CN103947650A - Bactericidal composition containing trifloxystrobin and difenoconazole and application of bactericidal composition - Google Patents
Bactericidal composition containing trifloxystrobin and difenoconazole and application of bactericidal composition Download PDFInfo
- Publication number
- CN103947650A CN103947650A CN201410152290.1A CN201410152290A CN103947650A CN 103947650 A CN103947650 A CN 103947650A CN 201410152290 A CN201410152290 A CN 201410152290A CN 103947650 A CN103947650 A CN 103947650A
- Authority
- CN
- China
- Prior art keywords
- difenoconazole
- bactericidal composition
- bacterium ester
- oxime bacterium
- water dispersible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a bactericidal composition containing trifloxystrobin and difenoconazole and application of the bactericidal composition. In the composition, the trifloxystrobin and the difenoconazole are compounded and play a quite good synergistic effect, wherein the weight ratio of the trifloxystrobin to the difenoconazole is (1-10):(1-10). The composition disclosed by the invention has the advantages of widening the bactericidal spectrum, improving the sterilization efficiency, avoiding the drug resistance on diseases, prolonging the lasting period of medicaments, and playing a quite good effect on preventing and treating the diseases such as glume blight, powdery mildew, and scab of food crops, vegetables and fruit trees.
Description
Technical field
The present invention relates to a kind of composition pesticide, be specifically related to a kind of bactericidal composition that contains oxime bacterium ester and Difenoconazole and application thereof, belong to technical field of pesticide.
Background technology
Difenoconazole (Difenoconazole); chemical name: suitable; the chloro-4-[4-methyl-2-1H-1 of trans-3-; 2; 4-triazol-1-yl methyl)-1; mute pentane-the 2-of 3-bis-yl) phenyl 4-chlorphenyl ether; belong to triazole bactericidal agent; to Ascomycetes, Basidiomycetes with partly know disease including Alternaria, Ascochyta, the mould genus of tail spore, Colletotrichum, ball Cuo Pseudomonas, Phoma, Ramularia, Septoria, Venturia, Erysiphaceae, Uredinales and some Seedborne pathogen have lasting protection and therapeutic action.
Oxime bacterium ester (Trifloxystrobin); chemical name: (2Z)-2-methoxyimino-2-[2-[[1-[3-(trifluoromethyl) phenyl] ethyleneimino] oxygen methyl] phenyl] methyl acetate; the new fungicides of a class extracting from natural products Strobilurins, successfully develop as bactericide lead compound, characteristics such as thering is efficient, wide spectrum, protection, treat, root out, infiltration, systemic activity, resistance of rainwater washing against, lasting period are long.Oxime bacterium ester is to Isosorbide-5-Nitrae-demethylation enzyme inhibitor, benzamides, it is effective that dicarboxyl amine and benzimidazole produce the bacterial strain of resistance, with at present existing bactericide without cross resistance; Nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease is all had to good activity as powdery mildew, rust, Ying's rot, net blotch, downy mildew, rice blast etc.; Except powdery mildew, leaf spot are had special efficacy, rust, downy mildew, damping off, apple apple scab are had to good activity; Capable of being fast degraded in soil, water because of it, therefore to crop safety, environmentally safe.
Long-term a large amount of use of single bactericide, easily makes disease develop immunity to drugs, and causes dosage increasing, preventive effect reduction, lasting period to shorten, and is unfavorable for environment sustainable development.Delaying disease one of the conventional method that develops immunity to drugs is to carry out composite to the active ingredient of the different mechanisms of action.By lot of experiments, determine best synergistic complex ratio, to expand fungicidal spectrum, improve germicidal efficiency.
Composite preparation taking oxime bacterium ester and Difenoconazole as active component is disclosed in patent CN 102246765 A, CN 102379292 A, CN 103348987 A, but they exist with the form such as aqua, suspending agent, have not yet to see the relevant report of the two water dispersible granules.
Summary of the invention
The object of the present invention is to provide a kind of bactericidal composition containing oxime bacterium ester and Difenoconazole, specifically disclose the formulation of its water dispersible granules, said composition function admirable, bactericidal effect excellence, can avoid disease to develop immunity to drugs, increase the medicine lasting period, be beneficial to environment sustainable development.
The present invention also provides the application of above-mentioned bactericidal composition in control cereal crops, vegetables, fruit diseases.
The present invention is achieved by the following measures:
A kind of bactericidal composition containing oxime bacterium ester and Difenoconazole, it is characterized in that: active constituents of medicine is oxime bacterium ester and Difenoconazole, the weight ratio of oxime bacterium ester and Difenoconazole is 1-10: 1-10, and preferred proportion is 1-5:1-5, and most preferred ratio is 1-2.5:1-2.5.
In above-mentioned bactericidal composition, the content of active constituents of medicine is 30-70wt%, preferably 40-60wt%.
The above-mentioned bactericidal composition containing oxime bacterium ester and Difenoconazole, can be by method known in those skilled in the art, makes the upper any formulation allowing of agricultural, is preferably water dispersible granules.
When composition is made water dispersible granules, the component that comprises following percentage by weight: active constituents of medicine 30%-70%, dispersant 4-10%, wetting agent 2-10%, disintegrant 1-20%, filler surplus.Preferably, composition is made up of the component of following percentage by weight: active constituents of medicine 30%-70%, dispersant 4.5%, wetting agent 2%, disintegrant 12.5%, filler surplus.More preferably formed by the component of following percentage by weight: active constituents of medicine 40%-60%, dispersant 4.5%, wetting agent 2%, disintegrant 12.5%, filler surplus.
Water dispersible granules preparation method is: Difenoconazole, oxime bacterium ester, dispersant, wetting agent, disintegrant, filler are mixed in mixer, after airslide disintegrating mill is crushed to particle diameter 20-40 μ m, mix again, mediate amount of water 20-30wt%, carry out extruder grain, 40-50 DEG C of oven dry, can be made into oxime bacterium ester difenoconazole water dispersible granule product.
Described dispersant is one or more of calcium lignosulfonate, maleic acid-acrylic acid copolymer salt, polyox-yethylene-polyoxypropylene block copolymer, alkylphenol sodium sulfonate, alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, ethylene oxide-propylene oxide block copolymer and polycarboxylate sodium.Preferred dispersants by polycarboxylate sodium and calcium lignosulfonate in mass ratio 2:1 mix.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, a-sulfo methyl ester, sodium tetradecyl sulfate, neopelex, Negel, a-alkene sulfonic acid sodium, alkyl phenol polyethenoxy ether sodium sulfate, sodium lignin sulfonate, Nekal BX, fatty acid sulphate and fatty acid ester sulphate, preferably wetting agent by lauryl sodium sulfate and sodium lignin sulfonate in mass ratio 1:1 mix.
Described disintegrant is selected from: one or more in potassium sulfate, sodium cellulose glycolate, potassium chloride, diammonium hydrogen phosphate, urea, sodium sulphate, ammonium sulfate, ammonium nitrate, calcium chloride and sodium chloride, preferably disintegrant by ammonium sulfate and urea in mass ratio for 1.5:1 mixes.
Described filler is selected from: one or more in kaolin, bentonite, talcum powder, attapulgite, diatomite, white carbon, starch, precipitated calcium carbonate, preferred filler is white carbon.
Composition of the present invention is mainly used in preventing and treating glume blight, powdery mildew and the scab in the disease in cereal crops, vegetables, fruit tree, especially cereal crops, fruit and vegetables.
Beneficial effect of the present invention: (1) present composition effective active composition oxime bacterium ester and Difenoconazole belong to the bactericide of two kinds of different mechanisms of action, and both mutual mixtures can not produce conflict, and have expanded fungicidal spectrum, improves germicidal efficiency; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single dose, and dosage is little, has avoided the pesticide resistance of disease, has extended the medicine lasting period, is beneficial to environment sustainable development; (3) present composition is made water dispersible granules, has avoided the use of organic solvent, has reduced environmental pollution, is also convenient to the packing of product and transport simultaneously; (4) present composition has special efficacy to the glume blight on cereal crops, vegetables, fruit tree, powdery mildew and scab.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, but the present invention is not limited thereto.If no special instructions, the percentage in following embodiment is all weight percentage.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is synergistic effect, on this basis, then carry out field trial.
oxime bacterium ester and Difenoconazole are composite to powdery mildew of cucumber bacterium Toxicity Determination
Test medicine provides by Shandong Weifang Rainbow Chemical Co., Ltd..
After the effective inhibition concentration scope of each medicament is determined in prerun, each medicament is established respectively a series of concentration gradient processing by active constituent content, establishes clear water for contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt mycelial growth rate method to measure the virulence of medicament to powdery mildew of cucumber.After 72h, measure colony diameter by right-angled intersection method, calculate each processing net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) converts logarithm value (x) to, try to achieve virulence regression equation (y=a+bx) with method of least squares, and calculate thus the EC of every kind of medicament
50value.Calculate the different proportioning synergy ratios of two medicaments (SR) according to Wadley method, SR < 0.5 is antagonism simultaneously, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein:
A1, b1 are respectively oxime bacterium ester and Difenoconazole shared ratio in combination;
A is oxime bacterium ester;
B is Difenoconazole.
Result of the test is as shown in table 1:
From table 1, oxime bacterium ester, the EC of Difenoconazole to powdery mildew of cucumber
50be respectively 1.346mg/L and 7.397mg/L, the virulence of oxime bacterium ester is apparently higher than the virulence of Difenoconazole.Oxime bacterium ester and Difenoconazole mixture within the scope of 1-10:1-10 all shows synergistic effect, within the scope of 1-5:1-5 synergy more obvious, within the scope of 1-2.5:1-2.5, synergy is the most remarkable.
Lower mask body is enumerated representative embodiment of the present invention.
embodiment 133% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 3%, Difenoconazole 30%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.
Preparation method is: Difenoconazole, oxime bacterium ester, dispersant, wetting agent, disintegrant, filler are mixed in mixer, after airslide disintegrating mill is crushed to particle diameter 20-40 μ m, mix again, mediate amount of water 20-30%, carry out extruder grain, 40-50 DEG C of oven dry, can be made into 33% water dispersible granules.
embodiment 254% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 9%, Difenoconazole 45%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.Preparation method is with embodiment 1.
embodiment 370% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 20%, Difenoconazole 50%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.Preparation method is with embodiment 1.
embodiment 440% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 20%, Difenoconazole 20%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.Preparation method is with embodiment 1.
embodiment 556% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 40%, Difenoconazole 16%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.Preparation method is with embodiment 1.
embodiment 630% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 25%, Difenoconazole 5%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.Preparation method is with embodiment 1.
embodiment 760% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 54.5%, Difenoconazole 5.5%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.Preparation method is with embodiment 1.
embodiment 840.7% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 3.7%, Difenoconazole 37%, alkylphenol sodium sulfonate 8%, calcium lignosulfonate 1.5%, lauryl sodium sulfate 1%, sodium lignin sulfonate 1%, potassium sulfate 15%, urea 7%, sodium cellulose glycolate 5%, bentonite add to 100%.Preparation method is with embodiment 1.
embodiment 930.6% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 5.1%, Difenoconazole 25.5%, polycarboxylate sodium 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 1.5%, ethylene oxide-propylene oxide block copolymer 2%, lauryl sodium sulfate 1%, a-alkene sulfonic acid sodium 2%, sodium chloride 25%, talcum powder add to 100%.Preparation method is with embodiment 1.
embodiment 1035% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 10%, Difenoconazole 25%, polycarboxylate sodium 3%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 2%, ethylene oxide-propylene oxide block copolymer 2%, lauryl sodium sulfate 1%, a-alkene sulfonic acid sodium 2%, sodium chloride 25%, attapulgite add to 100%.Preparation method is with embodiment 1.
embodiment 1162% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 31%, Difenoconazole 31%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%, calcium lignosulfonate 2%, fatty acid ester sulphate 1%, Nekal BX 2%, calcium chloride 22%, bentonite add to 100%.Preparation method is with embodiment 1.
embodiment 1256% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 40%, Difenoconazole 16%, maleic acid-acrylic acid copolymer salt 3%, polyox-yethylene-polyoxypropylene block copolymer 2%, ethylene oxide-propylene oxide block copolymer 1%, fatty acid sulphate 1%, sodium lignin sulfonate 2%, sodium sulphate 20%, starch add to 100%.Preparation method is with embodiment 1.
embodiment 1337.2% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 31%, Difenoconazole 6.2%, calcium lignosulfonate 2%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 2%, ethylene oxide-propylene oxide block copolymer 2%, neopelex 1.5%, a-alkene sulfonic acid sodium 2%, ammonium sulfate 12.5%, diatomite add to 100%.Preparation method is with embodiment 1.
embodiment 1444% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 40%, Difenoconazole 4%, alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt 3%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%, ethylene oxide-propylene oxide block copolymer 2%, sodium tetradecyl sulfate 1%, a-alkene sulfonic acid sodium 2%, potassium chloride 10%, urea 5%, attapulgite add to 100%.Preparation method is with embodiment 1.
Oxime bacterium ester prepared by above-described embodiment and Difenoconazole complex preparation constant product quality are tested, and the results are shown in following table 2.
Data by table 2 can be found out, in embodiment 8,9,10,11,12,13,14, degradation after heat storage, and use the embodiment 1,2,3,4,5,6,7 of preferred promoter before heat storage and after heat storage, quality is all good, and preferred promoter plays key effect in product quality.
effect experiment
1, the oxime bacterium ester of being prepared by above-described embodiment and Difenoconazole complex preparation control wheat glume blight situation are carried out the test of pesticide effectiveness.This experimental establishment is carried out in this locality, and contrast medicament is 50% trifloxystrobin water dispersible granule (commercial), 10% difenoconazole water dispersible granule (commercial).
Test in wheat glume blight their early stage (heading stage), with the spraying of workers and peasants-16 type knapsack hand sprayer cauline leaf, dispenser in every 7 days once, is sprayed medicine three times altogether.Be watered 450kg by per hectare preparation and be equipped with liquid.Dispenser was fine the same day, 23 DEG C of daily mean temperatures, and relative moisture 50%, after medicine, 48h is interior without rainfall.Before dispenser and after dispenser for the third time, within 7 days, investigate the disease number of sheets and disease index, finally calculate control efficiency.
Preventive effect computational methods are:
Above-described check plot is clear water check plot, does not spray medicament.
Duration of test, in test scope of medication, complex preparation of the present invention has no adverse effects to wheat, and experimental result is as follows:
As can be seen from Table 3, after oxime bacterium ester and Difenoconazole are composite, can effectively prevent and treat the generation of wheat glume blight, control efficiency is all better than contrasting medicament.Wherein, use the embodiment preventive effect of preferred promoter and proportioning will obviously be better than other embodiment, and wheat glume blight preventive effect is reached more than 90%; Other embodiment preventive effects, in 80% left and right, are also better than contrasting medicament.
2, the oxime bacterium ester of being prepared by above-described embodiment and Difenoconazole complex preparation control banana freckle situation are carried out the test of pesticide effectiveness, this experimental establishment is in Haikou City, Hainan Province, and contrast medicament is 50% trifloxystrobin water dispersible granule (commercial), 10% difenoconazole water dispersible granule (commercial).
Test in banana freckle their early stage, with the spraying of workers and peasants-16 type knapsack hand sprayer cauline leaf, dispenser in every 7 days once, is total to dispenser 3 times, and dispenser was fine the same day, 27 DEG C of daily mean temperatures, and after medicine, 48h is interior without rainfall.Before dispenser and after dispenser for the third time, within 7 days, investigate the disease number of sheets and disease index, finally calculate control efficiency.
Preventive effect computational methods are as follows:
Above-described check plot is clear water check plot, does not spray medicament.
Duration of test, in test scope of medication, complex preparation of the present invention has no adverse effects to banana, and result of the test is as follows:
As can be seen from Table 4, can effectively prevent and treat the generation of banana freckle after oxime bacterium ester and Difenoconazole are composite, control efficiency is all better than contrasting medicament.Wherein, use the embodiment preventive effect of preferred promoter and proportioning will obviously be better than other embodiment, and banana freckle preventive effect is reached more than 90%; Other embodiment preventive effects, in 80% left and right, are also better than contrasting medicament.
3, oxime bacterium ester, the Difenoconazole complex preparation prepared by above-described embodiment are prevented and treated powdery mildew of cucumber situation and are carried out the test of pesticide effectiveness.This experimental establishment is carried out in locality, and contrast medicament is 50% trifloxystrobin water dispersible granule (commercial), 10% difenoconazole water dispersible granule (commercial).
Test in powdery mildew of cucumber their early stage, with the spraying of workers and peasants-16 type knapsack hand sprayer cauline leaf, dispenser in every 7 days once, is total to dispenser 3 times, and dispenser was fine the same day, 27 DEG C of daily mean temperatures, and after medicine, 48h is interior without rainfall.Before dispenser and after dispenser for the third time, within 7 days, investigate the disease number of sheets and disease index, finally calculate control efficiency.
Preventive effect computational methods are as follows:
Above-described check plot is clear water check plot, does not spray medicament.
Duration of test, in test scope of medication, complex preparation of the present invention has no adverse effects to cucumber, and result of the test is as follows:
Can be found out by table 5, after oxime bacterium ester and Difenoconazole are composite, can effectively prevent and treat the generation of powdery mildew of cucumber, control efficiency is all better than contrasting medicament.Wherein, use the embodiment preventive effect of preferred promoter and proportioning will obviously be better than other embodiment, and powdery mildew of cucumber preventive effect is reached more than 90%; Other embodiment preventive effects, in 80% left and right, are also better than contrasting medicament.
Claims (10)
1. containing a bactericidal composition for oxime bacterium ester and Difenoconazole, it is characterized in that: active constituents of medicine comprises that weight ratio is oxime bacterium ester and the Difenoconazole of 1-10: 1-10.
2. bactericidal composition according to claim 1, is characterized in that: the weight ratio of oxime bacterium ester and Difenoconazole is 1-5:1-5, preferably 1-2.5:1-2.5.
3. bactericidal composition according to claim 1 and 2, is characterized in that: formulation is water dispersible granules.
4. bactericidal composition according to claim 1 and 2, is characterized in that: the content of active constituents of medicine is 30-70wt%, preferably 40-60wt%.
5. bactericidal composition according to claim 3, it is characterized in that: when formulation is water dispersible granules, composition is made up of the component of following percentage by weight: active constituents of medicine 30%-70%, dispersant 4-10%, wetting agent 2-10%, disintegrant 1-20%, filler surplus.
6. bactericidal composition according to claim 5, it is characterized in that: when formulation is water dispersible granules, composition is made up of the component of following percentage by weight: active constituents of medicine 30%-70%, dispersant 4.5%, wetting agent 2%, disintegrant 12.5%, filler surplus.
7. bactericidal composition according to claim 6, it is characterized in that: when formulation is water dispersible granules, composition is made up of the component of following percentage by weight: active constituents of medicine 40%-60%, dispersant 4.5%, wetting agent 2%, disintegrant 12.5%, filler surplus.
8. according to the bactericidal composition described in any one in claim 5-7, it is characterized in that: dispersant by polycarboxylate sodium and calcium lignosulfonate in mass ratio 2:1 mix, wetting agent by lauryl sodium sulfate and sodium lignin sulfonate in mass ratio 1:1 mix, disintegrant is by ammonium sulfate and urea in mass ratio for 1.5:1 mixes, and filler is white carbon.
9. the application of the bactericidal composition containing oxime bacterium ester and Difenoconazole described in any one in control cereal crops, vegetables, fruit diseases in claim 1-8.
10. application according to claim 9, is characterized in that: described disease is glume blight, powdery mildew or scab.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410152290.1A CN103947650B (en) | 2014-04-16 | 2014-04-16 | A kind of bactericidal composition and application thereof containing oxime bacterium ester and Difenoconazole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410152290.1A CN103947650B (en) | 2014-04-16 | 2014-04-16 | A kind of bactericidal composition and application thereof containing oxime bacterium ester and Difenoconazole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103947650A true CN103947650A (en) | 2014-07-30 |
| CN103947650B CN103947650B (en) | 2016-05-25 |
Family
ID=51325122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410152290.1A Active CN103947650B (en) | 2014-04-16 | 2014-04-16 | A kind of bactericidal composition and application thereof containing oxime bacterium ester and Difenoconazole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103947650B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109792987A (en) * | 2019-01-21 | 2019-05-24 | 深圳诺普信农化股份有限公司 | Dry suspending agent and preparation method thereof |
| WO2023100120A1 (en) * | 2021-12-01 | 2023-06-08 | Rallis India Limited | Fungicide composition, formulations and process for preparation thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005036963A1 (en) * | 2003-09-23 | 2005-04-28 | Bayer Cropscience Aktiengesellschaft | Concentrated suspensions |
| CN102246765A (en) * | 2011-07-27 | 2011-11-23 | 南宁市德丰富化工有限责任公司 | Composite bactericide containing trifloxystrobin |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
| CN102657179A (en) * | 2012-04-26 | 2012-09-12 | 杭州宇龙化工有限公司 | Sterilization composition containing phenylate diazole and trifloxystrobin |
| CN103348987A (en) * | 2013-07-31 | 2013-10-16 | 河北博嘉农业有限公司 | Film-spreading oil agent capable of preventing and curing rice banded sclerotial blight |
-
2014
- 2014-04-16 CN CN201410152290.1A patent/CN103947650B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005036963A1 (en) * | 2003-09-23 | 2005-04-28 | Bayer Cropscience Aktiengesellschaft | Concentrated suspensions |
| CN102246765A (en) * | 2011-07-27 | 2011-11-23 | 南宁市德丰富化工有限责任公司 | Composite bactericide containing trifloxystrobin |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
| CN102657179A (en) * | 2012-04-26 | 2012-09-12 | 杭州宇龙化工有限公司 | Sterilization composition containing phenylate diazole and trifloxystrobin |
| CN103348987A (en) * | 2013-07-31 | 2013-10-16 | 河北博嘉农业有限公司 | Film-spreading oil agent capable of preventing and curing rice banded sclerotial blight |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109792987A (en) * | 2019-01-21 | 2019-05-24 | 深圳诺普信农化股份有限公司 | Dry suspending agent and preparation method thereof |
| WO2023100120A1 (en) * | 2021-12-01 | 2023-06-08 | Rallis India Limited | Fungicide composition, formulations and process for preparation thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103947650B (en) | 2016-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102204546B (en) | Bactericidal composition containing thifluzamide and triazole compounds | |
| CN101971812B (en) | Eugenol-containing germicidal composition | |
| CN103766350A (en) | Bactericidal composition containing trifloxystrobin and tebuconazole | |
| CN103798247A (en) | Fungicidal composition containing trifloxystrobin and tebuconazole and application of fungicidal composition | |
| CN103250717A (en) | Bactericidal composition containing procymidone | |
| CN106172388A (en) | The water dispersible granules of a kind of containing trifloxystrobin and phosethyl-Al and application thereof | |
| CN102138562B (en) | Antibacterial composition containing polyoxin and amide compounds | |
| CN103749472B (en) | A kind of bactericidal composition and application thereof containing oxime bacterium ester and cyproconazole | |
| CN101755837B (en) | Fungicidal composition containing bromothalonil and prochloraz manganese | |
| CN103947650B (en) | A kind of bactericidal composition and application thereof containing oxime bacterium ester and Difenoconazole | |
| CN104137836B (en) | A kind of bactericidal composition of fluorine-containing azoles bacterium aniline and methoxy acrylic | |
| CN102273462A (en) | Novel pesticide composition containing prothioconazole and triazoles | |
| CN102210310B (en) | Sterilizing composite containing famoxadone and triazole compound | |
| CN104285954A (en) | Efficient fungicidal composition | |
| CN102217605A (en) | Sterilizing composition containing flutolanil and triazole compound | |
| CN101720767B (en) | Bactericidal composition containing dithianone and prochloraz manganese | |
| CN103478152B (en) | Fenamidone-containing sterilization composition | |
| CN102461528A (en) | Bactericidal composition containing mandipropamid | |
| CN101715772B (en) | Bactericidal composition containing carbendazim and ethirimol | |
| CN104106582B (en) | A kind of bactericidal composition containing chlorine nalidixic bacterium ester and thiocarbamates | |
| CN101785471B (en) | Sterilization composition containing ZJ0712 and Prochloraz manganese | |
| CN104757007B (en) | A kind of bactericidal composition containing Hexanaphthene flusulfamide | |
| CN103416416B (en) | A kind of bactericidal composition containing tiadinil | |
| CN101697720B (en) | Bactericide composition containing ethirimol and kresoxim | |
| CN108112593A (en) | A kind of bactericidal composition containing bronopol |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171116 Address after: No. 8, Hai Pu North Road, New River ecological and chemical technology industry base in Pingdu City, Qingdao, Shandong Patentee after: Qingdao run agricultural chemical Co., Ltd. Address before: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee before: Shandong Weifang Rainbow Chemical Co., Ltd. |