CN104292976B - A kind of damage resistant printing-ink and preparation method thereof - Google Patents
A kind of damage resistant printing-ink and preparation method thereof Download PDFInfo
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- CN104292976B CN104292976B CN201410630486.7A CN201410630486A CN104292976B CN 104292976 B CN104292976 B CN 104292976B CN 201410630486 A CN201410630486 A CN 201410630486A CN 104292976 B CN104292976 B CN 104292976B
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- ink
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- damage resistant
- resistant printing
- printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of damage resistant printing-ink, it is characterized in that, be made up of the raw material of following weight portion: amino resins 20-25, tetrabutyl titanate 8-10, dipropylene glycol methyl ether 9-13, isophorone 3-5, Apis cerana Fabricius 4-6, aluminium oxide 1.1-2.4, erucyl amide 2.1-3.6, Oleum Arachidis hypogaeae semen 3-4, Paprika 1-2, Gypsum Fibrosum 2-4, kieselguhr 2-3, ethyl cellulose 0.4-0.9, organic pigment 4-6, auxiliary agent 5-7; Inventive formulation reasonable process is simple, easy and simple to handle, add erucyl amide powder in raw material, the smoothness of ink can be improved, increase the wearability of leaflet, scratch resistance, and smoothness of the surface, utilize the damage resistant printing-ink that the present invention prepares can meet people's requirement to the damage resistant of the safety glass incrustation that household electrical appliances, contact panel, house ornamentation etc. use, allow the said goods not come off at longer a period of time incrustation ink.
Description
Technical field
The present invention relates to printing material technical field, be specifically related to a kind of damage resistant printing-ink and preparation method thereof.
Background technology
Ink is for forming the material of graph text information in printing process, by chromoplast (such as pigment, dyestuff etc.), link stuff, fill out the homogeneous mixture of the pulpous state adherent with certain fluidity that the materials such as (filling) material, additional material form, can print, and dry in printed body. Therefore ink should have chromatic colour, good printing adaptability, suitable rate of drying. Additionally, also should have the application indexes of the aspects such as certain solvent resistant, acid, alkali, water, light, heat, wear-resisting, fungus and mildew resistance. More and more higher along with printing, paper and other requirement etc., the printing-ink that prior art produces cannot meet the demand of printing industry and goods completely.
For overcoming the deficiencies in the prior art, it is necessary existing printing-ink production technology is improved, thus producing the printing-ink with functions such as cost is low, function diversification, high temperature resistant, hardness is high, wear-resisting, chemically burn into rate of drying is fast, printing adaptability is good.
Summary of the invention
It is an object of the invention to provide a kind of damage resistant printing-ink and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of damage resistant printing-ink, it is characterized in that, be made up of the raw material of following weight portion: amino resins 20-25, tetrabutyl titanate 8-10, dipropylene glycol methyl ether 9-13, isophorone 3-5, Apis cerana Fabricius 4-6, aluminium oxide 1.1-2.4, erucyl amide 2.1-3.6, Oleum Arachidis hypogaeae semen 3-4, Paprika 1-2, Gypsum Fibrosum 2-4, kieselguhr 2-3, ethyl cellulose 0.4-0.9, organic pigment 4-6, auxiliary agent 5-7.
Described auxiliary agent is made up of following raw materials in part by weight: organobentonite 4-7, hollow glass micro-ball 1-2, Rutile type titanium dioxide 1-3, white vaseline 3-5, isobutyl methacrylate 6-9, polymethacrylates 6-8, butanethiol stannum 0.2-0.5, stannous sulfate 0.3-0.6, triethyl aluminum 2-3, red drying oil 1-4, dimethicone 3-5, Oleum Verniciae fordii 2.1-3.5, ethylene glycol 4-6, hydroxypropyl methyl cellulose 0.4-0.8, its preparation method is first to be soaked 5-7 hour by the hydrochloric acid solution of organobentonite 5-10%, deionized water wash 4-5 time, soak 5-6 hour with the sodium hydroxide solution of 6-11% again, deionization washing is for several times in neutrality, dry, secondly organobentonite after the treatment adds isobutyl methacrylate, ethylene glycol, red drying oil, dimethicone, stannous sulfate heated and stirred 2-3 hour, drying grinds to form super fine, finally add other residual components ultrasonic grindings 30-40 minute and get final product.
The preparation method of described a kind of damage resistant printing-ink, it is characterised in that comprise the following steps:
(1) Paprika, Gypsum Fibrosum, kieselguhr being put in calcining furnace and processed 40-50 minute at 370-470 DEG C, cooling adds aluminium oxide, Oleum Arachidis hypogaeae semen grinds 30-50 minute;
(2) by tetrabutyl titanate, dipropylene glycol methyl ether, isophorone stirring and evenly mixing, it is heated to 70-95 DEG C of addition amino resins, Apis cerana Fabricius, erucyl amide to stir 1-2 hour, it is cooled to 45-60 DEG C, add above-mentioned reaction mass and other residual components agitation grindings 2-3 hour, it is dispersed to granularity sucking filtration, discharging below 30 ��m.
The present invention has following beneficial effect: inventive formulation reasonable process is simple, easy and simple to handle, add erucyl amide powder in raw material, the smoothness of ink can be improved, increase the wearability of leaflet, scratch resistance, and smoothness of the surface, utilize the damage resistant printing-ink that the present invention prepares can meet people's requirement to the damage resistant of the safety glass incrustation that household electrical appliances, contact panel, house ornamentation etc. use, allow the said goods not come off at longer a period of time incrustation ink.
Detailed description of the invention
Described a kind of damage resistant printing-ink, it is characterized in that, be made up of the raw material of following weight portion: amino resins 23, tetrabutyl titanate 8, dipropylene glycol methyl ether 9, isophorone 3, Apis cerana Fabricius 4, aluminium oxide 1.8, erucyl amide 2.8, Oleum Arachidis hypogaeae semen 3, Paprika 1, Gypsum Fibrosum 4, kieselguhr 3, ethyl cellulose 0.7, organic pigment 4, auxiliary agent 7.
Described auxiliary agent is made up of following raw materials in part by weight: organobentonite 5, hollow glass micro-ball 1, Rutile type titanium dioxide 2, white vaseline 4, isobutyl methacrylate 8, polymethacrylates 7, butanethiol stannum 0.4, stannous sulfate 0.3, triethyl aluminum 2, red drying oil 1, dimethicone 3, Oleum Verniciae fordii 2.8, ethylene glycol 4, hydroxypropyl methyl cellulose 0.7, its preparation method is first to be soaked 5-7 hour by the hydrochloric acid solution of organobentonite 5-10%, deionized water wash 4-5 time, soak 5-6 hour with the sodium hydroxide solution of 6-11% again, deionization washing is for several times in neutrality, dry, secondly organobentonite after the treatment adds isobutyl methacrylate, ethylene glycol, red drying oil, dimethicone, stannous sulfate heated and stirred 2-3 hour, drying grinds to form super fine, finally add other residual components ultrasonic grindings 30-40 minute and get final product.
Manufacture method comprises the following steps:
(1) Paprika, Gypsum Fibrosum, kieselguhr being put in calcining furnace and processed 40-50 minute at 370-470 DEG C, cooling adds aluminium oxide, Oleum Arachidis hypogaeae semen grinds 30-50 minute;
(2) by tetrabutyl titanate, dipropylene glycol methyl ether, isophorone stirring and evenly mixing, it is heated to 70-95 DEG C of addition amino resins, Apis cerana Fabricius, erucyl amide to stir 1-2 hour, it is cooled to 45-60 DEG C, add above-mentioned reaction mass and other residual components agitation grindings 2-3 hour, it is dispersed to granularity sucking filtration, discharging below 30 ��m.
The technical parameter index using the printing-ink of present invention production is as follows:
(1) wear-resisting, use cross-hatching Corii Bovis seu Bubali adhesive tape to peel off, draw compartment from 1mm, 100% attachment;
(2) tinting strength, tinting power (%): 97.4;
(3) viscosity (S): 49.3;
(4) alkaline-resisting, water-fast (24h): good.
Claims (2)
1. a damage resistant printing-ink, it is characterized in that, be made up of the raw material of following weight portion: amino resins 20-25, tetrabutyl titanate 8-10, dipropylene glycol methyl ether 9-13, isophorone 3-5, Apis cerana Fabricius 4-6, aluminium oxide 1.1-2.4, erucyl amide 2.1-3.6, Oleum Arachidis hypogaeae semen 3-4, Paprika 1-2, Gypsum Fibrosum 2-4, kieselguhr 2-3, ethyl cellulose 0.4-0.9, organic pigment 4-6, auxiliary agent 5-7;Described auxiliary agent is made up of following raw materials in part by weight: organobentonite 4-7, hollow glass micro-ball 1-2, Rutile type titanium dioxide 1-3, white vaseline 3-5, isobutyl methacrylate 6-9, polymethacrylates 6-8, butanethiol stannum 0.2-0.5, stannous sulfate 0.3-0.6, triethyl aluminum 2-3, red drying oil 1-4, dimethicone 3-5, Oleum Verniciae fordii 2.1-3.5, ethylene glycol 4-6, hydroxypropyl methyl cellulose 0.4-0.8, its preparation method is first to be soaked 5-7 hour by the hydrochloric acid solution of organobentonite 5-10%, deionized water wash 4-5 time, soak 5-6 hour with the sodium hydroxide solution of 6-11% again, deionization washing is for several times in neutrality, dry, secondly organobentonite after the treatment adds isobutyl methacrylate, ethylene glycol, red drying oil, dimethicone, stannous sulfate heated and stirred 2-3 hour, drying grinds to form super fine, finally add other residual components ultrasonic grindings 30-40 minute and get final product.
2. the manufacture method of a damage resistant printing-ink as claimed in claim 1, it is characterised in that comprise the following steps:
(1) Paprika, Gypsum Fibrosum, kieselguhr being put in calcining furnace and processed 40-50 minute at 370-470 DEG C, cooling adds aluminium oxide, Oleum Arachidis hypogaeae semen grinds 30-50 minute;
(2) by tetrabutyl titanate, dipropylene glycol methyl ether, isophorone stirring and evenly mixing, it is heated to 70-95 DEG C of addition amino resins, Apis cerana Fabricius, erucyl amide to stir 1-2 hour, it is cooled to 45-60 DEG C, add above-mentioned reaction mass and other residual components agitation grindings 2-3 hour, it is dispersed to granularity sucking filtration, discharging below 30 ��m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630486.7A CN104292976B (en) | 2014-11-11 | 2014-11-11 | A kind of damage resistant printing-ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630486.7A CN104292976B (en) | 2014-11-11 | 2014-11-11 | A kind of damage resistant printing-ink and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104292976A CN104292976A (en) | 2015-01-21 |
| CN104292976B true CN104292976B (en) | 2016-06-08 |
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| CN201410630486.7A Active CN104292976B (en) | 2014-11-11 | 2014-11-11 | A kind of damage resistant printing-ink and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1276398A (en) * | 1999-06-03 | 2000-12-13 | 王奇凡 | Water ink of compound resin |
| EP1146096A1 (en) * | 2000-04-12 | 2001-10-17 | Akzo Nobel N.V. | Printing ink compositions |
| JP2007112963A (en) * | 2005-10-24 | 2007-05-10 | Toyo Ink Mfg Co Ltd | Water-based lithographic ink and printed product |
| CN103160170A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Printing ink |
-
2014
- 2014-11-11 CN CN201410630486.7A patent/CN104292976B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1276398A (en) * | 1999-06-03 | 2000-12-13 | 王奇凡 | Water ink of compound resin |
| EP1146096A1 (en) * | 2000-04-12 | 2001-10-17 | Akzo Nobel N.V. | Printing ink compositions |
| JP2007112963A (en) * | 2005-10-24 | 2007-05-10 | Toyo Ink Mfg Co Ltd | Water-based lithographic ink and printed product |
| CN103160170A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Printing ink |
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| Publication number | Publication date |
|---|---|
| CN104292976A (en) | 2015-01-21 |
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Inventor after: Xu Shugeng Inventor before: Zhu Jiangling |
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Effective date of registration: 20170519 Address after: 515000, Guangdong, Shantou province Jinping District Qishan Street Long Village East Wai Patentee after: Shantou gold Paper Co., Ltd. Address before: 230001 Anhui City, Hefei Province, Tunxi Road, No. 193, No. 3 Ningguo Road, building Electronics Patentee before: HEFEI WANWEI ELECTRICAL EQUIPMENT ENGINEERING CO., LTD. |