CN104292948A - 一种汽车涂料用改性糖酸钙填料及其制备方法 - Google Patents

一种汽车涂料用改性糖酸钙填料及其制备方法 Download PDF

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CN104292948A
CN104292948A CN201410500624.XA CN201410500624A CN104292948A CN 104292948 A CN104292948 A CN 104292948A CN 201410500624 A CN201410500624 A CN 201410500624A CN 104292948 A CN104292948 A CN 104292948A
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徐泽军
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Ruizhan Tongling Technologies Co Ltd
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Abstract

一种汽车涂料用改性糖酸钙填料,由下列重量份的原料制成：环氧大豆油1-1.5、双酚A抗氧剂2-3、L-天门冬氨酸锌1-2、尼泊金甲酯1-2、三氧化二锑4-6、氰尿酸锌2-3、氧化锌5-8、铬刚玉6-9、锆英砂4-7、红柱石5-8、轻质碳酸钙55-60、水适量、4-6%盐酸适量、助剂15-20；本发明填料颗粒细致，分散性好，可提涂料的耐刮擦性、耐磨性、耐腐蚀性等性能，并能起补强作用，该填料能增加涂料中油漆的光泽，提高产品的光洁度、干燥性、遮盖力；通过添加三氧化二锑、氧化锌，能够增加隔膜的阻燃性能和抗紫外线性能，延长涂料的使用寿命。

Description

一种汽车涂料用改性糖酸钙填料及其制备方法
技术领域
本发明属于涂料领域，特别涉及一种汽车涂料用改性糖酸钙填料及其制备方法。
背景技术
汽车涂料就是指涂装在轿车等各类车辆车身及零部件上的涂料，一般指新车的涂料及辅助材料和车辆修补用涂料，现有的汽车涂料的种类较多，人们对车档次和性能的要求越来越高，包括对涂料的要求也提高了，不仅要求美观还具有良好的粘结强度、耐热、耐寒、耐酸碱、耐光，涂膜要平整光泽，同时要求环保健康，然而现有的涂料还难以达到各项要求，或者成本较高。通过使用填料不仅可以节约成本而且能提高涂料的性能。
发明内容
本发明的目的在于提供一种汽车涂料用改性糖酸钙填料及其制备方法，该填料颗粒细致，分散性好，可提涂料的耐刮擦性、耐磨性、耐腐蚀性等性能，并能起补强作用，该填料能增加涂料中油漆的光泽，提高产品的光洁度、干燥性、遮盖力，能够增加隔膜的阻燃性能和抗紫外线性能，延长涂料的使用寿命。
本发明的技术方案如下：
一种汽车涂料用改性糖酸钙填料,其特征在于由下列重量份的原料制成：环氧大豆油1-1.5、双酚A抗氧剂2-3、L-天门冬氨酸锌1-2、尼泊金甲酯1-2、三氧化二锑4-6、氰尿酸锌2-3、氧化锌5-8、铬刚玉6-9、锆英砂4-7、红柱石5-8、轻质碳酸钙75-80、水适量、4-6%盐酸适量、助剂12-15；
所述助剂由下列重量份的原料制成：二甲基乙酰胺1-2、液体石蜡1-1.5、苯甲酸钠0.5-0.8、活性碳酸钙2-3、竹炭粉5-7、3-4%氢氧化钠溶液10-15、二茂铁0.4-0.6、太古油0.1-0.2、丙烯酸乙酯2-3、丙烯酸甲酯1-1.5、桂花精油0.1-0.2、硫磷丁辛基锌盐0.2-0.3、碳酸氢铵0.2-0.3、氧化铍0.5-0.8、磷酸三丁脂0.3-0.5、亚硫酸钙0.3-0.6、过硫酸钾0.1-0.2、过硫酸铵0.1-0.2、水适量；制备方法为：将竹炭粉与3-4%氢氧化钠溶液混合，加热至80-90℃，搅拌反应20-30分钟，水洗至pH为7-9，烘干，再与二甲基乙酰胺、液体石蜡、苯甲酸钠、二茂铁、桂花精油、硫磷丁辛基锌盐、碳酸氢铵、磷酸三丁脂、亚硫酸钙混合，研磨15-20分钟，得竹炭颗粒；再将太古油加入适量水中，再加入竹炭颗粒，搅拌均匀后加入丙烯酸乙酯，搅拌均匀后升温至70-80℃，加入过硫酸铵，搅拌反应20-30分钟，再加入活性碳酸钙、丙烯酸甲酯，搅拌均匀后加入其他剩余成分，继续搅拌反应40-50分钟，烘干，分散研磨成2-50μm的颗粒，即得。
所述的汽车涂料用改性糖酸钙填料的制备方法，其特征在于包括以下步骤：
（1）将轻质碳酸钙送入煅烧炉中，在700-800℃下煅烧2-3个小时，取出粉碎，过100目筛，再加入2-3倍的4-6%盐酸，加热至50-70℃，搅拌10-20分钟，过滤，得滤渣，按上述方法再酸洗一次，再水洗至中性，过滤，得颗粒；
（2）将铬刚玉、锆英砂、红柱石粉碎，过100目筛，与环氧大豆油、双酚A抗氧剂、L-天门冬氨酸锌、尼泊金甲酯、三氧化二锑、氰尿酸锌、氧化锌混合，研磨20-30分钟，得混合物料；
（3）将第（1）步和第（2）步得到的物料混合，加入适量水搅拌成泥状，研磨成2-50μm的浆料，喷雾干燥，再与其他剩余成分混合均匀，即得。
本发明的有益效果
本发明填料颗粒细致，分散性好，可提涂料的耐刮擦性、耐磨性、耐腐蚀性等性能，并能起补强作用，该填料能增加涂料中油漆的光泽，提高产品的光洁度、干燥性、遮盖力；通过添加三氧化二锑、氧化锌，能够增加隔膜的阻燃性能和抗紫外线性能，延长涂料的使用寿命。
具体实施方式
一种汽车涂料用改性糖酸钙填料,由下列重量份（公斤）的原料制成：环氧大豆油1.3、双酚A抗氧剂2.5、L-天门冬氨酸锌1.5、尼泊金甲酯1.5、三氧化二锑5、氰尿酸锌2.5、氧化锌7、铬刚玉7、锆英砂6、红柱石6、轻质碳酸钙78、水适量、5%盐酸适量、助剂13；
所述助剂由下列重量份（公斤）的原料制成：二甲基乙酰胺1.5、液体石蜡1.3、苯甲酸钠0.6、活性碳酸钙2.5、竹炭粉6、3.5%氢氧化钠溶液13、二茂铁0.5、太古油0.1、丙烯酸乙酯2.5、丙烯酸甲酯1.3、桂花精油0.1、硫磷丁辛基锌盐0.2、碳酸氢铵0.3、氧化铍0.7、磷酸三丁脂0.4、亚硫酸钙0.5、过硫酸钾0.1、过硫酸铵0.1、水适量；制备方法为：将竹炭粉与3.5%氢氧化钠溶液混合，加热至85℃，搅拌反应25分钟，水洗至pH为8，烘干，再与二甲基乙酰胺、液体石蜡、苯甲酸钠、二茂铁、桂花精油、硫磷丁辛基锌盐、碳酸氢铵、磷酸三丁脂、亚硫酸钙混合，研磨17分钟，得竹炭颗粒；再将太古油加入适量水中，再加入竹炭颗粒，搅拌均匀后加入丙烯酸乙酯，搅拌均匀后升温至75℃，加入过硫酸铵，搅拌反应25分钟，再加入活性碳酸钙、丙烯酸甲酯，搅拌均匀后加入其他剩余成分，继续搅拌反应45分钟，烘干，分散研磨成2-50μm的颗粒，即得。
所述的汽车涂料用改性糖酸钙填料的制备方法，包括以下步骤：
（1）将轻质碳酸钙送入煅烧炉中，在750℃下煅烧2.5个小时，取出粉碎，过100目筛，再加入2.5倍的5%盐酸，加热至60℃，搅拌15分钟，过滤，得滤渣，按上述方法再酸洗一次，再水洗至中性，过滤，得颗粒；
（2）将铬刚玉、锆英砂、红柱石粉碎，过100目筛，与环氧大豆油、双酚A抗氧剂、L-天门冬氨酸锌、尼泊金甲酯、三氧化二锑、氰尿酸锌、氧化锌混合，研磨25分钟，得混合物料；
（3）将第（1）步和第（2）步得到的物料混合，加入适量水搅拌成泥状，研磨成2-50μm的浆料，喷雾干燥，再与其他剩余成分混合均匀，即得。
实验数据：将本实施例的填料添加到丙烯酸聚氨酯涂料中，添加量为8%，经检测干刮伤性（光泽保持率%）为92%，普通为83%；湿刮伤性（光泽保持率%）为84%，普通为71%
涂膜光泽（60°）：4%，
耐水性：（25℃，96小时）：无变化
耐乙醇性：（48小时）：无变化
耐中性盐雾1000小时：合格
从以上数据可以看出该填料能够提高涂料的性能。

Claims (2)

1.一种汽车涂料用改性糖酸钙填料,其特征在于由下列重量份的原料制成：环氧大豆油1-1.5、双酚A抗氧剂2-3、L-天门冬氨酸锌1-2、尼泊金甲酯1-2、三氧化二锑4-6、氰尿酸锌2-3、氧化锌5-8、铬刚玉6-9、锆英砂4-7、红柱石5-8、轻质碳酸钙75-80、水适量、4-6%盐酸适量、助剂12-15；
所述助剂由下列重量份的原料制成：二甲基乙酰胺1-2、液体石蜡1-1.5、苯甲酸钠0.5-0.8、活性碳酸钙2-3、竹炭粉5-7、3-4%氢氧化钠溶液10-15、二茂铁0.4-0.6、太古油0.1-0.2、丙烯酸乙酯2-3、丙烯酸甲酯1-1.5、桂花精油0.1-0.2、硫磷丁辛基锌盐0.2-0.3、碳酸氢铵0.2-0.3、氧化铍0.5-0.8、磷酸三丁脂0.3-0.5、亚硫酸钙0.3-0.6、过硫酸钾0.1-0.2、过硫酸铵0.1-0.2、水适量；制备方法为：将竹炭粉与3-4%氢氧化钠溶液混合，加热至80-90℃，搅拌反应20-30分钟，水洗至pH为7-9，烘干，再与二甲基乙酰胺、液体石蜡、苯甲酸钠、二茂铁、桂花精油、硫磷丁辛基锌盐、碳酸氢铵、磷酸三丁脂、亚硫酸钙混合，研磨15-20分钟，得竹炭颗粒；再将太古油加入适量水中，再加入竹炭颗粒，搅拌均匀后加入丙烯酸乙酯，搅拌均匀后升温至70-80℃，加入过硫酸铵，搅拌反应20-30分钟，再加入活性碳酸钙、丙烯酸甲酯，搅拌均匀后加入其他剩余成分，继续搅拌反应40-50分钟，烘干，分散研磨成2-50μm的颗粒，即得。
2.根据权利要求1所述的汽车涂料用改性糖酸钙填料的制备方法，其特征在于包括以下步骤：
（1）将轻质碳酸钙送入煅烧炉中，在700-800℃下煅烧2-3个小时，取出粉碎，过100目筛，再加入2-3倍的4-6%盐酸，加热至50-70℃，搅拌10-20分钟，过滤，得滤渣，按上述方法再酸洗一次，再水洗至中性，过滤，得颗粒；
（2）将铬刚玉、锆英砂、红柱石粉碎，过100目筛，与环氧大豆油、双酚A抗氧剂、L-天门冬氨酸锌、尼泊金甲酯、三氧化二锑、氰尿酸锌、氧化锌混合，研磨20-30分钟，得混合物料；
（3）将第（1）步和第（2）步得到的物料混合，加入适量水搅拌成泥状，研磨成2-50μm的浆料，喷雾干燥，再与其他剩余成分混合均匀，即得。
CN201410500624.XA 2014-09-26 2014-09-26 一种汽车涂料用改性糖酸钙填料及其制备方法 Pending CN104292948A (zh)

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