A kind of multiple-effect granulated boric fertilizer and manufacture method
Technical field
The present invention relates to a kind of novel boron fertilizer, belong to fertilizer manufacture field, also relate to the manufacture method of boron fertilizer in addition.
Background technology
In the whole world, most of boron resource is distributed in the western hemisphere, the U.S., Turkey, Russia, Chile, Peru etc.Relatively centralized, China's boron rock amount of having is few, grade is low, high three deficiencies of foreign matter content.China's boron resource wretched insufficiency, cultivated soil big area boron deficiency, and field crop needs boron in a large number, and as rape, cotton, beet, fruit etc.At present, the boron fertilizer product of domestic main use mainly contains: (1) borax decahydrate, pure Boron contents is about 10.9%, is water white transparency crystallization or powder, is the most frequently used benefit boron product of China, use-pattern is that soil base is executed, also spray, its shortcoming to be the aqueous solution be alkalescence, can not with most of mixed pesticide, boron utilization ratio is low, mends effect of boron limited.(2) boric acid, boracic is acid-state, expensive, is not easily plant absorption, easily with aqueous vapor volatilization, easily runs off, easily causes and burn and boron poisoning.(3) boron magnesium mixed fertilizer, boron-containing quantity is low, poorly soluble, cannot supplement boron needed for soil and crop fast.(4) granulated boric fertilizer, by adopting sulfuric acid and borax mixed solution as binding agent, carries out granulation, obtained granulated boric fertilizer to powdery borax, boric acid powdery mixture, see patent No. CN101585720A, exist active low, easily lose, fertilizer efficiency is single, and utilization ratio is low, the shortcoming that cost is high.
Summary of the invention
The object of the invention is to overcome above-mentioned not enough problem, provide a kind of Novel multi-effect granulated boric fertilizer, boron fertilizer fertilizer efficiency meets crop whole breeding time to boron nutrient demand, and grain graininess even, and intensity is high, good fluidity, is easy to use; Another object of the present invention is to provide the manufacture method of Novel multi-effect granulated boric fertilizer, and technique is simple, easy handling.
The present invention is achieved through the following technical solutions: a kind of Novel multi-effect granulated boric fertilizer, adopt ulexite breeze, borax, boric acid, methylene urea are as pulverulent mixture material, mix by following part by weight, at 60-90 degree temperature and acidic medium condition, carry out polyreaction granulation to obtain, wherein each raw material weight number is as follows:
Ulexite breeze: 30-60
Borax: 0-40
Boric acid: 0-20
Methylene urea: 5-10
Acidic medium is one or more in the vitriol oil, phosphoric acid, citric acid.
The mixture of described raw material methylene urea to be component be MDU, dimethyl triuret, trimethylammonium four urea and tetramethyl-five urea.
The percent mass concentration of described acidic medium is 1-15%, preferably 5%.
Described raw material ulexite breeze, borax, boric acid, methylene urea all adopt particle diameter 60 order-120 order raw material.
The manufacture method of a kind of Novel multi-effect granulated boric fertilizer of the present invention, concrete manufacturing step is as follows:
The first, raw material ulexite breeze, borax, boric acid, methylene urea grinding and processing are become 60 order-120 orders, fully stirs through ulexite breeze, borax, boric acid, the methylene urea pulverized, mix to obtain mixture;
The second, one or more of getting in sulfuric acid, phosphoric acid, citric acid prepare acid medium solution, and the acidic medium strength of solution 1-15% after preparation, as granulation liquid phase;
3rd, progressively joined in granulation disc by mixture, first use a small amount of acidic medium solution impregnation, while add mixture, limit spray acidic medium solution and water vapor, keep prilling temperature 60-90 degree to carry out granulation, until particle reaches required particle diameter;
4th, carry out drying, cool, sieve obtained finished product.
In described 3rd step, prilling temperature is 80 degree.
Beneficial effect of the present invention: by under certain temperature and acidity condition, to ulexite breeze, borax, boric acid, methylene level urea, carry out polyreaction granulation, wherein methylene urea is amino many ureas (MethyleneUrea) is amino many ureas long-chain organism, there is good chemical bonding and covered effect, the boron fertilizer of different fertilizer efficiency is made well to realize polymerization, bonding, coated granulation, finished product multiple-effect granulated boric fertilizer boron nutrient is in chemical bonding effect, under polymerization and coating function, realize quick-acting, middle effect, long-acting equilibrium release, improve boron fertilizer utilising efficiency.Product discharges in conversion process in soil, methylene urea can improve soil microbial activities, promote abundant absorption and the conversion of boron nutrient, give full play to boron fertilizer fertilizer efficiency, meet crop whole breeding time to boron nutrient demand, and grain graininess even, intensity is high, good fluidity, is easy to use.Meanwhile, adopt boron ore powder as raw material, make full use of resource, reduce the production cost of boron particles, increase economic efficiency.
Product of the present invention can ensure single-dose application, continue supply boron nutrient, overcome most of boron fertilizer on market not easily to absorb, easily run off, easily cause the common disadvantage of boron poisoning, lasting effective correction crop boron deficiency, improve the boracic situation of soil, its distinctive physicochemical character make it have boron release balanced, continue long-acting feature, crop whole breeding time can be met to the needs of boron nutrient, while reducing labour cost, effectively improve the yield and quality of crop.
Accompanying drawing explanation
Fig. 1 is multiple-effect granulated boric fertilizer nutrient release curve of the present invention and Crop boron graphic representation.
Embodiment
Embodiment 1
Take and be crushed to 60 order-120 object ulexite breeze 500 kilograms; borax 200 kilograms; boric acid 200 kilograms; methylene urea (N40%) 100 kilograms; mix as pulverulent mixture material; using 5% sulphuric acid soln as liquid phase; in granulating disc (50 revs/min), by the pulverulent mixture material mixed, progressively join in granulation disc; first infiltrate on a small quantity with acidic medium solution; while add pulverulent mixture material, limit spray acidic medium solution and water vapor, keep prilling temperature 85 degree; carry out granulation, until particle reaches required particle diameter.Carry out drying, cool, sieve obtained finished product: B
2o
336.9%, the N mass content that mass content accounts for total content accounts for 4%, 2-4mm, intensity 30N of total content.
Peanut application example:
The Peanut Fields of northeast, Lvshunkou District, Daliang City of Liaoning Province mountain village one peasant household is chosen as manure trial ground in 2013, peanut was sowed at the beginning of 2013 4 months, gather at the beginning of 2013 9 months, multiple-effect granulated boric fertilizer with contrast boron fertilizer and all make base fertilizer and use, every mu of 250g, between breeding time, the Boron contents of plant leaf is detected, detect five times altogether respectively at the Seedling Stage of peanut, lower pin phase of blooming, fruiting period, full fruit ripening stage and harvesting time; Harvesting time records output, uses the peanut whole breeding time of multiple-effect granulated boric fertilizer, and the concentration of blade boron is sufficient, does not occur boron deficiency symptom, robust plant, grows fine; And the peanut leaf using contrast boron fertilizer obviously declines to later stage Boron contents, and there is boron deficiency symptom in plant, and concrete data are as shown in the table:
Table 1: peanut different growing dry matter weight of leaf boron-containing quantity and output
Embodiment 2
Take and be crushed to 60 order-120 object ulexite breeze 300 kilograms; borax 400 kilograms; boric acid 200 kilograms; methylene urea (N40%) 100 kilograms; mix as pulverulent mixture material; using 10% phosphoric acid solution as liquid phase; in granulating disc (55 revs/min), by the pulverulent mixture material mixed, progressively join in granulation disc; first infiltrate on a small quantity with acidic medium solution; while add pulverulent mixture material, limit spray acidic medium solution and water vapor, keep prilling temperature 75 degree; carry out granulation, until particle reaches required particle diameter.Carry out drying, cool, sieve obtained finished product.Product specification: B
2o
340.1%, the N mass content that mass content accounts for total content accounts for 4%, 2-4mm, intensity 28N of total content.
Example used by oranges and tangerines:
Choose Chongqing City in 2013 and choose the citrus orchard of certain peasant household as manure trial ground, multiple-effect granulated boric fertilizer with contrast boron fertilizer and all make base fertilizer and use, used before oranges and tangerines green sprouting in 2013, every strain 40g, between breeding time, the Boron contents of Citrus leaf is detected, detect five times altogether respectively at the leaf development stage of oranges and tangerines, flowering period, just fruit phase, fruit expanding period, collection period; Harvesting time records output, uses the oranges and tangerines whole breeding time of multiple-effect granulated boric fertilizer, and the concentration of blade boron is sufficient, does not occur boron deficiency symptom, robust plant, grows fine; And the Citrus leaf using contrast boron fertilizer obviously declines to later stage Boron contents, and there is boron deficiency symptom in plant, and concrete data are as shown in the table:
Table 2: oranges and tangerines different growing dry matter weight of leaf boron-containing quantity and output
Embodiment 3
Take the ulexite breeze 600 kilograms being crushed to less than 0.5 millimeter; borax 250 kilograms; boric acid 100 kilograms; methylene urea (N40%) 50 kilograms; mix as pulverulent mixture material; using 10% citric acid solution as liquid phase; in granulating disc (60 revs/min), by the pulverulent mixture material mixed, progressively join in granulation disc; first infiltrate on a small quantity with acidic medium solution; while add pulverulent mixture material, limit spray acidic medium solution and water vapor, keep prilling temperature 65 degree; carry out granulation, until particle reaches required particle diameter.Carry out drying, cool, sieve obtained finished product.Product specification: B
2o
3mass content accounts for 36.85% of total content, and mass content accounts for the N2% of total content, 2-4mm, intensity 35N.
Rape uses example
The Rapeseed Field of Huaining County, Anhui Province peasant household is chosen as manure trial ground in 2012, rape is sowed in by the end of September, 2012 in, gather in by the end of May, 2013, multiple-effect granulated boric fertilizer with contrast boron fertilizer and all make base fertilizer and use, every mu of 300g, between breeding time, the Boron contents of plant leaf is detected, respectively seedling stage, transplant before, transplant latter 20 days, elongation; Harvesting time records output, use the rape whole breeding time of multiple-effect granulated boric fertilizer, the concentration of blade boron is sufficient, do not occur boron deficiency symptom, and the rape leaf using contrast boron fertilizer obviously declines to later stage Boron contents, and there is boron deficiency symptom in plant, monitor in rape breeding time simultaneously, Boron In Soil change in concentration situation (see figure mono-), as shown in Figure 1, in figure: crop boron absorption curve is conventional regulation of fertilizer requirement in rape breeding time; Multiple-effect boron is the concentration curve after the present embodiment 3 product is manured into soil; Conventional boron is the concentration curve commonly using borax in the market.Concrete data are as shown in the table:
Table 3: rape different growing dry matter weight of leaf boron-containing quantity and output
Embodiment 4
Take and be crushed to 60 order-120 object ulexite breeze 600 kilograms; borax 100 kilograms; boric acid 200 kilograms; methylene urea (N40%) 100 kilograms; mix as pulverulent mixture material; using 10% sulphuric acid soln as liquid phase; in granulating disc (50 revs/min), by the pulverulent mixture material mixed, progressively join in granulation disc; first infiltrate on a small quantity with acidic medium solution; while add pulverulent mixture material, limit spray acidic medium solution and water vapor, keep prilling temperature 70 degree; carry out granulation, until particle reaches required particle diameter.Carry out drying, cool, sieve obtained finished product: B
2o
335.2%, the N mass content that mass content accounts for total content accounts for 4%, 2-4mm, intensity 30N of total content.
Example used by cherry:
Choosing the auspicious cherry picking garden of cloud, Guo Jia village, Tie Shan street, Tie Shan street, Lvshunkou District, Daliang City of Liaoning Province in 2013 is experimental plot, large cherry kind is red light, multiple-effect granulated boric fertilizer with contrast boron fertilizer and all make base fertilizer and use, use before green sprouting in 2013, every strain 40g, florescence, fruit phase and mid-July gather the detection that blade carries out blade Boron contents respectively after plucking, harvesting time records output, measure the sugar content of fruit etc., use the large cherry whole breeding time of multiple-effect granulated boric fertilizer, the concentration of blade boron is sufficient, there is not boron deficiency symptom, robust plant, grow fine, and the Citrus leaf using contrast boron fertilizer obviously declines to later stage Boron contents, and there is boron deficiency symptom in plant, and concrete data are as shown in the table:
Table 4, large cherry different times dry matter weight of leaf boron-containing quantity and output
Embodiment 5
Take and be crushed to 60 order-120 object ulexite breeze 520 kilograms; borax 400 kilograms; boric acid 30 kilograms; methylene urea (N40%) 50 kilograms; mix as pulverulent mixture material; using 5% citric acid solution as liquid phase; in granulating disc (50 revs/min), by the pulverulent mixture material mixed, progressively join in granulation disc; first infiltrate on a small quantity with acidic medium solution; while add pulverulent mixture material, limit spray acidic medium solution and water vapor, keep prilling temperature 80 degree; carry out granulation, until particle reaches required particle diameter.Carry out drying, cool, sieve obtained finished product: B
2o
337.52%, the N mass content that mass content accounts for total content accounts for 2%, 2-4mm, intensity 30N of total content.
Tobacco uses example:
It is chose Longyang District one, Baoshan, Yunnan city peasant household tobacco planting in 2013 experimental plot, multiple-effect granulated boric fertilizer with contrast boron fertilizer and all make base fertilizer and use, use before tobacco transplant, every mu of 300g, the detection that blade carries out blade Boron contents is gathered respectively at Seedling Stage, prosperous long-term, ripening stage, harvesting time records output, plant height, the number of blade etc., uses the tobacco whole breeding time of multiple-effect granulated boric fertilizer, plant key is strengthened, the number of blade increases, leaf look dark green, and disease and pest significantly reduces, and Flue-cured tobacco Quality improves.There is not boron deficiency symptom, grow fine; And the tobacco leaf using contrast boron fertilizer obviously declines to later stage Boron contents, and there is boron deficiency symptom in plant, and concrete data are as shown in the table:
Table 5, tobacco different times dry matter weight of leaf boron-containing quantity and output