CN103881628A - Decabromodiphenyl ether flame-retardant flocking adhesive - Google Patents
Decabromodiphenyl ether flame-retardant flocking adhesive Download PDFInfo
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- CN103881628A CN103881628A CN201410104369.7A CN201410104369A CN103881628A CN 103881628 A CN103881628 A CN 103881628A CN 201410104369 A CN201410104369 A CN 201410104369A CN 103881628 A CN103881628 A CN 103881628A
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- parts
- retardant
- decabromodiphynly oxide
- decabromodiphenyl ether
- flocking adhesive
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Abstract
The invention discloses a decabromodiphenyl ether flame-retardant flocking adhesive which is characterized by comprising the following components in parts by weight: 525-550 parts of methyl acrylate, 186-210 parts of hydroxypropyl methacrylate, 260-300 parts of ethyl acrylate, 9-15 parts of acrylic acid, 16-20 parts of N-methacrylamide, 190-220 parts of E-S1 epoxy resin, 11-15 parts of benzoyl peroxide, 11-13 parts of N-dimethylbenzylamine, 350-380 parts of vinyl acetate, 9-15 parts of decabromodiphenyl ether, 7-12 parts of sodium polyacrylate and 3-5 parts of aluminum sulfate. The decabromodiphenyl ether flame-retardant flocking adhesive has the advantages of available raw materials, low cost, environmental friendliness and good effects, and is convenient to use convenience.
Description
Technical field
The invention belongs to a kind of tackiness agent.
Background technology
The features such as splicing (bonding, bonding, cementing, gluing) refers to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together, and has stress distribution continuous, lightweight, or sealing, and most technological temperatures are low.Glued joint the connection that is specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and high-and-new science and technology progress and people's daily life improvement are had to great effect.Therefore, research, all kinds of tackiness agent of development and production are very important.Tackiness agent (Bonding agent) is one of most important subsidiary material, and in package handling, application is very extensive.Tackiness agent is the sticking material of tool, the material of two kinds of separation can be linked together by its viscosity.The kind of tackiness agent is a lot.1. natural glue it be taken from the material of occurring in nature.Comprise the biological adhesives such as starch, protein, dextrin, gelatin, shellac, hide glue, rosin; Also comprise the mineral binders such as pitch.2. artificial tackiness agent this be to use made material, comprise the inorganic adhesives such as water glass, and the organic binder bond such as synthetic resins, synthetic rubber.Service performance divides 1. Watersoluble Adhesive to use water as the tackiness agent of solvent, mainly contains starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose etc.2. Hotmelt Adhesive makes to use after adhesive melts by heating, is a kind of solid binder.General thermoplastic resin all can use, as urethane, polystyrene, polyacrylic ester, ethene-acetate ethylene copolymer etc.3. Solvent Adhesive is water insoluble and be dissolved in the tackiness agent of certain solvent.As shellac, isoprene-isobutylene rubber etc.4. Emulsion Adhesive is many is suspension in water, as vinyl acetate resin, acrylic resin, chlorinated rubber etc.5. solvent-free liquid adhesive is thick liquid nano at normal temperatures, as epoxy resin etc.Tackiness agent is the medium between label material and bonding substrates, plays link effect.Can be divided into two kinds of permanent and removable property by its characteristic.It has multiple formulations, is applicable to different plane materiels and different occasions.Tackiness agent is the most important composition in adhesive material technology, is the key of tag application technology.The features such as splicing (bonding, bonding, cementing, gluing) refers to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together, and has stress distribution continuous, lightweight, or sealing, and most technological temperatures are low.Glued joint the connection that is specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and high-and-new science and technology progress and people's daily life improvement are had to great effect.Therefore, research, all kinds of tackiness agent of development and production are very important.
Through Chinese publication retrieval, do not find the scheme identical with present patent application.
Summary of the invention:
The object of the invention is to; The fire-retardant Flock Adhesive stick of a kind of decabromodiphynly oxide is proposed.
The fire-retardant Flock Adhesive stick of decabromodiphynly oxide of the present invention, is characterized in that: it is filled a prescription by weight, by methyl acrylate 525-550 part, Propylene glycol monoacrylate 186-210 part, ethyl propenoate 260-300 part, vinylformic acid 9-15 part, N-methacrylic acid acid amides 16-20 part, E-S1 epoxy is counted fat 190-220 part, benzoyl peroxide 11-15 part, N, N-dimethyl benzylamine 11-13 part, vinyl acetate 350-380 part, decabromodiphynly oxide 9-15 part, sodium polyacrylate 7-12 part, Tai-Ace S 150 3-5 part composition.
The fire-retardant flocking adhesive preparation method of decabromodiphynly oxide of the present invention, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 525-550 part, Propylene glycol monoacrylate 186-210 part, ethyl propenoate 260-300 part, vinylformic acid 9-15 part, N-methacrylic acid acid amides 16-20 part, E-S1 epoxy is counted fat 190-220 part, benzoyl peroxide 11-15 part, N, N-dimethyl benzylamine 11-13 part, vinyl acetate 350-380 part, decabromodiphynly oxide 9-15 part, sodium polyacrylate 7-12 part, Tai-Ace S 150 3-5 part composition, after solid materials is dissolved at 70-75 ℃ with ethanol, be diluted to 15% ethanolic soln, whole materials are added, at room temperature stirring reaction 12-22 hour, obtain product.
Product of the present invention, can adapt to the use of various occasions, and bond strength reaches the more than 2 times of prior art.
The present invention compared with prior art its beneficial effect is: have raw material and be easy to get, work simplification, is easy to manufacture the advantage such as cost is low, and environmental protection is easy to use, effective.
Embodiment:
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited to this.
Product of the present invention is raw materials used buys acquisition.
Embodiment 1
The fire-retardant flocking adhesive preparation method of decabromodiphynly oxide of the present invention, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 525-550 part, Propylene glycol monoacrylate 186-210 part, ethyl propenoate 260-300 part, vinylformic acid 9-15 part, N-methacrylic acid acid amides 16-20 part, E-S1 epoxy is counted fat 190-220 part, benzoyl peroxide 11-15 part, N, N-dimethyl benzylamine 11-13 part, vinyl acetate 350-380 part, decabromodiphynly oxide 9-15 part, sodium polyacrylate 7-12 part, Tai-Ace S 150 3-5 part composition, after solid materials is dissolved at 70-75 ℃ with ethanol, be diluted to 15% ethanolic soln, whole materials are added, at room temperature stirring reaction 12-22 hour, obtain product.
Embodiment 2
The fire-retardant flocking adhesive preparation method of decabromodiphynly oxide of the present invention, it is characterized in that: it is filled a prescription by weight, by 525 parts of methyl acrylates, 186 parts of Propylene glycol monoacrylates, 260 parts of ethyl propenoates, 9 parts, vinylformic acid, 16 parts of N-methacrylic acid acid amides, E-S1 epoxy is counted 190 parts, fat, 11 parts of benzoyl peroxides, N, 11 parts of N-dimethyl benzylamines, 350 parts of vinyl acetates, 9 parts of decabromodiphynly oxides, 7 parts of sodium polyacrylates, 3 parts of compositions of Tai-Ace S 150, after solid materials is dissolved at 70-75 ℃ with ethanol, be diluted to 15% ethanolic soln, whole materials are added, at room temperature stirring reaction 12-22 hour, obtain product.
Embodiment 3
The fire-retardant flocking adhesive preparation method of decabromodiphynly oxide of the present invention, it is characterized in that: it is filled a prescription by weight, by 550 parts of methyl acrylates, 210 parts of Propylene glycol monoacrylates, 300 parts of ethyl propenoates, 15 parts, vinylformic acid, 20 parts of N-methacrylic acid acid amides, E-S1 epoxy is counted 220 parts, fat, 15 parts of benzoyl peroxides, N, 13 parts of N-dimethyl benzylamines, 380 parts of vinyl acetates, 15 parts of decabromodiphynly oxides, 12 parts of sodium polyacrylates, 5 parts of compositions of Tai-Ace S 150, after solid materials is dissolved at 70-75 ℃ with ethanol, be diluted to 15% ethanolic soln, whole materials are added, at room temperature stirring reaction 12-22 hour, obtain product.
Embodiment 4
The fire-retardant flocking adhesive preparation method of decabromodiphynly oxide of the present invention, it is characterized in that: it is filled a prescription by weight, by 525 parts of methyl acrylates, 210 parts of Propylene glycol monoacrylates, 260 parts of ethyl propenoates, 15 parts, vinylformic acid, 16 parts of N-methacrylic acid acid amides, E-S1 epoxy is counted 220 parts, fat, 11 parts of benzoyl peroxides, N, 13 parts of N-dimethyl benzylamines, 350 parts of vinyl acetates, 9 parts of decabromodiphynly oxides, 12 parts of sodium polyacrylates, 3 parts of compositions of Tai-Ace S 150, after solid materials is dissolved at 70-75 ℃ with ethanol, be diluted to 15% ethanolic soln, whole materials are added, at room temperature stirring reaction 12-22 hour, obtain product.
Embodiment 5
The fire-retardant flocking adhesive preparation method of decabromodiphynly oxide of the present invention, it is characterized in that: it is filled a prescription by weight, by 550 parts of methyl acrylates, 186 parts of Propylene glycol monoacrylates, 300 parts of ethyl propenoates, 9 parts, vinylformic acid, 20 parts of N-methacrylic acid acid amides, E-S1 epoxy is counted 190 parts, fat, 15 parts of benzoyl peroxides, N, 11 parts of N-dimethyl benzylamines, 380 parts of vinyl acetates, 9 parts of decabromodiphynly oxides, 12 parts of sodium polyacrylates, 3 parts of compositions of Tai-Ace S 150, after solid materials is dissolved at 70-75 ℃ with ethanol, be diluted to 15% ethanolic soln, whole materials are added, at room temperature stirring reaction 12-22 hour, obtain product.
Product specification of the present invention, quality: solid content is more than 80%, and its 1% solution pH value is 7.0-7.5; Viscosity 120-130 centipoise.
Claims (2)
1. the fire-retardant Flock Adhesive stick of decabromodiphynly oxide, is characterized in that: it is filled a prescription by weight, by methyl acrylate 525-550 part, Propylene glycol monoacrylate 186-210 part, ethyl propenoate 260-300 part, vinylformic acid 9-15 part, N-methacrylic acid acid amides 16-20 part, E-S1 epoxy is counted fat 190-220 part, benzoyl peroxide 11-15 part, N, N-dimethyl benzylamine 11-13 part, vinyl acetate 350-380 part, decabromodiphynly oxide 9-15 part, sodium polyacrylate 7-12 part, Tai-Ace S 150 3-5 part composition.
2. the fire-retardant flocking adhesive preparation method of decabromodiphynly oxide, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 525-550 part, Propylene glycol monoacrylate 186-210 part, ethyl propenoate 260-300 part, vinylformic acid 9-15 part, N-methacrylic acid acid amides 16-20 part, E-S1 epoxy is counted fat 190-220 part, benzoyl peroxide 11-15 part, N, N-dimethyl benzylamine 11-13 part, vinyl acetate 350-380 part, decabromodiphynly oxide 9-15 part, sodium polyacrylate 7-12 part, Tai-Ace S 150 3-5 part composition, after solid materials is dissolved at 70-75 ℃ with ethanol, be diluted to 15% ethanolic soln, whole materials are added, at room temperature stirring reaction 12-22 hour, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104369.7A CN103881628B (en) | 2014-03-20 | 2014-03-20 | The fire-retardant Flock Adhesive stick of decabromodiphynly oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104369.7A CN103881628B (en) | 2014-03-20 | 2014-03-20 | The fire-retardant Flock Adhesive stick of decabromodiphynly oxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103881628A true CN103881628A (en) | 2014-06-25 |
| CN103881628B CN103881628B (en) | 2016-03-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410104369.7A Active CN103881628B (en) | 2014-03-20 | 2014-03-20 | The fire-retardant Flock Adhesive stick of decabromodiphynly oxide |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517404A (en) * | 2018-11-13 | 2019-03-26 | 贵州大自然科技股份有限公司 | A kind of plant fibre sheet material production adhesive and application method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1032617B1 (en) * | 1997-11-20 | 2003-05-28 | Lucent Technologies Inc. | Pressure-sensitive flame retardant adhesive |
| CN103525341A (en) * | 2013-10-10 | 2014-01-22 | 杨毅 | Acrylate bonding agent |
| CN103525345A (en) * | 2013-10-10 | 2014-01-22 | 杨毅 | Flocking bonding agent |
-
2014
- 2014-03-20 CN CN201410104369.7A patent/CN103881628B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1032617B1 (en) * | 1997-11-20 | 2003-05-28 | Lucent Technologies Inc. | Pressure-sensitive flame retardant adhesive |
| CN103525341A (en) * | 2013-10-10 | 2014-01-22 | 杨毅 | Acrylate bonding agent |
| CN103525345A (en) * | 2013-10-10 | 2014-01-22 | 杨毅 | Flocking bonding agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517404A (en) * | 2018-11-13 | 2019-03-26 | 贵州大自然科技股份有限公司 | A kind of plant fibre sheet material production adhesive and application method |
| CN109517404B (en) * | 2018-11-13 | 2021-04-13 | 大自然科技股份有限公司 | Adhesive for plant fiber sheet production and use method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103881628B (en) | 2016-03-30 |
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Effective date of registration: 20191021 Address after: 314502 202a, building B, 369 GONGMAO Avenue, Puyuan Town, Tongxiang City, Jiaxing City, Zhejiang Province Patentee after: Tongxiang Hongchen Industrial Design Co., Ltd Address before: 542800 No. 13 Garden Street, eight steps, the Guangxi Zhuang Autonomous Region, Hezhou Patentee before: Yang Yi |
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