CN104312249B - Environmental colored antibacterial mastic powder - Google Patents

Environmental colored antibacterial mastic powder Download PDF

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Publication number
CN104312249B
CN104312249B CN201410631749.6A CN201410631749A CN104312249B CN 104312249 B CN104312249 B CN 104312249B CN 201410631749 A CN201410631749 A CN 201410631749A CN 104312249 B CN104312249 B CN 104312249B
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parts
powder
environmental
negative ion
titanium oxide
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CN104312249A (en
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黄美忠
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Junwon Energy Saving Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34Filling pastes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of environmental colored antibacterial mastic powder, its formula proportion is calculated by weight as: triple superphosphate cement 150~200 parts, white cement 150~200 parts, flyash 300~350 parts, natural colour sand 50~80 parts, negative ion antibiotic additive 20~30 parts, redispersable latex powder 13~18 parts, polyacrylonitrile fibre 0.1~2 parts, hydroxymethyl cellulose 0.1~2 parts, and inorganic pigment 1~10 parts;The formula proportion of wherein said negative ion antibiotic additive is calculated by weight as: montmorillonite 80~120 parts, nano titanium oxide 4~10 parts, silver nitrate 4~10 parts, and dodecylbenzene sodium sulfonate 0.1~0.5 part.Powder of lacquer putty for use on smooth surface of the present invention, natural in color, can not only be used for basic unit's alignment material, it is possible to replace coating to be used as decoration, safety and environmental protection, the anion that sustainable release is useful to health, it is possible to absorption objectionable impurities and gas, purify air.

Description

Environmental colored antibacterial mastic powder
Technical field
The invention belongs to building external paint technical field, be specifically related to a kind of environmental colored antibacterial mastic Powder.
Background technology
Powder of lacquer putty for use on is a kind of high-performance basic unit alignment material, in order to remove the rugged defect of metope.Greasy The performance of sub-powder has vital effect to wall decoration, and coating can be brushed once or repeatedly for several years, Putty then can not so do, particularly exterior wall putty, can only be disposably to carry out, otherwise, and once exterior wall On putty gone out quality problems, exterior wall latex paint the best on brush, all without success, and tie up afterwards Repairing very difficult, expense is the highest.
Tradition putty is made up of, in vain inorganic coagulation material (cement, ash calcium etc.), filler and inorganic additive Color, is used as basic unit levelling.Typically do not take into account that and directly make ornament materials of putty, common construction process, On metope is criticized and is scraped after putty, then prime, finish paint, and priming paint, finish paint are typically made up of organic material, The harmful substance such as Diazolidinyl Urea, toluene, this not only increases workload, reduces efficiency of construction, Waste resource, and pollute environment, human body is also had the biggest damaging effect.So, if can make For a kind of putty being directly used as decorative material for wall surface, and this putty has effect of anion releasing, Objectionable impurities in adsorbable air and gas, purify air, eliminates abnormal flavour, then for wall decoration and Environmental conservation is the most of great advantage.
Summary of the invention
The invention discloses a kind of environmental colored antibacterial mastic powder, wall decoration can be directly used as, its tool Having the anion releasing of excellence, purify air effect, its formula proportion is calculated by weight as: triple superphosphate Cement 150~200 parts, white cement 150~200 parts, flyash 300~350 parts, natural colour sand 50~ 80 parts, negative ion antibiotic additive 20~30 parts, redispersable latex powder 13~18 parts, polyacrylonitrile Fiber 0.1~2 parts, hydroxymethyl cellulose 0.1~2 parts, and inorganic pigment 1~10 parts;
The formula proportion of wherein said negative ion antibiotic additive is calculated by weight as: montmorillonite 80~120 Part, nano titanium oxide 4~10 parts, silver nitrate 4~10 parts, and dodecylbenzene sodium sulfonate 0.1~ 0.5 part.
The preparation method of described negative ion antibiotic additive is:
(1) add montmorillonite in a kettle., add the water that quality is montmorillonite quality 40 times, At a temperature of 70~80 DEG C, the speed with 500rpm stirs 1h;
(2) keep temperature constant with rotating speed, add dodecylbenzene sodium sulfonate, stir 30min;
(3) it is slowly added to silver nitrate and nano titanium oxide, cools the temperature to 60~70 DEG C, with 300rpm Speed stirring 2h;
(4) wash, filter, the solid obtained is dried in 120 DEG C of baking ovens;
(5) solid after drying is calcined under 800 DEG C of environment in nitrogen atmosphere, obtains metallic silver particles With the modified montmorillonoid micropowder material of nano titanium oxide load, it is described negative ion antibiotic additive.
The fineness of described white cement is 50~100 mesh.
The fineness of described triple superphosphate cement, flyash, inorganic pigment and natural colour sand all >=300 mesh.
Preferably, described inorganic pigment is ferrum oxide serial pigment.
Described redispersable latex powder is ethylene/vinyl acetate emulsion copolymer powder.
There is advantages that
(1) present invention is with silver nitrate for silver source, and montmorillonite is base material, adds that having excellent antibacterial sterilization makees Nano titanium oxide, through being sufficiently mixed stirring dipping, high-temperature heating in atmosphere of inert gases, Being prepared as the modified montmorillonoid material of nanometer silver and the load of nano titanium oxide high degree of dispersion, this material can Sustained release anion, the objectionable impurities in absorption air and gas, eliminate abnormal flavour, in effective clean room Outdoor air;
(2) present invention natural inorganic colour coloring earth using high-quality etc. is as face, filler, with triple superphosphate Cement, white cement as Binder Materials, the natural colour sand that additional appropriate natural in color is beautiful, preparation greasy Sub-powder is fine and smooth, construction is easy, cracking resistance, good weatherability, and various colors is colorful, complete alternative coating As decorative material for wall surface, time saving and energy saving, decrease the harmful gas pollution to environment of coating release.
Detailed description of the invention
Below by detailed description of the invention, the present invention will be further described in detail.
Embodiment 1
First prepare negative ion antibiotic additive, concretely comprise the following steps:
(1) add 80g montmorillonite in a kettle., add 3200g water, the temperature of 70~80 DEG C Under degree, the speed with 500rpm stirs 1h;
(2) keep temperature constant with rotating speed, add 0.1g dodecylbenzene sodium sulfonate, stir 30min;
(3) it is slowly added to 4g silver nitrate and 4g nano titanium oxide, cools the temperature to 60~70 DEG C, 2h is stirred with the speed of 300rpm;
(4) wash, filter, the solid obtained is dried in 120 DEG C of baking ovens;
(5) solid after drying is calcined under 800 DEG C of environment in nitrogen atmosphere, obtains metallic silver particles With the modified montmorillonoid micropowder material of nano titanium oxide load, it is described negative ion antibiotic additive.
Take the negative ion antibiotic additive 20g of above-mentioned preparation, triple superphosphate cement 150g, white cement 150g, powder Coal ash 300g, natural colour sand 50g, ethylene/vinyl acetate emulsion copolymer powder 13g, polyacrylonitrile fibre 0.1g, Hydroxymethyl cellulose 0.1g, and ferrum oxide serial pigment 1g, stir in mixing and blending machine, to obtain final product Described environmental colored antibacterial mastic powder.
Recording product negative ion concentration is 3350/cm3
Embodiment 2
First prepare negative ion antibiotic additive, concretely comprise the following steps:
(1) add 120g montmorillonite in a kettle., add 4800g water, the temperature of 70~80 DEG C Under degree, the speed with 500rpm stirs 1h;
(2) keep temperature constant with rotating speed, add 0.5g dodecylbenzene sodium sulfonate, stir 30min;
(3) it is slowly added to 10g silver nitrate and 10g nano titanium oxide, cools the temperature to 60~70 DEG C, 2h is stirred with the speed of 300rpm;
(4) wash, filter, the solid obtained is dried in 120 DEG C of baking ovens;
(5) solid after drying is calcined under 800 DEG C of environment in nitrogen atmosphere, obtains metallic silver particles With the modified montmorillonoid micropowder material of nano titanium oxide load, it is described negative ion antibiotic additive.
Take the negative ion antibiotic additive 30g of above-mentioned preparation, triple superphosphate cement 200g, white cement 200g, powder Coal ash 350g, natural colour sand 80g, ethylene/vinyl acetate emulsion copolymer powder 18g, polyacrylonitrile fibre 2g, Hydroxymethyl cellulose 2g, and ferrum oxide serial pigment 10g, stir in mixing and blending machine, to obtain final product Described environmental colored antibacterial mastic powder.
Recording product negative ion concentration is 3165/cm3
Embodiment 3
First prepare negative ion antibiotic additive, concretely comprise the following steps:
(1) add 100g montmorillonite in a kettle., add 4000g water, the temperature of 70~80 DEG C Under degree, the speed with 500rpm stirs 1h;
(2) keep temperature constant with rotating speed, add 0.3g dodecylbenzene sodium sulfonate, stir 30min;
(3) it is slowly added to 7g silver nitrate and 7g nano titanium oxide, cools the temperature to 60~70 DEG C, 2h is stirred with the speed of 300rpm;
(4) wash, filter, the solid obtained is dried in 120 DEG C of baking ovens;
(5) solid after drying is calcined under 800 DEG C of environment in nitrogen atmosphere, obtains metallic silver particles With the modified montmorillonoid micropowder material of nano titanium oxide load, it is described negative ion antibiotic additive.
Take the negative ion antibiotic additive 25g of above-mentioned preparation, triple superphosphate cement 180g, white cement 180g, powder Coal ash 330g, natural colour sand 65g, ethylene/vinyl acetate emulsion copolymer powder 16g, polyacrylonitrile fibre 1g, Hydroxymethyl cellulose 1g, and ferrum oxide serial pigment 5g, stir in mixing and blending machine, obtain institute State environmental colored antibacterial mastic powder.
Recording product negative ion concentration is 3235/cm3
Embodiment 4
First prepare negative ion antibiotic additive, concretely comprise the following steps:
(1) add 110g montmorillonite in a kettle., add 4400g water, the temperature of 70~80 DEG C Under degree, the speed with 500rpm stirs 1h;
(2) keep temperature constant with rotating speed, add 0.4g dodecylbenzene sodium sulfonate, stir 30min;
(3) it is slowly added to 9g silver nitrate and 6g nano titanium oxide, cools the temperature to 60~70 DEG C, 2h is stirred with the speed of 300rpm;
(4) wash, filter, the solid obtained is dried in 120 DEG C of baking ovens;
(5) solid after drying is calcined under 800 DEG C of environment in nitrogen atmosphere, obtains metallic silver particles With the modified montmorillonoid micropowder material of nano titanium oxide load, it is described negative ion antibiotic additive.
Take the negative ion antibiotic additive 28g of above-mentioned preparation, triple superphosphate cement 160g, white cement 190g, powder Coal ash 310g, natural colour sand 55g, ethylene/vinyl acetate emulsion copolymer powder 17g, polyacrylonitrile fibre 1.2g, Hydroxymethyl cellulose 0.7g, and ferrum oxide serial pigment 7g, stir in mixing and blending machine, to obtain final product Described environmental colored antibacterial mastic powder.
Recording product negative ion concentration is 3500/cm3
Embodiment 5
First prepare negative ion antibiotic additive, concretely comprise the following steps:
(1) add 90g montmorillonite in a kettle., add 3600g water, the temperature of 70~80 DEG C Under degree, the speed with 500rpm stirs 1h;
(2) keep temperature constant with rotating speed, add 0.2g dodecylbenzene sodium sulfonate, stir 30min;
(3) it is slowly added to 6g silver nitrate and 8g nano titanium oxide, cools the temperature to 60~70 DEG C, 2h is stirred with the speed of 300rpm;
(4) wash, filter, the solid obtained is dried in 120 DEG C of baking ovens;
(5) solid after drying is calcined under 800 DEG C of environment in nitrogen atmosphere, obtains metallic silver particles With the modified montmorillonoid micropowder material of nano titanium oxide load, it is described negative ion antibiotic additive.
Take the negative ion antibiotic additive 22g of above-mentioned preparation, triple superphosphate cement 185g, white cement 160g, powder Coal ash 340g, natural colour sand 75g, ethylene/vinyl acetate emulsion copolymer powder 14g, polyacrylonitrile fibre 1.5g, Hydroxymethyl cellulose 0.5g, and ferrum oxide serial pigment 3g, stir in mixing and blending machine, to obtain final product Described environmental colored antibacterial mastic powder.
Recording product negative ion concentration is 2970/cm3
Although specifically show and describe the present invention in conjunction with preferred embodiment, but the technology people of art Member should be understood that in the spirit and scope of the present invention limited without departing from appended claims, And in details, the present invention is made a variety of changes in form, be protection scope of the present invention.

Claims (7)

1. an environmental colored antibacterial mastic powder, it is characterised in that its formula proportion is by weight It is calculated as:
Triple superphosphate cement 150~200 parts, white cement 150~200 parts, flyash 300~350 parts, natural Color sand 50~80 parts, negative ion antibiotic additive 20~30 parts, redispersable latex powder 13~18 parts, Polyacrylonitrile fibre 0.1~2 parts, hydroxymethyl cellulose 0.1~2 parts, and inorganic pigment 1~10 parts;
The formula proportion of wherein said negative ion antibiotic additive is calculated by weight as:
Montmorillonite 80~120 parts, nano titanium oxide 4~10 parts, silver nitrate 4~10 parts, and 12 Sodium alkyl benzene sulfonate 0.1~0.5 part.
2. the most environmental colored antibacterial mastic powder, it is characterised in that its recipe ratio Example is calculated by weight as:
Triple superphosphate cement 180 parts, white cement 180 parts, 330 parts of flyash, natural colour sand 65 parts, bear from Sub-antibacterial additives 25 parts, redispersable latex powder 16 parts, polyacrylonitrile fibre 1 part, methylol is fine Dimension element 1 part, and inorganic pigment 5 parts;
The formula proportion of wherein said negative ion antibiotic additive is calculated by weight as:
Montmorillonite 100 parts, nano titanium oxide 7 parts, silver nitrate 7 parts, and dodecylbenzene sodium sulfonate 0.3 part.
3. the most environmental colored antibacterial mastic powder, it is characterised in that described anion The preparation method of antibacterial additives is:
(1) add montmorillonite in a kettle., add the water that quality is montmorillonite quality 40 times, At a temperature of 70~80 DEG C, the speed with 500rpm stirs 1h;
(2) keep temperature constant with rotating speed, add dodecylbenzene sodium sulfonate, stir 30min;
(3) it is slowly added to silver nitrate and nano titanium oxide, cools the temperature to 60~70 DEG C, with 300rpm Speed stirring 2h;
(4) wash, filter, the solid obtained is dried in 120 DEG C of baking ovens;
(5) solid after drying is calcined under 800 DEG C of environment in nitrogen atmosphere, obtains metallic silver particles With the modified montmorillonoid micropowder material of nano titanium oxide load, it is described negative ion antibiotic additive.
4. the most environmental colored antibacterial mastic powder, it is characterised in that described white cement Fineness be 50~100 mesh.
5. the most environmental colored antibacterial mastic powder, it is characterised in that described triple superphosphate water The fineness of mud, flyash, inorganic pigment and natural colour sand all >=300 mesh.
6. the most environmental colored antibacterial mastic powder, it is characterised in that described inorganic face Material is ferrum oxide serial pigment.
7. as claimed in claim 1 environmental colored antibacterial mastic powder, it is characterised in that described can divide again Scattered latex powder is ethylene/vinyl acetate emulsion copolymer powder.
CN201410631749.6A 2014-11-11 2014-11-11 Environmental colored antibacterial mastic powder Active CN104312249B (en)

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105802319A (en) * 2016-05-11 2016-07-27 何嘉铧 Anti-microbial putty powder and preparation method thereof
CN106082811B (en) * 2016-06-14 2018-05-29 雄子(上海)新材料科技有限公司 Inorganic mould proof dry powder paint and preparation method thereof
CN106186850A (en) * 2016-06-30 2016-12-07 刘世超 A kind of mildewing desiccating proof powder coating
CN108912865A (en) * 2017-04-05 2018-11-30 杨更生 A kind of natural bottom surface integrated color coating of exterior wall
CN107383982A (en) * 2017-08-16 2017-11-24 河北卓达建材研究院有限公司 A kind of negative ion putty powder and preparation method thereof
CN107345088A (en) * 2017-09-01 2017-11-14 重庆卡美伦科技有限公司合川分公司 A kind of environment friendly mildew resistant powder of lacquer putty for use on and preparation method thereof
CN111849234A (en) * 2019-04-30 2020-10-30 李卫东 Negative ion putty powder
CN112430407B (en) * 2020-11-14 2023-08-18 广东薇氧生态科技有限公司 Material with air purifying and negative ion releasing effects, preparation method thereof and application thereof in coating
CN116656167A (en) * 2023-06-03 2023-08-29 广东托肯新材料科技有限公司 Color sand powder putty powder and preparation method thereof

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CN101134859A (en) * 2006-08-30 2008-03-05 北京阔达建筑装饰工程有限责任公司 Inner wall special-purpose chromatic powdery waterproof putty and construction method
CN102875089A (en) * 2012-09-29 2013-01-16 北京东方雨虹防水技术股份有限公司 Low-alkali water-proof putty powder and preparation and utilization method thereof
CN103497564B (en) * 2013-08-29 2015-09-30 王传福 Dry powder latex paint water resistant putty powder

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Inventor after: Xi Jiawei

Inventor before: Huang Meizhong

COR Change of bibliographic data
TR01 Transfer of patent right

Effective date of registration: 20170116

Address after: 132101 Jilin city of Jilin province Jilin economic and Technological Development Zone to build a new road No. 101 (Kelongrui in room 206)

Patentee after: JUNWON ENERGY SAVING TECHNOLOGY CO.,LTD.

Address before: 532200 the Guangxi Zhuang Autonomous Region Chongzuo Jiangzhou District No. 120 Jianshe Road

Patentee before: Huang Meizhong

PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Ecotype color antibacterial putty powder

Effective date of registration: 20230718

Granted publication date: 20161130

Pledgee: Agricultural Bank of China Limited Shanghai pilot Free Trade Zone New Area Branch

Pledgor: JUNWON ENERGY SAVING TECHNOLOGY CO.,LTD.

Registration number: Y2023980048741

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