CN104250510B - A kind of solvent-free epoxy self-leveling roller coat floor coatings and preparation using method - Google Patents
A kind of solvent-free epoxy self-leveling roller coat floor coatings and preparation using method Download PDFInfo
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Abstract
A kind of solvent-free epoxy self-leveling roller coat floor coatings and preparation using method, this coating contains low viscosity epoxy resin compound, reactive diluent, non-activated thinner, defoamer, levelling agent, wetting dispersing agent, thixotroping auxiliary agent, solvent-free phthalocyanine blue slurry, solvent-free lemon yellow slurry, solvent-free titanium dioxide slurry, solvent-free carbon black, silica flour, blanc fixe and modification aliphatic cyclic amine curing agent, preparation using method comprises the preparation of various solvent-free monochromatic slurries, the preparation of first component, three steps of occupation mode, low viscosity epoxy resin compound is the compound of bisphenol A type epoxy resin and bisphenol f type epoxy resin, in the situation that not adding solvent, greatly reduce the viscosity of this compound system, improve the viscosity of solvent-free system, reduce the use of active and non-activated thinner, in ensureing film physical and mechanical properties, give the levelability that coating is good, thereby make coating of the present invention possess roller coat self-leveling, workability excellence.
Description
Technical field
The invention belongs to environment-friendly type terrace technical field of coatings, refer more particularly to a kind of solvent-free epoxy self-leveling roller coat floor coatings and preparation using method.
Background technology
Floor coatings just started to apply gradually in the nineties in last century, but floor coatings industry development is rapid, substantially all modern plants are all brought into use floor coatings at present, within 2011, the floor coatings output value has exceeded 18,000,000,000 yuan, particularly developing rapidly along with modern industrial technology and production, owner has proposed more and more higher requirement to the production environment in factory building, workshop, require floor coatings corrosion-resistant, clean and wear-resisting, room air dustiness is low, efficiency of construction is high, this is not only the demand of improving working conditions, especially the guarantee of modern product quality.
Epoxy flooring coating dominate in industry ground slab, in epoxy flooring coating, approximately 80% is solvent-borne type, and solvent based coating can discharge a large amount of volatile organic matter VOC in production, construction and solidification process, volatile organic matter not only affects the healthy of people, and can cause environmental pollution.
Solventless Epoxy Self-Leveling Floor Coatings viscosity is large, levelability is not good, adopts sawtooth trowel trowel painting mode to construct more, easily causes trowel trace, and will reach Self-leveling effect, and coated designs thickness is large, and commercial Application cost is high.
In Chinese patent CN103409042A and CN103555145A, all just disclose a kind of non-solvent epoxy floor paint and manufacture method thereof, the consumption to this floor paint and form of construction work do not describe.
Disclosed no-solvent type epoxy self-leveling floor coating of Chinese patent CN103525249A and preparation method thereof and using method, this no-solvent type epoxy self-leveling floor coating finish paint adopts trowel painting mode to construct, film forming thickness reaches 2～3mm, and theoretical use amount has reached 3.2～4.8kg/m2, the materials amount of not only constructing waste, and one film forming thickness is large, and paint film cohesive force likely destroys the xoncrete structure of substrate greatly, causes terrace to destroy.
To sum up, there is easy construction, solvent-free terrace coating widely applicable, with low cost yet there are no relevant report.
Summary of the invention
For addressing the above problem, the invention provides a kind of solvent-free epoxy self-leveling roller coat floor coatings and preparation using method, easy construction, widely applicable, with low cost, the solvent-free epoxy self-leveling roller coat terrace finish paint of workability, mechanical performance and antiseptic property excellence.
Object of the present invention is achieved through the following technical solutions:
A kind of solvent-free epoxy self-leveling roller coat floor coatings, first component in this floor coatings contains low viscosity epoxy resin compound, reactive diluent, non-activated thinner, defoamer, levelling agent, wetting dispersing agent, thixotroping auxiliary agent, silica flour and blanc fixe, second component in this floor coatings is modification aliphatic cyclic amine curing agent, and feature of the present invention is as follows:
In described first component, also contain solvent-free phthalocyanine blue slurry, solvent-free lemon yellow slurry, solvent-free titanium dioxide slurry and solvent-free carbon black.
Described first component all proportioning is by weight as follows:
120～160 parts of low viscosity epoxy resin compounds, 10～15 parts of reactive diluents, 10～15 parts of non-activated thinners, 0.3～2.4 part of defoamer, 3～6 parts of levelling agents, 1.0～2.0 parts of wetting dispersing agents, 1.3～1.8 parts of thixotroping auxiliary agents, 0.032～0.06 part, solvent-free phthalocyanine blue slurry, 0.032～1.92 part, solvent-free lemon yellow slurry, 32.8～39.6 parts of solvent-free titanium dioxide slurries, 0.44～0.9 part of solvent-free carbon black, 50～80 parts of silica flours, 50～80 parts of blanc fixes.
Blend in process actual, the addition of solvent-free phthalocyanine blue slurry, solvent-free lemon yellow slurry, solvent-free titanium dioxide slurry and solvent-free carbon black can be added and subtracted in right amount according to mixed colours demand, and said ratio is the reference value under a kind of particular case.
Above-mentioned low viscosity epoxy resin compound is the compound of bisphenol A type epoxy resin and bisphenol f type epoxy resin, bisphenol A type epoxy resin: bisphenol f type epoxy resin=10:{2～6}, and this ratio is by weight.
Further, bisphenol A type epoxy resin is CYD-128E, and bisphenol f type epoxy resin is GEFR170, and CYD-128E is by Ba Ling petrochemical iy produced in suggestion, and suggestion GEFR170 is produced by Guangdong Hong Chang。
Above-mentioned reactive diluent be 12 to myristyl glycidol ether AGE and n-butyl glycidyl ether BGE in any, or its two kinds of compositions.
Above-mentioned non-activated thinner is phenmethylol.
Above-mentioned defoamer be BYK-A530,6800 and FoamexN in any, suggestion BYK-A530 by Bi Ke chemical production, suggestion 6800 by moral modest (Shanghai) Chemical Co., Ltd. produce, suggestion FoamexN by win wound extraordinary Chemical Co., Ltd. produce.
Above-mentioned levelling agent is any in BYK-354 and BYK-358N, or its two kinds of compositions, and suggestion BYK-354 and BYK-358N are by Bi Ke chemical production.
Above-mentioned wetting dispersing agent is any in BYK-220s and BYK-P104s, and suggestion BYK-220s and BYK-P104s are by Bi Ke chemical production.
Above-mentioned thixotropic agent is organobentoniteBP-881, suggestion BP-881 is produced by Taiyuan Mei Te Xiang.
Above-mentioned solvent-free phthalocyanine blue slurry all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the phthalocyanine blue pigment of 10 parts, the wetting dispersing agent BYK-9076 of 5 parts, the silica flour of 100 parts.
Above-mentioned solvent-free lemon yellow slurry all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the lemon yellow pigment of 100 parts, the wetting dispersing agent BYK-110 of 4 parts.
Above-mentioned solvent-free titanium dioxide slurry all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the anatase thpe white powder of 100 parts, the wetting dispersing agent BYK-110 of 4 parts.
Above-mentioned solvent-free carbon black all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the charcoal blacks of 10 parts, the wetting dispersing agent BYK-110 of 1 part, the silica flour of 100 parts.
Above-mentioned wetting dispersing agent BYK-9076 and BYK-110 advise by Bi Ke chemical production.
Above-mentioned silica flour need sieve through 600 orders.
Above-mentioned blanc fixe need sieve through 800 orders.
Above-mentioned modification aliphatic cyclic amine curing agent is H-3368 curing agent, and suggestion H-3368 curing agent is produced by Shenzhen Ye Xu Industrial Co., Ltd.。
Described first component: described component B={ 4～6}:1, this ratio by weight.
A preparation using method for solvent-free epoxy self-leveling roller coat floor coatings, this prepares preparation, the preparation of first component, three steps of occupation mode that using method comprises various solvent-free monochromatic slurries, and each step is described below:
The preparation of the various solvent-free monochromatic slurries of I
Various solvent-free monochromatic slurries comprise solvent-free phthalocyanine blue slurry, solvent-free lemon yellow slurry, solvent-free titanium dioxide slurry and solvent-free carbon black.
The preparation of solvent-free phthalocyanine blue slurry: the phthalocyanine blue pigment of the wetting dispersing agent of the reactive diluent AGE of the GEFR170 of 100 weight portions, 10 weight portions, 5 weight portions, 10 weight portions, 100 weight portions the silica flour that sieves through 600 orders are added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20um, prepare solvent-free phthalocyanine blue slurry for subsequent use.
The preparation of solvent-free lemon yellow slurry: the wetting dispersing agent BYK-110 of the lemon yellow pigment of the reactive diluent AGE of the GEFR170 resin of 100 weight portions, 10 weight portions, 100 weight portions, 4 weight portions is added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20um, prepare solvent-free lemon yellow slurry for subsequent use.
The preparation of solvent-free titanium dioxide slurry: the wetting dispersing agent BYK-110 of the anatase thpe white powder of the reactive diluent AGE of the GEFR170 resin of 100 weight portions, 10 weight portions, 100 weight portions, 4 weight portions is added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20um, prepare solvent-free titanium dioxide slurry for subsequent use.
The preparation of solvent-free carbon black: the wetting dispersing agent BYK-110 of the charcoal blacks of the reactive diluent AGE of the GEFR170 resin of 100 weight portions, 10 weight portions, 10 weight portions, 1 weight portion, 100 weight portions the silica flour that sieves through 600 orders are added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20um, prepare solvent-free carbon black for subsequent use.
The preparation of II first component
First component comprises low viscosity epoxy resin compound, reactive diluent, non-activated thinner, defoamer, levelling agent, wetting dispersing agent, thixotroping auxiliary agent, solvent-free phthalocyanine blue slurry, solvent-free lemon yellow slurry, solvent-free titanium dioxide slurry and solvent-free carbon black, silica flour and blanc fixe, be wherein the compound of bisphenol A type epoxy resin and bisphenol f type epoxy resin, described compound allocation ratio is by weight: bisphenol A type epoxy resin: bisphenol f type epoxy resin=10:{2～6}.
First the described compound of 120～160 weight portions is added and disperse in agitator, under the rotating speed of 400～600r/min respectively by the reactive diluent of 10～15 weight portions, the thixotroping auxiliary agent of 1.3～1.8 weight portions, the wetting dispersing agent of 1.0～2.0 weight portions adds and disperses to stir 10～20 minutes in agitator, after stirring, the rotating speed that disperses agitator is increased to the non-activated thinner that 1000～1500r/min adds 10～15 weight portions more successively, the levelling agent of 3～6 weight portions, the defoamer of 0.3～2.4 weight portion, the solvent-free phthalocyanine blue slurry of 0.032～0.06 weight portion, the solvent-free lemon yellow slurry of 0.032～1.92 weight portion, the solvent-free titanium dioxide slurry of 32.8～39.6 weight portions, the solvent-free carbon black of 0.44～0.9 weight portion, 50～80 weight portions the silica flour sieving through 600 orders, 50～80 weight portions the blanc fixe sieving through 800 orders, high speed dispersion was filtered through 60 eye mesh screens after 15～25 minutes, prepare first component.
III occupation mode
When blending, scene adds component B in first component, second component is modification aliphatic cyclic amine curing agent, first component and the component B ratio of blending is by weight: first component: component B=4～6}:1, and blend stir after leave standstill 5 minutes froth breakings prepare solvent-free epoxy self-leveling roller coat floor coatings.
In adopting when use, hair roller carries out roller coat application in the substrate of carrying out screed-coat with roll coating model, and the THICKNESS CONTROL of single track film is at 300～500um, and theoretical consumption is controlled at 0.4～0.6kg/m2, after normal temperature cure 24h, complete coating decoration.
In preparation using method, the concrete title of each raw material is identical with above-mentioned solvent-free epoxy self-leveling roller coat floor coatings, does not separately repeat.
Owing to adopting technical scheme described above, the present invention produces following beneficial effect:
1, the present invention adopts the compound system of bisphenol A type epoxy resin and bisphenol f type epoxy resin, in the situation that not adding solvent, greatly reduce the viscosity of this compound system, improve the viscosity of solvent-free system, reduce the use of active and non-activated thinner, in ensureing film physical and mechanical properties, give the levelability that coating is good, thereby make coating of the present invention possess roller coat self-leveling, workability excellence.
2, the present invention adopts various solvent-free monochromatic slurries to mix colours, the preparation process of coating is without sand milling, and preparation technology is simple, has improved production efficiency, and the tonings of various solvent-free monochromatic slurries can reduce the floating phenomenon in coating application process, give coating better apparent state.
3, coating of the present invention can adopt roller application, and single track film thickness can reach 300～500um, and theoretical consumption is only 0.4～0.6kg/m2; Although application consumption is less, film physical and mechanical properties excellence, anti-corrosive properties are strong, and coating good leveling property, the full homogeneous of the apparent color and luster of film, painting effect is good.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is done to further detailed description, but embodiments of the present invention are not limited to this.
Following table is the raw material proportioning of embodiment 1-3:
The preparation using method of solvent-free epoxy self-leveling roller coat floor coatings, referring to technical scheme of the present invention, does not separately repeat.
Establishing criteria GBT22374-2008 " terrace coating material " and HGT3829-2006 " floor coatings " test the correlated performance of embodiment 1-3, under its test result is shown inTable：
Upper table absolutely proves:
1, the solvent-free epoxy self-leveling roller coat floor coatings that the present invention prepares has the feature such as physical and mechanical properties and antiseptic property excellence, this is that what to adopt due to resin system of the present invention is bisphenol-A and Bisphenol F resin compound system, the appropriate diluent of arranging in pairs or groups, system viscosity is little, good leveling property, therefore can adopt roll coating model, single track scumbling can realize Self-leveling effect.
2, the solvent-free epoxy self-leveling roller coat floor coatings that the present invention prepares has easy construction, and painting cost is low, the full homogeneous of terrace color and luster, and levelability is good, smooth, without floating phenomenon, has good mirror effect.
3, in coating of the present invention, do not contain solvent, adopt the color coordinate of various solvent-free monochromatic slurries, it is good that various solvent-free monochromatic slurries have dispersion effect, and therefore without floating phenomenon, film color and luster is full, has good mirror effect.
4,, owing to having adopted well behaved modification aliphatic cyclic amine curing agent H-3368, can well, physical and mechanical properties and the antiseptic property of paint film excellence have been given with composite curable epoxy resin.
Above-mentioned three embodiment are preferably embodiments of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other is any does not deviate from change, the modification done under Spirit Essence of the present invention and principle, substitute, combination, simplify; all should be equivalent substitute mode, within being all included in protection scope of the present invention.
Claims (1)
1. the preparation using method of a solvent-free epoxy self-leveling roller coat floor coatings, first component in this floor coatings contains low viscosity epoxy resin compound, reactive diluent, non-activated thinner, defoamer, levelling agent, wetting dispersing agent, thixotroping auxiliary agent, silica flour and blanc fixe, second component in this floor coatings is modification aliphatic cyclic amine curing agent, also contains solvent-free phthalocyanine blue slurry, solvent-free lemon yellow slurry, solvent-free titanium dioxide slurry and solvent-free carbon black in described first component; This prepares preparation, the preparation of first component, three steps of occupation mode that using method comprises various solvent-free monochromatic slurries, it is characterized in that:
Described first component all proportioning is by weight as follows:
120～160 parts of low viscosity epoxy resin compounds, 10～15 parts of reactive diluents, 10～15 parts of non-activated thinners, 0.3～2.4 part of defoamer, 3～6 parts of levelling agents, 1.0～2.0 parts of wetting dispersing agents, 1.3～1.8 parts of thixotroping auxiliary agents, 0.032～0.06 part, solvent-free phthalocyanine blue slurry, 0.032～1.92 part, solvent-free lemon yellow slurry, 32.8～39.6 parts of solvent-free titanium dioxide slurries, 0.44～0.9 part of solvent-free carbon black, 50～80 parts of silica flours, 50～80 parts of blanc fixes;
Above-mentioned low viscosity epoxy resin compound is the compound of bisphenol A type epoxy resin and bisphenol f type epoxy resin, bisphenol A type epoxy resin: bisphenol f type epoxy resin=10:{2～6}, and this ratio is by weight;
Bisphenol A type epoxy resin is CYD-128E, and bisphenol f type epoxy resin is GEFR170;
Above-mentioned reactive diluent be 12 to myristyl glycidol ether AGE and n-butyl glycidyl ether BGE in any, or its two kinds of compositions;
Above-mentioned non-activated thinner is phenmethylol;
Above-mentioned defoamer be BYK-A530,6800 and FoamexN in any;
Above-mentioned levelling agent is any in BYK-354 and BYK-358N, or its two kinds of compositions;
Above-mentioned wetting dispersing agent is any in BYK-220s and BYK-P104s;
Above-mentioned thixotropic agent is organobentonite BP-881;
Above-mentioned solvent-free phthalocyanine blue slurry all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the phthalocyanine blue pigment of 10 parts, the wetting dispersing agent BYK-9076 of 5 parts, the silica flour of 100 parts;
Above-mentioned solvent-free lemon yellow slurry all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the lemon yellow pigment of 100 parts, the wetting dispersing agent BYK-110 of 4 parts;
Above-mentioned solvent-free titanium dioxide slurry all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the anatase thpe white powder of 100 parts, the wetting dispersing agent BYK-110 of 4 parts;
Above-mentioned solvent-free carbon black all proportioning is by weight as follows:
The GEFR170 resin of 100 parts, the reactive diluent AGE of 10 parts, the charcoal blacks of 10 parts, the wetting dispersing agent BYK-110 of 1 part, the silica flour of 100 parts;
Above-mentioned silica flour need sieve through 600 orders;
Above-mentioned blanc fixe need sieve through 800 orders;
Above-mentioned modification aliphatic cyclic amine curing agent is H-3368 curing agent;
Described first component: described component B=4～6}:1, this ratio is by weight;
The preparation of I, various solvent-free monochromatic slurries:
Various solvent-free monochromatic slurries comprise solvent-free phthalocyanine blue slurry, solvent-free lemon yellow slurry, solvent-free titanium dioxide slurry and solvent-free carbon black;
The preparation of solvent-free phthalocyanine blue slurry: the phthalocyanine blue pigment of the wetting dispersing agent of the reactive diluent AGE of the GEFR170 of 100 weight portions, 10 weight portions, 5 weight portions, 10 weight portions, 100 weight portions the silica flour that sieves through 600 orders are added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20 μ m, prepare solvent-free phthalocyanine blue slurry for subsequent use;
The preparation of solvent-free lemon yellow slurry: the wetting dispersing agent BYK-110 of the lemon yellow pigment of the reactive diluent AGE of the GEFR170 resin of 100 weight portions, 10 weight portions, 100 weight portions, 4 weight portions is added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20 μ m, prepare solvent-free lemon yellow slurry for subsequent use;
The preparation of solvent-free titanium dioxide slurry: the wetting dispersing agent BYK-110 of the anatase thpe white powder of the reactive diluent AGE of the GEFR170 resin of 100 weight portions, 10 weight portions, 100 weight portions, 4 weight portions is added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20 μ m, prepare solvent-free titanium dioxide slurry for subsequent use;
The preparation of solvent-free carbon black: the wetting dispersing agent BYK-110 of the charcoal blacks of the reactive diluent AGE of the GEFR170 resin of 100 weight portions, 10 weight portions, 10 weight portions, 1 weight portion, 100 weight portions the silica flour that sieves through 600 orders are added successively in dispersator and under the rotating speed of 400～600r/min and stirred 10 minutes, after stirring, disperse with sand mill sand milling, in the time that fineness reaches 20 μ m, prepare solvent-free carbon black for subsequent use;
The preparation of II, first component:
First the low viscosity epoxy resin compound of 120～160 weight portions is added and disperse in agitator, under the rotating speed of 400～600r/min respectively by the reactive diluent of 10～15 weight portions, the thixotroping auxiliary agent of 1.3～1.8 weight portions, the wetting dispersing agent of 1.0～2.0 weight portions adds and disperses to stir 10～20 minutes in agitator, after stirring, the rotating speed that disperses agitator is increased to the non-activated thinner that 1000～1500r/min adds 10～15 weight portions more successively, the levelling agent of 3～6 weight portions, the defoamer of 0.3～2.4 weight portion, the solvent-free phthalocyanine blue slurry of 0.032～0.06 weight portion, the solvent-free lemon yellow slurry of 0.032～1.92 weight portion, the solvent-free titanium dioxide slurry of 32.8～39.6 weight portions, the solvent-free carbon black of 0.44～0.9 weight portion, 50～80 weight portions the silica flour sieving through 600 orders, 50～80 weight portions the blanc fixe sieving through 800 orders, high speed dispersion was filtered through 60 eye mesh screens after 15～25 minutes, prepare first component,
III, occupation mode:
When blending, scene adds component B in first component, second component is modification aliphatic cyclic amine curing agent, first component and the component B ratio of blending is by weight: first component: component B=4～6}:1, and blend stir after leave standstill 5 minutes froth breakings prepare solvent-free epoxy self-leveling roller coat floor coatings;
In adopting when use, hair roller carries out roller coat application in the substrate of carrying out screed-coat with roll coating model, and the THICKNESS CONTROL of single track film is at 300～500 μ m, and theoretical consumption is controlled at 0.4～0.6kg/m2, after normal temperature cure 24h, complete coating decoration.
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| CN103525249A (en) * | 2013-10-08 | 2014-01-22 | 深圳市威尔地坪材料有限公司 | Solvent-free epoxy self-leveling floor paint, preparation method thereof and using method thereof |
| CN103555145A (en) * | 2013-11-08 | 2014-02-05 | 西北永新涂料有限公司 | Epoxy self-leveling floor coating and preparation method thereof |
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| US9676895B2 (en) * | 2006-08-04 | 2017-06-13 | Ndsu Research Foundation | Water dispersible epoxy urethane compounds and coating compositions |
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| EP1238028B1 (en) * | 1999-11-13 | 2004-10-27 | Cognis Deutschland GmbH & Co. KG | Aqueous coating compositions |
| CN1803952A (en) * | 2006-01-19 | 2006-07-19 | 天津可喜化工有限公司 | Decoration type antislip epoxy floor lacquer |
| CN102775884A (en) * | 2012-08-22 | 2012-11-14 | 山西省交通科学研究院 | Solvent-free colored floor coating |
| CN103305091A (en) * | 2013-05-23 | 2013-09-18 | 杭州宝力物资再生利用有限公司 | Epoxy floor coating |
| CN103525249A (en) * | 2013-10-08 | 2014-01-22 | 深圳市威尔地坪材料有限公司 | Solvent-free epoxy self-leveling floor paint, preparation method thereof and using method thereof |
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