CN102260450A - Anticorrosive paint - Google Patents
Anticorrosive paint Download PDFInfo
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- CN102260450A CN102260450A CN2011100393933A CN201110039393A CN102260450A CN 102260450 A CN102260450 A CN 102260450A CN 2011100393933 A CN2011100393933 A CN 2011100393933A CN 201110039393 A CN201110039393 A CN 201110039393A CN 102260450 A CN102260450 A CN 102260450A
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Abstract
The invention belongs to the field of metal paint, in particular relates to paint which can be used at a high temperature and resists corrosion. The invention aims to provide paint which still has strong mechanical strength, strong adhesion force and corrosion resistance when uses at a high temperature. According to the technical scheme provided by the invention, the high-temperature anticorrosive paint comprises a base stock, a solvent, a curing agent, pigment and filler, a silane coupling agent, a drier and assistants. The anticorrosive paint has the beneficial effects of good adhesion force, impact resistance, mechanical strength and corrosion resistance, the thickness of a paint film is 50 mu m, and the coating of the paint can resist the temperature of 600 DEG C.
Description
Technical field
The invention belongs to the metallic paint field, particularly relate to a kind of can at high temperature the use and corrosion resistant coating.
Background technology
Most protective systems all belong to normal temperature rot-resistant category, and the cement mill burn till the tails dedusting device, in the petrochemical factory in high-temperature high-pressure reaction kettle and the thermal power plant equipment such as boiler in deep-etching gases such as pyritous sulfur-bearing, chlorine, move mostly for a long time.Under such harsh conditions, the life-span of hardware reduces, and production cost increases, and brings great hidden danger to safety in production.Also develop some high temp anti-corrosion materials in recent years, but exist a little less than the physical strength, poor adhesive force and easily by problem such as corrosion-resistant.
Summary of the invention
Technical problem to be solved by this invention provides that a kind of still to have physical strength when at high temperature using strong, strong adhesion, corrosion resistant coating.
In order to address the above problem, technical scheme provided by the present invention is:
A kind of protective system comprises base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, and described base-material is at least a in modified organic silicon Resins, epoxy and ACRYLIC EMULSION, urethane resin, the water glass; Described solvent is at least a in Virahol, ethyl acetate, ethylene glycol, butanols, deionized water, sodium hydroxide solution or the dimethylbenzene; Described solidifying agent is at least a among polyamide 6 50,651 or the 330#; Described color stuffing is at least a in sepiolite powder, zirconia powder, kaolin, aluminium triphosphate, glass flake, light calcium carbonate, titanium dioxide, aluminum oxide powder, terra alba, asbestos powder, the wollastonite powder; Described silane coupling agent is at least a in r-aminopropyltriethoxywerene werene, r-sulfydryl third class triethoxyl silane or the r glycidyl ether Trimethoxy silane; Described siccative is at least a in octylate or the epoxy hydrochlorate; Described auxiliary agent is at least a in film auxiliary agent, the wetting agent.
Preferably, described octylate is zinc octoate, sad magnesium, cobalt octoate, iron octoate; Described epoxy hydrochlorate is epoxyeicosatrienoic acid cobalt, epoxyeicosatrienoic acid nickel, epoxyeicosatrienoic acid manganese, epoxyeicosatrienoic acid zinc, epoxyeicosatrienoic acid calcium, epoxyeicosatrienoic acid potassium, epoxyeicosatrienoic acid zirconium epoxyeicosatrienoic acid vanadium.
Preferably, the weight percent of each component is:
Beneficial effect of the present invention is: the present invention is to be base-material with modified organic silicone resin and solidifying agent, adds thermostable rustproof color stuffing, silane coupling agent and siccative, auxiliary agent and solvent composition.This coating introducing, ACRYLIC EMULSION or vibrin etc. have good sticking power, impact resistance and physical strength, and coating thickness is 50 μ m, and coating can anti-600 ℃ of temperature, and have good anti-corrosion.This coating application is convenient, is widely used in various high temperature resistant equipment.
Embodiment
Embodiment 1
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 39.39%, this embodiment solvent is a Virahol, its weight percent is 50%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 3.5%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 5%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.1%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.01%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 2%.
Embodiment 2
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 46.45%, this embodiment solvent is a Virahol, its weight percent is 41%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 3.4%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 7%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.2%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.05%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.9%.
Embodiment 3
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 38.5%, this embodiment solvent is a Virahol, its weight percent is 48%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 3.3%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 8%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.3%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.1%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.8%.
Embodiment 4
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 41.65%, this embodiment solvent is a Virahol, its weight percent is 43%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 3.1%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 10%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.4%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.15%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.7%.
Embodiment 5
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 41.7%, this embodiment solvent is a Virahol, its weight percent is 41%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 3%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 12%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.5%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.2%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.6%.
Embodiment 6
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 31.75%, this embodiment solvent is a Virahol, its weight percent is 49%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 2.9%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 14%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.6%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.25%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.5%.
Embodiment 7
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 42.9%, this embodiment solvent is a Virahol, its weight percent is 36%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 2.7%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 16%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.7%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.3%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.4%.
Embodiment 8
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 43.95%, this embodiment solvent is a Virahol, its weight percent is 33%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 2.6%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 18%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.8%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.35%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.3%.
Embodiment 9
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 29%, this embodiment solvent is a Virahol, its weight percent is 31%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 2.5%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 35%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 0.9%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.4%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.2%.
Embodiment 10
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 37%, this embodiment solvent is a Virahol, its weight percent is 25.15%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 2.3%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 33%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 1%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.45%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1.1%.
Embodiment 11
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 37.4%, this embodiment solvent is a Virahol, its weight percent is 27%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 2%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 31%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 1.1%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.5%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 1%.
Embodiment 12
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 35.62%, this embodiment solvent is a Virahol, its weight percent is 25%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 1.8%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 35%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 1.2%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.48%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 0.9%.
Embodiment 13
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 10%, this embodiment solvent is a Virahol, its weight percent is 55%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 1.6%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 30.87%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 1.3%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.43%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 0.8%.
Embodiment 14
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 39%, this embodiment solvent is a Virahol, its weight percent is 32.12%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 1.4%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 25%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 1.4%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.38%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 0.7%.
Embodiment 15
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 24.37%, this embodiment solvent is a Virahol, its weight percent is 49%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 1.2%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 23%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 1.6%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.33%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 0.5%.
Embodiment 16
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 20%, this embodiment solvent is a Virahol, its weight percent is 54.67%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 1%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 22%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 1.8%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.23%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 0.3%.
Embodiment 17
A kind of protective system, comprise base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, base-material in the present embodiment is a modified organic silicon Resins, epoxy, its weight percent 55%, this embodiment solvent is a Virahol, its weight percent is 26%, solidifying agent among this embodiment is a polyamide 6 50, its mass percent is 0.8%, color stuffing among this embodiment is a sepiolite powder, its mass percent is 15.82%, and the silane coupling agent in the present embodiment is the r-aminopropyltriethoxywerene werene, and weight percent is 2%, siccative in the present embodiment is an octylate zinc, its weight percent is 0.18%, and the auxiliary agent in the present embodiment is the film auxiliary agent, and its weight percent is 0.2%.
Base-material among the embodiment 1 to embodiment 17 can be at least a in modified organic silicon Resins, epoxy and ACRYLIC EMULSION, urethane resin, the water glass;
Solvent among the embodiment 1 to embodiment 17 can be at least a in Virahol, ethyl acetate, ethylene glycol, butanols, deionized water, sodium hydroxide solution or the dimethylbenzene;
Solidifying agent among the embodiment 1 to embodiment 17 can be at least a among polyamide 6 50,651 or the 330#;
Color stuffing among the embodiment 1 to embodiment 17 can be at least a in sepiolite powder, zirconia powder, kaolin, aluminium triphosphate, glass flake, light calcium carbonate, titanium dioxide, aluminum oxide powder, terra alba, asbestos powder, the wollastonite powder;
Silane coupling agent among the embodiment 1 to embodiment 17 can be at least a in r-aminopropyltriethoxywerene werene, r-sulfydryl third class triethoxyl silane or the r glycidyl ether Trimethoxy silane;
Siccative among the embodiment 1 to embodiment 17 can be at least a in octylate or the epoxy hydrochlorate, and octylate is zinc octoate, sad magnesium, cobalt octoate, iron octoate; The epoxy hydrochlorate is epoxyeicosatrienoic acid cobalt, epoxyeicosatrienoic acid nickel, epoxyeicosatrienoic acid manganese, epoxyeicosatrienoic acid zinc, epoxyeicosatrienoic acid calcium, epoxyeicosatrienoic acid potassium, epoxyeicosatrienoic acid zirconium epoxyeicosatrienoic acid vanadium;
Auxiliary agent among the embodiment 1 to embodiment 17 can be at least a in film auxiliary agent, the wetting agent
The preparation process of the protective system among the embodiment 1 to embodiment 17 is:
(1), and stirs with color stuffing, auxiliary agent, solvent;
(2) add siccative, stir;
(3) add base-material, silane coupling agent, solidifying agent, stir;
Purposes of the present invention is: the cement mill burn till the tails dedusting device, places such as boiler, chimney of electric plant can be used in petrochemical factory's mesohigh reactor and the thermal power plant.
Claims (3)
1. a protective system is characterized in that comprising base-material, solvent, solidifying agent, color stuffing, silane coupling agent, siccative, auxiliary agent, and described base-material is at least a in modified organic silicon Resins, epoxy and ACRYLIC EMULSION, urethane resin, the water glass; Described solvent is at least a in Virahol, ethyl acetate, ethylene glycol, butanols, deionized water, sodium hydroxide solution or the dimethylbenzene; Described solidifying agent is at least a among polyamide 6 50,651 or the 330#; Described color stuffing is at least a in sepiolite powder, zirconia powder, kaolin, aluminium triphosphate, glass flake, light calcium carbonate, titanium dioxide, aluminum oxide powder, terra alba, asbestos powder, the wollastonite powder; Described silane coupling agent is at least a in r-aminopropyltriethoxywerene werene, r-sulfydryl third class triethoxyl silane or the r glycidyl ether Trimethoxy silane; Described siccative is at least a in octylate or the epoxy hydrochlorate; Described auxiliary agent is at least a in film auxiliary agent, the wetting agent.
2. a kind of protective system according to claim 1 is characterized in that: described octylate is zinc octoate, sad magnesium, cobalt octoate, iron octoate; Described epoxy hydrochlorate is epoxyeicosatrienoic acid cobalt, epoxyeicosatrienoic acid nickel, epoxyeicosatrienoic acid manganese, epoxyeicosatrienoic acid zinc, epoxyeicosatrienoic acid calcium, epoxyeicosatrienoic acid potassium, epoxyeicosatrienoic acid zirconium epoxyeicosatrienoic acid vanadium.
3. a kind of protective system according to claim 1 is characterized in that the weight percent of each component is:
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011100393933A CN102260450A (en) | 2011-02-17 | 2011-02-17 | Anticorrosive paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100393933A CN102260450A (en) | 2011-02-17 | 2011-02-17 | Anticorrosive paint |
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Application publication date: 20111130 |