CN106752824A - A kind of transport vehicle inwall anticorrosive and preparation method thereof - Google Patents

A kind of transport vehicle inwall anticorrosive and preparation method thereof Download PDF

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Publication number
CN106752824A
CN106752824A CN201611199374.6A CN201611199374A CN106752824A CN 106752824 A CN106752824 A CN 106752824A CN 201611199374 A CN201611199374 A CN 201611199374A CN 106752824 A CN106752824 A CN 106752824A
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China
Prior art keywords
parts
transport vehicle
vehicle inwall
inwall anticorrosive
anticorrosive
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Pending
Application number
CN201611199374.6A
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Chinese (zh)
Inventor
刘如义
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Tianjin Tong Polytron Technologies Inc
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Tianjin Tong Polytron Technologies Inc
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Priority to CN201611199374.6A priority Critical patent/CN106752824A/en
Publication of CN106752824A publication Critical patent/CN106752824A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of transport vehicle inwall anticorrosive and preparation method thereof.Raw material including following parts by weight:20 40 parts of glass dust, 10 15 parts of zinc acrylate resin, 12 16 parts of polyurethane, 35 parts of barium sulfate, 35 parts of titanium white, 35 parts of dispersant, 38 parts of preservative, 24 parts of coupling agent, 24 parts of curing agent, 35 parts of thickener, 30 50 parts of water.Chemical material transport vehicle inwall anticorrosive prepared by the present invention, antiseptic property is good, easy to use, is applied to transport vehicle inwall, long service life, it is not easy to stain dirt, uses for a long time without changing.

Description

A kind of transport vehicle inwall anticorrosive and preparation method thereof
Technical field
The present invention relates to wholesale business technical field, more particularly to a kind of transport vehicle inwall anticorrosive and its preparation side Method.
Background technology
The transport of chemical material such as oil, Polymer Solution, latex, azide etc. needs special haulage vehicle, fortune The in-car wall of defeated vehicle needs to take anti-corrosion measure, and general to be prepared using difficult corrosion material, cost is high, and anti-corrosion is coated using inwall The method of erosion is a kind of selection well, but, current anticorrosive service life is short, and easily accumulates dirt, changes It is difficult.
Patent 201510346954.2 discloses a kind of shaft in wall anti-corrosion method, including contains admittedly to shaft in wall addition It is the silicon zirconium complex liquid that 10~50%, temperature is 30~90 DEG C to measure, and precipitation membrane is formed in shaft in wall;Then, in precipitation membrane The crude oil of 1~10% fluorine-containing surfactant and/or organic silicon surfactant is added, absorption is formed on the basis of precipitation membrane Oil film.The shaft in wall anti-corrosion method, can strengthen the corrosion resistance of shaft in wall, extend its service life.But, in pit shaft After wall coated with precipitated film, dirt is easily accumulated, the use to the borehole wall causes trouble.
The content of the invention
The present invention be in order to overcome above-mentioned defect in the prior art, propose a kind of transport vehicle inwall anticorrosive and its Preparation method.
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:Glass dust 20-40 parts, propylene 10-15 parts of sour zinc resin, polyurethane 12-16 parts, barium sulfate 3-5 parts, titanium white 3-5 parts, dispersant 3-5 parts, preservative 3-8 parts, Coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, water 30-50 parts.
The dispersant be zinc acetate, acrylic acid -2- acrylamide-2-methyl propane sulfonic copolymers, hydroxypropyl chitosan, Phosphorus pentasulfide, to one or more in isopropoxy methyl benzoate.
The preservative is Tebuconazole, Cyproconazole, propiconazole, thiophanate methyl, titanium dioxide, to carboxyl benzoic acid first One or more in ester.
The coupling agent is dimethyl silicone polymer, tetraethyl orthosilicate, silane coupler, boric acid ester coupler, Aluminate One or more in coupling agent.
The curing agent be calcium lignosulfonate, sodium lignin sulfonate, gypsum, NPE, carbon peroxy acid- One or more in O, O- (1,1- dimethyl propyls)-O- (2- ethylhexyls) ester.
The thickener is polyethylene glycol, ammonium persulfate, sucrose fatty ester, dibutyl tin laurate, eriochrome black T In one or more.
Also contain 1-3 parts of potassium tantalate in the material.
The preparation method of above-mentioned transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, glass dust 20-40 parts, zinc acrylate resin 10-15 parts, polyurethane 12-16 parts, sulfuric acid Barium 3-5 parts, titanium white 3-5 parts, it is well mixed, adds 30-50 parts of water, stirs 10-20min;
(2) 3-5 parts of dispersant, preservative 3-8 parts, coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, ball are added Mill 10-20min, is made.
Compared with prior art, the present invention has the advantages that:Transport vehicle inwall anticorrosion prepared by the present invention Material, antiseptic property is good, easy to use, is applied to transport vehicle inwall, long service life, it is not easy to stain dirt, for a long time Using without changing.
Specific embodiment
Specific embodiment of the invention is described in detail below, it is to be understood that protection scope of the present invention is not Limited by specific embodiment.
Embodiment 1
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:30 parts of glass dust, zinc acrylate resin 12 parts of resin, 14 parts of polyurethane, 4 parts of barium sulfate, 4 parts of titanium white, 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer, 3 parts of calcium lignosulfonate, 4 parts of polyethylene glycol, 40 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) 30 parts of glass dust, 12 parts of zinc acrylate resin, 14 parts of polyurethane, 4 parts of barium sulfate, titanium are taken according to parts by weight White 4 parts, it is well mixed, adds 40 parts of water, stirs 15min;
(2) 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer, 3 parts of calcium lignosulfonate, polyethylene glycol are added 4 parts, ball milling 15min is made.
Embodiment 2
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:20 parts of glass dust, zinc acrylate resin 10 parts of resin, 12 parts of polyurethane, 3 parts of barium sulfate, 3 parts of titanium white, acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer 3 Part, 3 parts of thiophanate methyl, 2 parts of tetraethyl orthosilicate, 2 parts of gypsum, 3 parts of ammonium persulfate, 30 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 20 parts of glass dust, 10 parts of zinc acrylate resin, 12 parts of polyurethane, 3 parts of barium sulfate, titanium are taken White 3 parts, it is well mixed, adds 30 parts of water, stirs 10min;
(2) 3 parts of acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer, 3 parts of thiophanate methyl, positive silicic acid second are added 2 parts of ester, 2 parts of gypsum, 3 parts of ammonium persulfate, ball milling 10min is made.
Embodiment 3
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:40 parts of glass dust, zinc acrylate resin 15 parts of resin, 16 parts of polyurethane, 5 parts of barium sulfate, 5 parts of titanium white, 5 parts of hydroxypropyl chitosan, 8 parts of titanium dioxide, silane coupler 4 Part, 4 parts of NPE, 5 parts of sucrose fatty ester, 50 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 40 parts of glass dust, 15 parts of zinc acrylate resin, 16 parts of polyurethane, 5 parts of barium sulfate, titanium are taken White 5 parts, it is well mixed, adds 50 parts of water, stirs 20min;
(2) 5 parts of hydroxypropyl chitosan of addition, 8 parts of titanium dioxide, 4 parts of silane coupler, 4 parts of NPE, 5 parts of sucrose fatty ester, ball milling 20min is made.
Embodiment 4
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:22 parts of glass dust, zinc acrylate resin 11 parts of resin, 13 parts of polyurethane, 3 parts of barium sulfate, 5 parts of titanium white, 5 parts of phosphorus pentasulfide, to 3 parts of carboxyl methyl benzoate, boric acid 4 parts of ester coupling agent, 2 parts of carbon peroxy acid-O, O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T, 38 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 22 parts of glass dust, 11 parts of zinc acrylate resin, 13 parts of polyurethane, 3 parts of barium sulfate, titanium are taken White 5 parts, it is well mixed, adds 38 parts of water, stirs 12min;
(2) 5 parts of phosphorus pentasulfide is added, to 3 parts of carboxyl methyl benzoate, 4 parts of boric acid ester coupler, carbon peroxy acid-O, 2 parts of O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T, ball milling 18min is made.
Embodiment 5
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:22 parts of glass dust, zinc acrylate resin 11 parts of resin, 13 parts of polyurethane, 3 parts of barium sulfate, 5 parts of titanium white, 5 parts of phosphorus pentasulfide, to 3 parts of carboxyl methyl benzoate, boric acid 4 parts of ester coupling agent, 2 parts of carbon peroxy acid-O, O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T, 38 parts of water, 2 parts of potassium tantalate.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 22 parts of glass dust, 11 parts of zinc acrylate resin, 13 parts of polyurethane, 3 parts of barium sulfate, titanium are taken White 5 parts, it is well mixed, adds 38 parts of water, stirs 12min;
(2) 5 parts of phosphorus pentasulfide is added, to 3 parts of carboxyl methyl benzoate, 4 parts of boric acid ester coupler, carbon peroxy acid-O, 2 parts of O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T, 2 parts of potassium tantalate, ball milling 18min, system Into.
Embodiment 6
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:30 parts of glass dust, zinc acrylate resin 12 parts of resin, 14 parts of polyurethane, 4 parts of barium sulfate, 4 parts of titanium white, 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer, 3 parts of calcium lignosulfonate, 4 parts of polyethylene glycol, 10 parts of benzyl lactate, 40 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 30 parts of glass dust, 12 parts of zinc acrylate resin, 14 parts of polyurethane, 4 parts of barium sulfate, titanium are taken White 4 parts, it is well mixed, adds 40 parts of water, stirs 15min;
(2) 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer, 3 parts of calcium lignosulfonate, polyethylene glycol are added 4 parts, 10 parts of benzyl lactate, ball milling 15min is made.
Embodiment 7
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:20 parts of glass dust, zinc acrylate resin 10 parts of resin, 12 parts of polyurethane, 3 parts of barium sulfate, 3 parts of titanium white, acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer 3 Part, 3 parts of thiophanate methyl, 2 parts of tetraethyl orthosilicate, 2 parts of gypsum, 3 parts of ammonium persulfate, 4- oxo tetrahydrochysene thiophene phenol -3- carboxylate methyl esters 10 parts, 30 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 20 parts of glass dust, 10 parts of zinc acrylate resin, 12 parts of polyurethane, 3 parts of barium sulfate, titanium are taken White 3 parts, 10 parts of 4- oxo tetrahydrochysene thiophene phenol -3- carboxylate methyl esters are well mixed, and add 30 parts of water, stir 10min;
(2) 3 parts of acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer, 3 parts of thiophanate methyl, positive silicic acid second are added 2 parts of ester, 2 parts of gypsum, 3 parts of ammonium persulfate, ball milling 10min is made.
Comparative example 1
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:40 parts of glass dust, polyurethane 16 Part, 5 parts of barium sulfate, 5 parts of titanium white, 5 parts of hydroxypropyl chitosan, 8 parts of titanium dioxide, 4 parts of silane coupler, Nonyl pheno 4 parts of ether, 5 parts of sucrose fatty ester, 50 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 40 parts of glass dust is taken, 16 parts of polyurethane, 5 parts of barium sulfate, 5 parts of titanium white is well mixed, plus Enter 50 parts of water, stir 20min;
(2) 5 parts of hydroxypropyl chitosan of addition, 8 parts of titanium dioxide, 4 parts of silane coupler, 4 parts of NPE, 5 parts of sucrose fatty ester, ball milling 20min is made.
Comparative example 2
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:22 parts of glass dust, zinc acrylate resin 11 parts of resin, 13 parts of polyurethane, 3 parts of barium sulfate, 5 parts of titanium white, 5 parts of phosphorus pentasulfide, to 3 parts of carboxyl methyl benzoate, boric acid 4 parts of ester coupling agent, 38 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 22 parts of glass dust, 11 parts of zinc acrylate resin, 13 parts of polyurethane, 3 parts of barium sulfate, titanium are taken White 5 parts, it is well mixed, adds 38 parts of water, stirs 12min;
(2) 5 parts of phosphorus pentasulfide is added, to 3 parts of carboxyl methyl benzoate, 4 parts of boric acid ester coupler, ball milling 18min, system Into.
Performance test:The anticorrosive of embodiment 1-7 and comparative example 1-2 is coated on the oil truck of transporting petroleum respectively Inwall, transported for 1 year, calculated corroded area and incrustation thickness, coating oil truck area 200m2.The results are shown in Table 1:
Table 1
Detection object Corroded area m2 Incrustation thickness mm
Embodiment 1 4m2 2mm
Embodiment 2 3m2 3mm
Embodiment 3 3m2 2mm
Embodiment 4 5m2 3mm
Embodiment 5 1m2 2mm
Embodiment 6 0 1mm
Embodiment 7 0 1mm
Comparative example 1 13m2 4mm
Comparative example 2 17m2 6mm
The embodiment of above formulation ratio and technique is to elaborate general principle of the invention and characteristic, and the present invention is not Limited by the implementation of above-mentioned technique and proportioning, without departing from the spirit and scope of the invention, the present invention can also make various Modification and conversion.Therefore these changes and modifications are belonged in the scope of the invention.

Claims (8)

1. a kind of transport vehicle inwall anticorrosive, it is characterised in that the raw material including following parts by weight:Glass dust 20- 40 parts, zinc acrylate resin 10-15 parts, polyurethane 12-16 parts, barium sulfate 3-5 parts, titanium white 3-5 parts, dispersant 3-5 parts, anti-corrosion Agent 3-8 parts, coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, water 30-50 parts.
2. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the dispersant is acetic acid Zinc, acrylic acid -2- acrylamide-2-methyl propane sulfonic copolymers, hydroxypropyl chitosan, phosphorus pentasulfide, to isopropoxy benzene One or more in methyl formate.
3. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the preservative is penta azoles Alcohol, Cyproconazole, propiconazole, thiophanate methyl, titanium dioxide, to one or more in carboxyl methyl benzoate.
4. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the coupling agent is poly- diformazan Radical siloxane, tetraethyl orthosilicate, silane coupler, boric acid ester coupler, one or more in aluminate coupling agent.
5. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the curing agent is lignin Sulfoacid calcium, sodium lignin sulfonate, gypsum, NPE, carbon peroxy acid-O, O- (1,1- dimethyl propyl)-O- (2- Ethylhexyl) one or more in ester.
6. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the thickener is poly- second two Alcohol, ammonium persulfate, sucrose fatty ester, dibutyl tin laurate, one or more in eriochrome black T.
7. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that also contain 1- in the material 3 parts of potassium tantalates.
8. the preparation method of the transport vehicle inwall anticorrosive described in claim 1, it is characterised in that in accordance with the following steps Carry out:
(1) according to parts by weight, glass dust 20-40 parts, zinc acrylate resin 10-15 parts, polyurethane 12-16 parts, barium sulfate are taken 3-5 parts, titanium white 3-5 parts, it is well mixed, adds 30-50 parts of water, stirs 10-20min;
(2) 3-5 parts of dispersant, preservative 3-8 parts, coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, ball milling are added 10-20min, is made.
CN201611199374.6A 2016-12-22 2016-12-22 A kind of transport vehicle inwall anticorrosive and preparation method thereof Pending CN106752824A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117828A (en) * 2017-12-07 2018-06-05 安徽科汇钢结构工程有限公司 A kind of oxidation-resistant corrosion-resistant metallic paint

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53129235A (en) * 1977-04-18 1978-11-11 Lion Corp Method of anticorrosive coating
CN102260450A (en) * 2011-02-17 2011-11-30 湖南晟通科技集团有限公司 Anticorrosive paint
CN106186973A (en) * 2016-06-30 2016-12-07 浙江大学 A kind of antibacterial anticorrosive paint of photocatalysis and coating processes thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53129235A (en) * 1977-04-18 1978-11-11 Lion Corp Method of anticorrosive coating
CN102260450A (en) * 2011-02-17 2011-11-30 湖南晟通科技集团有限公司 Anticorrosive paint
CN106186973A (en) * 2016-06-30 2016-12-07 浙江大学 A kind of antibacterial anticorrosive paint of photocatalysis and coating processes thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117828A (en) * 2017-12-07 2018-06-05 安徽科汇钢结构工程有限公司 A kind of oxidation-resistant corrosion-resistant metallic paint

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