CN104830156B - It is a kind of to produce the ink for dialling glaze effect - Google Patents
It is a kind of to produce the ink for dialling glaze effect Download PDFInfo
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- CN104830156B CN104830156B CN201510225336.2A CN201510225336A CN104830156B CN 104830156 B CN104830156 B CN 104830156B CN 201510225336 A CN201510225336 A CN 201510225336A CN 104830156 B CN104830156 B CN 104830156B
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- ink
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- hydrophobic compound
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Glass Compositions (AREA)
Abstract
The ink of glaze effect is dialled the present invention relates to a kind of can produce, the ink includes hydrophobic compound, wherein, hydrophobic compound is low molecule organic fluoride, and it is 0.05% 5.0% that hydrophobic compound, which accounts for the mass percent of ink,.Heretofore described ink has hydrophobic effect, thus in the ban on ceramic body after ink described in spray printing, use water sprayed on ink etc. as solvent slurry, these slurries are although uniformly spray in ink layer, but due to the hydrophobicity of ink layer, the slurry at these inks can be caused to peel away, so as to form depression.
Description
Technical field
It is more particularly to a kind of that there is the ink-jet ink for dialling glaze effect and its make the invention belongs to ceramic ink jet technical field
With method, belong to building ceramic decoration field.
Background technology
Ceramic ink jet technology is as a kind of new technique, to present ceramic tile personalized, art up, diversified, fine
Change, the development of low-carbon environment-friendly has important effect；Since introducing First ceramic ink jet machine from China in 2009, through in a few years
Development, the occupation rate of market more and more higher of ceramic ink jet product；The high speed development of ceramic ink jet technology result in major ceramics
The keen competition of enterprise, technique, design are only constantly courageously combined, develop a series of pottery of specific functions with new material
Ceramic ink water, and be combined with traditional handicraft, the ceramic tile with special decorative effect is developed, could be preferably based on market.
The ink that application number 201410163383.4 is prepared using inorganic salts, it is chemical anti-by occurring at high temperature with cover-coat enamel
Z-Correct bump mapping Z-correct should be formed, there is certain requirement to glaze temperature, sagging place is not pure matte effect；And the inorganic matter used contains
Toxicity, is unfavorable for environmental protection.
Use with the ceramic ink for dialling glaze effect, can make the texture for embodying bumps that Ceramic Tiles are finer, soft
The texture of sum, the particularly utilization on imitative stone material, imitative wood grain tile, can play the use for reducing concavo-convex grinding tool, improve simultaneously
The decorative effect of ceramic tile.Thus, turn into one of important directions that those skilled in the art study with the ink for dialling glaze effect.
The content of the invention
It is contemplated that overcoming prior art can not to be sunk and pure matt effect while realizing and obtaining crack in ceramic surface
The technical problem of fruit, the invention provides a kind of ink-jet ink and its application method for having and dialling glaze effect.
The ink of group glaze effect can be produced the invention provides a kind of, the ink includes hydrophobic compound, wherein, dredge
Aqueous compounds can be low molecule organic fluoride, and the mass percent that hydrophobic compound accounts for ink is 0.05%-5.0%,
It is preferred that 0.1%-5.0%.
It is preferred that low molecule organic fluoride includes trifluorotrichloroethane, dichlorodifluoromethane, perfluorotributylamine, difluoro
Ethyl acetate and/or perfluor alkane etc..
It is preferred that the ink is also containing the solvent that mass percent is 94%-99%, wherein, it is molten that solvent includes hydro carbons
Agent and/or esters solvent.
It is preferred that the ink is also containing the organic toner that mass percent is 0.1%-0.5%, the preferred first of organic toner
Base is blue, methyl red.
It is preferred that the contact angle of the ink and water is more than 100 degree.
It is preferred that the mass percent that the hydrophobic compound accounts for ink can be 0.1%~2%.
Also, present invention also offers a kind of ceramics prepared using above-mentioned ink, spray printing successively on the ceramic base substrate
There are the ink, transparent glaze layer.
Heretofore described ink has hydrophobic effect, thus in the ban on ceramic body after ink described in spray printing, in ink
Use water of spray waterborne etc. as solvent slurry, although these slurries are uniformly sprayed in ink layer, due to ink layer
Hydrophobicity, the slurry at these inks can be caused to peel away, so as to form depression.By such ceramic body through burning
Into, polishing etc. processing after, you can obtain surface have depression and recess be matt ceramic product.Ink inside of the present invention
It can be realized by such mode on ceramic body and dial glaze effect.
In addition, present invention also offers above-mentioned ceramic preparation method, the preparation method includes：
1) cover coat slurry, transparent glaze layer slurry, the above-mentioned ink with group glaze effect are prepared；
2) cover coat slurry is sprayed or drenched on ceramic body；
3) ink described in spray printing on the cover-coat enamel of ceramic body, and dry；
4) spray or drench in the ink layer of ceramic body bright glaze layer slurry；
5) above-mentioned steps are prepared into base substrate through burning till, polishing and obtains the ceramics.
It is preferred that the composition of cover coat includes：It is calculated in mass percent, SiO259-62%, Al2O325-27%, Fe2O3
0.1-0.4%, TiO20.1-0.3%, CaO0.2-0.4%, MgO0.1-0.3%, K2O4.0-5.0%, Na2O2.5-3.5%,
P2O50.2-0.5%, ZrO2：5-7%；
The composition of transparent glaze layer includes：It is calculated in mass percent, SiO253-56%, Al2O313.5-15.5%, Fe2O3
Content ＜ 0.3%, TiO2Content ＜ 0.3%, CaO10-13%, MgO2.5-4%, K2O1-2%, Na2O3-6%, IL (represent to burn
Vector, is primarily referred to as organic matter) 6-8%, ZnO2-4%.
It is preferred that solvent can be water in cover coat slurry, the amount ratio of cover coat component and solvent is 1g：0.35~
0.45mL；
Solvent can be water in transparent glaze layer slurry, and the amount ratio of transparent glaze layer component and solvent is 1g：0.35~
0.45mL (water is substantially the maximum generally the least expensive solvent of surface tension)；
The usage amount of the ink is relevant with pattern effect design, different pattern very different.
It is preferred that firing temperature can be 1180~1240 DEG C, soaking time can be 15~30 minutes, and heating rate can
For 10~50 DEG C/min.
Beneficial effects of the present invention：
1st, it is creative：Surface forms more uniform small bumps according to pattern lines, closer to lithotome, it may have three-dimensional
Feel effect；
2nd, good decorating effect：Relatively former imitative stone material Imitation Rock Porcelain Tiles, present level more enriches；
3rd, it is applied widely：The present invention can be widely used in various inner-outer walls and ground decoration not by such environmental effects；
4th, easy cleaning：This imitative stone material Imitation Rock Porcelain Tiles is fully sintered, and water absorption rate is controlled within 0.5%, and polished rear beat surpasses
Clean bright, good antifouling effect, glossiness is high；Easy cleaning；
5th, durable：Inventive can be stablized, smaller by time, environmental impact factor, and abrasion resistance is high, can keep for a long time
Feel as new, service life is long, with wide market economy benefit.
Brief description of the drawings
Fig. 1 shows the contact angle (being more than 100 degree) of the ink prepared in one embodiment of the present invention and water, wherein,
A- waters surface layer, b- hydrophobicity inks, the angle of c- waters surface layer and hydrophobicity ink；
Fig. 2 shows hydrophobicity ink jet and transparent glaze layer combination effect diagram in one embodiment of the present invention,
Wherein, the pattern of 1- hydrophobicitys ink printed, the transparent glaze layers of 2-, 3- cover coats, 4- blank material layers；
Fig. 3 shows ceramic photo in kind prepared by one embodiment of the present invention.
Embodiment
The present invention is further illustrated below in conjunction with accompanying drawing and following embodiments, it should be appreciated that accompanying drawing and following embodiments
The present invention is merely to illustrate, is not intended to limit the present invention.
The sagging place in similar stone material crack prepared by prior art can not realize pure matt effect, and the present invention provides a kind of
With ceramic ink for dialling glaze effect and preparation method thereof and application method, it is intended to overcome this defect.
The purpose of the present invention can be realized by following technical elements：
By adding a certain proportion of low molecule hydrophobic compound in the ink, its pattern formed has strongly hydrophobic
Performance, special group glaze effect can not be formed, is formed according to change in pattern in its superficial residence by spraying or drench superincumbent glaze
Even Z-Correct bump mapping Z-correct.Burnt till again by high temperature, then polishing forms strong light and dark contrast effect.
The hydrophobicity ink that ink-jet ink is used, main composition is solvent, hydrophobic compound, organic toner, and ratio is
Solvent 94-99%, hydrophobic compound is 0.1-5.0%, organic toner 0.1-0.5%.
The solvent be varsol or esters solvent, such as:Styrene, ethylbenzene, ethyl acetate.
Hydrophobic compound is low molecule fluoride, such as trifluorotrichloroethane, dichlorodifluoromethane etc..
Organic toner methyl blue, methyl red etc..
The hydrophobicity ink requirement and the contact angle of water are more than 100 degree, such as Fig. 1.Thus show, ink inside of the present invention
With good hydrophobicity.
For more specifically, Fig. 2 shows the combination of hydrophobicity ink and transparent glaze layer in one embodiment of the present of invention
Design sketch：Spray printing has cover coat, the pattern using hydrophobicity ink printed and transparent glaze layer successively on blank material layer.In the present invention
Ink can be by means of lyophobic dust therein so that ink shows hydrophobicity.And then, due to the hydrophobicity of ink, make
The ceramic body of the ink must be printed with, when continuing to spray clear frit, even if it is equally distributed during spray, but due to ink shape
Into hydrophobic pattern presence so that these slurries are peeled away, and such ceramic body is by the technique such as burning till, you can obtain
With the ceramics for dialling glaze effect.
The composition of the cover coat can be：
By percentage to the quality, SiO2：59-62%；Al2O3：25-27%；Fe2O3：0.1-0.4%；TiO2：0.1-
0.3%；CaO：0.2-0.4%；MgO：0.1-0.3%；K2O：4.0-5.0%；Na2O：2.5-3.5%；P2O5：0.2-0.5%；
ZrO2：5-7%.
, can be with the transparent glaze layer of spray printing on the pattern of the hydrophobicity ink printed.
The composition of the clear frit can be：
By percentage to the quality, SiO2：53-56%；Al2O3：13.5-15.5%；Fe2O3：＜ 0.3%；TiO2：＜
0.3%；CaO：10-13%；MgO：2.5-4%；K2O：1-2%；Na2O：3-6%；IL：6-8%；ZnO：2-4%.
The present invention can reach following beneficial effect after using above-mentioned technical proposal：
1st, it is creative：Surface forms more uniform small bumps according to pattern lines, closer to lithotome, it may have three-dimensional
Feel effect；
2nd, good decorating effect：Relatively former imitative stone material Imitation Rock Porcelain Tiles, present level more enriches；
3rd, it is applied widely：The present invention can be widely used in various inner-outer walls and ground decoration not by such environmental effects；
4th, easy cleaning：This imitative stone material Imitation Rock Porcelain Tiles is fully sintered, and water absorption rate is controlled within 0.5%, and polished rear beat surpasses
Clean bright, good antifouling effect, glossiness is high；Easy cleaning；
5th, durable：Inventive can be stablized, smaller by time, environmental impact factor, and abrasion resistance is high, can keep for a long time
Feel as new, service life is long, with wide market economy benefit.
Embodiment is enumerated further below to describe the present invention in detail.It will similarly be understood that following examples are served only for this
Invention is further described, it is impossible to be interpreted as limiting the scope of the invention, those skilled in the art is according to this hair
Some nonessential modifications and adaptations that bright the above is made belong to protection scope of the present invention.Following examples are specific
Technological parameter etc. is also only that an example in OK range, i.e. those skilled in the art can be done properly by this paper explanation
In the range of select, and do not really want to be defined in the concrete numerical value of hereafter example.
Embodiment 1
The preparation method of the present invention may comprise steps of：
1st, cover coat slurry, clear frit slurry are prepared by required proportioning, wherein, the consumption of cover coat component and solvent
Than for 1g：Solvent is water in 0.4mL, cover coat slurry, and the composition of cover coat is：By percentage to the quality, SiO2：59.57%；
Al2O3：25.55%；Fe2O3：0.29%；TiO2：0.12%；CaO：0.28%；MgO：0.11%；K2O：4.47%th, Na2O：
2.80%th, P2O5：0.30%th, ZrO26.21%；
The amount ratio of transparent glaze layer component and solvent is 1g：Solvent is water in 0.35~0.45mL, clear frit slurry,
Clear frit is constituted：By percentage to the quality, SiO2：53.87%；Al2O3：14.38%；Fe2O3：0.17%；TiO2：
0.16%；CaO：11.29%；MgO：3.21%；K2O：1.05%；Na2O：5.27%；IL：7.14%；ZnO：2.58%；
2nd, ink-jet ink is made by oneself：Solvent is 98.5%, defoamer 0.3%；Hydrophobic organic compound 1.2%, methyl red
0.2%；After stirring, using inside special passage；
3rd, step 2 is sprayed with the adobe for spraying or having drenched cover-coat enamel) ink for preparing, used ink amount is designed with pattern effect
Close, different pattern very different；
4th, sprayed after ink through the drying of small dry kiln, it is ensured that ink is killed completely；
5th, the clear frit slurry that adobe after drying, spray or pouring have been configured on request；
(firing temperature is 1200 DEG C, and soaking time is 20 minutes, and heating rate is 30 DEG C/min) is burnt till through kiln to throw afterwards
Light, with 1 group of 800 mesh, 1,000 2 groups of mesh, 1,500 4 groups of mesh；1800 3 groups of mesh；Polishing；Require that glossiness can reach 35-40 after polishing
Degree；Beat super clean bright again.
From figure 3, it can be seen that the ceramic surface prepared in the present invention has depression, and show matt effect.
Claims (5)
1. a kind of can produce the ink-jet ink for dialling glaze effect, it is characterised in that by percentage to the quality, the ink-jet ink is included
0.05%-5.0% hydrophobic compounds, 0.1%-0.5% organic toners and 94%-99% solvents, wherein, hydrophobic compound is low point
Sub- organic fluoride, the low molecule organic fluoride is trifluorotrichloroethane, dichlorodifluoromethane, perfluorotributylamine, difluoro
Ethyl acetate and/or perfluor alkane, the solvent include varsol and/or esters solvent.
2. ink according to claim 1, it is characterised in that the mass percent that the hydrophobic compound accounts for ink is
0.1%-5.0%。
3. ink according to claim 1, it is characterised in that the organic toner includes methyl blue, methyl red.
4. according to any described ink in claim 1-3, it is characterised in that the contact angle of the ink and water is more than 100
Degree.
5. ink according to claim 2, it is characterised in that the mass percent that the hydrophobic compound accounts for ink is
0.1%-2%。
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| CN201510225336.2A CN104830156B (en) | 2015-05-04 | 2015-05-04 | It is a kind of to produce the ink for dialling glaze effect |
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| CN201510225336.2A CN104830156B (en) | 2015-05-04 | 2015-05-04 | It is a kind of to produce the ink for dialling glaze effect |
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| CN104830156B true CN104830156B (en) | 2017-08-04 |
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|---|---|---|---|---|
| CN105647287A (en) * | 2016-03-15 | 2016-06-08 | 佛山市迈瑞思科技有限公司 | Ceramic ink with glaze separating function, and preparation method and production method thereof |
| CN105647286A (en) * | 2016-03-15 | 2016-06-08 | 佛山市迈瑞思科技有限公司 | Ceramic ink with glue function and preparation method and production method thereof |
| CN105924233A (en) * | 2016-04-29 | 2016-09-07 | 山东狮子王陶瓷科技有限公司 | Peeling-glaze marble tile and preparation method thereof |
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| CN108002866A (en) * | 2017-12-18 | 2018-05-08 | 黄岳娇 | A kind of manufacture method of the Ceramic Tiles with three-dimensional decorative effect |
| CN108046847A (en) * | 2017-12-18 | 2018-05-18 | 黄岳娇 | A kind of manufacturing method of Ceramic Tiles |
| CN108250839A (en) * | 2017-12-28 | 2018-07-06 | 佛山市道氏科技有限公司 | The preparation method of hydrophobic inorganic powder and ceramic ink jet printing ink |
| CN109795237A (en) * | 2019-01-31 | 2019-05-24 | 佛山希望数码印刷设备有限公司 | A kind of wear-resistant texture coating method with concave-convex hand feeling |
| CN110357432B (en) * | 2019-07-16 | 2022-08-19 | 江西唯美陶瓷有限公司 | Method for manufacturing ceramic thin plate with concave-convex mould effect on plane blank |
| CN110485664B (en) * | 2019-08-06 | 2021-04-13 | 佛山希望数码印刷设备有限公司 | Manufacturing process for concave line and crack effect, decorative plate structure and manufacturing system thereof |
| CN110485663B (en) * | 2019-08-06 | 2021-04-23 | 佛山希望数码印刷设备有限公司 | Manufacturing process of three-dimensional cracks and concave lines, decorative plate structure and manufacturing system of three-dimensional cracks and concave lines |
| CN110483103A (en) * | 2019-08-26 | 2019-11-22 | 广东萨米特陶瓷有限公司 | A kind of ceramic board and preparation method thereof of three-dimensional fine braiding grain effect |
| CN111393906A (en) * | 2020-06-02 | 2020-07-10 | 佛山东华盛昌新材料有限公司 | Super-hydrophobic ceramic ink, preparation method thereof, product using super-hydrophobic ceramic ink and decoration method |
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| CN102786325A (en) * | 2012-08-17 | 2012-11-21 | 广东蒙娜丽莎新型材料集团有限公司 | Concave convex surface ceramic product and preparation method thereof |
| CN104177922A (en) * | 2014-08-18 | 2014-12-03 | 佛山市禾才科技服务有限公司 | Ceramic ink with effect of separating glaze, as well as preparation and using methods and ceramic tile of ceramic ink |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102786325A (en) * | 2012-08-17 | 2012-11-21 | 广东蒙娜丽莎新型材料集团有限公司 | Concave convex surface ceramic product and preparation method thereof |
| CN104177922A (en) * | 2014-08-18 | 2014-12-03 | 佛山市禾才科技服务有限公司 | Ceramic ink with effect of separating glaze, as well as preparation and using methods and ceramic tile of ceramic ink |
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