CN104068071B - Containing the Pesticidal combination of four chlorantraniliproles - Google Patents
Containing the Pesticidal combination of four chlorantraniliproles Download PDFInfo
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- CN104068071B CN104068071B CN201410320045.7A CN201410320045A CN104068071B CN 104068071 B CN104068071 B CN 104068071B CN 201410320045 A CN201410320045 A CN 201410320045A CN 104068071 B CN104068071 B CN 104068071B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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Abstract
The invention discloses a kind of Pesticidal combination containing four chlorantraniliproles, be made up of active ingredient, auxiliary agent, binding agent and filler, the component composition of the formulation consists weight ratio of described granule: four chlorantraniliprole 0.01-10%, Biphenthrin 0.01-15%, scarp 0.1-20%, auxiliary agent 1-15%, binding agent 1-10%, filler supplies 100%.The present invention can not only realize the generation of prevention and control insect pest effectively, can also promote that crop tuber is grown and plant strain growth, improve the yield and quality of crop.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of Pesticidal combination containing four chlorantraniliproles
Background technology
At present, domestic cultural control soil insect generally adopts granule, due to the forbidding of the active component of carbofuran, terbufos, thimet, Isofenphos methyl, the contour poison of phonamiphos.In recent years, based on middle low toxicity active composition as Avermectin, the granule of poisoning board, diazinon, clothianidin etc. with poison are also applied in agricultural gradually, although solve high, the residual problem such as to exceed standard of toxicity, but the action spectrum of these active components is narrower, dosage is large, easily develop immunity to drugs, control efficiency is not ideal, can not meet the demand of peasant household.And granular insecticide effect is at present comparatively single.
Scarp, the tobacco waste residue that the tobacco company for all parts of the country leaves over, measuring many and cannot process in time, there are high in cost of production problems in process.
Four chlorantraniliproles, the noval chemical compound that Shi Zhonghua agrochemical Co., Ltd and Shenyang Chemical Engineering Inst develop jointly, the bromo-N-(2 of chemical name: 3-, the chloro-6-of 4-bis-(methylformamide) base)-1-(3,5-dichloro-2-pyridyl base)-1H-pyrazoles-5-formamide, it belongs to ryanodine receptor activator insecticides, it is combined by ryanodine receptor in pest body, open calcium channel, make to be stored in intracellular calcium ion sustained release in sarcoplasm, calcium ion and sarcoplasm mesostroma protein combination, cause muscle contracts last.Insect bodies Symptoms is tic, food refusal, finally dead.Four chlorantraniliproles are low toxicity, broad spectrum pesticide, all have good activity to lepidoptera pest.
Biphenthrin (bifenthrin) chemical name: 2-methyl biphenyl-3-ylmethyl-(Z)-(1RS)-cis-3-(2-chloro-3,3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, speed of knocking down is fast, the longevity of residure is long, and insecticidal spectrum is wide, also has favorable effect to mite.Be mainly used in preventing and treating each Species of Lepidopterous Larvae, aleyrodid, aphid, phytophagy tetranychid.
Four chlorantraniliproles and Biphenthrin are used alone, fine to the control efficiency of insect in its control spectrum, but exist necessarily limiting, control spectrum is narrow, and along with a large amount of on a large scale use in the whole nation, various insect increases to the pesticide resistance of these two kinds of medicament single doses, and consumption medicine is also along with increase, but insecticidal activity reduces greatly.As a large amount of uses due to Imidacloprid, the fold resistance of rice fulgorid to Imidacloprid reaches 250 ~ 400 times, and the plant protection unit in part paddy rice region has been issued control rice fulgorid and to have been stopped using the notice of Imidacloprid.
Applicant finds, at present less to the composition research of four chlorantraniliproles, patent only has the combination research about Avermectin and four chlorantraniliproles, metaflumizone and four chlorantraniliproles, four chlorantraniliproles and emamectin-benzoate, multiple killing teichomycin and four chlorantraniliproles, four chlorantraniliproles and chlorfenapyr, four chlorantraniliproles and indoxacarb, four chlorantraniliproles and butene-fipronil, four chlorantraniliproles and methoxyfenozide of 8 sections of Beijing Yanhua Yongle Biotechnology Co., Ltd..
So far now, applicant not yet finds in any patent and periodical and openly reports four chlorantraniliproles, Biphenthrin and scarp ternary built composition pesticide.
Summary of the invention
Object of the present invention solves the problems of the technologies described above, and provide a kind of Pesticidal combination containing four chlorantraniliproles, the present invention can not only realize the generation of prevention and control insect pest effectively, can also promote that crop tuber is grown and plant strain growth, improve the yield and quality of crop.
For realizing above-mentioned object, technical scheme of the present invention is:
Contain a Pesticidal combination for four chlorantraniliproles, comprise active ingredient, described active ingredient is made up of the component of following weight portion: four chlorantraniliprole 0.01-10 parts, Biphenthrin 0.01-15 part, scarp 0.1-20 part.
The above active ingredient is made up of the component of following weight portion: four chlorantraniliprole 0.01-5 parts, Biphenthrin 0.01-10 part, scarp 0.1-10 part.
The above-mentioned Pesticidal combination containing four chlorantraniliproles also comprises the component of following weight portion: 1-15 part auxiliary agent, 0-10 part binding agent and 30-97.88 part filler.
The above-mentioned formulation containing the Pesticidal combination of four chlorantraniliproles is granule.
The above auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, fatty alcohol-polyoxyethylene ether, dioctyl sodium sulfosuccinate and MorwetD-425 naphthalene sulphonate.
The above binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol and carboxymethyl cellulose.
The above filler is one or more combinations in white carbon, diatomite, composite fertilizer, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, phosphide potassium dihydrogen, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate and talcum powder.
Scarp has certain regulating action also known as cigarette foam to crop growing state, it contains the elements such as abundant organic matter, amino acid, biological clamps, be the nuisanceless ecological organic fertilizer of a kind of fully natural green, have certain killing action simultaneously to insect, it is extremely low that applicant tests rear discovery scarp single dose preventive effect.
Former medicine used in the present invention, auxiliary agent, binding agent and filler are all bought from other producers.
Compared with prior art, the beneficial effect that the present invention has is:
1. Synergistic.The present invention is through experimental studies have found that, with four chlorantraniliproles, Biphenthrin and scarp, any two kinds is that active ingredient is composite, synergistic effect is not had to the control of grub, root-knot nematode, thrips, aphid, snout moth's larva, and when weight ratio 0.01-10:0.01-15:0.1-20 ternary built, synergistic function is possessed to the control of grub, root-knot nematode, thrips, aphid, snout moth's larva, under 0.01-5:0.01-10:0.1-10 part weight ratio, synergistic function is particularly evident.
2. consumption is few, the lasting period long and cost is low.After the present invention four chlorantraniliprole Biphenthrin scarp is composite, under the identical even less effective dose of use, the preventive effect of preparation is more than 85%, and higher than three kinds of single dose preventive effect 4-50%, visible three kinds of compositions are composite good synergistic effect.Meanwhile, complex preparation desinsection preventive effect of 15d after medicine is greater than 7d after medicine, and compared with single dose, the lasting period is longer.
3. wide spectrum.Granule of the present invention, can be used for preventing and treating sugarcane, peanut, corn, the soil insect of crop of banana, nematode and insect on the ground, comprises grub, root-knot nematode, thrips, aphid, snout moth's larva etc.
4. crop yield can be improved.When the present invention is using calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate as filler, the nutrient components such as N, P, K, S, the Ca needed for crop can be supplied, improve crop yield further.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to the scope that embodiment represents.
Embodiment 1
0.12% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 0.01kg, Biphenthrin 0.01kg, scarp 0.1kg, calcium lignosulfonate 0.4kg, lauryl sodium sulfate 0.6kg, polyvinyl alcohol 0.1kg, composite fertilizer 10kg, ammonium dihydrogen phosphate (ADP) 25kg, kaolin 20kg, sodium sulphate complements to 100kg.
Above-mentioned raw materials component is mixed, pulverizes, stir after adding water-wet, then use granulator granulation, sieve after drying and obtain 0.12% 4 chlorantraniliprole Biphenthrin scarp granule.
The processing technology of following examples 2 ~ embodiment 13 is with embodiment 1.
Embodiment 2
2% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 0.3kg, Biphenthrin 0.2kg, scarp 1.5kg, fatty alcohol-polyoxyethylene ether 1kg, lauryl sodium sulfate 0.5kg, starch 1kg, potassium sulfate 25kg, ammonium chloride 20kg, kaolin 15kg, diatomite supplies 100kg.
Embodiment 3
7% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 5kg, Biphenthrin 1kg, scarp 1kg, dioctyl sodium sulfosuccinate 1kg, naphthalenesulfonate formaldehyde condensation compound 3kg, sucrose 2kg, carboxymethyl cellulose 3kg, amine sulfate 15kg, calcium carbonate 20kg, kaolin supplies 100kg.
Embodiment 4
10% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 1kg, Biphenthrin 8kg, scarp 1kg, sodium butylnaphthalenesulfonate 4kg, fatty alcohol-polyoxyethylene ether 2kg, carboxymethyl cellulose 3kg, potassium dihydrogen phosphate 18kg, urea 5kg, bentonite supplies 100kg.
Embodiment 5
14% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 2kg, Biphenthrin 4kg, scarp 8kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Embodiment 6
10.11% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 10kg, Biphenthrin 0.01kg, scarp 0.1kg, lauryl sodium sulfate 3kg, fatty alcohol-polyoxyethylene ether 3.5kg, carboxymethyl cellulose 2kg, starch 2kg, potassium sulfate 5kg, urea 10kg, calcium carbonate complement to 100kg.
Embodiment 7
6.11% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 0.01kg, Biphenthrin 6kg, scarp 0.1kg, sodium lignin sulfonate 3kg, fatty alcohol-polyoxyethylene ether 2kg, polyvinyl alcohol 3kg, ammonium dihydrogen phosphate (ADP) 3kg, calcium dihydrogen phosphate 5kg, 100kg supplied by urea.
Embodiment 8
25.1% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 10kg, Biphenthrin 15kg, scarp 0.1kg, calcium lignosulfonate 5kg, fatty alcohol-polyoxyethylene ether 2kg, carboxymethyl cellulose 3kg, composite fertilizer 15kg, potassium sulfate 1kg, kaolin supplies 100kg.
Embodiment 9
30.01% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 10kg, Biphenthrin 0.01kg, scarp 20kg, MorwetD-425 naphthalene sulphonate 4kg, lauryl sodium sulfate 2kg, sodium sulphate 5kg, polyvinyl alcohol 0.5kg, white carbon 10kg, 100kg supplies in composite fertilizer.
Embodiment 10
0.3% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 0.1kg, Biphenthrin 0.1kg, scarp 0.1kg, MorwetD-425 naphthalene sulphonate 4kg, calcium lignosulfonate 1kg, fatty alcohol-polyoxyethylene ether 1.5kg, calcium dihydrogen phosphate 10kg, 100kg mended by urea.
Embodiment 11
11% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 0.5kg, Biphenthrin 0.5kg, scarp 10kg, sodium lignin sulfonate 3.4kg, fatty alcohol-polyoxyethylene ether 3.5kg, polyvinyl alcohol 4kg, ammonium sulfate 6kg, 100kg supplied by urea.
Embodiment 12
45% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 10kg, Biphenthrin 15kg, scarp 20kg, sodium butylnaphthalenesulfonate 8kg, lauryl sodium sulfate 7kg, carboxymethyl cellulose 10kg, urea 10kg, ammonium dihydrogen phosphate (ADP) 3kg, diatomite supplies 100kg.
Embodiment 13
0.7% 4 chlorantraniliprole Biphenthrin scarp granule
Four chlorantraniliprole 0.3kg, Biphenthrin 0.3kg, scarp 0.1kg, MorwetD-425 naphthalene sulphonate 4kg, lauryl sodium sulfate 1kg, carboxymethyl cellulose 3kg, composite fertilizer 5kg, ammonium dihydrogen phosphate (ADP) 6kg, 100kg supplied by urea.
Embodiment 14
10% 4 chlorantraniliprole granule
Four chlorantraniliprole 10kg, sodium butylnaphthalenesulfonate 4kg, carboxymethyl cellulose 3kg, urea 10kg, ammonium dihydrogen phosphate (ADP) 3kg, diatomite supplies 100kg.
Embodiment 15
40% scarp granule
Scarp 40kg, sodium butylnaphthalenesulfonate 4kg, carboxymethyl cellulose 3kg, urea 10kg, ammonium dihydrogen phosphate (ADP) 3kg, diatomite supplies 100kg.
Embodiment 16
6% 4 chlorantraniliprole Biphenthrin granule
Four chlorantraniliprole 2kg, Biphenthrin 4kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Embodiment 17
10% 4 chlorantraniliprole scarp granule
Four chlorantraniliprole 2kg, scarp 8kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Embodiment 18
12% Biphenthrin scarp granule
Biphenthrin 4kg, scarp 8kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 3kg, starch 5kg, talcum powder 20kg, calcium sulphate 5kg, calcium dihydrogen phosphate complements to 100kg.
Application Example 1
The indoor joint toxicity measuring test of four chlorantraniliprole Biphenthrin scarps
Four chlorantraniliproles, Biphenthrin and scarp are made into ternary built agent by the active ingredient part by weight mixing of embodiment 1 ~ embodiment 13 respectively, test method is with reference to NY/T1154.7-2006, NY/T1154.6-2006, adopt dip method, with sugarcane moth borer 3 instar larvae for examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each process arranges 5 concentration gradients.Carry out statistical analysis with SPSS statistical analysis software, calculate the LC50 of each medicament, evaluate the activity of reagent agent to examination worm according to this, according to the abundant calculating co-toxicity coefficient (CTC) of Sun Yun.
Actual measurement toxicity index=standard agent LC50/ reagent agent LC50 × 100
The theoretical toxicity index of the single dose=content of single dose actual measurement toxicity index × single dose in mixture
The theoretical toxicity index sum of mixture theoretical toxicity index=each single dose
Theoretical toxicity index × 100 of toxicity index/mixture of co-toxicity coefficient=mixture actual measurement
Evaluation criterion: CTC≤80 are antagonism, 80 < CTC < 120 are summation action, and CTC >=120 are synergistic effect, and experimental result please refer to table 1;
Table 1 four chlorantraniliprole Biphenthrin scarp ternary built is to the indoor joint toxicity measuring result of sugarcane moth borer
Measurement result is in table 1, measurement result shows: four chlorantraniliprole Biphenthrin scarps are hybridly prepared into ternary built agent by above-mentioned weight ratio, 178.9,170.7,159.1,172.4,152.7,174.9,160.0,164.9,162.6,179.8,173.3,226.1,180.6 are respectively to the co-toxicity coefficient of sugarcane moth borer 3 instar larvae, show compositely in the content range that four chlorantraniliprole Biphenthrin scarps limit by claim 1 all have notable synergistic effect to sugarcane moth borer afterwards.
Application Example 2
The indoor joint toxicity measuring test of four chlorantraniliprole Biphenthrin scarps
Four chlorantraniliproles, Biphenthrin and scarp are made into ternary built agent by the active ingredient part by weight mixing of embodiment 1 ~ embodiment 13 respectively, test method is with reference to NY/T1154.7-2006, NY/T1154.15-2009, adopt dip method, with peanut grub 2 Initial instar larvae in age for examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each process arranges 5 concentration gradients.Carry out statistical analysis with SPSS statistical analysis software, calculate the LC50 of each medicament, evaluate the activity of reagent agent to examination worm according to this, according to the abundant calculating co-toxicity coefficient (CTC) of Sun Yun.
Actual measurement toxicity index=standard agent LC50/ reagent agent LC50 × 100
The theoretical toxicity index of the single dose=content of single dose actual measurement toxicity index × single dose in mixture
The theoretical toxicity index sum of mixture theoretical toxicity index=each single dose
Theoretical toxicity index × 100 of toxicity index/mixture of co-toxicity coefficient=mixture actual measurement
Evaluation criterion: CTC≤80 are antagonism, 80 < CTC < 120 are summation action, and CTC >=120 are synergistic effect, and experimental result please refer to table 2;
Table 2 four chlorantraniliprole Biphenthrin scarp ternary built is to the indoor joint toxicity measuring result of peanut grub
Measurement result is in table 2, measurement result shows: four chlorantraniliprole Biphenthrin scarps are hybridly prepared into ternary built agent by above-mentioned weight ratio, 111.3,98.7,91.4,158.6,170.2,165.6,172.8,165.3,174.6,219.5,159.9,178.2,199.8,183.4,195.6,212.2 are respectively to the co-toxicity coefficient of peanut grub 2 Initial instar larvae in age, show compositely in the content range that four chlorantraniliprole Biphenthrin scarps limit by claim 1 all have notable synergistic effect to peanut grub afterwards.
Application Example 3
On the basis of Toxicity Determination, with each embodiment sample, field medicine effect test checking is carried out to peanut grub, verify its synergistic effect to other insects except sugarcane moth borer.Test method and drug effect computational methods: with reference to " pesticide field efficacy medicine test criterion (two) the 72nd part: insecticide control nonirrigated farmland soil insect ".Controlling object: peanut grub; Test site: Fusui County, Chongzuo City, Guangxi peanut ground; Application method: spread fertilizer over the fields;
Contrast medicament: 0.2% Biphenthrin granule (Xinhui District, Jiangmen City of Guangdong Province Nong get Feng Co., Ltd, commercial dosage 90-150 gram/ha), 10% 4 chlorantraniliprole granule (embodiment 14), 40% scarp granule (embodiment 15), 6% 4 chlorantraniliprole Biphenthrin granule (embodiment 16), 10% 4 chlorantraniliprole scarp granule (embodiment 17), 12% Biphenthrin scarp granule (embodiment 18).
The each embodiment of table 3 is to the control efficiency of peanut grub and increase of production rate
As can be seen from the above data, different formulations carries out in composite process, under the identical even less effective dose of use, after four chlorantraniliprole Biphenthrin scarps are composite, the preventive effect of preparation will apparently higher than three kinds of single doses, the peanut grub preventive effect of 7d after medicine of complex preparation has all exceeded 85%, and the peanut grub preventive effect of three single doses is respectively 81.15%, 37.45% and 51.88%, and visible three kinds of compositions are composite good synergistic effect.Meanwhile, complex preparation desinsection preventive effect of 15d after medicine is greater than 7d after medicine, and compared with single dose, the lasting period is longer.
Claims (6)
1., containing a Pesticidal combination for four chlorantraniliproles, comprise active ingredient, it is characterized in that: described active ingredient is made up of the component of following weight portion: four chlorantraniliprole 0.01-10 parts, Biphenthrin 0.01-15 part, scarp 0.1-20 part.
2. the Pesticidal combination containing four chlorantraniliproles according to claim 1, is characterized in that: described active ingredient is made up of the component of following weight portion: four chlorantraniliprole 0.01-5 parts, Biphenthrin 0.01-10 part, scarp 0.1-10 part.
3. the Pesticidal combination containing four chlorantraniliproles according to claim 1 and 2, is characterized in that: this Pesticidal combination also comprises the component of following weight portion: one or more combinations in the lauryl sodium sulfate of 1-15 part, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, fatty alcohol-polyoxyethylene ether, dioctyl sodium sulfosuccinate and MorwetD-425 naphthalene sulphonate, 0-10 part binding agent and 30-97.88 part filler; The formulation of this Pesticidal combination is granule.
4. the Pesticidal combination containing four chlorantraniliproles according to claim 3, is characterized in that: described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol and carboxymethyl cellulose.
5. the Pesticidal combination containing four chlorantraniliproles according to claim 3, is characterized in that: described filler is one or more combinations in white carbon, diatomite, composite fertilizer, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, phosphide potassium dihydrogen, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate and talcum powder.
6. the Pesticidal combination containing four chlorantraniliproles according to any one of claim 1-2 or 4-5, is characterized in that: for control of grubs, root-knot nematode, thrips, aphid and snout moth's larva.
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