CN106752824A - A kind of transport vehicle inwall anticorrosive and preparation method thereof - Google Patents
A kind of transport vehicle inwall anticorrosive and preparation method thereof Download PDFInfo
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- CN106752824A CN106752824A CN201611199374.6A CN201611199374A CN106752824A CN 106752824 A CN106752824 A CN 106752824A CN 201611199374 A CN201611199374 A CN 201611199374A CN 106752824 A CN106752824 A CN 106752824A
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- Prior art keywords
- parts
- transport vehicle
- vehicle inwall
- inwall anticorrosive
- anticorrosive
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of transport vehicle inwall anticorrosive and preparation method thereof.Raw material including following parts by weight:20 40 parts of glass dust, 10 15 parts of zinc acrylate resin, 12 16 parts of polyurethane, 35 parts of barium sulfate, 35 parts of titanium white, 35 parts of dispersant, 38 parts of preservative, 24 parts of coupling agent, 24 parts of curing agent, 35 parts of thickener, 30 50 parts of water.Chemical material transport vehicle inwall anticorrosive prepared by the present invention, antiseptic property is good, easy to use, is applied to transport vehicle inwall, long service life, it is not easy to stain dirt, uses for a long time without changing.
Description
Technical field
The present invention relates to wholesale business technical field, more particularly to a kind of transport vehicle inwall anticorrosive and its preparation side
Method.
Background technology
The transport of chemical material such as oil, Polymer Solution, latex, azide etc. needs special haulage vehicle, fortune
The in-car wall of defeated vehicle needs to take anti-corrosion measure, and general to be prepared using difficult corrosion material, cost is high, and anti-corrosion is coated using inwall
The method of erosion is a kind of selection well, but, current anticorrosive service life is short, and easily accumulates dirt, changes
It is difficult.
Patent 201510346954.2 discloses a kind of shaft in wall anti-corrosion method, including contains admittedly to shaft in wall addition
It is the silicon zirconium complex liquid that 10~50%, temperature is 30~90 DEG C to measure, and precipitation membrane is formed in shaft in wall;Then, in precipitation membrane
The crude oil of 1~10% fluorine-containing surfactant and/or organic silicon surfactant is added, absorption is formed on the basis of precipitation membrane
Oil film.The shaft in wall anti-corrosion method, can strengthen the corrosion resistance of shaft in wall, extend its service life.But, in pit shaft
After wall coated with precipitated film, dirt is easily accumulated, the use to the borehole wall causes trouble.
The content of the invention
The present invention be in order to overcome above-mentioned defect in the prior art, propose a kind of transport vehicle inwall anticorrosive and its
Preparation method.
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:Glass dust 20-40 parts, propylene
10-15 parts of sour zinc resin, polyurethane 12-16 parts, barium sulfate 3-5 parts, titanium white 3-5 parts, dispersant 3-5 parts, preservative 3-8 parts,
Coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, water 30-50 parts.
The dispersant be zinc acetate, acrylic acid -2- acrylamide-2-methyl propane sulfonic copolymers, hydroxypropyl chitosan,
Phosphorus pentasulfide, to one or more in isopropoxy methyl benzoate.
The preservative is Tebuconazole, Cyproconazole, propiconazole, thiophanate methyl, titanium dioxide, to carboxyl benzoic acid first
One or more in ester.
The coupling agent is dimethyl silicone polymer, tetraethyl orthosilicate, silane coupler, boric acid ester coupler, Aluminate
One or more in coupling agent.
The curing agent be calcium lignosulfonate, sodium lignin sulfonate, gypsum, NPE, carbon peroxy acid-
One or more in O, O- (1,1- dimethyl propyls)-O- (2- ethylhexyls) ester.
The thickener is polyethylene glycol, ammonium persulfate, sucrose fatty ester, dibutyl tin laurate, eriochrome black T
In one or more.
Also contain 1-3 parts of potassium tantalate in the material.
The preparation method of above-mentioned transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, glass dust 20-40 parts, zinc acrylate resin 10-15 parts, polyurethane 12-16 parts, sulfuric acid
Barium 3-5 parts, titanium white 3-5 parts, it is well mixed, adds 30-50 parts of water, stirs 10-20min;
(2) 3-5 parts of dispersant, preservative 3-8 parts, coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, ball are added
Mill 10-20min, is made.
Compared with prior art, the present invention has the advantages that:Transport vehicle inwall anticorrosion prepared by the present invention
Material, antiseptic property is good, easy to use, is applied to transport vehicle inwall, long service life, it is not easy to stain dirt, for a long time
Using without changing.
Specific embodiment
Specific embodiment of the invention is described in detail below, it is to be understood that protection scope of the present invention is not
Limited by specific embodiment.
Embodiment 1
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:30 parts of glass dust, zinc acrylate resin
12 parts of resin, 14 parts of polyurethane, 4 parts of barium sulfate, 4 parts of titanium white, 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer,
3 parts of calcium lignosulfonate, 4 parts of polyethylene glycol, 40 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) 30 parts of glass dust, 12 parts of zinc acrylate resin, 14 parts of polyurethane, 4 parts of barium sulfate, titanium are taken according to parts by weight
White 4 parts, it is well mixed, adds 40 parts of water, stirs 15min;
(2) 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer, 3 parts of calcium lignosulfonate, polyethylene glycol are added
4 parts, ball milling 15min is made.
Embodiment 2
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:20 parts of glass dust, zinc acrylate resin
10 parts of resin, 12 parts of polyurethane, 3 parts of barium sulfate, 3 parts of titanium white, acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer 3
Part, 3 parts of thiophanate methyl, 2 parts of tetraethyl orthosilicate, 2 parts of gypsum, 3 parts of ammonium persulfate, 30 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 20 parts of glass dust, 10 parts of zinc acrylate resin, 12 parts of polyurethane, 3 parts of barium sulfate, titanium are taken
White 3 parts, it is well mixed, adds 30 parts of water, stirs 10min;
(2) 3 parts of acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer, 3 parts of thiophanate methyl, positive silicic acid second are added
2 parts of ester, 2 parts of gypsum, 3 parts of ammonium persulfate, ball milling 10min is made.
Embodiment 3
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:40 parts of glass dust, zinc acrylate resin
15 parts of resin, 16 parts of polyurethane, 5 parts of barium sulfate, 5 parts of titanium white, 5 parts of hydroxypropyl chitosan, 8 parts of titanium dioxide, silane coupler 4
Part, 4 parts of NPE, 5 parts of sucrose fatty ester, 50 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 40 parts of glass dust, 15 parts of zinc acrylate resin, 16 parts of polyurethane, 5 parts of barium sulfate, titanium are taken
White 5 parts, it is well mixed, adds 50 parts of water, stirs 20min;
(2) 5 parts of hydroxypropyl chitosan of addition, 8 parts of titanium dioxide, 4 parts of silane coupler, 4 parts of NPE,
5 parts of sucrose fatty ester, ball milling 20min is made.
Embodiment 4
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:22 parts of glass dust, zinc acrylate resin
11 parts of resin, 13 parts of polyurethane, 3 parts of barium sulfate, 5 parts of titanium white, 5 parts of phosphorus pentasulfide, to 3 parts of carboxyl methyl benzoate, boric acid
4 parts of ester coupling agent, 2 parts of carbon peroxy acid-O, O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T,
38 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 22 parts of glass dust, 11 parts of zinc acrylate resin, 13 parts of polyurethane, 3 parts of barium sulfate, titanium are taken
White 5 parts, it is well mixed, adds 38 parts of water, stirs 12min;
(2) 5 parts of phosphorus pentasulfide is added, to 3 parts of carboxyl methyl benzoate, 4 parts of boric acid ester coupler, carbon peroxy acid-O,
2 parts of O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T, ball milling 18min is made.
Embodiment 5
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:22 parts of glass dust, zinc acrylate resin
11 parts of resin, 13 parts of polyurethane, 3 parts of barium sulfate, 5 parts of titanium white, 5 parts of phosphorus pentasulfide, to 3 parts of carboxyl methyl benzoate, boric acid
4 parts of ester coupling agent, 2 parts of carbon peroxy acid-O, O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T,
38 parts of water, 2 parts of potassium tantalate.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 22 parts of glass dust, 11 parts of zinc acrylate resin, 13 parts of polyurethane, 3 parts of barium sulfate, titanium are taken
White 5 parts, it is well mixed, adds 38 parts of water, stirs 12min;
(2) 5 parts of phosphorus pentasulfide is added, to 3 parts of carboxyl methyl benzoate, 4 parts of boric acid ester coupler, carbon peroxy acid-O,
2 parts of O- (1,1- dimethyl propyl)-O- (2- ethylhexyls) ester, 3 parts of eriochrome black T, 2 parts of potassium tantalate, ball milling 18min, system
Into.
Embodiment 6
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:30 parts of glass dust, zinc acrylate resin
12 parts of resin, 14 parts of polyurethane, 4 parts of barium sulfate, 4 parts of titanium white, 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer,
3 parts of calcium lignosulfonate, 4 parts of polyethylene glycol, 10 parts of benzyl lactate, 40 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 30 parts of glass dust, 12 parts of zinc acrylate resin, 14 parts of polyurethane, 4 parts of barium sulfate, titanium are taken
White 4 parts, it is well mixed, adds 40 parts of water, stirs 15min;
(2) 4 parts of zinc acetate, 6 parts of Tebuconazole, 3 parts of dimethyl silicone polymer, 3 parts of calcium lignosulfonate, polyethylene glycol are added
4 parts, 10 parts of benzyl lactate, ball milling 15min is made.
Embodiment 7
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:20 parts of glass dust, zinc acrylate resin
10 parts of resin, 12 parts of polyurethane, 3 parts of barium sulfate, 3 parts of titanium white, acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer 3
Part, 3 parts of thiophanate methyl, 2 parts of tetraethyl orthosilicate, 2 parts of gypsum, 3 parts of ammonium persulfate, 4- oxo tetrahydrochysene thiophene phenol -3- carboxylate methyl esters
10 parts, 30 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 20 parts of glass dust, 10 parts of zinc acrylate resin, 12 parts of polyurethane, 3 parts of barium sulfate, titanium are taken
White 3 parts, 10 parts of 4- oxo tetrahydrochysene thiophene phenol -3- carboxylate methyl esters are well mixed, and add 30 parts of water, stir 10min;
(2) 3 parts of acrylic acid -2- acrylamide-2-methyl propane sulfonics copolymer, 3 parts of thiophanate methyl, positive silicic acid second are added
2 parts of ester, 2 parts of gypsum, 3 parts of ammonium persulfate, ball milling 10min is made.
Comparative example 1
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:40 parts of glass dust, polyurethane 16
Part, 5 parts of barium sulfate, 5 parts of titanium white, 5 parts of hydroxypropyl chitosan, 8 parts of titanium dioxide, 4 parts of silane coupler, Nonyl pheno
4 parts of ether, 5 parts of sucrose fatty ester, 50 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 40 parts of glass dust is taken, 16 parts of polyurethane, 5 parts of barium sulfate, 5 parts of titanium white is well mixed, plus
Enter 50 parts of water, stir 20min;
(2) 5 parts of hydroxypropyl chitosan of addition, 8 parts of titanium dioxide, 4 parts of silane coupler, 4 parts of NPE,
5 parts of sucrose fatty ester, ball milling 20min is made.
Comparative example 2
A kind of transport vehicle inwall anticorrosive, including following parts by weight raw material:22 parts of glass dust, zinc acrylate resin
11 parts of resin, 13 parts of polyurethane, 3 parts of barium sulfate, 5 parts of titanium white, 5 parts of phosphorus pentasulfide, to 3 parts of carboxyl methyl benzoate, boric acid
4 parts of ester coupling agent, 38 parts of water.
The preparation method of above-mentioned chemical material transport vehicle inwall anticorrosive, is carried out in accordance with the following steps:
(1) according to parts by weight, 22 parts of glass dust, 11 parts of zinc acrylate resin, 13 parts of polyurethane, 3 parts of barium sulfate, titanium are taken
White 5 parts, it is well mixed, adds 38 parts of water, stirs 12min;
(2) 5 parts of phosphorus pentasulfide is added, to 3 parts of carboxyl methyl benzoate, 4 parts of boric acid ester coupler, ball milling 18min, system
Into.
Performance test:The anticorrosive of embodiment 1-7 and comparative example 1-2 is coated on the oil truck of transporting petroleum respectively
Inwall, transported for 1 year, calculated corroded area and incrustation thickness, coating oil truck area 200m2.The results are shown in Table 1:
Table 1
Detection object | Corroded area m2 | Incrustation thickness mm |
Embodiment 1 | 4m2 | 2mm |
Embodiment 2 | 3m2 | 3mm |
Embodiment 3 | 3m2 | 2mm |
Embodiment 4 | 5m2 | 3mm |
Embodiment 5 | 1m2 | 2mm |
Embodiment 6 | 0 | 1mm |
Embodiment 7 | 0 | 1mm |
Comparative example 1 | 13m2 | 4mm |
Comparative example 2 | 17m2 | 6mm |
The embodiment of above formulation ratio and technique is to elaborate general principle of the invention and characteristic, and the present invention is not
Limited by the implementation of above-mentioned technique and proportioning, without departing from the spirit and scope of the invention, the present invention can also make various
Modification and conversion.Therefore these changes and modifications are belonged in the scope of the invention.
Claims (8)
1. a kind of transport vehicle inwall anticorrosive, it is characterised in that the raw material including following parts by weight:Glass dust 20-
40 parts, zinc acrylate resin 10-15 parts, polyurethane 12-16 parts, barium sulfate 3-5 parts, titanium white 3-5 parts, dispersant 3-5 parts, anti-corrosion
Agent 3-8 parts, coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, water 30-50 parts.
2. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the dispersant is acetic acid
Zinc, acrylic acid -2- acrylamide-2-methyl propane sulfonic copolymers, hydroxypropyl chitosan, phosphorus pentasulfide, to isopropoxy benzene
One or more in methyl formate.
3. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the preservative is penta azoles
Alcohol, Cyproconazole, propiconazole, thiophanate methyl, titanium dioxide, to one or more in carboxyl methyl benzoate.
4. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the coupling agent is poly- diformazan
Radical siloxane, tetraethyl orthosilicate, silane coupler, boric acid ester coupler, one or more in aluminate coupling agent.
5. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the curing agent is lignin
Sulfoacid calcium, sodium lignin sulfonate, gypsum, NPE, carbon peroxy acid-O, O- (1,1- dimethyl propyl)-O- (2-
Ethylhexyl) one or more in ester.
6. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that the thickener is poly- second two
Alcohol, ammonium persulfate, sucrose fatty ester, dibutyl tin laurate, one or more in eriochrome black T.
7. transport vehicle inwall anticorrosive according to claim 1, it is characterised in that also contain 1- in the material
3 parts of potassium tantalates.
8. the preparation method of the transport vehicle inwall anticorrosive described in claim 1, it is characterised in that in accordance with the following steps
Carry out:
(1) according to parts by weight, glass dust 20-40 parts, zinc acrylate resin 10-15 parts, polyurethane 12-16 parts, barium sulfate are taken
3-5 parts, titanium white 3-5 parts, it is well mixed, adds 30-50 parts of water, stirs 10-20min;
(2) 3-5 parts of dispersant, preservative 3-8 parts, coupling agent 2-4 parts, curing agent 2-4 parts, thickener 3-5 parts, ball milling are added
10-20min, is made.
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CN201611199374.6A CN106752824A (en) | 2016-12-22 | 2016-12-22 | A kind of transport vehicle inwall anticorrosive and preparation method thereof |
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CN201611199374.6A CN106752824A (en) | 2016-12-22 | 2016-12-22 | A kind of transport vehicle inwall anticorrosive and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108117828A (en) * | 2017-12-07 | 2018-06-05 | 安徽科汇钢结构工程有限公司 | A kind of oxidation-resistant corrosion-resistant metallic paint |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53129235A (en) * | 1977-04-18 | 1978-11-11 | Lion Corp | Method of anticorrosive coating |
CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
CN106186973A (en) * | 2016-06-30 | 2016-12-07 | 浙江大学 | A kind of antibacterial anticorrosive paint of photocatalysis and coating processes thereof |
-
2016
- 2016-12-22 CN CN201611199374.6A patent/CN106752824A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53129235A (en) * | 1977-04-18 | 1978-11-11 | Lion Corp | Method of anticorrosive coating |
CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
CN106186973A (en) * | 2016-06-30 | 2016-12-07 | 浙江大学 | A kind of antibacterial anticorrosive paint of photocatalysis and coating processes thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108117828A (en) * | 2017-12-07 | 2018-06-05 | 安徽科汇钢结构工程有限公司 | A kind of oxidation-resistant corrosion-resistant metallic paint |
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