CN104177922B - Ceramic ink with effect of separating glaze, as well as preparation and using methods and ceramic tile of ceramic ink - Google Patents
Ceramic ink with effect of separating glaze, as well as preparation and using methods and ceramic tile of ceramic ink Download PDFInfo
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Abstract
The invention provides ceramic ink with an effect of separating glaze, as well as preparation and using methods and a ceramic tile of the ceramic ink. The preparation method of the ceramic ink comprises the following steps: a, mixing the following raw materials in parts by weight: 25-30 parts of urethane acrylate, 30-50 parts of propyl allyl ether carbonate or dodecyl vinyl ether, 10-20 parts of hydroquinone or p-methoxyphenol, 0-20 parts of paraffin oil or industrial solvent oil and 3-5 parts of an auxiliary; b, uniformly stirring the mixture of the raw materials at high speed to obtain a primary mixed material; c, initially grinding and dispersing the primary mixed material by using a ball mill, and transferring into a sand mill for further grinding to obtain the ceramic ink with fineness less than 1 micron. A ceramic tile product prepared by adopting the ceramic ink which is dissoluble with ceramic glaze has an uneven decorating effect without a punch-cum-blanking die, the process is simple, the production is safe, the stability of the ink can be improved, and the clarity and layer sense of patterns can be improved.
Description
Technical field
The present invention relates to ceramic pigment field, particularly relate to a kind of ceramic ink separating glaze effect and preparation thereof
With using method and ceramic tile.
Background technology
Along with the development of digitizing technique is with universal, inkjet technology is gradually answered in ceramic industry field
With.Pottery air brushing technology be by one by ceramic powder (colorant, coloring agent), solvent, dispersant and other
The ink that adjuvant is constituted, sprays from the nozzle of diameter some tens of pm, with the deposition rate of thousands of per second at base
Decoration technique on body, glaze.Owing to being contactless decoration, can decorate at any convex-concave surface,
Product therefore more personalized, true to nature, fine and smooth, more rich texture variations.Simultaneously because air brushing technology without
Need to web plate processed, the most time-consuming, improve again efficiency, therefore, the most welcome, and market development
Space is very big.
Having the glaze decorating effect of Z-Correct bump mapping Z-correct can allow the decorative effect in brick face the most three-dimensional, has recessed simultaneously
Burr reason also makes product have more preferable non-skid property, is particularly suitable for public space application.At conventional art
In, in order to obtain concavo-convex glazing effect, need to use male and female mold, i.e. arrange on mould and have and set
The relief pattern that meter pattern is contrary.The pattern accuracy that this mode obtains is inadequate, and works as concave convex texture relatively
Time deep, the defects such as disconnected glaze easily occur.Meanwhile, the Design of Dies of concave convex texture also can make formed product defect increase
High.
Summary of the invention
It is an object of the invention to solve tile product in prior art and produce the problem proposition of concavo-convex decorative effect
A kind of ceramic ink separating glaze effect and preparation and application and ceramic tile.
For reaching this purpose, the present invention by the following technical solutions:
A kind of ceramic ink separating glaze effect, includes urethane acrylate 25-30 part according to parts by weight,
Carbonic acid propyl group propenyl ether or dodecyl vinyl 30-50 part, hydroquinone or p methoxy phenol
10-20 part, alkane oil or industrial solvent 0-20 part, auxiliary agent 3-5 part.
Preferential, described auxiliary agent includes levelling agent, dispersant and anti-settling agent.
Preferential, described levelling agent is organic modified polyorganosiloxane acrylic type levelling agent.
Preferential, described dispersant is high molecular polyurethane type dispersant or high molecular weight polypropylene acid esters type
Dispersant.
Preferential, described anti-settling agent is one or more mixture of oxidic polyethylene or polyamide wax.
The preparation method of the ceramic ink separating glaze effect as described in claim 1-3 any one, including
Following steps:
A, by raw material mix；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink.
Preferential, the using method of the ceramic ink that preparation method as claimed in claim 4 obtains, at pottery
Porcelain biscuit surface is sprayed described ceramic ink and is formed predetermined pattern, drenches glaze the most again, finally burns till acquisition ceramic tile.
Preferential, the ceramic tile of using method as claimed in claim 5 acquisition.
The present invention, by preparing the ceramic ink immiscible with ceramic glaze, then uses described ceramic ink to prepare
Tile product in the case of not using male and female mold, tile product just can have irregular decorative effect；
And technique is simple, production safety, moreover it is possible to improve the stability of ink, improves definition and the level of pattern
Sense.
Accompanying drawing explanation
Fig. 1 is the preparation flow figure of Ceramic Tiles of the present invention.
Detailed description of the invention
Technical scheme is further illustrated below by detailed description of the invention.
Referring to the drawings 1, the preparation and application of a kind of ceramic ink separating glaze effect, comprise the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 25 parts-30, carbonic acid propyl group propenyl ether
Or dodecyl vinyl 30-50 part, hydroquinone or p methoxy phenol 10-20 part, alkane oil or
Industrial solvent 0-20 part, auxiliary agent 3-5 part mixes；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink；
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Preferential, described auxiliary agent includes levelling agent, dispersant and anti-settling agent.
Preferential, described levelling agent is organic modified polyorganosiloxane acrylic type levelling agent.
Preferential, described dispersant is high molecular polyurethane type dispersant or high molecular weight polypropylene acid esters type
Dispersant.
Preferential, described anti-settling agent is one or more mixture of oxidic polyethylene or polyamide wax.
The ceramic ink using above component and above method to prepare is immiscible with ceramic glaze, so at pottery element
Ceramic ink described in the spray printing of base surface forms predetermined pattern, drenches glaze the most again, and the ceramic tile finally burning till acquisition produces
Product have concave-convex effect.Owing to ceramic glaze and above-mentioned obtained ceramic ink are immiscible, so at pottery
On ceramic tile or adobe surface after ceramic ink described in spray printing, then drenching glaze, glaze is not bound to ceramic ink
In the localities, so will sag in the place that spray printing has described ceramic ink, the tile product after burning till will
Demonstrate concavo-convex decorative effect；So need not male and female mold, just can be formed and there is concavo-convex decorative effect
Tile product, and the tile product produced in prior art needs just can make in the case of using male and female mold
Tile product has concavo-convex decorative effect.
Described urethane acrylate viscosity is low, makes ink have relatively low viscosity, and when drenching glaze, glaze will not
It is stained with on ink, thus realizes the effect that ink separates with glaze.
Described carbonic acid propyl group propenyl ether or dodecyl vinyl can be able to reduce human body as diluent
Zest, be not result in producing and use the human allergy of glaze or burnt, it is ensured that produce and use
Safety.
Described hydroquinone or p methoxy phenol as polymerization inhibitor, can rapidly and free radical effect, slow down or
Suppress undesirable chemical reaction substance, play inhibition, for extending the storage of some monomer and resin
Deposit the phase, the storage period for ceramic glaze and useful life can be extended.
Described organic modified polyorganosiloxane acrylic type levelling agent, dispersant and anti-settling agent contribute to material and are grinding
Mill makes fully to mix, and makes glaze reach good sprawling in use in ceramic plane, the most organic changes
Property polysiloxanes acrylic type levelling agent make glaze have strong levelability, regulate further the wettability of ink
Can so that it is on base substrate, present good effect of sprawling, and organic modified polyorganosiloxane acrylic type levelling
Agent has defoaming capacity, also plays the effect of defoamer, does not affect ply adhesion.
Embodiment 1
With reference to Fig. 1, the preparation and application of a kind of ceramic ink separating glaze effect, comprise the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 25 parts, carbonic acid propyl group propenyl ether 30
Part, hydroquinone 20 parts, industrial solvent 20 parts, organic modified polyorganosiloxane acrylic type levelling agent 3
Part, high molecular polyurethane type dispersant 1 part, polyamide wax 1 part；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink；
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.7mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.0mm, by the ink amount that ink amount is pattern gray scale 45 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about 0.7mm, the lines of ink-jetting pattern
Average live width be about 0.8mm；The excellence rate of product is 92%, and production cost is about 34 yuan/sheet
(800X800X12mm specification).
Comparative example 1
For explanation this programme advantage, the present invention also provides for a comparative example.
A kind of preparation method of the Ceramic Tiles with Z-Correct bump mapping Z-correct, its step includes:
(1) blank, cover-coat enamel, are prepared；(same as in Example 1)
(2), blank in mould brick molding formed base brick, mould brick is provided with rough lines, concavo-convex
The degree of depth of uneven lines is in the range of for about 0.5mm；
(3) the base brick sintering, after molding is dried, and sintering temperature is 1170 DEG C-1200 DEG C；
(4), dry body drenches glaze；Glaze thickness is about 0.4mm；(glaze component is same as in Example 1)
(5) kiln twice firing, is entered；Firing temperature is same as in Example 1.
(6), polishing, edging.
There is following defect in the Ceramic Tiles with Z-Correct bump mapping Z-correct that this method prepares: (1) can not be kept away due to mould
Exempt from artificial trace, not there is natural random decorative effect, therefore cause produced pottery
Brick decorative effect is stiff, stiff, unnatural；(2) to obtain different textured patterns, then need to change
Mould, causes production cost to increase；Also can not combine with other decorative pattern well.
The excellence rate of product is only 83%, and production cost is about 45 yuan/sheet (800X800X12mm specification).
Embodiment 2
The preparation and application of a kind of ceramic ink separating glaze effect, comprises the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 26 parts, carbonic acid propyl group propenyl ether 50
Part, p methoxy phenol 10 parts, industrial solvent 11 parts, organic modified polyorganosiloxane acrylic type levelling
Agent 1 part, high molecular weight polypropylene acid esters type dispersant 1 part, oxidic polyethylene 1 part；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink.
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.6mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.1mm, by the ink amount that ink amount is pattern gray scale 46 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about 0.6mm, the lines of ink-jetting pattern
Average live width be about 0.85mm；The excellence rate of product is 90%, and production cost is about 33 yuan/sheet
(800X800X12mm specification).
Embodiment 3
The preparation and application of a kind of ceramic ink separating glaze effect, comprises the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 27 parts, dodecyl vinyl 35
Part, hydroquinone 16 parts, alkane oil 18 parts, organic modified polyorganosiloxane acrylic type levelling agent 1 part,
High molecular weight polypropylene acid esters type dispersant 2 parts, polyamide wax 1 part；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink.
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.7mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.0mm, by the ink amount that ink amount is pattern gray scale 55 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about 0.7mm, the lines of ink-jetting pattern
Average live width be about 0.75mm；The excellence rate of product is 97%, and production cost is about 34 yuan/sheet
(800X800X12mm specification).
Embodiment 4
The preparation and application of a kind of ceramic ink separating glaze effect, comprises the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 28 parts, dodecyl vinyl 40
Part, p methoxy phenol 15 parts, industrial solvent 12 parts, organic modified polyorganosiloxane acrylic type levelling
Agent 1 part, high molecular polyurethane type dispersant 1 part, oxidic polyethylene 3 parts；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink；
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.75mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.0mm, by the ink amount that ink amount is pattern gray scale 47 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about 0.75mm, the stricture of vagina of ink-jetting pattern
The average live width on road is about 0.8mm；The excellence rate of product is only 95%, and production cost is about 33 yuan/sheet
(800X800X12mm specification).
Embodiment 5
The preparation and application of a kind of ceramic ink separating glaze effect, comprises the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 29 parts, carbonic acid propyl group propenyl ether 45
Part, p methoxy phenol 12 parts, alkane oil 10 parts, organic modified polyorganosiloxane acrylic type levelling agent 2
Part, high molecular weight polypropylene acid esters type dispersant 1 part, polyamide wax 0.5 part, oxidic polyethylene 0.5 part
Part；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink；
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.6mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.1mm, by the ink amount that ink amount is pattern gray scale 54 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about 0.6mm, the lines of ink-jetting pattern
Average live width be about 0.85mm；The excellence rate of product is only 91%, and production cost is about 32 yuan/sheet
(800X800X12mm specification).
Embodiment 6
The preparation and application of a kind of ceramic ink separating glaze effect, comprises the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 30 parts, carbonic acid propyl group propenyl ether 30
Part, hydroquinone 18 parts, alkane oil 17 parts, organic modified polyorganosiloxane acrylic type levelling agent 2 parts,
High molecular polyurethane type dispersant 2 parts, oxidic polyethylene 1 part；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink；
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.8mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.2mm, by the ink amount that ink amount is pattern gray scale 52 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about 0.8mm, the lines of ink-jetting pattern
Average live width be about 0.95mm；The excellence rate of product is 94%, and production cost is about 34 yuan/sheet
(800X800X12mm specification).
Embodiment 7
The preparation and application of a kind of ceramic ink separating glaze effect, comprises the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 25 parts, dodecyl vinyl 50
Part, p methoxy phenol 20 parts, alkane oil 0 part, organic modified polyorganosiloxane acrylic type levelling agent 1 part,
High molecular weight polypropylene acid esters type dispersant 2 parts, polyamide wax 1 part, oxidic polyethylene 1 part；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink；
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.65mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.0mm, by the ink amount that ink amount is pattern gray scale 50 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about mm, the lines of ink-jetting pattern
The a width of 0.85mm of average line；The excellence rate of product is only 93%, and production cost is about 35 yuan/sheet
(800X800X12mm specification).
Embodiment 8
The preparation and application of a kind of ceramic ink separating glaze effect, comprises the following steps:
A, according to the following ratio by raw material mix: urethane acrylate 28 parts, dodecyl vinyl 37
Part, hydroquinone 17 parts, alkane oil 15 parts, organic modified polyorganosiloxane acrylic type levelling agent 1 part,
High molecular weight polypropylene acid esters type dispersant 1 part, polyamide wax 1 part；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink；
D, by the ceramic ink spray printing obtained by step c to biscuit of ceramics surface, then drench glaze；The thickness of glaze
Degree is about 0.55mm；
E, it is finally putting into kiln, at a temperature of 1000 DEG C-1200 DEG C, fires 2-4h；
F, polishing, edging can be prepared by the tile product with concavo-convex decorative effect.
Need exist for illustrating that base substrate used above, glaze formula are conventional formulation well known in the art,
Suitably can select according to process conditions in practice, this partial content is not the inventive point of the present invention.
The texture that decorative pattern is striated that wherein ink-jet of step d is formed, the average line of striped is a width of
1.0mm, by the ink amount that ink amount is pattern gray scale 48 degree.
The pottery concavo-convex glaze product that this method prepares, the degree of depth of its depression is about 0.55mm, the stricture of vagina of ink-jetting pattern
The average live width on road is about 0.85mm；The excellence rate of product is only 93%, and production cost is about 34 yuan/sheet
(800X800X12mm specification).
It addition, the scheme that the present invention provides can prepare the Z-Correct bump mapping Z-correct of fine patterning, this is conventional ones work
Skill institute is inaccessiable.In traditional handicraft, Sheet Metal Forming Technology is only suitable for rough composition, otherwise can be because of glaze
Covering and make Z-Correct bump mapping Z-correct inconspicuous, and cup depth is the biggest, and disconnected glaze defect is the most obvious.This
Bright scheme well solves above contradiction.By ink jet layer make its covering part not with glaze slip moistening, sintering
Rear formation concave affect, this mode, technique is simple, and defect is few, and is suitable for composition in advance.
The know-why of the present invention is described above in association with specific embodiment.These describe and are intended merely to explain this
The principle of invention, and limiting the scope of the invention can not be construed to by any way.Based on herein
Explaining, those skilled in the art need not pay performing creative labour can associate other tool of the present invention
Body embodiment, within these modes fall within protection scope of the present invention.
Claims (4)
1. the ceramic ink separating glaze effect, it is characterised in that: according to parts by weight by following components system
For forming: urethane acrylate 27 parts, dodecyl vinyl 35 parts, hydroquinone 16 parts, alkane
Hydrocarbon ils 18 parts, organic modified polyorganosiloxane acrylic type levelling agent 1 part, high molecular weight polypropylene acid esters type
Dispersant 2 parts and polyamide wax 1 part.
2. the preparation method of the ceramic ink separating glaze effect as claimed in claim 1, it is characterised in that:
Comprise the following steps:
A, by raw material mix；
B, above-mentioned raw materials mixture high-speed stirred is uniform, obtain initial mixture material；
C, by initial mixture material use the preliminary grinding distribution of ball mill, then proceed to sand mill and grind further,
Fineness is less than 1 micron, it is thus achieved that ceramic ink.
3. the using method of the ceramic ink that preparation method as claimed in claim 2 obtains, it is characterised in that:
Spray described ceramic ink on biscuit of ceramics surface and form predetermined pattern, drench glaze the most again, finally burn till acquisition porcelain
Brick.
4. the ceramic tile that using method as claimed in claim 3 obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410407753.4A CN104177922B (en) | 2014-08-18 | 2014-08-18 | Ceramic ink with effect of separating glaze, as well as preparation and using methods and ceramic tile of ceramic ink |
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|---|---|---|---|
| CN201410407753.4A CN104177922B (en) | 2014-08-18 | 2014-08-18 | Ceramic ink with effect of separating glaze, as well as preparation and using methods and ceramic tile of ceramic ink |
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| CN104177922A CN104177922A (en) | 2014-12-03 |
| CN104177922B true CN104177922B (en) | 2017-01-11 |
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| CN104830156B (en) * | 2015-05-04 | 2017-08-04 | 蒙娜丽莎集团股份有限公司 | It is a kind of to produce the ink for dialling glaze effect |
| CN104892034B (en) * | 2015-05-04 | 2017-07-25 | 蒙娜丽莎集团股份有限公司 | It is a kind of that there are ceramics of group glaze effect and preparation method thereof |
| CN107235632B (en) * | 2017-07-12 | 2020-05-15 | 广东协进陶瓷有限公司 | Preparation method of ceramic tile with high-simulation 3D digital glaze spraying three-dimensional pattern effect function |
| CN107756607A (en) * | 2017-10-12 | 2018-03-06 | 福建省德化云水窑陶瓷有限公司 | With ceramic of the solid without glaze decorative pattern and preparation technology and stamp |
| CN109663726A (en) * | 2019-01-31 | 2019-04-23 | 佛山希望数码印刷设备有限公司 | A kind of concave-convex hand feeling texture coating method that fidelity is high |
| CN110483103A (en) * | 2019-08-26 | 2019-11-22 | 广东萨米特陶瓷有限公司 | A kind of ceramic board and preparation method thereof of three-dimensional fine braiding grain effect |
| CN113233921B (en) * | 2021-05-18 | 2022-11-29 | 广东宏海陶瓷实业发展有限公司 | Preparation method of mold texture ceramic tile and ceramic tile |
| CN115093251B (en) * | 2022-06-25 | 2023-08-11 | 广东道氏陶瓷材料有限公司 | Glaze slip capable of printing three-dimensional patterns and preparation method of high-three-dimensional ceramic |
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|---|---|---|---|---|
| CN102964920A (en) * | 2012-11-27 | 2013-03-13 | 广东道氏技术股份有限公司 | Ink for ceramic ink-jet printing and method for preparing same |
| CN103224736A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Matte glaze ink for ceramic jet printing and preparation method thereof |
| CN103224726A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Glaze ink with leather pattern effect for ceramic jet printing and preparation method thereof |
| CN103965692A (en) * | 2014-04-24 | 2014-08-06 | 佛山远牧数码科技有限公司 | Ultraviolet light polymerization printing ink for ceramic ink jet and preparation method of printing ink |
-
2014
- 2014-08-18 CN CN201410407753.4A patent/CN104177922B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964920A (en) * | 2012-11-27 | 2013-03-13 | 广东道氏技术股份有限公司 | Ink for ceramic ink-jet printing and method for preparing same |
| CN103224736A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Matte glaze ink for ceramic jet printing and preparation method thereof |
| CN103224726A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Glaze ink with leather pattern effect for ceramic jet printing and preparation method thereof |
| CN103965692A (en) * | 2014-04-24 | 2014-08-06 | 佛山远牧数码科技有限公司 | Ultraviolet light polymerization printing ink for ceramic ink jet and preparation method of printing ink |
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