CN104068071A - Insecticidal composition containing tetra-chlorantraniliprole - Google Patents
Insecticidal composition containing tetra-chlorantraniliprole Download PDFInfo
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- CN104068071A CN104068071A CN201410320045.7A CN201410320045A CN104068071A CN 104068071 A CN104068071 A CN 104068071A CN 201410320045 A CN201410320045 A CN 201410320045A CN 104068071 A CN104068071 A CN 104068071A
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- insect amide
- tetrachloro insect
- pesticidal combination
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- biphenthrin
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention discloses an insecticidal composition containing tetra-chlorantraniliprole. The insecticidal composition consists of an effective component, an auxiliary, an adhesive and a filler, wherein granules consists of the following components in percentage by weight: 0.01-10 percent of tetra-chlorantraniliprole, 0.01-15 percent of bifenthrin, 0.1-20 percent of smoke slag, 1-15 percent of auxiliary, 1-10 percent of adhesive and the balance of filler. The insecticidal composition can effectively prevent and control insect pests and also promote development of crop roots and growth of plants, so that the yield and the quality of the crops are improved.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of Pesticidal combination containing tetrachloro insect amide
Background technology
At present, domestic cultural control soil insect generally adopts granule, due to the forbidding of the active component with carbofuran, terbufos, thimet, Isofenphos methyl, the contour poison of phonamiphos.In recent years, take middle low toxicity active composition as Avermectin, poison board, diazinon, clothianidin etc. with poison and be that main granule is also applied in agricultural gradually, although solved high, the residual problem such as exceed standard of toxicity, but the action spectrum of these active components is narrower, dosage is large, easily develop immunity to drugs, control efficiency is not ideal, can not meet the demand of peasant household.And granular insecticide effect is at present comparatively single.
Scarp, is the tobacco waste residue that tobacco company in all parts of the country leaves over, and measures many and cannot process in time, processes and has high in cost of production problems.
Tetrachloro insect amide, it is the noval chemical compound that Zhong Huanonghua Co., Ltd and Shenyang Chemical Engineering Inst develop jointly, the bromo-N-(2 of chemical name: 3-, the chloro-6-of 4-bis-(methylformamide) base)-1-(3,5-dichloro-2-pyridyl base)-1H-pyrazoles-5-formamide, it belongs to ryanodine receptor activator insecticides, it is combined by ryanodine receptor in pest body, open calcium channel, make to be stored in intracellular calcium ion sustained release in sarcoplasm, calcium ion and sarcoplasm mesostroma protein combination, cause that muscle continues to shrink.Insect bodies Symptoms is tic, food refusal, finally dead.Tetrachloro insect amide is low toxicity, broad spectrum pesticide, and lepidoptera pest is all had to good activity.
Biphenthrin (bifenthrin) chemical name: 2-methyl biphenyl-3-ylmethyl-(2-chloro-3 for (Z)-(1RS)-cis-3-, 3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, the speed of knocking down is fast, the longevity of residure is long, and insecticidal spectrum is wide, and mite is also had to favorable effect.Be mainly used in preventing and treating each Species of Lepidopterous Larvae, aleyrodid, aphid, phytophagy tetranychid.
Tetrachloro insect amide and Biphenthrin are used separately, control efficiency to insect in its control spectrum is fine, but there is certain limit, control spectrum is narrow, and along with the whole nation a large amount of use on a large scale, various insects increase the pesticide resistance to these two kinds of medicament single doses, and consumption medicine is also along with increase, but insecticidal activity reduces greatly.As a large amount of uses due to Imidacloprid, rice fulgorid reaches 250～400 times to the pesticide resistance multiple of Imidacloprid, and the plant protection unit in part paddy rice region has been issued the notice of the inactive Imidacloprid of control rice fulgorid.
Applicant finds, at present less to the composition research of tetrachloro insect amide, patent only has the combination research about Avermectin and tetrachloro insect amide, metaflumizone and tetrachloro insect amide, tetrachloro insect amide and emamectin-benzoate, multiple killing teichomycin and tetrachloro insect amide, tetrachloro insect amide and chlorfenapyr, tetrachloro insect amide and indoxacarb, tetrachloro insect amide and butene-fipronil, tetrachloro insect amide and methoxyfenozide of the eternally happy biotech inc of swallowization, 8 pieces of Beijing.
So far now, applicant not yet finds and in any patent and periodical, openly reports tetrachloro insect amide, Biphenthrin and scarp ternary built composition pesticide.
Summary of the invention
Object of the present invention solves the problems of the technologies described above, and a kind of Pesticidal combination containing tetrachloro insect amide is provided, and the present invention not only can realize the generation of prevention and control insect pest effectively, can also promote crop tuber to grow and plant strain growth, improves the yield and quality of crop.
For realizing above-mentioned object, technical scheme of the present invention is:
A Pesticidal combination containing tetrachloro insect amide, comprises active ingredient, and described active ingredient is comprised of the component of following weight portion: tetrachloro insect amide 0.01-10 part, Biphenthrin 0.01-15 part, scarp 0.1-20 part.
The above active ingredient is comprised of the component of following weight portion: tetrachloro insect amide 0.01-5 part, Biphenthrin 0.01-10 part, scarp 0.1-10 part.
The above-mentioned Pesticidal combination containing tetrachloro insect amide also comprises the component of following weight portion: 1-15 part auxiliary agent, 0-10 part binding agent and 30-97.88 part filler.
The formulation of the above-mentioned Pesticidal combination containing tetrachloro insect amide is granule.
The above auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, fatty alcohol-polyoxyethylene ether, dioctyl sodium sulfosuccinate and Morwet D-425 naphthalene sulfonate condensation polymer.
The above binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol and carboxymethyl cellulose.
The above filler is one or more combinations in white carbon, diatomite, composite fertilizer, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, phosphide potassium dihydrogen, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate and talcum powder.
Scarp claims again cigarette foam to have certain regulating action to crop growing state, it contains the elements such as abundant organic matter, amino acid, biological potassium, be the nuisanceless ecological organic fertilizer of a kind of fully natural green, insect had to certain killing action simultaneously, it is extremely low that applicant tests rear discovery scarp single dose preventive effect.
Former medicine used in the present invention, auxiliary agent, binding agent and filler are all bought from other producers.
Compared with prior art, the beneficial effect that the present invention has is:
1. Synergistic.The present invention is through experimental studies have found that, take tetrachloro insect amide, Biphenthrin and scarp any two kinds as active ingredient composite, control to grub, root-knot nematode, thrips, aphid, snout moth's larva does not have synergistic effect, and the in the situation that of weight ratio 0.01-10:0.01-15:0.1-20 ternary built, control to grub, root-knot nematode, thrips, aphid, snout moth's larva possesses synergistic function, under 0.01-5:0.01-10:0.1-10 part weight ratio, synergistic function is particularly evident.
2. consumption is few, the lasting period is long and cost is low.After tetrachloro insect amide Biphenthrin scarp of the present invention is composite, using under identical effective dose even still less, the preventive effect of preparation surpasses 85%, and higher than three kinds of single dose preventive effect 4-50%, visible three kinds of compositions are composite good synergistic effect.Meanwhile, complex preparation desinsection preventive effect of 15d after medicine is greater than 7d after medicine, compares with single dose, and the lasting period is longer.
3. wide spectrum.Granule of the present invention, can be used for preventing and treating the soil insect, nematode of the crop of sugarcane, peanut, corn, banana and insect on the ground, comprises grub, root-knot nematode, thrips, aphid, snout moth's larva etc.
4. can improve crop yield.The present invention is usingd calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate during as filler, can supply the nutrient components such as the required N of crop, P, K, S, Ca, further improve crop yield.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to the scope that embodiment represents.
Embodiment 1
0.12% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 0.01kg, Biphenthrin 0.01kg, scarp 0.1kg, calcium lignosulfonate 0.4kg, lauryl sodium sulfate 0.6kg, polyvinyl alcohol 0.1kg, composite fertilizer 10kg, ammonium dihydrogen phosphate (ADP) 25kg, kaolin 20kg, sodium sulphate complements to 100kg.
Above-mentioned raw materials component is mixed, pulverize, stir after adding water-wet, then use granulator granulation, sieve after dry and obtain 0.12% tetrachloro insect amide Biphenthrin scarp granule.
The processing technology of following examples 2～embodiment 13 is with embodiment 1.
Embodiment 2
2% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 0.3kg, Biphenthrin 0.2kg, scarp 1.5kg, fatty alcohol-polyoxyethylene ether 1kg, lauryl sodium sulfate 0.5kg, starch 1kg, potassium sulfate 25kg, ammonium chloride 20kg, kaolin 15kg, diatomite is supplied 100kg.
Embodiment 3
7% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 5kg, Biphenthrin 1kg, scarp 1kg, dioctyl sodium sulfosuccinate 1kg, naphthalenesulfonate formaldehyde condensation compound 3kg, sucrose 2kg, carboxymethyl cellulose 3kg, sulfuric acid amine 15kg, calcium carbonate 20kg, kaolin is supplied 100kg.
Embodiment 4
10% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 1kg, Biphenthrin 8kg, scarp 1kg, sodium butylnaphthalenesulfonate 4kg, fatty alcohol-polyoxyethylene ether 2kg, carboxymethyl cellulose 3kg, potassium dihydrogen phosphate 18kg, urea 5kg, bentonite is supplied 100kg.
Embodiment 5
14% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 2kg, Biphenthrin 4kg, scarp 8kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Embodiment 6
10.11% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 10kg, Biphenthrin 0.01kg, scarp 0.1kg, lauryl sodium sulfate 3kg, fatty alcohol-polyoxyethylene ether 3.5kg, carboxymethyl cellulose 2kg, starch 2kg, potassium sulfate 5kg, urea 10kg, calcium carbonate complement to 100kg.
Embodiment 7
6.11% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 0.01kg, Biphenthrin 6kg, scarp 0.1kg, sodium lignin sulfonate 3kg, fatty alcohol-polyoxyethylene ether 2kg, polyvinyl alcohol 3kg, ammonium dihydrogen phosphate (ADP) 3kg, calcium dihydrogen phosphate 5kg, urea is supplied 100kg.
Embodiment 8
25.1% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 10kg, Biphenthrin 15kg, scarp 0.1kg, calcium lignosulfonate 5kg, fatty alcohol-polyoxyethylene ether 2kg, carboxymethyl cellulose 3kg, composite fertilizer 15kg, potassium sulfate 1kg, kaolin is supplied 100kg.
Embodiment 9
30.01% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 10kg, Biphenthrin 0.01kg, scarp 20kg, Morwet D-425 naphthalene sulfonate condensation polymer 4kg, lauryl sodium sulfate 2kg, sodium sulphate 5kg, polyvinyl alcohol 0.5kg, white carbon 10kg, 100kg supplies in composite fertilizer.
Embodiment 10
0.3% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 0.1kg, Biphenthrin 0.1kg, scarp 0.1kg, Morwet D-425 naphthalene sulfonate condensation polymer 4kg, calcium lignosulfonate 1kg, fatty alcohol-polyoxyethylene ether 1.5kg, calcium dihydrogen phosphate 10kg, urea is mended 100kg.
Embodiment 11
11% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 0.5kg, Biphenthrin 0.5kg, scarp 10kg, sodium lignin sulfonate 3.4kg, fatty alcohol-polyoxyethylene ether 3.5kg, polyvinyl alcohol 4kg, ammonium sulfate 6kg, urea is supplied 100kg.
Embodiment 12
45% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 10kg, Biphenthrin 15kg, scarp 20kg, sodium butylnaphthalenesulfonate 8kg, lauryl sodium sulfate 7kg, carboxymethyl cellulose 10kg, urea 10kg, ammonium dihydrogen phosphate (ADP) 3kg, diatomite is supplied 100kg.
Embodiment 13
0.7% tetrachloro insect amide Biphenthrin scarp granule
Tetrachloro insect amide 0.3kg, Biphenthrin 0.3kg, scarp 0.1kg, Morwet D-425 naphthalene sulfonate condensation polymer 4kg, lauryl sodium sulfate 1kg, carboxymethyl cellulose 3kg, composite fertilizer 5kg, ammonium dihydrogen phosphate (ADP) 6kg, urea is supplied 100kg.
Embodiment 14
10% tetrachloro insect amide granule
Tetrachloro insect amide 10kg, sodium butylnaphthalenesulfonate 4kg, carboxymethyl cellulose 3kg, urea 10kg, ammonium dihydrogen phosphate (ADP) 3kg, diatomite is supplied 100kg.
Embodiment 15
40% scarp granule
Scarp 40kg, sodium butylnaphthalenesulfonate 4kg, carboxymethyl cellulose 3kg, urea 10kg, ammonium dihydrogen phosphate (ADP) 3kg, diatomite is supplied 100kg.
Embodiment 16
6% tetrachloro insect amide Biphenthrin granule
Tetrachloro insect amide 2kg, Biphenthrin 4kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Embodiment 17
10% tetrachloro insect amide scarp granule
Tetrachloro insect amide 2kg, scarp 8kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Embodiment 18
12% Biphenthrin scarp granule
Biphenthrin 4kg, scarp 8kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Application Example 1
The indoor joint toxicity measuring test of tetrachloro insect amide Biphenthrin scarp
Tetrachloro insect amide, Biphenthrin and scarp are mixed and are made into ternary built agent by the active ingredient part by weight of embodiment 1～embodiment 13 respectively, test method is with reference to NY/T1154.7-2006, NY/T1154.6-2006, adopt dip method, take sugarcane moth borer 3 instar larvaes as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC50 of each medicament, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
Actual measurement toxicity index=standard medicament LC50/ reagent agent LC50 * 100
The content of single dose theoretical toxicity index=single dose actual measurement toxicity index * single dose in mixture
The theoretical toxicity index sum of mixture theoretical toxicity index=each single dose
Theoretical toxicity index * 100 of toxicity index/mixture of co-toxicity coefficient=mixture actual measurement
Evaluation criterion: CTC≤80 are antagonism, 80 < CTC < 120 are summation action, and CTC >=120 are synergistic effect, and experimental result please refer to table 1;
Table 1 tetrachloro insect amide Biphenthrin scarp ternary built is to the indoor joint toxicity measuring result of sugarcane moth borer
Measurement result is in Table 1, measurement result shows: tetrachloro insect amide Biphenthrin scarp is hybridly prepared into ternary built agent by above-mentioned weight ratio, co-toxicity coefficient to sugarcane moth borer 3 instar larvaes is respectively 178.9,170.7,159.1,172.4,152.7,174.9,160.0,164.9,162.6,179.8,173.3,226.1,180.6, and showing compositely in content range that tetrachloro insect amide Biphenthrin scarp limits by claim 1 all has notable synergistic effect to sugarcane moth borer afterwards.
Application Example 2
The indoor joint toxicity measuring test of tetrachloro insect amide Biphenthrin scarp
Tetrachloro insect amide, Biphenthrin and scarp are mixed and are made into ternary built agent by the active ingredient part by weight of embodiment 1～embodiment 13 respectively, test method is with reference to NY/T1154.7-2006, NY/T1154.15-2009, adopt dip method, take peanut grub Initial instar larvae in 2 age as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC50 of each medicament, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
Actual measurement toxicity index=standard medicament LC50/ reagent agent LC50 * 100
The content of single dose theoretical toxicity index=single dose actual measurement toxicity index * single dose in mixture
The theoretical toxicity index sum of mixture theoretical toxicity index=each single dose
Theoretical toxicity index * 100 of toxicity index/mixture of co-toxicity coefficient=mixture actual measurement
Evaluation criterion: CTC≤80 are antagonism, 80 < CTC < 120 are summation action, and CTC >=120 are synergistic effect, and experimental result please refer to table 2;
Table 2 tetrachloro insect amide Biphenthrin scarp ternary built is to the indoor joint toxicity measuring result of peanut grub
Measurement result is in Table 2, measurement result shows: tetrachloro insect amide Biphenthrin scarp is hybridly prepared into ternary built agent by above-mentioned weight ratio, co-toxicity coefficient to peanut grub Initial instar larvae in 2 age is respectively 111.3,98.7,91.4,158.6,170.2,165.6,172.8,165.3,174.6,219.5,159.9,178.2,199.8,183.4,195.6,212.2, and showing compositely in content range that tetrachloro insect amide Biphenthrin scarp limits by claim 1 all has notable synergistic effect to peanut grub afterwards.
Application Example 3
On the basis of Toxicity Determination, with each embodiment sample, peanut grub is carried out to field medicine effect test checking, verify its synergistic effect to other insects except sugarcane moth borer.Test method and drug effect computational methods: with reference to < < pesticide field efficacy medicine test criterion (two) the 72nd part: insecticide control nonirrigated farmland soil insect > >.Controlling object: peanut grub; Test site: Fusui County, Chongzuo City, Guangxi peanut ground; Application method: spread fertilizer over the fields;
Contrast medicament: 0.2% Biphenthrin granule (Xinhui District, Jiangmen City of Guangdong Province Nong get Feng Co., Ltd, commercial dosage 90-150 gram/ha), 10% tetrachloro insect amide granule (embodiment 14), 40% scarp granule (embodiment 15), 6% tetrachloro insect amide Biphenthrin granule (embodiment 16), 10% tetrachloro insect amide scarp granule (embodiment 17), 12% Biphenthrin scarp granule (embodiment 18).
Each embodiment of table 3 is to the control efficiency of peanut grub and increase of production rate
As can be seen from the above data, different formulations carries out in composite process, using under identical effective dose even still less, after tetrachloro insect amide Biphenthrin scarp is composite, the preventive effect of preparation will be apparently higher than three kinds of single doses, the peanut grub preventive effect of 7d after medicine of complex preparation has all surpassed 85%, and the peanut grub preventive effect of three single doses is respectively 81.15%, 37.45% and 51.88%, and visible three kinds of compositions are composite good synergistic effect.Meanwhile, complex preparation desinsection preventive effect of 15d after medicine is greater than 7d after medicine, compares with single dose, and the lasting period is longer.
Claims (8)
1. containing a Pesticidal combination for tetrachloro insect amide, comprise active ingredient, it is characterized in that: described active ingredient is comprised of the component of following weight portion: tetrachloro insect amide 0.01-10 part, Biphenthrin 0.01-15 part, scarp 0.1-20 part.
2. the Pesticidal combination containing tetrachloro insect amide according to claim 1, is characterized in that: described active ingredient is comprised of the component of following weight portion: tetrachloro insect amide 0.01-5 part, Biphenthrin 0.01-10 part, scarp 0.1-10 part.
3. the Pesticidal combination containing tetrachloro insect amide according to claim 1 and 2, is characterized in that: this Pesticidal combination also comprises the component of following weight portion: 1-15 part auxiliary agent, 0-10 part binding agent and 30-97.88 part filler.
4. the Pesticidal combination containing tetrachloro insect amide according to claim 3, is characterized in that: the formulation of this Pesticidal combination is granule.
5. the Pesticidal combination containing tetrachloro insect amide according to claim 4, is characterized in that: described auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, fatty alcohol-polyoxyethylene ether, dioctyl sodium sulfosuccinate and Morwet D-425 naphthalene sulfonate condensation polymer.
6. the Pesticidal combination containing tetrachloro insect amide according to claim 4, is characterized in that: described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol and carboxymethyl cellulose.
7. according to the Pesticidal combination containing tetrachloro insect amide described in claim 4, it is characterized in that: described filler is one or more combinations in white carbon, diatomite, composite fertilizer, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, phosphide potassium dihydrogen, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate and talcum powder.
8. the Pesticidal combination containing tetrachloro insect amide as described in any one in claim 1-7, is characterized in that: for control of grubs, root-knot nematode, thrips, aphid and snout moth's larva.
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