CN104341249A - Improved humic acid fertilizer and processing process thereof - Google Patents

Improved humic acid fertilizer and processing process thereof Download PDF

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Publication number
CN104341249A
CN104341249A CN201410571104.8A CN201410571104A CN104341249A CN 104341249 A CN104341249 A CN 104341249A CN 201410571104 A CN201410571104 A CN 201410571104A CN 104341249 A CN104341249 A CN 104341249A
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China
Prior art keywords
humic acid
humic
humic acids
acid fertilizer
modified version
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CN201410571104.8A
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Chinese (zh)
Inventor
吴志明
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HANGZHOU LVYE TECHNOLOGY Co Ltd
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HANGZHOU LVYE TECHNOLOGY Co Ltd
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Priority to CN201410571104.8A priority Critical patent/CN104341249A/en
Publication of CN104341249A publication Critical patent/CN104341249A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates

Abstract

The invention discloses an improved humic acid fertilizer comprising the following materials in percentage by mass: 45% of mineral-based humic acid, 20% of biochemical potassium humate, 1% of biological active enzyme, 7% of microelements, 10% of urea, 8 parts of amino acids, 4% of potassium nitrate, 4% of monopotassium phosphate as well as a certain amount of a chelate added in the later stage. The chelating agent can be used for effectively protecting addition and reaction of the microelements. The improved humic acid fertilizer has the advantages of effectively solving the soil granulation problem, loosening soil, improving the soil environment, activating effective microorganisms such as nitrogen-fixing bacteria, phosphate solubilizing bacteria and potassium solubilizing bacteria, improving the content of the effective microorganisms to be more than 1 billion per gram, providing more than 40% of nutrients to plants, improving the absorption of various microelements by crops to be more than 50% and efficiently improving the yield and quality of the crops.

Description

A kind of modified version humic acid fertilizer and complete processing thereof
Technical field
The present invention relates to a kind of modified version humic acid fertilizer and complete processing thereof.
Background technology
The arable land of China accounts for 7% of the world, and but employ the chemical fertilizer accounting for the world about 35%, fertilizer amount occupies first place in the world.The soil compaction brought due to long-term application chemical fertilizer in recent years, soil fertility decline, ecological damage, environmental pollution and agricultural product quality decline, and the exploitation of humic acid fertilizer, apply the great attention receiving agricultural science and technology circle.Humic acid fertilizer is developing the effect in an agriculture featuring high yields, fine quality and high efficiency gradually by people are familiar with as a kind of new agrotechnical measure.
Current soil status brings advantage to humic acid fertilizer.Agricultural will be increased production, and fertilizer plays Main Function, but particularly relies on for a long time nitrogenous fertilizer due to the long-term nitrogen fertilizer application partially of peasant, causes soil compaction, salinification phenomenon very general.Current China utilization rate of fertilizer is also very low: nitrogenous fertilizer very easily loses after being applied to soil, and the approach of loss has drip washing, gas loss and fixes, and the utilization ratio of nitrogenous fertilizer only has about 30%, and loss is serious.China every year by the nitrogenous fertilizer of drip washing and volatilization loss at 1200 ~ 1,400 ten thousand tons, cause huge waste.Potash fertilizer also produces loss by drip washing and runoff in soil, and its utilization ratio is slightly high, also only has about 35%.Fertilizer loss is except causing waste, and serious environment pollution simultaneously, reduces quality of agricultural product.Because humic acid fertilizer has the function of potassium decomposing, phosphorus decomposing, fixed nitrogen, greatly can improve the utilization ratio of fertilizer, be subject to the favor of vast farmers gradually.
Industrialized agriculture is an important directions of China's Agriculture strategy structural adjustment, is an important means of growth of agricultural efficiency, increasing peasant income, and development at present rapidly.But installment agriculture growth changes edatope, its temperature, humidity, illumination etc. all there occurs wide variation, soil be often in high temperature, high humidity, high evaporation, without in the environment of rain.Under this ecological environmental condition, as unreasonable in continuous cropping for many years, rich water quality management etc., easily cause that some soil physical chemistry and biological character worsen, continuous cropping obstacle obviously, soil-borne disease insect pest increases, yields poorly, the of inferior quality series of problems of quality, affect the Sustainable development of industrialized agriculture production.
Country advocates and uses humic acid fertilizer in a large number, and policy support puts more effort.Governments at all levels also protect farmland improvement soil, develop and agriculture oriented for export and foreign exchange earnings of promoting export is grabbed as cardinal task; Attention and development nuisanceless green vegetables must strengthen the input to humic acid fertilizer.
Peasant changes by fertile custom, brings opportunity to humic acid fertilizer.In production practice, many peasant's firsthand experiences are to humic acid fertilizer effect aborning.So they no longer do not want to take the trouble, consciously take rational application of fertilizers, collocation fertilising, initiatively drops into humic acid fertilizer in ground.
Therefore improve soil, make soil restoration natural optimum, and the utilization ratio improving fertilizer is the main trend of current industrialized agriculture dedicated fertilizer development.
At present, there are multiple technologies can improve the utilization ratio of fertilizer, slow down the material of nutrients release by interpolation in fertilizer and fertilizer is carried out coating process etc.Main Problems existing is that cost material environment friendly that is high, that add has a big risk, complex manufacturing etc.
Along with the widespread use of soil improvement agent in agricultural and ecotope, the product innovation of domestic and international soil improvement agent also gets more and more.Countries in the world, in order to protect the fields and bring more land under cultivation, improve farming output, and Study and Development all soil moisturizing agent, agent of loosening the soil, sand-fixation agent, fertilizer synergist, sterilizing agent and deacidification alkaline agent etc., exist the problem of secondary pollution equally.
Comprehensive above reason, research and develop a kind of environmental protection, possess soil improvement characteristic then promote higher yield of crops humic acid fertilizer be a kind of trend.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of modified version humic acid fertilizer and complete processing thereof, and this product effectively can realize the improvement to soil, and himself process based prediction model is stablized, and is convenient to store and transport.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of modified version humic acid fertilizer, it is characterized in that: the material comprising following mass fraction: mineral sources humic acids 45%, biochemical humic acid potassium 20%, bioactive enzyme 1%, trace element 7%, urea 10%, amino acid 8%, saltpetre 4%, potassium primary phosphate 4%, comprise a certain amount of inner complex that the later stage adds in addition.Sequestrant can protect micro-interpolation and reaction by available protecting.
A complete processing for modified version humic acid fertilizer, comprises the steps:
1), choose quantitative humic acid activity enzyme, and organized enzyme is performed screening and separation circuit, select effective organized enzyme preservation for subsequent use, organized enzyme remains on about 25 DEG C;
2), select quantitative humic acids base material, perform broken manufacturing procedure, processing granular fineness is more than 80 orders, and preservation is for subsequent use;
3), to step 2) described in humic acids base material in add macroelement and the trace element such as nitrogen, phosphorus, potassium, boron, manganese, zinc;
4), to described step 3) add the effective active enzyme chosen in obtained humic acids base material, and the mixtures such as described humic acids base material and organized enzyme are placed in the uncovered reactor under room temperature environment, leave standstill 1 hour;
5), by step 4) in the humic acids filter sieve that reacted separate solid phase prod, obtain required modified version humic acids.
Improve as one, described step 1) described in the consumption of bioactive enzyme and total quality of materials ratio be 10Kg/T.
As one improve, described step 1) in organized enzyme screening process, by the effective bacterium equipment of microorganism testing, by described organized enzyme screening and separating.
Improve as one, described step 1) in the dosage ratio of inner complex be 5-10Kg/T.
Improve as one, described step 2) in the weight ratio of base material consumption and organized enzyme be 100:1, described humic acids base material is positioned over the local back up of natural ventilation.
Improve as one, described step 3) in macroelement and trace element dosage and humic acids substrate mass ratio be 5:13, the interpolation of described trace element is carried out with the form of following compound: potassium dihydrogen, saltpetre, urea, potassium hydrogen phosphate, need carry out in reactor herein.Because it is easy to absorb moisture, tide is rotten can effectively to prevent it from seeing in reactor.
Potash fertilizer mixes with humic acids to be used, and the acidic-group of humic acids and potassium ion form complex compound, effectively can prevent fixing to potassium ion of soil crystal, increase the content of exchangeable potassium, and can reduce potassium amount of outflowing with water in sand and the strong soil of leaching.The potassium humate organic-inorganic mixed fertilizer made with humic acids and potash fertilizer, can avoid the detrimentally affect because long-term application potassium sulfate, Repone K and the negatively charged ion left over cause soil after being manured into soil.Humic acids can also have an impact to the trace element in soil, and energy and Ca, Mg, Tu, Zn etc. generate inner complex, so in supplementary crop trace element, play active effect.
Humic acids can improve crop cell film and plasmic perviousness, and acceleration nutritive substance enters makes object.Wherein, macroelement type product is divided into solid or liquid two kinds, and microelement type product is only solid dosage.Humic acids, as the fusion person of large fertilizer, can merge N, P, K, and unitary merges, binary merges or ternary merges, as humic acids nitrogenous fertilizer, humic acid phosphate fertilizer, Potassium humate fertilizer, Remixed humic acid fertilizer.Humic acids merges N, P, K, have versatile and flexible, prominent function, synergy significantly, utilization ratio high, the integrated result of 1+1 > 2 can be reached.
The technical solution used in the present invention, its beneficial effect is: the modified version humic acids stable physical property in this product, be convenient to standing storage and transport, and its nutritive element enriches, fully can decompose under the effect of enzyme and microorganism, the natural organic matter in soil can increase substantially, and the consumption of organized enzyme is 10 kilograms/T, not easily in implementation process because external environmental factor is all dead, fully can regulate and improve effective microbe content; Make the probiotics reproduction speed in soil improve more than 25%, effectively improve soil granular, have chessom, improve edatope; Effective bacterial content such as vinelandii, phosphate solubilizing bacteria, potassium solubilizing bacteria can be activated greatly promote simultaneously, make effective bacterial content reach more than 1,000,000,000/gram; The nutrition that crop plays more than 40% can be provided; Promote that the absorbing power of crop various trace elements reaches more than 50%; The seed output and quality of abundant raising crop.
Embodiment
In the present embodiment described, a kind of modified version humic acid fertilizer, comprise the material of following mass fraction: mineral sources humic acids 45%, biochemical humic acid potassium 20%, bioactive enzyme 1%, trace element 7%, urea 10%, amino acid 8%, saltpetre 4%, potassium primary phosphate 4%, comprise a certain amount of inner complex that the later stage adds in addition.Sequestrant can protect micro-interpolation and reaction by available protecting;
The complete processing of above-mentioned modified version humic acid fertilizer, comprises the steps:
1), choose quantitative humic acid activity enzyme, and organized enzyme is performed screening and separation circuit, select effective organized enzyme preservation for subsequent use, organized enzyme remains on about 25 °;
2), select quantitative humic acids base material, perform broken manufacturing procedure, processing granular fineness is more than 80 orders, and preservation is for subsequent use;
3), to step 2) described in humic acids base material in add the trace element such as nitrogen, phosphorus, potassium;
4), to described step 3) add de-salted water in obtained humic acids base material, stir mixing, the effective active enzyme chosen, and the mixtures such as described humic acids base material and organized enzyme are placed in the uncovered reactor under room temperature environment, leave standstill 1 hour;
5), by step 4) in the humic acids filter sieve that reacted separate solid phase prod, obtain required modified version humic acids.
In the present embodiment, described step 1) described in the consumption of bioactive enzyme and total quality of materials ratio be 10Kg/T.
In the present embodiment, described step 1) in organized enzyme screening process, by the effective bacterium equipment of microorganism testing, by described organized enzyme screening and separating.
In the present embodiment, described step 1) in the dosage ratio of inner complex be 5-10Kg/T.
In the present embodiment, described step 2) in the weight ratio of base material consumption and organized enzyme be 100:1, described humic acids base material is positioned over the local back up of natural ventilation.
In the present embodiment, described step 3) in macroelement and trace element dosage and humic acids substrate mass ratio be 5:13, the interpolation of described trace element is carried out with the form of following compound: potassium dihydrogen, saltpetre, urea, potassium hydrogen phosphate, this process need carried out in reactor, because it is easy to absorb moisture, tide is rotten can effectively to prevent it from seeing in reactor.
Potash fertilizer mixes with humic acids to be used, and the acidic-group of humic acids and potassium ion form complex compound, effectively can prevent soil crystal fixing potassium ion, increase the content of exchangeable potassium.And potassium can be reduced in sand and the strong soil of leaching, outflow with water quantity.The potassium humate organic-inorganic mixed fertilizer made with humic acids and potash fertilizer, can avoid the detrimentally affect because long-term application potassium sulfate, Repone K and the negatively charged ion left over cause soil after being manured into soil.Humic acids can also have an impact to the trace element in soil, and energy and Ca, Mg, Tu, Zn etc. generate inner complex, so in supplementary crop trace element, play active effect.
Humic acids can improve crop cell film and plasmic perviousness, and acceleration nutritive substance enters makes object.Wherein, macroelement type product is divided into solid or liquid two kinds, and microelement type product is only solid dosage.Humic acids, as the fusion person of large fertilizer, can merge N, P, K, and unitary merges, binary merges or ternary merges, as humic acids nitrogenous fertilizer, humic acid phosphate fertilizer, Potassium humate fertilizer, Remixed humic acid fertilizer.Humic acids merges N, P, K, has versatile and flexible a, prominent function, synergy shows, utilization ratio is a high feature, can reach the integrated result of 1+1 > 2.
The technical solution used in the present invention, modified version humic acids stable physical property, be convenient to standing storage and transport, and its nutritive element enriches, fully can decompose under the effect of enzyme and microorganism, the natural organic matter in soil can increase substantially, and the consumption of organized enzyme is 10 kilograms/T, not easily in implementation process because external environmental factor is all dead, fully can regulate and improve effective microbe content; Make the probiotics reproduction speed in soil improve more than 25%, effectively improve soil granular, have chessom, improve edatope; Effective bacterial content such as vinelandii, phosphate solubilizing bacteria, potassium solubilizing bacteria can be activated greatly promote simultaneously, make effective bacterial content reach more than 1,000,000,000/gram; The nutrition that crop plays more than 40% can be provided; Promote that the absorbing power of crop various trace elements reaches more than 50%; The seed output and quality of abundant raising crop.
Except above preferred embodiment, the present invention also has other embodiment, and those skilled in the art can make various change and distortion according to the present invention, only otherwise depart from spirit of the present invention, all should belong to the scope that claims of the present invention define.

Claims (7)

1. a modified version humic acid fertilizer, it is characterized in that: the material comprising following mass fraction: mineral sources humic acids 45%, biochemical humic acid potassium 20%, bioactive enzyme 1%, trace element 7%, urea 10%, amino acid 8%, saltpetre 4%, potassium primary phosphate 4%, comprise a certain amount of inner complex that the later stage adds in addition.
2. the complete processing of a kind of modified version humic acid fertilizer according to claim 1, is characterized in that: comprise the steps:
1), choose quantitative bioactive enzyme, and organized enzyme is performed screening and separation circuit, select effective organized enzyme preservation for subsequent use, organized enzyme remains on about 25C °;
2), select quantitative humic acids base material, perform broken manufacturing procedure, processing granular fineness is more than 80 orders, for subsequent use;
3), to step 2) described in humic acids base material in add macroelement and the trace element such as boron, zinc, manganese, nitrogen, phosphorus, potassium;
4), to described step 3) obtained humic acids adds the effective active enzyme chosen, and the mixtures such as described humic acids base material and organized enzyme is placed in the uncovered reactor under room temperature environment, stir;
5), by step 4) in the humic acids filter sieve that reacted separate solid phase prod, obtain required modified version humic acids.
3. the complete processing of a kind of modified version humic acid fertilizer according to claim 2, is characterized in that: described step 1) described in the consumption of bioactive enzyme and total quality of materials ratio be 10Kg/T.
4. the complete processing of a kind of modified version humic acid fertilizer according to claim 2, is characterized in that: described step 1) in organized enzyme screening process, by the effective bacterium equipment of microorganism testing, by described organized enzyme screening and separating.
5. the complete processing of a kind of modified version humic acid fertilizer according to claim 2, is characterized in that: described step 1) in the dosage ratio of inner complex be 5-10Kg/T.
6. the complete processing of a kind of modified version humic acid fertilizer according to claim 2, is characterized in that: described step 2) in the weight ratio of base material consumption and organized enzyme be 100:1, described humic acids base material is positioned over the local back up of natural ventilation.
7. the complete processing of a kind of modified version humic acid fertilizer according to claim 2, it is characterized in that: described step 3) dosage of macroelement and medium trace element and humic acids substrate mass ratio be 5:13, the interpolation of described trace element is carried out with the form of following compound: potassium dihydrogen, saltpetre, urea, potassium primary phosphate, and this process need carried out in reactor.
CN201410571104.8A 2014-10-23 2014-10-23 Improved humic acid fertilizer and processing process thereof Pending CN104341249A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108218617A (en) * 2018-01-04 2018-06-29 中化农业(临沂)研发中心有限公司 A kind of dedicated synergy chelating fertilizer of tomato top dressing and preparation method thereof
CN109997442A (en) * 2019-03-19 2019-07-12 湖州灵粮生态农业有限公司 A kind of method of biology in situ rehabilitating soil
CN110407647A (en) * 2019-08-02 2019-11-05 甘肃祁连山药业股份有限公司 A kind of potassium humate punching fertilising processing technology
CN111763114A (en) * 2020-07-02 2020-10-13 山东喜福乐生物科技有限公司 Water-retaining fertilizer containing biochemical potassium fulvate and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1413963A (en) * 2002-09-19 2003-04-30 上海九康农业科技发展有限公司 Compound application technology for nano-biological fertilizer and soil conditioner
CN1546438A (en) * 2003-12-12 2004-11-17 华东理工大学 Multifunctional chitin release-controlled fertilizer
CN101391933A (en) * 2008-11-10 2009-03-25 河南三农生态产业有限公司 Soil organism modifying agent
CN103936519A (en) * 2014-04-28 2014-07-23 唐振铭 Selenium-rich fruit tree cell resurgence nutrient

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1413963A (en) * 2002-09-19 2003-04-30 上海九康农业科技发展有限公司 Compound application technology for nano-biological fertilizer and soil conditioner
CN1546438A (en) * 2003-12-12 2004-11-17 华东理工大学 Multifunctional chitin release-controlled fertilizer
CN101391933A (en) * 2008-11-10 2009-03-25 河南三农生态产业有限公司 Soil organism modifying agent
CN103936519A (en) * 2014-04-28 2014-07-23 唐振铭 Selenium-rich fruit tree cell resurgence nutrient

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108218617A (en) * 2018-01-04 2018-06-29 中化农业(临沂)研发中心有限公司 A kind of dedicated synergy chelating fertilizer of tomato top dressing and preparation method thereof
CN109997442A (en) * 2019-03-19 2019-07-12 湖州灵粮生态农业有限公司 A kind of method of biology in situ rehabilitating soil
CN110407647A (en) * 2019-08-02 2019-11-05 甘肃祁连山药业股份有限公司 A kind of potassium humate punching fertilising processing technology
CN111763114A (en) * 2020-07-02 2020-10-13 山东喜福乐生物科技有限公司 Water-retaining fertilizer containing biochemical potassium fulvate and preparation method thereof

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