CN107267004A - A kind of imitative stone multi-color and its production technology - Google Patents
A kind of imitative stone multi-color and its production technology Download PDFInfo
- Publication number
- CN107267004A CN107267004A CN201710647258.4A CN201710647258A CN107267004A CN 107267004 A CN107267004 A CN 107267004A CN 201710647258 A CN201710647258 A CN 201710647258A CN 107267004 A CN107267004 A CN 107267004A
- Authority
- CN
- China
- Prior art keywords
- parts
- color
- imitative stone
- stone multi
- production technology
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/185—Acids containing aromatic rings containing two or more aromatic rings
- C08G63/187—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings
- C08G63/189—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings containing a naphthalene ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to imitative stone multi-color, and in particular to a kind of imitative stone multi-color and its production technology, the multi-color are made up of following raw material：2,6 4 15 parts of naphthalenedicarboxylic acids, 3 12 parts of terephthalic acid (TPA), 27 parts of butanediol, 49 parts of octadecyltrimethylammonium, 18 parts of montmorillonite powder, 15 25 parts of acrylic emulsion, 10 25 parts of laccol epoxy resin, 27 parts of nano titanium oxide, 37 parts of lauryl sodium sulfate, 38 parts of colorful rock dust, 26 parts of thickener, 13 parts of defoamer；Technical scheme provided by the present invention can make up the heat resistance difference for the multi-color presence that prior art is provided and the defect of heat resistance difference to a certain extent.
Description
Technical field
The present invention relates to imitative stone multi-color, and in particular to a kind of imitative stone multi-color and its production technology.
Background technology
Imitative stone multi-color is to use acrylic emulsion and fluorocarbon resin emulsion for base-material, with reference to high-quality inorganic pigment and high property
Can auxiliary agent, breakthrough painting principle, the water-based exterior wall multicolor finish processed through special process.
For obtaining a kind of parian multicolor finish preparation side in patent application CN105733388A disclosed in China
Method, it includes：With water, mt-jfII protections rubber powder, PVC thinners etc. for 5%, the 10% of the raw material preparation for protecting glue, with water
Bag water hydroxyethyl cellulose, dispersant, thick-slurry type defoamer, rutile titanium white powder, kaolin are the preparation of the base paint of raw material,
Preparation and granulation and lacquering step with continuous phases such as suspending agent, TD-661 emulsions, coalescents, ethylene glycol, defoamers.This
Invent a kind of parian multicolor finish, cheap, rich color, full of flourishes, more texture and third dimension, emulator be more
It is high, ornamental strong.For obtaining a kind of waterborne marble-imitated multicolor paint in patent application CN105419542A disclosed in China,
Include the component of following parts by weight, 200-300 parts of deionized water, 3.5-5.5 parts of hydroxyethyl cellulose, powdered whiting 10-15
Part, 0.5-2.0 parts of wetting agent, 1.5-2.5 parts of defoamer, 10-20 parts of propane diols, 8.5-10.5 parts of ethylene glycol, coalescents
17.5-20.5 parts, 2.5-5.5 parts of polyurethane thickener, 350-450 parts of silicone acrylic emulsion, 2.5-4.5 parts of levelling agent, drier
0.1-0.4 parts, 2.0-3.0 parts of sagging inhibitor, 2.0-3.0 parts of preservative, colored sliver 150-200 parts.The present invention's is aqueous imitative
Marble multi-color, acidproof, alkaline-resisting, chemically-resistant good behaviour, high anti-UV, Super-ageing resistance, yellowing-resistant and resistance to water-white.
Although the imitative stone multi-color that currently available technology is provided have rich color, it is full of flourishes, more texture and solid
Sense, emulator it is higher, it is ornamental strong the advantages of, but exist go heat resistance difference and heat resistance difference defect.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of imitative stone multi-color and its production technology.The present invention is carried
The technical scheme of confession can make up the imitative stone multi-color that prior art provided to a certain extent, and to there is heat resistance poor and resistance to
The defect of hot property difference.
In order to realize above-mentioned purpose, the present invention uses following technical scheme：
A kind of imitative stone multi-color, is made up of following parts by weight raw material：4-15 parts of 2,6- naphthalenedicarboxylic acids, terephthalic acid (TPA) 3-
12 parts, 2-7 parts of butanediol, 4-9 parts of octadecyltrimethylammonium, 1-8 parts of montmorillonite powder, 15-25 parts of acrylic emulsion, laccol
10-25 parts of epoxy resin, 2-7 parts of nano titanium oxide, 3-7 parts of lauryl sodium sulfate, colorful rock dust 3-8 parts, thickening
2-6 parts of agent, 1-3 parts of defoamer.
It is preferred that, the imitative stone multi-color is made up of following parts by weight raw material：7-12 parts of 2,6- naphthalenedicarboxylic acids, to benzene two
5-10 parts of formic acid, 3-5 parts of butanediol, 6-8 parts of octadecyltrimethylammonium, 3-6 parts of montmorillonite powder, acrylic emulsion 18-23
Part, 15-20 parts of laccol epoxy resin, 3-6 parts of nano titanium oxide, 2-6 parts of lauryl sodium sulfate, colorful rock dust 5-7
Part, 3-5 parts of thickener, 1-3 parts of defoamer.
It is preferred that, the thickener is polyurethane thickener.
It is preferred that, the imitative stone multi-color, production technology includes following several steps：
(1) butanediol, terephthalic acid (TPA) and NDA are put into reactor, in N2, will be anti-under protective atmosphere
Answer kettle temperature degree to be adjusted to certain temperature, reaction a period of time, take a small amount of reaction solution to determine acidity value, when acidity value is in 9-
After 12mgKOH/g, appropriate hydrochloric acid acidolysis is added, after acidity value reaches certain limit, export reaction solution cools down to obtain polyester resin；
(2) montmorillonite powder and acrylic emulsion are added in agitator, 85 DEG C are adjusted to, in electric stirring
In the case of, octadecyltrimethylammonium is added, heating water bath 3h is standby；
(3) nano titanium oxide and lauryl sodium sulfate are added and the two quality phase thereto as in reactor
Deng water, stood after stirring after 2h, ultrasonic disperse and processing 30min, then add laccol epoxy resin, mechanical agitation is equal
It is even, it is standby；
(4) by above-mentioned steps product and leftover materials be put into stirred tank, be uniformly mixed, obtain imitative stone colorful
Paint.
It is preferred that, reactor temperature is 240 DEG C in the step (1).
It is preferred that, acidity value scope is 30-35mgKOH/g in the step (1).
Using above-mentioned technical scheme, the beneficial effects of the invention are as follows：The naphthalene ring of 2,6- naphthalenedicarboxylic acids compares benzene two
The benzene ring structure of formic acid is more rigid, NDA molecular motion ability than phthalic acid molecular motion ability, two
Person's synthesis coordinates after butanediol polyester resin, improves glass transition temperature, the heat endurance of polyester resin, the powder of polyester resin
Last coating gloss and heat-resisting water resistance；Montmorillonite is a kind of silicate mineral of stratiform, with unique 2:1 layer structure
With excellent hydrating capacity, in acrylic emulsion, montmorillonite and octadecyltrimethylammonium are compound, former according to similar compatibility
Some organic molecules in reason, coating composition can enter the interlayer of montmorillonite by suction-operated, due to organic matter point
Modified montmorillonite used adjacent chip spacing can be supportted big and peel off it by subspace bulk effect, and montmorillonite particle is by original
Multi-disc lamination shape is changed into individual layer or thin layer dispersed, so that coating shows good suspension, and with anti-settling
Effect, improves the anti-heavy effect of coating；Nano titanium oxide is modified by lauryl sodium sulfate, is added to laccol epoxy
In resin, form and there is stronger hydrogen bond between advanced composite material (ACM), compound molecule, be conducive to improving the alkaline-resisting and resistance to of coating
Hot property, while being also beneficial to improve the mechanical performance of composite coating.
Embodiment is handed over flat
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
Embodiment 1：
A kind of imitative stone multi-color, is made up of following parts by weight raw material：4 parts of 2,6- naphthalenedicarboxylic acids, 3 parts of terephthalic acid (TPA),
2 parts of butanediol, 4 parts of octadecyltrimethylammonium, 1 part of montmorillonite powder, 15 parts of acrylic emulsion, 10 parts of laccol epoxy resin,
2 parts of nano titanium oxide, 3 parts of lauryl sodium sulfate, 3 parts of colorful rock dust, 2 parts of thickener, 1 part of defoamer.
A kind of imitative stone multi-color and its production technology, its production technology include following several steps：
(1) butanediol, terephthalic acid (TPA) and NDA are put into reactor, in N2, will be anti-under protective atmosphere
Answer kettle temperature degree to be adjusted to 240 DEG C, reaction a period of time, take a small amount of reaction solution to determine acidity value, after acidity value is in 9mgKOH/g,
Appropriate hydrochloric acid acidolysis is added, when acidity value is 30mgKOH/g, export reaction solution cools down to obtain polyester resin；
(2) montmorillonite powder and acrylic emulsion are added in agitator, 85 DEG C are adjusted to, in electric stirring
In the case of, octadecyltrimethylammonium is added, heating water bath 3h is standby；
(3) nano titanium oxide and lauryl sodium sulfate are added and the two quality phase thereto as in reactor
Deng water, stood after stirring after 2h, ultrasonic disperse and processing 30min, then add laccol epoxy resin, mechanical agitation is equal
It is even, it is standby；
(4) by above-mentioned steps product and leftover materials be put into stirred tank, be uniformly mixed, obtain imitative stone colorful
Paint.
Embodiment 2：
A kind of imitative stone multi-color, is made up of following parts by weight raw material：15 parts of 2,6- naphthalenedicarboxylic acids, terephthalic acid (TPA) 12
Part, 7 parts of butanediol, 9 parts of octadecyltrimethylammonium, 8 parts of montmorillonite powder, 25 parts of acrylic emulsion, laccol epoxy resin 25
Part, 7 parts of nano titanium oxide, 7 parts of lauryl sodium sulfate, 8 parts of colorful rock dust, 6 parts of thickener, 3 parts of defoamer.
A kind of imitative stone multi-color, its production technology includes following several steps：
(1) butanediol, terephthalic acid (TPA) and NDA are put into reactor, in N2, will be anti-under protective atmosphere
Answer kettle temperature degree to be adjusted to 240 DEG C, reaction a period of time, take a small amount of reaction solution to determine acidity value, when acidity value is in 12mgKOH/g
Afterwards, appropriate hydrochloric acid acidolysis is added, when acidity value is 35mgKOH/g, export reaction solution cools down to obtain polyester resin；
(2) montmorillonite powder and acrylic emulsion are added in agitator, 85 DEG C are adjusted to, in electric stirring
In the case of, octadecyltrimethylammonium is added, heating water bath 3h is standby；
(3) nano titanium oxide and lauryl sodium sulfate are added and the two quality phase thereto as in reactor
Deng water, stood after stirring after 2h, ultrasonic disperse and processing 30min, then add laccol epoxy resin, mechanical agitation is equal
It is even, it is standby；
(4) by above-mentioned steps product and leftover materials be put into stirred tank, be uniformly mixed, obtain imitative stone colorful
Paint.
Embodiment 3：
A kind of imitative stone multi-color, is made up of following parts by weight raw material：7 parts of 2,6- naphthalenedicarboxylic acids, 5 parts of terephthalic acid (TPA),
3 parts of butanediol, 6 parts of octadecyltrimethylammonium, 3 parts of montmorillonite powder, 18 parts of acrylic emulsion, 15 parts of laccol epoxy resin,
3 parts of nano titanium oxide, 2 parts of lauryl sodium sulfate, 5 parts of colorful rock dust, 3 parts of thickener, 1 part of defoamer.
A kind of imitative stone multi-color, its production technology includes following several steps：
(1) butanediol, terephthalic acid (TPA) and NDA are put into reactor, in N2, will be anti-under protective atmosphere
Answer kettle temperature degree to be adjusted to 240 DEG C, reaction a period of time, take a small amount of reaction solution to determine acidity value, when acidity value is in 10mgKOH/g
Afterwards, appropriate hydrochloric acid acidolysis is added, when acidity value is 31mgKOH/g, export reaction solution cools down to obtain polyester resin；
(2) montmorillonite powder and acrylic emulsion are added in agitator, 85 DEG C are adjusted to, in electric stirring
In the case of, octadecyltrimethylammonium is added, heating water bath 3h is standby；
(3) nano titanium oxide and lauryl sodium sulfate are added and the two quality phase thereto as in reactor
Deng water, stood after stirring after 2h, ultrasonic disperse and processing 30min, then add laccol epoxy resin, mechanical agitation is equal
It is even, it is standby；
(4) by above-mentioned steps product and leftover materials be put into stirred tank, be uniformly mixed, obtain imitative stone colorful
Paint.
Embodiment 4：
A kind of imitative stone multi-color, is made up of following parts by weight raw material：12 parts of 2,6- naphthalenedicarboxylic acids, terephthalic acid (TPA) 10
Part, 5 parts of butanediol, 8 parts of octadecyltrimethylammonium, 6 parts of montmorillonite powder, 23 parts of acrylic emulsion, laccol epoxy resin 20
Part, 6 parts of nano titanium oxide, 6 parts of lauryl sodium sulfate, 7 parts of colorful rock dust, 5 parts of thickener, 3 parts of defoamer.
A kind of imitative stone multi-color, its production technology includes following several steps：
(1) butanediol, terephthalic acid (TPA) and NDA are put into reactor, in N2, will be anti-under protective atmosphere
Answer kettle temperature degree to be adjusted to 240 DEG C, reaction a period of time, take a small amount of reaction solution to determine acidity value, when acidity value is in 11mgKOH/g
Afterwards, appropriate hydrochloric acid acidolysis is added, when acidity value is 33mgKOH/g, export reaction solution cools down to obtain polyester resin；
(2) montmorillonite powder and acrylic emulsion are added in agitator, 85 DEG C are adjusted to, in electric stirring
In the case of, octadecyltrimethylammonium is added, heating water bath 3h is standby；
(3) nano titanium oxide and lauryl sodium sulfate are added and the two quality phase thereto as in reactor
Deng water, stood after stirring after 2h, ultrasonic disperse and processing 30min, then add laccol epoxy resin, mechanical agitation is equal
It is even, it is standby；
(4) by above-mentioned steps product and leftover materials be put into stirred tank, be uniformly mixed, obtain imitative stone colorful
Paint.
Embodiment 5：
A kind of imitative stone multi-color, is made up of following parts by weight raw material：8 parts of 2,6- naphthalenedicarboxylic acids, 8 parts of terephthalic acid (TPA),
4 parts of butanediol, 7 parts of octadecyltrimethylammonium, 4 parts of montmorillonite powder, 20 parts of acrylic emulsion, 19 parts of laccol epoxy resin,
5 parts of nano titanium oxide, 4 parts of lauryl sodium sulfate, 6 parts of colorful rock dust, 4 parts of thickener, 2 parts of defoamer.
A kind of imitative stone multi-color, its production technology includes following several steps：
(1) butanediol, terephthalic acid (TPA) and NDA are put into reactor, in N2, will be anti-under protective atmosphere
Answer kettle temperature degree to be adjusted to 240 DEG C, reaction a period of time, take a small amount of reaction solution to determine acidity value, when acidity value is in 11mgKOH/g
Afterwards, appropriate hydrochloric acid acidolysis is added, when acidity value is 34mgKOH/g, export reaction solution cools down to obtain polyester resin；
(2) montmorillonite powder and acrylic emulsion are added in agitator, 85 DEG C are adjusted to, in electric stirring
In the case of, octadecyltrimethylammonium is added, heating water bath 3h is standby；
(3) nano titanium oxide and lauryl sodium sulfate are added and the two quality phase thereto as in reactor
Deng water, stood after stirring after 2h, ultrasonic disperse and processing 30min, then add laccol epoxy resin, mechanical agitation is equal
It is even, it is standby；
(4) by above-mentioned steps product and leftover materials be put into stirred tank, be uniformly mixed, obtain imitative stone colorful
Paint.
Imitative stone multi-color common in imitative stone multi-color in the present invention and market is made into performance test, its test result is such as
Under：
The imitative stone multi-color in the present invention is compared as can be seen from the above table has more with imitative stone multi-color common in market
Good water resistance and Heat-resistant stable performance.
Above example is only to the technical scheme for illustrating type of the present invention, rather than its limitations；Although implementing with reference to foregoing
Type of the present invention is described in detail example, it will be understood by those within the art that：It still can be to foregoing each
Technical scheme described in embodiment is modified, or carries out equivalent substitution to which part technical characteristic；And these are changed
Or replace, the essence of appropriate technical solution is departed from the spirit and scope of each embodiment technical scheme of type of the present invention.
Claims (6)
1. a kind of imitative stone multi-color, it is characterised in that be made up of following parts by weight raw material：It is 4-15 parts of 2,6- naphthalenedicarboxylic acids, right
3-12 parts of phthalic acid, 2-7 parts of butanediol, 4-9 parts of octadecyltrimethylammonium, 1-8 parts of montmorillonite powder, acrylic emulsion
15-25 parts, 10-25 parts of laccol epoxy resin, 2-7 parts of nano titanium oxide, 3-7 parts of lauryl sodium sulfate, colorful Rock Powder
Last 3-8 parts, 2-6 parts of thickener, 1-3 parts of defoamer.
2. imitative stone multi-color according to claim 1, it is characterised in that be made up of following parts by weight raw material：2,6- naphthalenes
7-12 parts of dioctyl phthalate, 5-10 parts of terephthalic acid (TPA), 3-5 parts of butanediol, 6-8 parts of octadecyltrimethylammonium, montmorillonite powder 3-6
Part, 18-23 parts of acrylic emulsion, 15-20 parts of laccol epoxy resin, 3-6 parts of nano titanium oxide, lauryl sodium sulfate 2-6
Part, colorful rock dust 5-7 parts, 3-5 parts of thickener, 1-3 parts of defoamer.
3. imitative stone multi-color according to claim 1, it is characterised in that the thickener is polyurethane thickener.
4. imitative stone multi-color according to claim 1, it is characterised in that production technology includes following several steps：
（1）, butanediol, terephthalic acid (TPA) and NDA be put into reactor, in N2Under protective atmosphere, by reactor
Temperature is adjusted to certain temperature, reaction a period of time, takes a small amount of reaction solution to determine acidity value, when acidity value is in 9-12mgKOH/g
Afterwards, appropriate hydrochloric acid acidolysis is added, after acidity value reaches certain limit, export reaction solution cools down to obtain polyester resin；
（2）, montmorillonite powder and acrylic emulsion be added in agitator, 85 DEG C are adjusted to, in electric stirring
In the case of, octadecyltrimethylammonium is added, heating water bath 3h is standby；
（3）, by nano titanium oxide and lauryl sodium sulfate as in reactor, add thereto equal with the two quality
Water, stands after 2h after stirring, ultrasonic disperse and processing 30min, then adds laccol epoxy resin, mechanical agitation is uniform,
It is standby；
（4）, by above-mentioned steps product and leftover materials be put into stirred tank, be uniformly mixed, obtain imitative stone multi-color.
5. the production technology of imitative stone multi-color according to claim 4, it is characterised in that the step（1）Middle reactor
Interior temperature is 240 DEG C.
6. the production technology of imitative stone multi-color according to claim 4, it is characterised in that the step（1）Middle acidity value
Scope is 30-35mgKOH/g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710647258.4A CN107267004A (en) | 2017-08-01 | 2017-08-01 | A kind of imitative stone multi-color and its production technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710647258.4A CN107267004A (en) | 2017-08-01 | 2017-08-01 | A kind of imitative stone multi-color and its production technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107267004A true CN107267004A (en) | 2017-10-20 |
Family
ID=60075704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710647258.4A Pending CN107267004A (en) | 2017-08-01 | 2017-08-01 | A kind of imitative stone multi-color and its production technology |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107267004A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040594A (en) * | 2019-12-02 | 2020-04-21 | 安徽科创美涂料科技股份有限公司 | Low-temperature curing real stone paint coating and preparation method thereof |
| CN117487422A (en) * | 2023-12-06 | 2024-02-02 | 宜兴汉光高新石化有限公司 | Water-based ceramic particle heat reflection coating and preparation method thereof |
| CN117487422B (en) * | 2023-12-06 | 2024-06-04 | 宜兴汉光高新石化有限公司 | Water-based ceramic particle heat reflection coating and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974696A (en) * | 2005-11-30 | 2007-06-06 | 巢启 | Sandy paint made of color paint flakes |
-
2017
- 2017-08-01 CN CN201710647258.4A patent/CN107267004A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974696A (en) * | 2005-11-30 | 2007-06-06 | 巢启 | Sandy paint made of color paint flakes |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040594A (en) * | 2019-12-02 | 2020-04-21 | 安徽科创美涂料科技股份有限公司 | Low-temperature curing real stone paint coating and preparation method thereof |
| CN117487422A (en) * | 2023-12-06 | 2024-02-02 | 宜兴汉光高新石化有限公司 | Water-based ceramic particle heat reflection coating and preparation method thereof |
| CN117487422B (en) * | 2023-12-06 | 2024-06-04 | 宜兴汉光高新石化有限公司 | Water-based ceramic particle heat reflection coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105199558B (en) | Special coil coating of anodic oxidation special-effect of a kind of aluminium sheet coiled material and preparation method thereof | |
| CN101591491A (en) | A kind of fully water based granite multicolor paint and preparation method thereof | |
| CN104231901B (en) | A kind of aqueous elastic handfeel paint and preparation method thereof | |
| CN106947424A (en) | A kind of senior strength adhesive of multipurpose and preparation method thereof | |
| CN106590252A (en) | Graphene-modified building exterior wall heat-insulation coating and preparation method thereof | |
| CN101717600A (en) | Single-component aqueous fluorocarbon paint and preparation method thereof | |
| CN109692797A (en) | A kind of preparation method of aluminum veneer | |
| CN105440820A (en) | Multifunctional waterborne color-adjustable reflective heat-insulation coating and preparation method thereof | |
| CN105778744A (en) | Preparation method of high-hardness high-fullness water-borne wood paint | |
| CN104497732A (en) | Heat discoloration emulsion paint and preparation method thereof | |
| CN112592654A (en) | Water-based high-temperature-resistant, anticorrosive and weather-resistant colorful orange-peel paint and preparation method thereof | |
| CN105001772B (en) | Super-high solid content nano-high molecule alloy coating | |
| CN104277579A (en) | Waterproof low-odor environment-friendly printing ink and preparation method thereof | |
| CN106046991A (en) | Ash-sticking-proof waterborne coating and preparation method thereof | |
| CN111349385A (en) | Polishing-free water-based primer surfacer matched with ceramic finish and preparation method thereof | |
| CN107267004A (en) | A kind of imitative stone multi-color and its production technology | |
| CN106221373A (en) | A kind of high-weatherability glass ink and preparation method thereof, using method | |
| CN104312265B (en) | Molten color inhibition plastic printing ink of a kind of environment-friendly type alcohol and preparation method thereof | |
| CN101613549A (en) | Gold-wire silk fabric inner wall paint | |
| CN104151957B (en) | A kind of interior wall coating for building | |
| CN111978859A (en) | Easily-cleaned high-hardness antibacterial water-based ceramic paint and preparation process thereof | |
| CN104292895B (en) | A kind of polyvinyl alcohol washable interior wall coating for building | |
| CN104559691A (en) | Polymer composite for heat transfer printing low-temperature crosslinking and preparation method thereof | |
| CN104672985B (en) | A kind of ink for decorative material surface printing treatment | |
| CN106854410A (en) | A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171020 |