CN102977666A - Zirconia loaded metal antirust paint and its preparation method - Google Patents
Zirconia loaded metal antirust paint and its preparation method Download PDFInfo
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- CN102977666A CN102977666A CN2012104325910A CN201210432591A CN102977666A CN 102977666 A CN102977666 A CN 102977666A CN 2012104325910 A CN2012104325910 A CN 2012104325910A CN 201210432591 A CN201210432591 A CN 201210432591A CN 102977666 A CN102977666 A CN 102977666A
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Abstract
The invention discloses a zirconia loaded metal antirust paint and its preparation method. The metal antirust paint comprises the following raw materials, by weight, 35-40 parts of an epoxy resin, 15-20 parts of a polytetrafluoroethylene resin, 23-28 parts of modified nanometer argil, 9-11 parts of zirconia, 8-10 parts of a butadiene-styrene latex, 1.3-1.8 parts of a tallow amine, 15-20 parts of polycaprolactone, 0.7-0.9 parts of glycerol monostearate, 0.4-0.6 parts of polybutylene terephthalate, 0.7-0.9 parts of poly-4-methyl-1-pentene, 0.4-0.6 parts of salicylic acid, 0.5-1.0 part of an oxidant 168, 3-5 parts of a modified styrene-acrylate emulsion, 0.8-1.2 parts of polyacrylic acid, 0.6-1.2 parts of vinyl-tri(beta-methoxyethoxy)silane, and 1.0-1.2 parts of fatty alcohol polyoxyethylene ether. The film of the metal antirust paint has the advantages of good adhesion, fast drying, good heat resistance, environmental protection and no pollution, the modified nanometer argil and the modified styrene-acrylate emulsion which are added into the raw materials improve the excellent performances of high-polymer materials in the raw materials, and simultaneously increase the corrosion and heat resistances of the metal antirust paint, and the preparation method has the advantages of simplicity, low cost and suitableness for large-scale production.
Description
Technical field
The present invention relates to metallic anti-rust paint of a kind of loaded zirconia and preparation method thereof, belong to the rush-resisting material technical field.
Background technology
Adopted in recent years industrial antirust paint protect metal take the epoxy zinc-rich lacquer as at most because the density ratio of metal zinc is larger, in order not make zinc powder settling or the settling velocity of the zinc powder that slows down, need in lacquer, add a certain amount of anti-sedimentation agent; The viscosity of the adding lacquer of anti-settling agent also increases thereupon, will select as much as possible the resin (E44) of small molecular weight when selecting polyamide resin; In order to satisfy brushing property, add a large amount of solvents in lacquer during construction, solvent serious harm workman's healthy, lacquer solvent evaporates contaminate environment, making of solvent in the air in drying process improved construction cost during construction; The fragility of paint film is large behind the small molecular weight resin solidification, metal heat-expansion shrinkage system greatly when temperature variation paint film easily chap or come off.
Summary of the invention
In order to alleviate shortcomings and deficiencies of the prior art, metallic anti-rust paint that provides a kind of loaded zirconia and preparation method thereof is provided the object of the invention.
The present invention adopts following technical scheme to achieve these goals:
The metallic anti-rust paint of loaded zirconia, the weight part of its constitutive material is: Resins, epoxy 35-40, teflon resin 15-20, modified Nano potter's clay 23-28, zirconium white 9-11; butadiene-styrene latex 8-10; tallow amine 1.3-1.8; vinegar 15-20 in the poly-caproic acid; stearic acid direactive glyceride 0.7-0.9; polybutylene terephthalate 0.4-0.6; poly--4-methyl-1-pentene 0.7-0.9; Whitfield's ointment 0.4-0.6; oxygenant 168 0.5-1.0; modifying cinepazid emulsion 3-5; polyacrylic acid 0.8-1.2; vinyl three ('beta '-methoxy oxyethyl group) silane 0.6-1.2 and fatty alcohol-polyoxyethylene ether 1.0-1.2.
The metallic anti-rust paint of loaded zirconia, the weight part of its constitutive material is: vinegar 18 in Resins, epoxy 38, teflon resin 18, modified Nano potter's clay 25, zirconium white 10, butadiene-styrene latex 9, tallow amine 1.5, the poly-caproic acid, stearic acid direactive glyceride 0.8, polybutylene terephthalate 0.5, poly--4-methyl-1-pentene 0.8, Whitfield's ointment 0.5, oxygenant 168 0.8, modifying cinepazid emulsion 4, polyacrylic acid 1, vinyl three ('beta '-methoxy oxyethyl group) silane 0.9 and fatty alcohol-polyoxyethylene ether 1.1.
The preparation method of the metallic anti-rust paint of loaded zirconia may further comprise the steps:
(1) weight part of pressing constitutive material is with Resins, epoxy, teflon resin, butadiene-styrene latex, zirconium white, modifying cinepazid emulsion, fatty alcohol-polyoxyethylene ether, modified Nano potter's clay and polyacrylic acid mixing and stirring, and high speed dispersion also is ground to below the 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar in tallow amine, the poly-caproic acid, stearic acid direactive glyceride, polybutylene terephthalate, poly--4-methyl-1-pentene, Whitfield's ointment, oxygenant 168 and vinyl three ('beta '-methoxy oxyethyl group) silane, at 700-800
Turn/
MinuteUnder the rotating speed high speed dispersion 10-15 minute, obtain finished product.
Described modified Nano potter's clay preparation method is that potter's clay mixes with the anilinomethyl triethoxysilane of 3-5%, be heated to 50-60 ℃ and stirred 20-30 minute, add again the nano silicon of 1-3%, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
Described modifying cinepazid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in the benzene emulsion, be mixed and heated to 70-80 ℃, and cooling obtains after 30-40 minute.
Beneficial effect of the present invention:
The metallic anti-rust paint paint film adhesion of the loaded zirconia of the present invention preparation is good, fast drying, good heat resistance, environment friendly and pollution-free, modified Nano potter's clay and modifying cinepazid emulsion have been added in the raw material, by the modification to nanometer potter's clay and benzene emulsion, improved the premium properties of the macromolecular material in the starting material, increased simultaneously erosion resistance and the thermotolerance of product, and preparation method of the present invention has been simple, cost is low, is fit to scale operation.
Embodiment
Embodiment:The metallic anti-rust paint of loaded zirconia, the weight part of its constitutive material is: vinegar 18 in Resins, epoxy 38, teflon resin 18, modified Nano potter's clay 25, zirconium white 10, butadiene-styrene latex 9, tallow amine 1.5, the poly-caproic acid, stearic acid direactive glyceride 0.8, polybutylene terephthalate 0.5, poly--4-methyl-1-pentene 0.8, Whitfield's ointment 0.5, oxygenant 168 0.8, modifying cinepazid emulsion 4, polyacrylic acid 1, vinyl three ('beta '-methoxy oxyethyl group) silane 0.9 and fatty alcohol-polyoxyethylene ether 1.1.
The preparation method of the metallic anti-rust paint of loaded zirconia may further comprise the steps:
(1) weight part of pressing constitutive material is with Resins, epoxy, teflon resin, butadiene-styrene latex, zirconium white, modifying cinepazid emulsion, fatty alcohol-polyoxyethylene ether, modified Nano potter's clay and polyacrylic acid mixing and stirring, and high speed dispersion also is ground to below the 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar in tallow amine, the poly-caproic acid, stearic acid direactive glyceride, polybutylene terephthalate, poly--4-methyl-1-pentene, Whitfield's ointment, oxygenant 168 and vinyl three ('beta '-methoxy oxyethyl group) silane, at 700-800
Turn/
MinuteUnder the rotating speed high speed dispersion 10-15 minute, obtain finished product.
Described modified Nano potter's clay preparation method is that potter's clay mixes with the anilinomethyl triethoxysilane of 3-5%, be heated to 50-60 ℃ and stirred 20-30 minute, add again the nano silicon of 1-3%, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
Described modifying cinepazid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in the benzene emulsion, be mixed and heated to 70-80 ℃, and cooling obtains after 30-40 minute.
Adopt the metallic anti-rust paint of embodiment 1 to carry out technology for detection, the result is as follows:
1, sticking power/level≤1 grade; 2, snappiness/level: 1 grade; 3, thermotolerance: 335 ℃ excellent; 4, alkali resistance: 20% sodium hydroxide stood intact in 36 days; 5, acid resistance 20% sulfuric acid stood intact in 35 days; 6, non-volatile content: 〉=84.7%.
Claims (5)
1. the metallic anti-rust paint of a loaded zirconia is characterized in that the weight part of its constitutive material is: Resins, epoxy 35-40, teflon resin 15-20, modified Nano potter's clay 23-28, zirconium white 9-11; butadiene-styrene latex 8-10; tallow amine 1.3-1.8; vinegar 15-20 in the poly-caproic acid; stearic acid direactive glyceride 0.7-0.9; polybutylene terephthalate 0.4-0.6; poly--4-methyl-1-pentene 0.7-0.9; Whitfield's ointment 0.4-0.6; oxygenant 168 0.5-1.0; modifying cinepazid emulsion 3-5; polyacrylic acid 0.8-1.2; vinyl three ('beta '-methoxy oxyethyl group) silane 0.6-1.2 and fatty alcohol-polyoxyethylene ether 1.0-1.2.
2. the metallic anti-rust paint of loaded zirconia according to claim 1 is characterized in that the weight part of its constitutive material is: vinegar 18 in Resins, epoxy 38, teflon resin 18, modified Nano potter's clay 25, zirconium white 10, butadiene-styrene latex 9, tallow amine 1.5, the poly-caproic acid, stearic acid direactive glyceride 0.8, polybutylene terephthalate 0.5, poly--4-methyl-1-pentene 0.8, Whitfield's ointment 0.5, oxygenant 168 0.8, modifying cinepazid emulsion 4, polyacrylic acid 1, vinyl three ('beta '-methoxy oxyethyl group) silane 0.9 and fatty alcohol-polyoxyethylene ether 1.1.
3. the preparation method of the metallic anti-rust paint of a loaded zirconia as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part of pressing constitutive material is with Resins, epoxy, teflon resin, butadiene-styrene latex, zirconium white, modifying cinepazid emulsion, fatty alcohol-polyoxyethylene ether, modified Nano potter's clay and polyacrylic acid mixing and stirring, and high speed dispersion also is ground to below the 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar in tallow amine, the poly-caproic acid, stearic acid direactive glyceride, polybutylene terephthalate, poly--4-methyl-1-pentene, Whitfield's ointment, oxygenant 168 and vinyl three ('beta '-methoxy oxyethyl group) silane, at 700-800
Turn/
MinuteUnder the rotating speed high speed dispersion 10-15 minute, obtain finished product.
4. the metallic anti-rust paint of loaded zirconia according to claim 1, it is characterized in that: described modified Nano potter's clay preparation method is that potter's clay mixes with the anilinomethyl triethoxysilane of 3-5%, being heated to 50-60 ℃ stirred 20-30 minute, the nano silicon that adds again 1-3%, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
5. the metallic anti-rust paint of loaded zirconia according to claim 1, it is characterized in that: described modifying cinepazid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in the benzene emulsion, be mixed and heated to 70-80 ℃, cool off after 30-40 minute and obtain.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210432591.0A CN102977666B (en) | 2012-11-02 | 2012-11-02 | Zirconia loaded metal antirust paint and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210432591.0A CN102977666B (en) | 2012-11-02 | 2012-11-02 | Zirconia loaded metal antirust paint and its preparation method |
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| Publication Number | Publication Date |
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| CN102977666A true CN102977666A (en) | 2013-03-20 |
| CN102977666B CN102977666B (en) | 2014-08-13 |
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| CN201210432591.0A Expired - Fee Related CN102977666B (en) | 2012-11-02 | 2012-11-02 | Zirconia loaded metal antirust paint and its preparation method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642366A (en) * | 2013-11-21 | 2014-03-19 | 江苏博思源防火材料科技有限公司 | Ageing and heat resistant wall coating and preparation method thereof |
| CN104513578A (en) * | 2014-11-28 | 2015-04-15 | 蚌埠南自仪表有限公司 | Lasting antifouling antirusting paint and preparation method thereof |
| CN106479287A (en) * | 2016-09-30 | 2017-03-08 | 合肥华运机械制造有限公司 | A kind of magnetic force pump case coating |
| CN115948082A (en) * | 2022-05-10 | 2023-04-11 | 首牵科技(广州)有限公司 | Water-based antirust coating for metal parts and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101292003A (en) * | 2005-10-20 | 2008-10-22 | 中国涂料株式会社 | Polyfunctional epoxy resin coating composition containing rust-preventive pigment, coating film obtained therefrom, base coated with the coating film, and method of rust prevention |
| CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
| JP2012001785A (en) * | 2010-06-18 | 2012-01-05 | Kansai Paint Co Ltd | Rust prevention treatment agent for metal |
-
2012
- 2012-11-02 CN CN201210432591.0A patent/CN102977666B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101292003A (en) * | 2005-10-20 | 2008-10-22 | 中国涂料株式会社 | Polyfunctional epoxy resin coating composition containing rust-preventive pigment, coating film obtained therefrom, base coated with the coating film, and method of rust prevention |
| JP2012001785A (en) * | 2010-06-18 | 2012-01-05 | Kansai Paint Co Ltd | Rust prevention treatment agent for metal |
| CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642366A (en) * | 2013-11-21 | 2014-03-19 | 江苏博思源防火材料科技有限公司 | Ageing and heat resistant wall coating and preparation method thereof |
| CN104513578A (en) * | 2014-11-28 | 2015-04-15 | 蚌埠南自仪表有限公司 | Lasting antifouling antirusting paint and preparation method thereof |
| CN106479287A (en) * | 2016-09-30 | 2017-03-08 | 合肥华运机械制造有限公司 | A kind of magnetic force pump case coating |
| CN115948082A (en) * | 2022-05-10 | 2023-04-11 | 首牵科技(广州)有限公司 | Water-based antirust coating for metal parts and preparation method thereof |
| CN115948082B (en) * | 2022-05-10 | 2024-02-02 | 首牵科技(广州)有限公司 | Water-based antirust paint for metal parts and preparation method thereof |
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| CN102977666B (en) | 2014-08-13 |
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