CN108003673A - A kind of MMA floor coatings and preparation method thereof - Google Patents
A kind of MMA floor coatings and preparation method thereof Download PDFInfo
- Publication number
- CN108003673A CN108003673A CN201711188882.9A CN201711188882A CN108003673A CN 108003673 A CN108003673 A CN 108003673A CN 201711188882 A CN201711188882 A CN 201711188882A CN 108003673 A CN108003673 A CN 108003673A
- Authority
- CN
- China
- Prior art keywords
- parts
- methyl methacrylate
- mma
- monomer
- butyl acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
Abstract
The invention discloses a kind of MMA floor coatings, are mixed by 15 25 parts of 700 900 parts of mian paint, 1 200 parts of mill base, 35 45 parts of initiator and curing accelerator, wherein, mian paint is made of the raw material of following parts by weight：300 500 parts of methyl methacrylate prepolymer, 100 200 parts of methyl methacrylate monomer, 100 200 parts of Butyl Acrylate Monomer, 100 200 parts of talcum powder, 80 100 parts of plasticizer, 10 30 parts of defoamer, 30 50 parts of scratch resistance wax assistant；Mill base is made of the raw material of following parts by weight：150 250 parts of methyl methacrylate prepolymer, 150 250 parts of methyl methacrylate monomer, 150 250 parts of Butyl Acrylate Monomer, 50 100 parts of dispersant, 30 50 parts of wetting agent, 150 450 parts of toner, 10 30 parts of defoamer.The MMA floor coatings of the present invention have the advantages that low-temperature fast-curing, curing, water-tolerant insensitive to moisture.
Description
Technical field
The invention belongs to paint field, and in particular to a kind of MMA floor coatings and preparation method thereof.
Background technology
In China the Yellow River northern area, winter temperature is even more that can reach zero in the Northeast generally below five degrees below zero
It is 30 degree or so lower.In such harsh environment, floor coatings such as common epoxy, polyurethane, vinyl currently on the market
It is difficult to film-forming.
The content of the invention
The above-mentioned deficiency of the prior art is exactly the advantage place of MMA floor coatings, it still can in low temperature minus 20 degrees
Rapid curing, this has absolute competitive advantage in north of china in winter construction, can be described as unique preferably selection at present.
MMA ground systems have shorter construction and curing time, available for the protection to building ground, and can be quick
The characteristics of repairing old ground and low-temperature setting.Peak of investment over China, 20 years, the Industrial Plant Ground that it is built are equal
There is different degrees of breakage, be badly in need of that building ground is carried out fast and effectively to transform and safeguard, to meet its production requirement
And the influence to production is reduced to greatest extent.So field is renovated and transformed on ground has wide application space.MMA
Plane system, can when 2-4 is small within complete construction, cure and maintenance processes, be general ground system (abrasion-resistant ground, ring at present
Oxygen ground) 1/10th.Acrylic acid composition, it can also resist ultraviolet, in prolonged ultraviolet irradiation environment and open air
Brittle and discoloration situation is less prone under rain erosion, chemically-resistant and drug resistance also have outstanding representation.
In addition, MMA floor coatings, which have, cures, water resistance special good (room temperature 5%NaCl aqueous solution soaking insensitive to moisture
6 months, nothing came off, without blistering) the characteristics of, so it has very big city in fields such as underground parking, subway station Grounds
Field prospect.
It is an object of the present invention to overcome above-mentioned prior art defect, there is provided a kind of MMA floor coatings and its preparation
Method.
Technical solution is used by the present invention solves above-mentioned technical problem：
A kind of MMA floor coatings, by 700-900 parts of mian paint, 1-200 parts of mill base, 35-45 parts of initiator and curing accelerator
15-25 parts mix, wherein,
Mian paint is made of the raw material of following parts by weight：Methyl methacrylate prepolymer (MMA prepolymers) 300-500
Part, 100-200 parts of methyl methacrylate monomer (MMA monomers), 100-200 parts of Butyl Acrylate Monomer (BA monomers), talcum
100-200 parts of powder, 80-100 parts of plasticizer, 10-30 parts of defoamer, 30-50 parts of scratch resistance wax assistant；
Mill base is made of the raw material of following parts by weight：Methyl methacrylate prepolymer (MMA prepolymers) 150-250
Part, 150-250 parts of methyl methacrylate monomer (MMA monomers), 150-250 parts of Butyl Acrylate Monomer (BA monomers), disperse
50-100 parts of agent, 30-50 parts of wetting agent, 150-450 parts of toner, 10-30 parts of defoamer.
Preferably, the methyl methacrylate prepolymer is made of the raw material of following parts by weight：Methyl methacrylate
500-700 parts of ester monomer, 300-400 parts of Butyl Acrylate Monomer, 60-80 parts of acrylic monomers, 1-3 parts of benzoyl peroxide.
Preferably, initiator is benzoyl peroxide (BPO).
Preferably, curing accelerator N ' accelerines (DMA).
Preferably, toner is any one in titanium dioxide, carbon black, organic pigment powder, iron oxide inorganic pigment powder.
A kind of method for preparing the MMA floor coatings, comprises the following steps：
(1) mian paint and mill base are uniformly mixed；
(2) initiator and curing accelerator are added under agitation, is sufficiently stirred to obtain the final product；
Mian paint is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) talcum powder, plasticizer, defoamer, scratch resistance wax assistant are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness；
Mill base is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) dispersant, wetting agent and defoamer are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness.
Compared with prior art, the present invention have the advantages that：
(1) preparation of PMMA pre-polymerization resins.The preparation of pre-polymerization resin is the important content of the present invention, and technology content is higher,
Difficulty is relatively large.The present invention prepares prepolymer-monomer mixture using a variety of (methyl) acrylic ester copolymers, as coating
Resin Composition.
(2) design and optimization of formula.The flexibility and the rigidity of organic glass of MMA water-repellent paints, both reasonably balance
It is the design aim and key of the present invention.
(3) selection and optimization of construction technology.The characteristics of rapid curing is the material and advantage, but for construction again
With operable time it is short the drawbacks of.The construction technology of a set of reasonable is made, is that the product must in promotion and application
An indispensable step.
(4) preparation of special-used colour starch and the selection of auxiliary agent.Traditional mill base easily settles in the system, solidification process
In there is phenomena such as loose colour, floating.The addition of the auxiliary agents such as common defoamer and dispersant can be directly to the solidification effect of system
Have an impact.
Embodiment
The present invention is further illustrated below by embodiment, and following embodiments are the specific embodiment party of the present invention
Formula, but embodiments of the present invention and from the limitation of following embodiments.
Embodiment 1
A kind of MMA floor coatings, by 800 parts of mian paint, 100 parts of mill base, PO40 parts of initiator B and curing accelerator DMA20
Part mixes, wherein,
Mian paint is made of the raw material of following parts by weight：400 parts of methyl methacrylate prepolymer, methyl methacrylate
150 parts of monomer, 150 parts of Butyl Acrylate Monomer, 150 parts of talcum powder, 90 parts of plasticizer, 20 parts of defoamer, scratch resistance wax assistant
40 parts；
Mill base is made of the raw material of following parts by weight：200 parts of methyl methacrylate prepolymer, methyl methacrylate
200 parts of monomer, 200 parts of Butyl Acrylate Monomer, 75 parts of dispersant, 40 parts of wetting agent, 300 parts of toner, 20 parts of defoamer.
Methyl methacrylate prepolymer is made of the raw material of following parts by weight：600 parts of methyl methacrylate monomer,
322 parts of Butyl Acrylate Monomer, 76 parts of acrylic monomers, 2 parts of benzoyl peroxide.
Toner is titanium dioxide.
A kind of method for preparing the MMA floor coatings, comprises the following steps：
(1) mian paint and mill base are uniformly mixed；
(2) initiator and curing accelerator are added under agitation, is sufficiently stirred to obtain the final product；
Mian paint is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) talcum powder, plasticizer, defoamer, scratch resistance wax assistant are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness；
Mill base is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) dispersant, wetting agent and defoamer are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness.
Embodiment 2
A kind of MMA floor coatings, by DMA15 parts of 700 parts of mian paint, 1 part of mill base, PO35 parts of initiator B and curing accelerator
Mix, wherein,
Mian paint is made of the raw material of following parts by weight：300 parts of methyl methacrylate prepolymer, methyl methacrylate
100 parts of monomer, 100 parts of Butyl Acrylate Monomer, 100 parts of talcum powder, 80 parts of plasticizer, 10 parts of defoamer, scratch resistance wax assistant
30 parts；
Mill base is made of the raw material of following parts by weight：150 parts of methyl methacrylate prepolymer, methyl methacrylate
150 parts of monomer, 150 parts of Butyl Acrylate Monomer, 50 parts of dispersant, 30 parts of wetting agent, 150 parts of toner, 10 parts of defoamer.
Methyl methacrylate prepolymer is made of the raw material of following parts by weight：500 parts of methyl methacrylate monomer,
300 parts of Butyl Acrylate Monomer, 60 parts of acrylic monomers, 1 part of benzoyl peroxide.
Toner is carbon black.
A kind of method for preparing the MMA floor coatings, comprises the following steps：
(1) mian paint and mill base are uniformly mixed；
(2) initiator and curing accelerator are added under agitation, is sufficiently stirred to obtain the final product；
Mian paint is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) talcum powder, plasticizer, defoamer, scratch resistance wax assistant are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness；
Mill base is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) dispersant, wetting agent and defoamer are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness..
Embodiment 3
A kind of MMA floor coatings, by 900 parts of mian paint, 200 parts of mill base, PO45 parts of initiator B and curing accelerator DMA25
Part mixes, wherein,
Mian paint is made of the raw material of following parts by weight：500 parts of methyl methacrylate prepolymer, methyl methacrylate
200 parts of monomer, 200 parts of Butyl Acrylate Monomer, 200 parts of talcum powder, 100 parts of plasticizer, 30 parts of defoamer, scratch resistance wax assistant
50 parts；
Mill base is made of the raw material of following parts by weight：250 parts of methyl methacrylate prepolymer, methyl methacrylate
250 parts of monomer, 250 parts of Butyl Acrylate Monomer, 100 parts of dispersant, 50 parts of wetting agent, 450 parts of toner, 30 parts of defoamer.
Methyl methacrylate prepolymer is made of the raw material of following parts by weight：700 parts of methyl methacrylate monomer,
400 parts of Butyl Acrylate Monomer, 80 parts of acrylic monomers, 3 parts of benzoyl peroxide.
Toner is iron oxide inorganic pigment powder.
A kind of method for preparing the MMA floor coatings, comprises the following steps：
(1) mian paint and mill base are uniformly mixed；
(2) initiator and curing accelerator are added under agitation, is sufficiently stirred to obtain the final product；
Mian paint is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) talcum powder, plasticizer, defoamer, scratch resistance wax assistant are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness；
Mill base is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) dispersant, wetting agent and defoamer are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness.
The MMA floor coatings paint film indexs of the embodiment of the present invention 1 are as follows：
It is to be understood that these embodiments are only illustrative of the invention and is not intended to limit the scope of the invention.Reading this
Invent lecture content after, those skilled in the art the present invention can be made with any same or similar means it is various conversion or
Modification, such equivalent forms are equally fallen under the scope of the present invention.
Claims (6)
1. a kind of MMA floor coatings, it is characterised in that by 700-900 parts of mian paint, 1-200 parts of mill base, 35-45 parts of initiator and consolidate
Change 15-25 parts of accelerating agent to mix, wherein,
The mian paint is made of the raw material of following parts by weight：300-500 parts of methyl methacrylate prepolymer, methacrylic acid
100-200 parts of methylmethacrylate monomer, 100-200 parts of Butyl Acrylate Monomer, 100-200 parts of talcum powder, 80-100 parts of plasticizer, defoaming
10-30 parts of agent, 30-50 parts of scratch resistance wax assistant；
The mill base is made of the raw material of following parts by weight：150-250 parts of methyl methacrylate prepolymer, methacrylic acid
150-250 parts of methylmethacrylate monomer, 150-250 parts of Butyl Acrylate Monomer, 50-100 parts of dispersant, 30-50 parts of wetting agent, toner
150-450 parts, 10-30 parts of defoamer.
2. MMA floor coatings according to claim 1, it is characterised in that the methyl methacrylate prepolymer is by as follows
The raw material of parts by weight is made：500-700 parts of methyl methacrylate monomer, 300-400 parts of Butyl Acrylate Monomer, acrylic acid
60-80 parts of monomer, 1-3 parts of benzoyl peroxide.
3. MMA floor coatings according to claim 1, it is characterised in that the initiator is benzoyl peroxide.
4. MMA floor coatings according to claim 1, it is characterised in that the curing accelerator is N ' N- dimethyl benzenes
Amine.
5. MMA floor coatings according to claim 1, it is characterised in that the toner is titanium dioxide, carbon black, organic pigment
Any one in powder, iron oxide inorganic pigment powder.
A kind of 6. method for preparing the MMA floor coatings described in claim 1-5, it is characterised in that comprise the following steps：
(1) mian paint and mill base are uniformly mixed；
(2) initiator and curing accelerator are added under agitation, is sufficiently stirred to obtain the final product；
The mian paint is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) talcum powder, plasticizer, defoamer, scratch resistance wax assistant are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness；
The mill base is made by following steps：
(1) at room temperature, by acrylic polymer methyl methacrylate and butyl acrylate dissolved dilution；
(2) dispersant, wetting agent and defoamer are added, is uniformly dispersed；
(3) it is ground and disperses to reach regulation fineness.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711188882.9A CN108003673A (en) | 2017-11-24 | 2017-11-24 | A kind of MMA floor coatings and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711188882.9A CN108003673A (en) | 2017-11-24 | 2017-11-24 | A kind of MMA floor coatings and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108003673A true CN108003673A (en) | 2018-05-08 |
Family
ID=62053675
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711188882.9A Pending CN108003673A (en) | 2017-11-24 | 2017-11-24 | A kind of MMA floor coatings and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108003673A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181378A (en) * | 2018-08-13 | 2019-01-11 | 山西中涂交通科技股份有限公司 | A kind of floor coating that can be low-temperature fast-curing |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533055A (en) * | 2012-01-09 | 2012-07-04 | 江苏格桑花涂料有限公司 | Polyhydroxyalkanoate wear-resistant clean floor coating and preparation method thereof |
| CN102911540A (en) * | 2012-10-24 | 2013-02-06 | 华南理工大学 | Hydrophobic MMA (Methl Methacrylate) resin floor coating and preparation method thereof |
| CN104046070A (en) * | 2014-05-05 | 2014-09-17 | 哈尔滨理工大学 | Methyl methacrylate (MMA) floor coating capable of rapidly solidifying |
| CN104250510A (en) * | 2014-09-30 | 2014-12-31 | 洛阳双瑞防腐工程技术有限公司 | Solvent-free epoxy self-leveling roller coating floor paint and preparation and use method thereof |
| CN105566549A (en) * | 2016-03-21 | 2016-05-11 | 浙江精通科技股份有限公司 | Preparation method of nano black resin particle emulsion |
-
2017
- 2017-11-24 CN CN201711188882.9A patent/CN108003673A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533055A (en) * | 2012-01-09 | 2012-07-04 | 江苏格桑花涂料有限公司 | Polyhydroxyalkanoate wear-resistant clean floor coating and preparation method thereof |
| CN102911540A (en) * | 2012-10-24 | 2013-02-06 | 华南理工大学 | Hydrophobic MMA (Methl Methacrylate) resin floor coating and preparation method thereof |
| CN104046070A (en) * | 2014-05-05 | 2014-09-17 | 哈尔滨理工大学 | Methyl methacrylate (MMA) floor coating capable of rapidly solidifying |
| CN104250510A (en) * | 2014-09-30 | 2014-12-31 | 洛阳双瑞防腐工程技术有限公司 | Solvent-free epoxy self-leveling roller coating floor paint and preparation and use method thereof |
| CN105566549A (en) * | 2016-03-21 | 2016-05-11 | 浙江精通科技股份有限公司 | Preparation method of nano black resin particle emulsion |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181378A (en) * | 2018-08-13 | 2019-01-11 | 山西中涂交通科技股份有限公司 | A kind of floor coating that can be low-temperature fast-curing |
| CN109181378B (en) * | 2018-08-13 | 2021-01-05 | 山西中涂交通科技股份有限公司 | Floor coating capable of being rapidly cured at low temperature |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106380144B (en) | A kind of semi-interpenetrating network polymer cement-based flexible tapestry brick and preparation method thereof | |
| CN101348611B (en) | Acroleic acid modified polysiloxane resin and coating thereof | |
| JP6545336B2 (en) | Makeup method | |
| CN110668757B (en) | Underwater-cured waterproof leaking stoppage grouting reinforcing material and preparation method thereof | |
| CN101633813A (en) | Composite ultraviolet curing waterborne wood coating and production method thereof | |
| KR20080105845A (en) | Waterproof agent for elastic membrane and preparing method thereof | |
| KR101992947B1 (en) | Anti-slip Composition For Pavement And Preparing Method Thereof | |
| CN107033296A (en) | Extra-weather-proof polysiloxane-modified acrylic resin and finish paint preparation method | |
| KR101088355B1 (en) | Soil hardener composition and construction methods | |
| CN104046070A (en) | Methyl methacrylate (MMA) floor coating capable of rapidly solidifying | |
| CN104072086A (en) | Dry powder decoration mortar free of cement | |
| CN108003673A (en) | A kind of MMA floor coatings and preparation method thereof | |
| CN104341124B (en) | A kind of fast repairing material for various roads type and construction usage method thereof | |
| CN105368316B (en) | A kind of UV quick curing methods of epoxy soybean oil acrylate resin | |
| JP2006124632A (en) | Water borne coating composition | |
| KR101131609B1 (en) | Flooring with Acrylic Resin | |
| CN110423054B (en) | Fracture-resistant durable cement-based composite material containing PP fibers | |
| CN109593469B (en) | Water-based marking paint and preparation method thereof | |
| CN104530943A (en) | Wear-resistant polyurea terrace coating and preparation method and application thereof | |
| JP2010248306A (en) | One-component aqueous coating composition which imparts architectural design to outer wall of building | |
| CN113755082A (en) | High-flash-point safe alkyd anticorrosive paint and preparation process thereof | |
| CN104893514A (en) | Formula and preparation method of polyester/epoxy resin powder coating | |
| CN106349841A (en) | High-performance acrylic amino baking varnish and preparation method thereof | |
| WO2004014815A1 (en) | Solvent-free method for hydrophobic color coating of glass granulates, product therefrom and use thereof | |
| CN101993658A (en) | Modified polysiloxane paint with high weather resistance and self-cleaning property |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180508 |