CN104136515B - 包括碳纳米管的聚合物组合物 - Google Patents

包括碳纳米管的聚合物组合物 Download PDF

Info

Publication number
CN104136515B
CN104136515B CN201380011249.6A CN201380011249A CN104136515B CN 104136515 B CN104136515 B CN 104136515B CN 201380011249 A CN201380011249 A CN 201380011249A CN 104136515 B CN104136515 B CN 104136515B
Authority
CN
China
Prior art keywords
compositions
weight
polystyrene
polyolefin
cnt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201380011249.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN104136515A (zh
Inventor
D.罗西奥克斯
M.杜克
P.罗德菲尔
O.罗斯特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Petrochemicals Research Feluy SA
Original Assignee
Total Petrochemicals Research Feluy SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Petrochemicals Research Feluy SA filed Critical Total Petrochemicals Research Feluy SA
Publication of CN104136515A publication Critical patent/CN104136515A/zh
Application granted granted Critical
Publication of CN104136515B publication Critical patent/CN104136515B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20—Conductive material dispersed in non-conductive organic material
    • H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02—Homopolymers or copolymers of hydrocarbons
    • C08J2425/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/019—Specific properties of additives the composition being defined by the absence of a certain additive

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CN201380011249.6A 2012-01-20 2013-01-18 包括碳纳米管的聚合物组合物 Expired - Fee Related CN104136515B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP12151931.8 2012-01-20
EP12151931 2012-01-20
PCT/EP2012/072471 WO2013107535A1 (en) 2012-01-20 2012-11-13 Polymer composition comprising carbon nanotubes
EPPCT/EP2012/072471 2012-11-13
PCT/EP2013/050963 WO2013107875A1 (en) 2012-01-20 2013-01-18 Polymer composition comprising carbon nanotubes

Publications (2)

Publication Number Publication Date
CN104136515A CN104136515A (zh) 2014-11-05
CN104136515B true CN104136515B (zh) 2016-08-24

Family

ID=47178021

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201380011249.6A Expired - Fee Related CN104136515B (zh) 2012-01-20 2013-01-18 包括碳纳米管的聚合物组合物
CN201380011022.1A Expired - Fee Related CN104136514B (zh) 2012-01-20 2013-01-18 使用母料制备导电组合物的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201380011022.1A Expired - Fee Related CN104136514B (zh) 2012-01-20 2013-01-18 使用母料制备导电组合物的方法

Country Status (9)

Country Link
US (2) US9384871B2 (enExample)
EP (2) EP2804899A1 (enExample)
CN (2) CN104136515B (enExample)
BR (2) BR112014017841A8 (enExample)
DK (1) DK2804898T5 (enExample)
ES (1) ES2628331T3 (enExample)
PL (1) PL2804898T3 (enExample)
SI (1) SI2804898T1 (enExample)
WO (3) WO2013107535A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6012906B2 (ja) * 2013-08-01 2016-10-25 トタル リサーチ アンド テクノロジー フエリユイ 高い伝導特性を有する複合材料を製造するためのマスターバッチと、その製造方法と、得られた複合材料
KR101698911B1 (ko) * 2015-02-25 2017-02-01 금호석유화학 주식회사 전도성 시트 제조용 고분자 복합재 조성물
EP3268415B1 (en) * 2015-03-12 2018-11-07 Total Research & Technology Feluy Process for the preparation of composite articles having enhanced electrical properties
TWI560798B (en) * 2015-06-25 2016-12-01 Gudeng Prec Ind Co Ltd A cycloolefin composition and a cycloolefin semiconductor substrate transport box made of the same
JP6780835B2 (ja) * 2015-09-14 2020-11-04 片野染革株式会社 樹脂組成物、樹脂組成物の製造方法、粉状混合物、レドックスフロー電池用双極板、及び燃料電池用セパレータ
US10549996B2 (en) 2015-12-29 2020-02-04 Georgia Tech Research Corporation Polymer coated multiwall carbon nanotubes
KR102046880B1 (ko) * 2016-04-25 2019-11-20 주식회사 엘지화학 대전방지용 탄소 복합재, 성형품 및 그 제조방법
KR102084641B1 (ko) * 2018-09-07 2020-03-04 금호석유화학 주식회사 전도성 수지 조성물 및 그 제조방법
KR102084640B1 (ko) * 2018-09-07 2020-03-04 금호석유화학 주식회사 전도성 수지 조성물 및 그 제조방법
CN110317426B (zh) * 2019-08-06 2022-03-08 河北沃美诺自动化科技有限公司 一种环保型感应防夹条导电橡胶条的制备方法
US11517859B2 (en) 2020-06-10 2022-12-06 Saudi Arabian Oil Company Composite material for removal of hydrophobic components from fluid mixtures

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040211942A1 (en) * 2003-04-28 2004-10-28 Clark Darren Cameron Electrically conductive compositions and method of manufacture thereof
US20040238793A1 (en) * 2003-05-29 2004-12-02 General Electric Company Method for making a conductive thermoplastic composition
CN101067031A (zh) * 2007-04-20 2007-11-07 广州迈迪瑞新材料科技有限公司 纳米炭黑改性的导电塑料的制备方法
CN101098921A (zh) * 2005-01-05 2008-01-02 阿克马法国公司 碳纳米管在制备导电有机组合物中的用途及这种组合物的应用
US20080160290A1 (en) * 2006-08-30 2008-07-03 Korea Electrotechnology Research Institute Aligned nanoparticle channel and method of fabricating aligned nanoparticle channel by applying shear force to immiscible binary polymer-blended nanoparticle composite
CN101475721A (zh) * 2009-01-13 2009-07-08 浙江三和塑料有限公司 用于smt载带的防静电塑料及其制备方法和应用
EP2151830A1 (de) * 2008-08-08 2010-02-10 pp-mid GmbH Polymerformkörper mit leitfähigen Strukturen auf der Oberfläche, sowie Verfahren zu dessen Herstellung
CN101848959A (zh) * 2007-09-24 2010-09-29 阿克马法国公司 制备复合材料的方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USB632416I5 (enExample) 1956-03-01 1976-03-09
JPS6020405B2 (ja) 1976-04-06 1985-05-22 三井東圧化学株式会社 低密度ポリエチレンの製造方法
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4354009A (en) 1981-07-30 1982-10-12 Union Carbide Corporation Catalyst composition for copolymerizing ethylene
US5844037A (en) * 1996-07-24 1998-12-01 The Dow Chemical Company Thermoplastic polymer compositions with modified electrical conductivity
US6864207B2 (en) 1997-01-28 2005-03-08 Fina Technology, Inc. Ziegler-Natta catalyst for polyolefins
US6930071B2 (en) 1997-01-28 2005-08-16 Fina Technology, Inc. Ziegler-natta catalyst for polyolefins
DE10259498A1 (de) * 2002-12-19 2004-07-01 Bayer Ag Leitfähige Thermoplaste mit Ruß und Kohlenstoff-Nanofibrillen
FR2893947A1 (fr) * 2005-11-30 2007-06-01 Arkema Sa Composition pulverulente de nanotubes de carbone, ses procedes d'obtention et ses utilisations, notamment dans des materiaux polymeres.
EP1947122A1 (en) 2007-01-22 2008-07-23 Total Petrochemicals France Process for preparing high impact monovinylaromatic polymers in the presence of a borane complex
CN101918478B (zh) * 2007-12-26 2012-12-12 电气化学工业株式会社 电子部件包装用片材
JP2012500458A (ja) * 2008-08-20 2012-01-05 バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト カーボンナノチューブを含有し、減少した抵抗を有する複合材料の製造方法
EP2184324A1 (en) * 2008-11-06 2010-05-12 Clariant International Ltd. Compositions comprising propylene-olefin-copolymer waxes and carbon nanotubes
CN101899185A (zh) * 2010-06-21 2010-12-01 中国科学院苏州纳米技术与纳米仿生研究所 一种碳纳米管/聚苯乙烯复合导电材料的制作方法
US8961834B2 (en) * 2011-03-23 2015-02-24 Sabic Global Technologies B.V. Carbon nanotube masterbatch, preparation thereof, and use in forming electrically conductive thermoplastic composition

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040211942A1 (en) * 2003-04-28 2004-10-28 Clark Darren Cameron Electrically conductive compositions and method of manufacture thereof
US20040238793A1 (en) * 2003-05-29 2004-12-02 General Electric Company Method for making a conductive thermoplastic composition
CN101098921A (zh) * 2005-01-05 2008-01-02 阿克马法国公司 碳纳米管在制备导电有机组合物中的用途及这种组合物的应用
US20080160290A1 (en) * 2006-08-30 2008-07-03 Korea Electrotechnology Research Institute Aligned nanoparticle channel and method of fabricating aligned nanoparticle channel by applying shear force to immiscible binary polymer-blended nanoparticle composite
CN101067031A (zh) * 2007-04-20 2007-11-07 广州迈迪瑞新材料科技有限公司 纳米炭黑改性的导电塑料的制备方法
CN101848959A (zh) * 2007-09-24 2010-09-29 阿克马法国公司 制备复合材料的方法
EP2151830A1 (de) * 2008-08-08 2010-02-10 pp-mid GmbH Polymerformkörper mit leitfähigen Strukturen auf der Oberfläche, sowie Verfahren zu dessen Herstellung
CN101475721A (zh) * 2009-01-13 2009-07-08 浙江三和塑料有限公司 用于smt载带的防静电塑料及其制备方法和应用

Also Published As

Publication number Publication date
EP2804898A1 (en) 2014-11-26
CN104136514A (zh) 2014-11-05
US20140378578A1 (en) 2014-12-25
BR112014017841A2 (enExample) 2017-06-20
DK2804898T3 (da) 2017-05-15
PL2804898T3 (pl) 2017-09-29
EP2804898B1 (en) 2017-03-22
SI2804898T1 (sl) 2017-07-31
CN104136515A (zh) 2014-11-05
US20150028267A1 (en) 2015-01-29
WO2013107875A1 (en) 2013-07-25
WO2013107535A1 (en) 2013-07-25
EP2804899A1 (en) 2014-11-26
DK2804898T5 (da) 2017-06-19
US9761350B2 (en) 2017-09-12
BR112014017851A8 (pt) 2017-07-11
BR112014017841A8 (pt) 2017-07-11
ES2628331T3 (es) 2017-08-02
US9384871B2 (en) 2016-07-05
CN104136514B (zh) 2016-08-17
WO2013107876A1 (en) 2013-07-25
BR112014017851A2 (enExample) 2017-06-20

Similar Documents

Publication Publication Date Title
CN104136515B (zh) 包括碳纳米管的聚合物组合物
US9163137B2 (en) Nanocomposite
JP6012906B2 (ja) 高い伝導特性を有する複合材料を製造するためのマスターバッチと、その製造方法と、得られた複合材料
US10550231B2 (en) Masterbatches for preparing a composite material based on semi-crystalline polymer with enhanced conductivity properties, process and composite materials produced therefrom
TR201901296T4 (tr) Geliştirilmiş elektriksel özellikleri olan kompozit ürünlerin hazırlanmasına yönelik işlem.
US9321905B2 (en) Nanocomposite
EP2766416B1 (en) Process for preparing nanocomposite
Gorrasi et al. Carbon nanotube‐filled ethylene/vinylacetate copolymers: from in situ catalyzed polymerization to high‐performance electro‐conductive nanocomposites
JP2008246851A (ja) 導電性ブロー成形品
JP2008246852A (ja) 導電性ブロー成形品

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160824

Termination date: 20210118

CF01 Termination of patent right due to non-payment of annual fee