CN104039141B - 包封的活性物质 - Google Patents
包封的活性物质 Download PDFInfo
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- CN104039141B CN104039141B CN201280061187.5A CN201280061187A CN104039141B CN 104039141 B CN104039141 B CN 104039141B CN 201280061187 A CN201280061187 A CN 201280061187A CN 104039141 B CN104039141 B CN 104039141B
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- active material
- encapsulating
- composition
- mixture
- metallic addition
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- 238000001311 chemical methods and process Methods 0.000 description 1
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- XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 description 1
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- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
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- 229920006037 cross link polymer Polymers 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
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- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
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- 150000004985 diamines Chemical class 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- GLUUGHFHXGJENI-UHFFFAOYSA-N diethylenediamine Natural products C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
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- 101150107144 hemC gene Proteins 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
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- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
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- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
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- 150000002484 inorganic compounds Chemical class 0.000 description 1
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- 230000001788 irregular Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
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- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- 239000011159 matrix material Substances 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
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- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
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- 239000008239 natural water Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
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- 238000012216 screening Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/007—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161581235P | 2011-12-29 | 2011-12-29 | |
| US61/581,235 | 2011-12-29 | ||
| PCT/US2012/071744 WO2013101889A1 (en) | 2011-12-29 | 2012-12-27 | Encapsulated actives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104039141A CN104039141A (zh) | 2014-09-10 |
| CN104039141B true CN104039141B (zh) | 2017-06-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280061187.5A Active CN104039141B (zh) | 2011-12-29 | 2012-12-27 | 包封的活性物质 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20140341962A1 (enExample) |
| EP (1) | EP2779832A1 (enExample) |
| JP (1) | JP6114758B2 (enExample) |
| KR (1) | KR102054685B1 (enExample) |
| CN (1) | CN104039141B (enExample) |
| BR (1) | BR112014014579A8 (enExample) |
| CL (1) | CL2014001544A1 (enExample) |
| WO (1) | WO2013101889A1 (enExample) |
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|---|---|---|---|---|
| US10653134B2 (en) | 2014-11-11 | 2020-05-19 | Council Of Scientific And Industrial Research | Microcapsule composition containing water-soluble amine and a process for the preparation thereof |
| WO2017095335A1 (en) | 2015-11-30 | 2017-06-08 | Aquafil S.P.A. | Microencapsulated biocides, coating compositions with microencapsulated biocides and use of coating compositions for fishing nets |
| EP3496533A4 (en) * | 2016-08-08 | 2020-04-01 | Autonomic Materials, Inc. | PROTECTIVE BIOCIDAL FORMULATIONS |
| KR101989582B1 (ko) * | 2017-06-27 | 2019-06-14 | 주식회사 엘브스바이오켐 | 기능성 물질이 담지된 서방형 나노 다공성 마이크로 입자의 제조 방법 및 그 마이크로입자 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4985064A (en) * | 1985-04-30 | 1991-01-15 | Rohm And Haas Company | Microsuspension process for preparing solvent core sequential polymer dispersion |
| JP2006282571A (ja) * | 2005-03-31 | 2006-10-19 | Dainippon Jochugiku Co Ltd | 水中防汚材 |
| WO2007101019A2 (en) * | 2006-02-23 | 2007-09-07 | Fmc Corporation | Stable mixtures of microencapsulated and non-encapsulated pesticides |
| CN101037554A (zh) * | 2006-03-16 | 2007-09-19 | 罗门哈斯公司 | 包囊的生物杀伤剂的混合物 |
| CN101137288A (zh) * | 2004-09-14 | 2008-03-05 | 微技术实验室公司 | 微胶囊化的杀生物剂和防污剂 |
| CN101378829A (zh) * | 2006-02-01 | 2009-03-04 | 朗盛德国有限责任公司 | 包含ipbc的凝聚体 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4253877A (en) * | 1979-08-02 | 1981-03-03 | University Of Miami | Anti-fouling marine paints containing microencapsulated anti-fouling agents and the process of microencapsulation |
| US4444699A (en) | 1982-04-20 | 1984-04-24 | Appleton Papers Inc. | Capsule manufacture |
| JPS5920209A (ja) * | 1982-07-26 | 1984-02-01 | Hokko Chem Ind Co Ltd | 改良された殺菌剤組成物 |
| JPH04124109A (ja) * | 1990-09-14 | 1992-04-24 | Tokyo Organ Chem Ind Ltd | 水中防汚剤組成物 |
| US7942958B1 (en) * | 1998-07-22 | 2011-05-17 | Arch Chemicals, Inc. | Composite biocidal particles |
| EP1118382B1 (en) | 2000-01-13 | 2003-04-02 | Kureha Kagaku Kogyo Kabushiki Kaisha | Microcapsule and process for production thereof |
| US7357949B2 (en) * | 2001-12-21 | 2008-04-15 | Agion Technologies Inc. | Encapsulated inorganic antimicrobial additive for controlled release |
| JP4853756B2 (ja) * | 2004-11-30 | 2012-01-11 | ナガセケムテックス株式会社 | 水性抗微生物製剤 |
| EP2532243B1 (en) * | 2011-06-07 | 2016-12-14 | Rohm and Haas Company | Stable biocide compositions |
| MY163188A (en) * | 2011-06-21 | 2017-08-15 | Akzo Nobel Coatings Int Bv | Biocidal foul release coating systems |
-
2012
- 2012-12-27 EP EP12818753.1A patent/EP2779832A1/en not_active Withdrawn
- 2012-12-27 CN CN201280061187.5A patent/CN104039141B/zh active Active
- 2012-12-27 US US14/369,088 patent/US20140341962A1/en not_active Abandoned
- 2012-12-27 KR KR1020147019614A patent/KR102054685B1/ko active Active
- 2012-12-27 WO PCT/US2012/071744 patent/WO2013101889A1/en not_active Ceased
- 2012-12-27 BR BR112014014579A patent/BR112014014579A8/pt not_active Application Discontinuation
- 2012-12-27 JP JP2014550449A patent/JP6114758B2/ja active Active
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2014
- 2014-06-12 CL CL2014001544A patent/CL2014001544A1/es unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4985064A (en) * | 1985-04-30 | 1991-01-15 | Rohm And Haas Company | Microsuspension process for preparing solvent core sequential polymer dispersion |
| CN101137288A (zh) * | 2004-09-14 | 2008-03-05 | 微技术实验室公司 | 微胶囊化的杀生物剂和防污剂 |
| JP2006282571A (ja) * | 2005-03-31 | 2006-10-19 | Dainippon Jochugiku Co Ltd | 水中防汚材 |
| CN101378829A (zh) * | 2006-02-01 | 2009-03-04 | 朗盛德国有限责任公司 | 包含ipbc的凝聚体 |
| WO2007101019A2 (en) * | 2006-02-23 | 2007-09-07 | Fmc Corporation | Stable mixtures of microencapsulated and non-encapsulated pesticides |
| CN101037554A (zh) * | 2006-03-16 | 2007-09-19 | 罗门哈斯公司 | 包囊的生物杀伤剂的混合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104039141A (zh) | 2014-09-10 |
| KR20140115315A (ko) | 2014-09-30 |
| JP2015507632A (ja) | 2015-03-12 |
| US20140341962A1 (en) | 2014-11-20 |
| BR112014014579A8 (pt) | 2017-07-04 |
| JP6114758B2 (ja) | 2017-04-12 |
| CL2014001544A1 (es) | 2014-11-03 |
| EP2779832A1 (en) | 2014-09-24 |
| WO2013101889A1 (en) | 2013-07-04 |
| KR102054685B1 (ko) | 2019-12-11 |
| BR112014014579A2 (pt) | 2017-06-13 |
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