effect is not the simple superposition of each composition activity, but tool
There is synergistic effect significantly；
(2) times for spraying is few, and drug cost is low；
(3) generation of resistance is slowed down, good to crop safety, meet the security requirement of pesticidal preparations；
(4) present invention effectively enhances the prevention to chrysanthemum anthracnose and the effect for the treatment of, instant effect, and the lasting period is long, right
Non-Target crops is without impact.
Detailed description of the invention
Below in conjunction with specific embodiment further describe the present invention, advantages of the present invention and feature will be with describe and
Apparent.But embodiment is only exemplary, the scope of the present invention is not constituted any restriction.Those skilled in the art should
It should be appreciated that, the details of technical solution of the present invention and form can be repaiied lower without departing from the spirit and scope of the present invention
Change or replace, but these amendments and replacement each fall within protection scope of the present invention.
Embodiment 1
20% Difenoconazole and allicin microemulsion
Each raw material components is by weight percentage:
Difenoconazole 19.5%
Allicin 0.5%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%
Nekal BX 6%
DMF 8%
Phenyl phenol polyoxyethanyl ether phosphate 5%
C8-10Aliphatic alcohols 0.2%
Arabic gum 0.05%
Glycerine 1.8%
Deionized water adds to 100%.
By above-mentioned each composition application conventional pesticide process technology, the microemulsion goods being suitable for agriculturally using made.This
In embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 256.2.
The microemulsion that the embodiment of the present invention 1 obtains is used for preventing and treating chrysanthemum anthracnose, chrysanthemum anthracnose early stage dispenser,
Active ingredient dosage is 15 grams/ha, sprays 2 times, and after secondary medicine, the prevention effect of 7 days, 14 days and 30 days is respectively
86.7%、88.5%、90.3%.25% Difenoconazole missible oil by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, 14 days and
The prevention effect of 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua presses 2000 times of spray pesticides 2 times, secondary
After medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.After Difenoconazole and allicin compound
Synergistic effect is obvious, and the preventive effect of anthracnose is significantly better than single dose.
Embodiment 2
30% Difenoconazole and allicin microemulsion
Each raw material components is by weight percentage:
Difenoconazole 29.9%
Allicin 0.1%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%
Nekal BX 8%
DMF 5%
Phenyl phenol polyoxyethanyl ether phosphate 4%
C8-10Aliphatic alcohols 0.3%
Arabic gum 0.08%
Glycerine 1%
Deionized water adds to 100%.
By above-mentioned each composition application conventional pesticide process technology, the microemulsion formulation being suitable for agriculturally using made.This
In embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 232.27.
The microemulsion that the embodiment of the present invention 2 obtains is used for preventing and treating chrysanthemum anthracnose, chrysanthemum anthracnose early stage dispenser,
Active ingredient dosage is 20 grams/ha, sprays 2 times, and after secondary medicine, the prevention effect of 7 days, 14 days and 30 days is respectively
83.1%、85.3%、88.3%.25% Difenoconazole missible oil by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, 14 days and
The prevention effect of 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua presses 2000 times of spray pesticides 2 times, secondary
After medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.After Difenoconazole and allicin compound
Synergistic effect is obvious, and the preventive effect of anthracnose is significantly better than single dose.
Embodiment 3
16% Difenoconazole and allicin microemulsion
Each raw material components is by weight percentage:
Difenoconazole 15%
Allicin 1%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%
Nekal BX 6%
DMF 5%
Phenyl phenol polyoxyethanyl ether phosphate 7%
C8-10Aliphatic alcohols 0.5%
Arabic gum 0.1%
Glycerine 2.5%
Deionized water adds to 100%.
By above-mentioned each composition application conventional pesticide process technology, the microemulsion goods being suitable for agriculturally using made.This
In embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 199.35.
The microemulsion that the embodiment of the present invention 3 obtains is used for preventing and treating chrysanthemum anthracnose, chrysanthemum anthracnose early stage dispenser,
Active ingredient dosage is 10 grams/ha, sprays 2 times, and after secondary medicine, the prevention effect of 7 days, 14 days and 30 days is respectively
81.8%、83.8%、85.8%.25% Difenoconazole missible oil by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, 14 days and
The prevention effect of 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua presses 2000 times of spray pesticides 2 times, secondary
After medicine, the prevention effect of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.After Difenoconazole and allicin compound
Synergistic effect is obvious, and the preventive effect of anthracnose is significantly better than single dose.
Claims (1)
1. the microemulsion for chrysanthemum, it is characterised in that in described microemulsion, each raw material components is by weight percentage:
Difenoconazole 19.5%, allicin 0.5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, Nekal BX 6%, N, N-bis-
NMF 8%, phenyl phenol polyoxyethanyl ether phosphate 5%, C8-10Aliphatic alcohols 0.2%, Arabic gum 0.05%, the third three
Alcohol 1.8%, deionized water add to 100%；
Described microemulsion is morbidity early stage for preventing and treating dispenser period of chrysanthemum anthracnose；Annual spraying times is 2 times；Dosage
It it is 15 grams/ha.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630333.2A CN104351196B (en) | 2014-11-11 | 2014-11-11 | A kind of microemulsion for chrysanthemum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630333.2A CN104351196B (en) | 2014-11-11 | 2014-11-11 | A kind of microemulsion for chrysanthemum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104351196A CN104351196A (en) | 2015-02-18 |
| CN104351196B true CN104351196B (en) | 2016-08-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410630333.2A Expired - Fee Related CN104351196B (en) | 2014-11-11 | 2014-11-11 | A kind of microemulsion for chrysanthemum |
Country Status (1)
| Country | Link |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111053082A (en) * | 2019-10-08 | 2020-04-24 | 海南正业中农高科股份有限公司 | Composition containing ethylicin and difenoconazole and application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1742579A (en) * | 2005-09-26 | 2006-03-08 | 田琳 | Farm-forestry crop sterilizer |
| CN102726415A (en) * | 2012-06-19 | 2012-10-17 | 河南省大地农化有限责任公司 | Allicin-containing prevention and treatment pesticide for crop plant diseases |
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2014
- 2014-11-11 CN CN201410630333.2A patent/CN104351196B/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN104351196A (en) | 2015-02-18 |
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Effective date of registration: 20160616 Address after: 266109, No. 111, sunny road, Chengyang District, Shandong, Qingdao Applicant after: JINAN CAVIN BIOTECHNOLOGY CO., LTD. Address before: 250001 Shandong Province, Ji'nan City District Court building 2303 No. 288 Applicant before: JINAN XINQIDIAN MEDICINE SCIENCE & TECHNOLOGY CO., LTD. |
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Inventor after: Yang Dong Inventor before: Sun Bo Inventor before: Sun Qian Inventor before: Mu Kexiao Inventor before: Hao Aihua Inventor before: Wang Mengmeng |
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Effective date of registration: 20170717 Address after: 300000 Tianjin District of Hongqiao City Rainbow gardens 1-204 Patentee after: Yang Dong Address before: 266109, No. 111, sunny road, Chengyang District, Shandong, Qingdao Patentee before: Qingdao Qingzhi Enterprise Management Consulting Co., Ltd. |
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Granted publication date: 20160824 Termination date: 20171111 |
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