CN104312362A - Antirust paint for improving brightness of finish and preparation method thereof - Google Patents
Antirust paint for improving brightness of finish and preparation method thereof Download PDFInfo
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- CN104312362A CN104312362A CN201410469136.7A CN201410469136A CN104312362A CN 104312362 A CN104312362 A CN 104312362A CN 201410469136 A CN201410469136 A CN 201410469136A CN 104312362 A CN104312362 A CN 104312362A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses antitrust paint for improving the brightness of finish. The antirust paint is the characterized by being prepared from 8-12 parts by weight of copal resin, 32-36 parts by weight of organosilicon epoxy resin, 3-5 parts by weight of tetraethylenepentamine, 5-7 parts by weight of 2-hydroxypropyl acrylate, 1-2 parts by weight of ammonium polyphosphate, 11-14 parts by weight of modified asphalt, 4-7 parts by weight of modified waste clay sand, 1-2 parts by weight of fluorescent pigment, 1-2 parts by weight of borneol, 0.3-0.7 parts by weight of a silane coupling agent, 1-2 parts by weight of polyolefin wax, 2-3 parts by weight of light calcium carbonate, 1-2 parts by weight of titanium dioxide, 2-3 parts by weight of cellulose acetate, 1-2 parts by weight of micaceous iron oxide, 10-13 parts by weight of a gasoline solvent No. 200 and 4-6 parts by weight of butyl acetate. By use of the natural resin copal, the antirust paint has the characteristics of nontoxicity and stable properties. The borneol in the paint has a fragrance and effects of relaxing and raising spirit and restoring consciousness, can effectively reduce the peculiar smell of the paint and smells comfortable. The used polyolefin wax can be uniformly disperse a filler to avoid paint quality influence caused by the formation of dust agglomeration. The used micaceous iron oxide has a strong anti-rust effect. The used fluorescent pigments and titanium dioxide can improve the brightness of the antirust paint and give people a comfortable visual enjoyment.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind ofly improve rust-inhibiting paint of finish paint brightness and preparation method thereof.
Background technology
Current paint various in style, of many uses, becomes the indispensable material of society, for the life of the mankind, industry and science and technology bring no small impact.The direct economic loss that China causes due to metallic corrosion every year accounts for 4% of gross national product.Corrosion of metal not only causes huge waste of material, and also result in huge financial loss.Therefore the Anticorrosion Problems of metal more and more causes the concern of people.
Clay-bonded sand is the molding sand using clay as binding agent, clay-bonded sand is recycling the thermolysis due to each component in process, there occurs the change of physicals, surface also has the dead clay losing viscosifying power because of heat, the ash content that coal dust etc. are residual and iron content, the composition silicate of the compositions such as aluminium, the words of recycling reduce the quality of molding sand, having to be replaced becomes Discarding Type sand, bulk deposition can have a strong impact on the quality of environmental pollution and soil, serious words are due to rainwash, wherein injurious factor can be left to river along with rainwater, the places such as plantation, finally be gathered in people's body by food chain, very large harm is brought to health, the present invention is directed to this situation discarded clay-bonded sand is carried out modification to add in paint as filler, not only reduce environmental pollution, and enhance the weathering resistance of paint, thermotolerance, erosion resistance, reduce the effect of production cost etc.
Summary of the invention
The object of this invention is to provide and a kind ofly improve rust-inhibiting paint of finish paint brightness and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
Improve a rust-inhibiting paint for finish paint brightness, be made up of the raw material of following weight part: kopol 8-12, organosilicon epoxy resin 32-36, tetraethylene pentamine 3-5, vinylformic acid-2-hydroxy propyl ester 5-7, ammonium polyphosphate 1-2, modifying asphalt 11-14, modified abandoned clay-bonded sand 4-7, high-visibility pigment 1-2, borneol 1-2, silane coupling agent 0.3-0.7, polyolefin-wax 1-2, light calcium carbonate 2-3, titanium dioxide 1-2, cellulose acetate 2-3, iron mica 1-2, No. 200 petrolic solvent 10-13, N-BUTYL ACETATE 4-6;
Described modifying asphalt is made up of the raw material of following weight part: chlorinated rubber 11-14, pitch 92-94, stearylamide 0.2-0.4, Diisopropyl azodicarboxylate 0.2-0.4, octa-BDE 0.3-0.7, water 5-8, polyoxyethylenated castor oil 0.3-0.6, Magnesium Stearate 0.6-1.2, Nano carbon white 1-2, nano diatomite 0.4-0.8, turps 6-9, synourin oil 2-3, hexanediamine 1-2, rare earth nitrate 0.02-0.07, the atlapulgite 1-2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of rust-inhibiting paint improving finish paint brightness of the present invention, be made up of following concrete steps:
(1) kopol and polyolefin-wax are heated to molten state and organosilicon epoxy resin, modifying asphalt, tetraethylene pentamine, No. 200 petrolic solvents, N-BUTYL ACETATE, the mixing of vinylformic acid-2-hydroxy propyl ester are added in reactor, temperature is controlled at 200-250 ° of C, then under 600-800 rev/min, stir 2-3 hour after being uniformly mixed by mixture;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, high-visibility pigment, iron mica, titanium dioxide, silane coupling agent stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Advantage of the present invention is: paint of the present invention with the addition of natural resin kopol, there is feature that is nontoxic, stable in properties, in paint, adding borneol, to have delicate fragrance a surname loose, the effect produced refreshing effect to the mind, effectively can reduce the peculiar smell in paint, to the olfactory sensations that people are comfortable, the polyolefin-wax added has the effect of dispersed filler, depositing dust is avoided to form the quality of caking impact paint, the iron mica added has very strong rust inhibition, the high-visibility pigment added and titanium dioxide can strengthen the brightness of paint, to the visual enjoyment that people is comfortable.
specific embodiments
Below by specific examples, the present invention is described in detail.
Improve a rust-inhibiting paint for finish paint brightness, be made up of the raw material of following weight part (kilogram): kopol 12, organosilicon epoxy resin 34, tetraethylene pentamine 4, vinylformic acid-2-hydroxy propyl ester 6, ammonium polyphosphate 2, modifying asphalt 12, modified abandoned clay-bonded sand 5, high-visibility pigment 1, borneol 1, silane coupling agent 0.5, polyolefin-wax 1, light calcium carbonate 2, titanium dioxide 1, cellulose acetate 2, iron mica 1, No. 200 petrolic solvents 10, N-BUTYL ACETATEs 6;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): chlorinated rubber 13, pitch 93, stearylamide 0.3, Diisopropyl azodicarboxylate 0.2, octa-BDE 0.4, water 6, polyoxyethylenated castor oil 0.5, Magnesium Stearate 0.7, Nano carbon white 2, nano diatomite 0.6, turps 8, synourin oil 3, hexanediamine 1, rare earth nitrate 0.02, the atlapulgite 2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of rust-inhibiting paint improving finish paint brightness of the present invention, be made up of following concrete steps:
(1) kopol and polyolefin-wax are heated to molten state and organosilicon epoxy resin, modifying asphalt, tetraethylene pentamine, No. 200 petrolic solvents, N-BUTYL ACETATE, the mixing of vinylformic acid-2-hydroxy propyl ester are added in reactor, temperature is controlled at 200-250 ° of C, then under 600-800 rev/min, stir 2-3 hour after being uniformly mixed by mixture;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, high-visibility pigment, iron mica, titanium dioxide, silane coupling agent stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
The each functional parameter of paint of the present invention is as follows: viscosity (S/25 DEG C) 83, and salt water resistance (30 days) paint film is unchanged, non-foaming, do not come off, non-corrosive, salt fog resistance (1000h) paint film is unchanged, non-foaming, do not come off, non-corrosive, resistance to distilled water (30 days) paint film is non-foaming, does not come off, sticking power (Mpa) 5.9, wear resistance (mg/500 turns) 5.1, shock-resistance (cm) 50, snappiness (mm) 1, artificial accelerated aging (500h) paint film without variable color, without efflorescence, flawless phenomenon.
Claims (3)
1. one kind is improved the rust-inhibiting paint of finish paint brightness, it is characterized in that, be made up of the raw material of following weight part: kopol 8-12, organosilicon epoxy resin 32-36, tetraethylene pentamine 3-5, vinylformic acid-2-hydroxy propyl ester 5-7, ammonium polyphosphate 1-2, modifying asphalt 11-14, modified abandoned clay-bonded sand 4-7, high-visibility pigment 1-2, borneol 1-2, silane coupling agent 0.3-0.7, polyolefin-wax 1-2, light calcium carbonate 2-3, titanium dioxide 1-2, cellulose acetate 2-3, iron mica 1-2, No. 200 petrolic solvent 10-13, N-BUTYL ACETATE 4-6;
Described modifying asphalt is made up of the raw material of following weight part: chlorinated rubber 11-14, pitch 92-94, stearylamide 0.2-0.4, Diisopropyl azodicarboxylate 0.2-0.4, octa-BDE 0.3-0.7, water 5-8, polyoxyethylenated castor oil 0.3-0.6, Magnesium Stearate 0.6-1.2, Nano carbon white 1-2, nano diatomite 0.4-0.8, turps 6-9, synourin oil 2-3, hexanediamine 1-2, rare earth nitrate 0.02-0.07, the atlapulgite 1-2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
2. a kind of rust-inhibiting paint improving finish paint brightness according to claim 1, is characterized in that, be made up of following concrete steps:
(1) kopol and polyolefin-wax are heated to molten state and organosilicon epoxy resin, modifying asphalt, tetraethylene pentamine, No. 200 petrolic solvents, N-BUTYL ACETATE, the mixing of vinylformic acid-2-hydroxy propyl ester are added in reactor, temperature is controlled at 200-250 ° of C, then under 600-800 rev/min, stir 2-3 hour after being uniformly mixed by mixture;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, high-visibility pigment, iron mica, titanium dioxide, silane coupling agent stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned clay-bonded sand according to claim 1, it is characterized in that, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410469136.7A CN104312362A (en) | 2014-09-16 | 2014-09-16 | Antirust paint for improving brightness of finish and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410469136.7A CN104312362A (en) | 2014-09-16 | 2014-09-16 | Antirust paint for improving brightness of finish and preparation method thereof |
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| CN104312362A true CN104312362A (en) | 2015-01-28 |
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| CN201410469136.7A Pending CN104312362A (en) | 2014-09-16 | 2014-09-16 | Antirust paint for improving brightness of finish and preparation method thereof |
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| US20080125542A1 (en) * | 2006-11-28 | 2008-05-29 | Masaaki Yamaya | Emulsion coating agent composition and coated products thereof |
| CN101481574A (en) * | 2009-01-21 | 2009-07-15 | 汕头市龙湖昌丰化工有限公司 | Coating capable of repetitively copying and transferring molding grating pattern and template film including the same |
| CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
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| CN102850536A (en) * | 2012-09-18 | 2013-01-02 | 江苏柏鹤涂料有限公司 | Silicon-containing acrylate-polyester resin, and finish coat and application thereof |
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2014
- 2014-09-16 CN CN201410469136.7A patent/CN104312362A/en active Pending
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| CN101481574A (en) * | 2009-01-21 | 2009-07-15 | 汕头市龙湖昌丰化工有限公司 | Coating capable of repetitively copying and transferring molding grating pattern and template film including the same |
| CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
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| CN102850536A (en) * | 2012-09-18 | 2013-01-02 | 江苏柏鹤涂料有限公司 | Silicon-containing acrylate-polyester resin, and finish coat and application thereof |
| CN103173091A (en) * | 2013-02-20 | 2013-06-26 | 江苏吉福新材料有限公司 | High temperature resistant anticorrosive paint |
| CN103820001A (en) * | 2013-11-29 | 2014-05-28 | 中国船舶重工集团公司第七二五研究所 | Silicone epoxy tie coat for low-surface-energy antifouling paint and preparation method for silicone epoxy tie coat |
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Application publication date: 20150128 |