CN104112651B - A kind of rectifier chip fabrication technique - Google Patents

A kind of rectifier chip fabrication technique Download PDF

Info

Publication number
CN104112651B
CN104112651B CN201410315792.1A CN201410315792A CN104112651B CN 104112651 B CN104112651 B CN 104112651B CN 201410315792 A CN201410315792 A CN 201410315792A CN 104112651 B CN104112651 B CN 104112651B
Authority
CN
China
Prior art keywords
silicon chip
boron
phosphorus
chip
diffusion furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201410315792.1A
Other languages
Chinese (zh)
Other versions
CN104112651A (en
Inventor
王道强
魏庆山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yangzhou Hy Technology Development Co Ltd
Original Assignee
Yangzhou Hy Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yangzhou Hy Technology Development Co Ltd filed Critical Yangzhou Hy Technology Development Co Ltd
Priority to CN201410315792.1A priority Critical patent/CN104112651B/en
Publication of CN104112651A publication Critical patent/CN104112651A/en
Application granted granted Critical
Publication of CN104112651B publication Critical patent/CN104112651B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02041Cleaning
    • H01L21/02096Cleaning only mechanical cleaning
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02041Cleaning
    • H01L21/02043Cleaning before device manufacture, i.e. Begin-Of-Line process
    • H01L21/02052Wet cleaning only
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/22Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
    • H01L21/2225Diffusion sources

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Cleaning Or Drying Semiconductors (AREA)

Abstract

The present invention relates to a kind of rectifier chip fabrication techniques, include the following steps:(1) silicon chip is put into nitration mixture and is thinned;(2) silicon chip in (1) is cleaned successively, attached phosphorus, phosphorus source pre-deposition, phosphorus fragment and sandblasting;(3) silicon chip after sandblasting cleaned successively, apply boron, phosphorus source and promotes again and oxide layer;(4) silicon chip after oxide layer cleaned successively, apply boron, boron diffusion and boron fragment;(5) mode of glassivation is finally combined, by chemical nickel plating, complete chip, and the product stability that the present invention makes is good, and reliability is high.

Description

A kind of rectifier chip fabrication technique
Technical field
The present invention relates to high-power semiconductor rectifying device technical field more particularly to a kind of rectifier chip manufacturing works Skill.
Background technology
From the point of view of the ESD tests of current conventional plain edition bridge rectifier, under normal air pattern, can usually it bear About 2KV is tested, and voltage can be born in order to promote test, through analysis, the predominantly chip of rectifier, using conventional making Mode, performance can not bear higher ESD test voltages, therefore be unable to reach client's test request after assembling.
Invention content
Technical problem to be solved by the invention is to provide a kind of rectifier chip fabrication techniques, solve in the prior art It is insufficient so that product can bear higher test voltage.
The technical solution that the present invention solves above-mentioned technical problem is as follows:
A kind of rectifier chip fabrication technique, includes the following steps:
(1) silicon chip is packed into the gaily decorated basket, is put into nitration mixture and is thinned;The gaily decorated basket is waved in corrosion process, and it is uniform to promote corrosion Property, it is ensured that the consistency of Reducing thickness, etching time 10-15s are quickly put into three-level flowing pure water after corroding and rinse, until Residual acid on silicon chip is rinsed well, and water resistance value is up to 10 Ω cm or more;
(2) silicon chip in (1) is cleaned successively, attached phosphorus, phosphorus source pre-deposition, phosphorus fragment and sandblasting;
When Wafer Cleaning, ultrasonic vibration is carried out using rub liquid and hot pure water of Kazakhstan respectively, liquid proportioning is rubbed to breathe out the powder that rubs in Kazakhstan:H2O =90g:14400ml, Warm degree:80 ± 5 DEG C, time 10-20min, then silicon chip is put into HF solution and impregnates 4-6min, HF is molten Liquid proportioning is HF:H2O:H2O2=2000:10000:200, Warm degree:It 25 ± 10 DEG C, finally washed by water, circulating water concussion, rushed Water, drying, Wafer Cleaning finish;
The attached phosphorus of silicon chip chooses the paper-like phosphorus source not less than 70% concentration, is clipped among 2 silicon chips, comes quartz boat successively On, enter diffusion furnace after drained and carries out phosphorus source pre-deposition;
Phosphorus fragment two-by-two relatively, is not easy to separate, need to put it into not less than 15 DEG C because of the complete silicon chip of phosphorus source pre-deposition Impregnated in HF, time 16-24H, after silicon chip naturally separate after, washed by water, ultrasonic vibration, bath, it is ensured that silicon chip surface is without residual Acid;
Sandblasting, the one side for not carrying out phosphorus source pre-deposition to silicon chip carry out sandblasting, select the white fused alumina sand of model W40, make Silicon chip is ground with sand-blasting machine, removal amount is in 15-25um.
(3) silicon chip after sandblasting is cleaned successively, phosphorus source promotes again and oxide layer;
Cleaning in same step (2) is cleaned, the silicon chip after cleaning is opposite two-by-two by the one side for having carried out phosphorus source pre-deposition, Neat is put into quartz boat, carries out phosphorus source and promotes again;
Oxide layer carries out sandblasting to silicon chip another side, removes surface oxide layer, removal amount 2-5um.
(4) silicon chip after oxide layer cleaned successively, apply boron, boron diffusion, boron fragment and sandblasting;
It cleans cleaning, the silicon chip after cleaning in same step (2) and painting boron is carried out to not attached phosphorus face, first carry out matching liquid:Boron water Prepare boron oxide:Ethylene glycol monomethyl ether=100g:400ml stirs 6 ± 2h, filters solution with filter paper after precipitating 6 ± 2h, applies boron The preparation boron water of liquid:Aluminum nitrate solution:Alumina powder=50ml:6ml:0.5g stirs 10min or more,
The not attached phosphorus one side of silicon chip is lain in upward and is applied on boron sol evenning machine turntable, suction piece key is first pressed and silicon chip is adsorbed on rotation On turntable, then make silicon chip start to rotate by start key, is dipped using writing brush and apply boron liquid (nib 4/5 need to immerse painting boron with upper volume In liquid) painting boron is carried out to silicon chip;Writing brush applies boron to edge, pen is lifted after filling silicon chip, machine can be automatically stopped from silicon chip, center Rotation is removed silicon chip and is placed on the filter paper of heating plate and dries 9 ± 1min, by sequencing when putting remove silicon chip be placed in it is stainless On the filter paper of steel disk, silicon chip is applied into boron face and is stacked relatively two-by-two with painting boron face, and a little aluminium powder is gently spread in attached phosphorus face, it is last neat Be put on quartz boat be ready for boron diffusion;
Boron fragment, the silicon chip after boron is spread, which is put into the HF not less than 15 DEG C, to be impregnated, time 10-18H, waits for silicon chip nature Separate after, washed by water, ultrasonic vibration, bath, it is ensured that silicon chip surface is without residual acid;
Sandblasting carries out sandblasting to silicon chip two sides, selects the white fused alumina sand of model W40, is carried out to silicon chip using sand-blasting machine Grinding, attached phosphorus face 1-3um apply boron face 5-6um.
Based on the above technical solution, the present invention can also be improved as follows:
Further, the nitration mixture in the step (1) is HF:HNO3:C2H4O2:H2SO4=9:9:12:4 mixed solution;
Further, the phosphorus source pre-deposition in the step (2) is that a concentration of 70% phosphorus source concentration of being not less than is attached to silicon chip After upper, phosphorus source decomposition is first carried out in the diffusion furnace for being 550 DEG C into temperature, time 1-2h, it is 1200 DEG C then to enter back into temperature Diffusion furnace in carry out pre-deposition, time 2-4h, it is nitrogen 92.3%- to be passed through the ratio of gas in the diffusion furnace 83.3%, oxygen 7.7%-16.7%;
Further, the phosphorus source of the step (3) promotes again spreads for silicon chip to be put into the diffusion furnace that temperature is 1250 DEG C, Time is 10-15h, and the ratio that gas is passed through in the diffusion furnace is nitrogen 90.9%-80%, oxygen 9.1%-20%;
Further, the boron is diffused as the silicon chip after painting boron being put into the diffusion furnace that temperature is 1250 DEG C and spread, the time For 15-20h, the ratio for being passed through gas is nitrogen 90.9%-80%, oxygen 9.1%-20%.
The made chip out of this art inventions, after being assembled into bridge rectifier, in terms of ESD electrostatic tests, more often Rule chip can bear higher voltage, and stability is also preferable, also higher in client use reliability.
The beneficial effects of the invention are as follows:
1. by the technology mode of triple diffusion, deepens silicon chip doping concentration, promote its functional characteristic;
2. having the higher resistance to survey of ESD electrostatic, reliability is higher;
3. also more conventional product wants low to finished product its power consumption after assembling.
Specific implementation mode
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
Embodiment 1:
A kind of rectifier chip fabrication technique, includes the following steps:
(1) silicon chip is put into nitration mixture and is thinned, etching time 10s is quickly put into three-level flowing pure water after corroding Middle flushing, until the residual acid on silicon chip is rinsed well, water resistance value is up to 10 Ω cm or more;
(2) silicon chip is carried out ultrasonic vibration and is cleaned using rub liquid and hot pure water of Kazakhstan respectively, after cleaning, chosen The paper-like phosphorus source of 70% concentration, is clipped among two panels silicon chip, comes on quartz boat successively, and entering diffusion furnace after drained carries out phosphorus Then source pre-deposition carries out phosphorus fragment and sandblasting;
(3) silicon chip is cleaned according to cleaning way in step (2), for the silicon chip after cleaning, by having carried out, phosphorus source is pre- The one side of deposition is opposite two-by-two, and neat is put into quartz boat, carries out phosphorus source and promotes again, is then sprayed to silicon chip another side Sand removes surface oxide layer, removal amount 5um;
(4) first silicon chip is cleaned according to the cleaning way in step (2), configuration applies boron liquid, by applying boron sol evenning machine to silicon Piece carries out painting boron, then carries out boron diffusion and boron fragment;
(5) mode of glassivation is finally combined, by chemical nickel plating, complete chip.
Wherein the nitration mixture is HF:HNO3:C2H4O2:H2SO4=9:9:12:4 mixed solution;
Phosphorus source pre-deposition in the step (2) be by silicon chip after attached phosphorus be put into temperature be in 550 DEG C of diffusion furnace it is advanced Row phosphorus source is decomposed, time 1h, is then entered back into the diffusion furnace that temperature is 1200 DEG C and is carried out pre-deposition, time 2h, the expansion The ratio that gas is passed through in scattered stove is 92.3%, oxygen 7.7%;
The phosphorus source of the step (3) promotes again to spread for silicon chip to be put into the diffusion furnace that temperature is 1250 DEG C, and the time is 15h, the ratio that gas is passed through in the diffusion furnace are nitrogen 90.9%, oxygen 9.1%;
The boron, which is diffused as the silicon chip after painting boron being put into the diffusion furnace that temperature is 1250 DEG C, to spread, and time 15h leads to The ratio for entering gas is nitrogen 90.9%, oxygen 9.1%;
The made chip out of this art inventions, after being assembled into bridge rectifier, in terms of ESD electrostatic tests, more often Rule chip can bear higher voltage, and stability is also preferable, also higher in client use reliability.
Embodiment 2:
A kind of rectifier chip fabrication technique, includes the following steps:
(1) silicon chip is put into nitration mixture and is thinned, etching time 15s is quickly put into three-level flowing pure water after corroding Middle flushing, until the residual acid on silicon chip is rinsed well, water resistance value is up to 10 Ω cm or more;
(2) silicon chip is carried out ultrasonic vibration and is cleaned using rub liquid and hot pure water of Kazakhstan respectively, after cleaning, chosen The paper-like phosphorus source of 80% concentration, is clipped among two panels silicon chip, comes on quartz boat successively, and entering diffusion furnace after drained carries out phosphorus Then source pre-deposition carries out phosphorus fragment and sandblasting;
(3) silicon chip is cleaned according to cleaning way in step (2), for the silicon chip after cleaning, by having carried out, phosphorus source is pre- The one side of deposition is opposite two-by-two, and neat is put into quartz boat, carries out phosphorus source and promotes again, is then sprayed to silicon chip another side Sand removes surface oxide layer, removal amount 5um;
(4) first silicon chip is cleaned according to the cleaning way in step (2), configuration applies boron liquid, by applying boron sol evenning machine to silicon Piece carries out painting boron, then carries out boron diffusion and boron fragment;
(5) mode of glassivation is finally combined, by chemical nickel plating, complete chip.
Wherein the nitration mixture is HF:HNO3:C2H4O2:H2SO4=9:9:12:4 mixed solution;
Phosphorus source pre-deposition in the step (2) be by silicon chip after attached phosphorus be put into temperature be in 550 DEG C of diffusion furnace it is advanced Row phosphorus source is decomposed, time 2h, is then entered back into the diffusion furnace that temperature is 1200 DEG C and is carried out pre-deposition, time 4h, the expansion The ratio that gas is passed through in scattered stove is nitrogen 83.3%, oxygen 16.7%;
The phosphorus source of the step (3) promotes again to spread for silicon chip to be put into the diffusion furnace that temperature is 1250 DEG C, and the time is 15h, the ratio that gas is passed through in the diffusion furnace are nitrogen 80%, oxygen 20%;
The boron, which is diffused as the silicon chip after painting boron being put into the diffusion furnace that temperature is 1250 DEG C, to spread, and time 20h leads to The ratio for entering gas is nitrogen 80%, oxygen 20%;
The made chip out of this art inventions, after being assembled into bridge rectifier, in terms of ESD electrostatic tests, more often Rule chip can bear higher voltage, and stability is also preferable, also higher in client use reliability.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.

Claims (3)

1. a kind of rectifier chip fabrication technique, which is characterized in that include the following steps:
(1) silicon chip is put into nitration mixture and is thinned, remove damaging layer;
(2) silicon chip is cleaned successively, attached phosphorus, phosphorus source pre-deposition, phosphorus fragment and sandblasting;
(3) silicon chip after sandblasting is cleaned successively, phosphorus source promotes again and oxide layer;
(4) silicon chip after oxide layer cleaned successively, apply boron, boron is spread and boron fragment, the boron are diffused as that boron will be applied Silicon chip afterwards, which is put into the diffusion furnace that temperature is 1250 DEG C, to spread, time 15-20h, and gas is passed through in proportion in the diffusion furnace Body:Nitrogen 90.9%-80%, oxygen 9.1%-20%;
(5) mode of glassivation is finally combined, by chemical nickel plating, complete chip.
2. a kind of rectifier chip fabrication technique according to claim 1, which is characterized in that the phosphorus in the step (2) Source pre-deposition is that phosphorus source decomposition is first carried out in the diffusion furnace for being 550 DEG C into temperature after phosphorus source is attached on silicon chip, time 1-2h, Then it is that pre-deposition is carried out in 1200 DEG C of diffusion furnace to enter back into temperature, time 2-4h, is passed through in proportion in the diffusion furnace Gas:Nitrogen 92.3%-83.3%, oxygen 7.7%-16.7%.
3. a kind of rectifier chip fabrication technique according to claim 1, which is characterized in that the phosphorus source of the step (3) It promotes and is spread for silicon chip to be put into the diffusion furnace that temperature is 1250 DEG C again, time 10-15h, in the diffusion furnace in proportion It is passed through gas:Nitrogen 90.9%-80%, oxygen 9.1%-20%.
CN201410315792.1A 2014-07-03 2014-07-03 A kind of rectifier chip fabrication technique Active CN104112651B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410315792.1A CN104112651B (en) 2014-07-03 2014-07-03 A kind of rectifier chip fabrication technique

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410315792.1A CN104112651B (en) 2014-07-03 2014-07-03 A kind of rectifier chip fabrication technique

Publications (2)

Publication Number Publication Date
CN104112651A CN104112651A (en) 2014-10-22
CN104112651B true CN104112651B (en) 2018-08-14

Family

ID=51709395

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410315792.1A Active CN104112651B (en) 2014-07-03 2014-07-03 A kind of rectifier chip fabrication technique

Country Status (1)

Country Link
CN (1) CN104112651B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105977155B (en) * 2016-07-01 2020-03-20 扬州虹扬科技发展有限公司 Manufacturing process of fast recovery chip
CN107068561B (en) * 2017-03-27 2019-08-06 扬州虹扬科技发展有限公司 A kind of preparation method of ultralow forward voltage rectifier chip
CN109712876A (en) * 2018-12-30 2019-05-03 重庆市妙格半导体研究院有限公司 A kind of PN junction method of diffusion

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102386092A (en) * 2010-09-02 2012-03-21 南通康比电子有限公司 Manufacturing method of low-leakage diode chip
CN102496619A (en) * 2011-12-26 2012-06-13 天津环联电子科技有限公司 Protector chip of light emitting diode and production technology thereof
CN102983072A (en) * 2012-10-25 2013-03-20 南通康比电子有限公司 Diffusion method for low fragment rate diode
CN103000500A (en) * 2012-10-25 2013-03-27 南通康比电子有限公司 Deep diffusion process for manufacturing diodes
CN103606522A (en) * 2013-10-23 2014-02-26 蚌埠天宇机械工具有限公司 GPP diode chip production process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102386092A (en) * 2010-09-02 2012-03-21 南通康比电子有限公司 Manufacturing method of low-leakage diode chip
CN102496619A (en) * 2011-12-26 2012-06-13 天津环联电子科技有限公司 Protector chip of light emitting diode and production technology thereof
CN102983072A (en) * 2012-10-25 2013-03-20 南通康比电子有限公司 Diffusion method for low fragment rate diode
CN103000500A (en) * 2012-10-25 2013-03-27 南通康比电子有限公司 Deep diffusion process for manufacturing diodes
CN103606522A (en) * 2013-10-23 2014-02-26 蚌埠天宇机械工具有限公司 GPP diode chip production process

Also Published As

Publication number Publication date
CN104112651A (en) 2014-10-22

Similar Documents

Publication Publication Date Title
CN104112651B (en) A kind of rectifier chip fabrication technique
CN104766790B (en) A kind of phosphorus, boron liquid source perfect diffusion technique
CN105576080B (en) The Buddha's warrior attendant wire cutting polysilicon chip and its etching method of a kind of one texture-etching side
WO2020006795A1 (en) Method and device for realizing etching and polishing of silicon wafer with alkaline system by using ozone
CN105977155B (en) Manufacturing process of fast recovery chip
CN103700733B (en) The clean method of the N-type crystalline silicon substrate of solar cell
CN101224458A (en) Method for cleaning ceramic parts surface in polysilicon etching cavity
TW201200483A (en) Method for treating inside surface of glass container, and glass container
CN103441187A (en) Method for cleaning solar cell silicon wafer after polishing
CN105529381B (en) A kind of preparation method of efficient solar battery
CN104505438A (en) Solar battery cell preparation system
WO2016203586A1 (en) Polishing agent, storage solution for polishing agent and polishing method
CN109119338A (en) A kind of highback polishing and efficient single crystal process
CN107068561B (en) A kind of preparation method of ultralow forward voltage rectifier chip
CN109713086A (en) A kind of nonmetallic black silicon Woolen-making liquid and the method using Woolen-making liquid progress making herbs into wool
CN106653600A (en) GPP chip electrophoresis fabrication process
CN109309142A (en) A kind of blunt preceding liquid source diffusion technique of silicon wafer glass
CN204315618U (en) A kind of solar battery sheet preparation system
JP2015189784A (en) Abrasive, storage liquid for abrasive and polishing method
CN109308996A (en) A kind of negative pressure diffusion technique of silicon wafer
CN111109674A (en) Low-surface-energy titanium heating wire, and preparation method and application thereof
CN106972078A (en) A kind of preparation method of high efficiency crystalline silicon solar cell
CN114005733B (en) Method for manufacturing vehicle-gauge-level rectification chip
US20020162572A1 (en) Method for removing residual particles from a polished surface
CN109370440A (en) A kind of solar battery back throwing monocrystalline silicon piece polishing fluid

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant