CN104293075A - 一种改性聚苯胺型防腐涂料及其制备方法 - Google Patents
一种改性聚苯胺型防腐涂料及其制备方法 Download PDFInfo
- Publication number
- CN104293075A CN104293075A CN201410582306.2A CN201410582306A CN104293075A CN 104293075 A CN104293075 A CN 104293075A CN 201410582306 A CN201410582306 A CN 201410582306A CN 104293075 A CN104293075 A CN 104293075A
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- Prior art keywords
- polyaniline
- modified
- protective system
- type protective
- methyl methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920000767 polyaniline Polymers 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 238000000576 coating method Methods 0.000 title abstract description 12
- 239000011248 coating agent Substances 0.000 title abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000010276 construction Methods 0.000 claims abstract description 13
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 30
- 150000001412 amines Chemical class 0.000 claims description 23
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 20
- 230000001681 protective effect Effects 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000006229 carbon black Substances 0.000 claims description 12
- -1 Polyoxyethylene Polymers 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 239000004816 latex Substances 0.000 claims description 10
- 229920000126 latex Polymers 0.000 claims description 10
- 239000004530 micro-emulsion Substances 0.000 claims description 10
- 239000013530 defoamer Substances 0.000 claims description 9
- 239000003822 epoxy resin Substances 0.000 claims description 9
- 229920000647 polyepoxide Polymers 0.000 claims description 9
- 239000003973 paint Substances 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 239000005457 ice water Substances 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 229920001451 polypropylene glycol Polymers 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 abstract description 7
- 229920001940 conductive polymer Polymers 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 4
- 238000000593 microemulsion method Methods 0.000 abstract description 2
- 239000002322 conducting polymer Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 6
- 239000012467 final product Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410582306.2A CN104293075B (zh) | 2014-10-28 | 2014-10-28 | 一种改性聚苯胺型防腐涂料及其制备方法 |
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CN201410582306.2A CN104293075B (zh) | 2014-10-28 | 2014-10-28 | 一种改性聚苯胺型防腐涂料及其制备方法 |
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CN104293075A true CN104293075A (zh) | 2015-01-21 |
CN104293075B CN104293075B (zh) | 2016-08-24 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104910752A (zh) * | 2015-06-10 | 2015-09-16 | 华南理工大学 | 一种聚苯胺石墨烯纳米复合防腐涂料及其制备方法 |
CN105176378A (zh) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | 一种水性聚苯胺防腐导静电涂料及其制备方法 |
CN106566326A (zh) * | 2016-11-17 | 2017-04-19 | 闻承岳 | 一种表面负载聚苯胺的沸石分子筛改性的氯磺化聚乙烯防腐涂料 |
CN106590191A (zh) * | 2016-11-17 | 2017-04-26 | 闻承岳 | 一种掺杂改性聚苯胺防腐增强的氯磺化聚乙烯防腐涂料 |
CN110183960A (zh) * | 2019-05-31 | 2019-08-30 | 北京三盈联合石油技术有限公司 | 一种耐车用尿素腐蚀涂料及其在尿素加注机上的应用方法 |
CN113930131A (zh) * | 2021-11-11 | 2022-01-14 | 铜陵有色金属集团铜冠建筑安装股份有限公司 | 一种石墨烯改性环氧防腐涂料及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1528845A (zh) * | 2003-09-29 | 2004-09-15 | 华东理工大学 | 水性金属防腐涂料 |
JP2004331960A (ja) * | 2003-04-14 | 2004-11-25 | Nippon Shokubai Co Ltd | ポリアニリン類含有組成物 |
CN101362918A (zh) * | 2008-07-31 | 2009-02-11 | 傅晓平 | 聚苯胺金属防腐水性工业涂料 |
CN101824264A (zh) * | 2010-05-06 | 2010-09-08 | 山东大学 | 一种核壳导电聚苯胺水性抗静电涂料及其制备方法 |
CN102492349A (zh) * | 2011-11-30 | 2012-06-13 | 山东大学 | 一种含有纳米核壳结构导电聚苯胺的水性环氧抗静电涂料及其制备 |
-
2014
- 2014-10-28 CN CN201410582306.2A patent/CN104293075B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004331960A (ja) * | 2003-04-14 | 2004-11-25 | Nippon Shokubai Co Ltd | ポリアニリン類含有組成物 |
CN1528845A (zh) * | 2003-09-29 | 2004-09-15 | 华东理工大学 | 水性金属防腐涂料 |
CN101362918A (zh) * | 2008-07-31 | 2009-02-11 | 傅晓平 | 聚苯胺金属防腐水性工业涂料 |
CN101824264A (zh) * | 2010-05-06 | 2010-09-08 | 山东大学 | 一种核壳导电聚苯胺水性抗静电涂料及其制备方法 |
CN102492349A (zh) * | 2011-11-30 | 2012-06-13 | 山东大学 | 一种含有纳米核壳结构导电聚苯胺的水性环氧抗静电涂料及其制备 |
Non-Patent Citations (1)
Title |
---|
吕生华等: ""聚苯胺导电复合材料的制备及其性能研究"", 《塑料》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104910752A (zh) * | 2015-06-10 | 2015-09-16 | 华南理工大学 | 一种聚苯胺石墨烯纳米复合防腐涂料及其制备方法 |
CN105176378A (zh) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | 一种水性聚苯胺防腐导静电涂料及其制备方法 |
CN106566326A (zh) * | 2016-11-17 | 2017-04-19 | 闻承岳 | 一种表面负载聚苯胺的沸石分子筛改性的氯磺化聚乙烯防腐涂料 |
CN106590191A (zh) * | 2016-11-17 | 2017-04-26 | 闻承岳 | 一种掺杂改性聚苯胺防腐增强的氯磺化聚乙烯防腐涂料 |
CN110183960A (zh) * | 2019-05-31 | 2019-08-30 | 北京三盈联合石油技术有限公司 | 一种耐车用尿素腐蚀涂料及其在尿素加注机上的应用方法 |
CN113930131A (zh) * | 2021-11-11 | 2022-01-14 | 铜陵有色金属集团铜冠建筑安装股份有限公司 | 一种石墨烯改性环氧防腐涂料及其制备方法 |
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Effective date of registration: 20160612 Address after: 257000, Shandong, Dongying province Dongying Xicheng West Road, building wins Applicant after: Zhang Haihong Address before: 250062, No. ten, No. 16369, Lixia District, Ji'nan City, Shandong Province Applicant before: SHANDONG ZHONGDA PHARMACEUTICAL CO., LTD. |
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