CN103525341A - Acrylate bonding agent - Google Patents

Acrylate bonding agent Download PDF

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Publication number
CN103525341A
CN103525341A CN201310469063.7A CN201310469063A CN103525341A CN 103525341 A CN103525341 A CN 103525341A CN 201310469063 A CN201310469063 A CN 201310469063A CN 103525341 A CN103525341 A CN 103525341A
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CN
China
Prior art keywords
parts
acrylate
tackiness agent
potassium persulphate
polyoxyethylene nonylphenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201310469063.7A
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Chinese (zh)
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CN103525341B (en
Inventor
杨毅
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Panjin Yi Li Kai Tai New Material Co. Ltd.
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杨毅
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Publication date
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Priority to CN201310469063.7A priority Critical patent/CN103525341B/en
Publication of CN103525341A publication Critical patent/CN103525341A/en
Application granted granted Critical
Publication of CN103525341B publication Critical patent/CN103525341B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses an acrylate bonding agent which is characterized by comprising the following components by weight: 90-120 parts of methyl acrylate, 350-400 parts of isobutyl acrylate, 150-200 parts of ethyl acrylate, 15-20 parts of acrylic acid, 13-30 parts of N-methylacrylamide, 700-880 parts of water, 40-60 parts of nonylphenol polyoxyethylene ether, 1-5 parts of sodium metasulfite, and 1-5 parts of potassium peroxodisulfate. The acrylate bonding agent has the advantages of easily-obtained raw materials, low cost, green environmental protection, convenient use and good effect.

Description

CALCIUM ACRYLATE tackiness agent
Technical field
The invention belongs to a kind of tackiness agent.
Background technology
Tackiness agent (Bonding agent) is one of most important subsidiary material, and in package handling, application is very extensive.Tackiness agent is the sticking material of tool, by its viscosity, two kinds of separated materials can be linked together.The kind of tackiness agent is a lot.1. natural glue it be taken from the material of occurring in nature.Comprise the biological adhesives such as starch, protein, dextrin, gelatin, shellac, hide glue, rosin; Also comprise the mineral binders such as pitch.2. artificial tackiness agent this be to use made material, comprise the inorganic adhesives such as water glass, and the organic binder bond such as synthetic resins, synthetic rubber.The features such as splicing (bonding, bonding, cementing, gluing) refers to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together, and has stress distribution continuous, lightweight, or sealing, and most technological temperatures are low.Glued joint the connection that is specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and high-and-new science and technology progress and people's daily life improvement are had to great effect.Therefore, research, all kinds of tackiness agent of development and production are very important.
Through Chinese publication retrieval, do not find the scheme identical with present patent application.
Summary of the invention:
The object of the invention is to; A kind of CALCIUM ACRYLATE tackiness agent is proposed.
CALCIUM ACRYLATE tackiness agent of the present invention, it is characterized in that: by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, water 700-880 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, Potassium Persulphate 1-5 part forms, by methyl acrylate, isobutyl acrylate, ethyl propenoate, vinylformic acid, N-methacrylic acid acid amides, after water heating for dissolving, add polyoxyethylene nonylphenol ether, sodium metabisulphite, Potassium Persulphate, under nitrogen gas sweet smell, at 40-70 ℃, react 120-220 minute, obtain product.
CALCIUM ACRYLATE tackiness agent of the present invention, self-vulcanizing, the shearing resistance of sticky object reaches 35-40Mpa; High strength.
The present invention compared with prior art its beneficial effect is: have raw material and be easy to get, cost is low, and environmental protection is easy to use, effective advantage.
Embodiment:
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited to this.
CALCIUM ACRYLATE tackiness agent of the present invention, raw materials usedly buys acquisition.
Embodiment 1
CALCIUM ACRYLATE tackiness agent of the present invention, it is characterized in that: by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, water 700-880 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, Potassium Persulphate 1-5 part forms, by methyl acrylate, isobutyl acrylate, ethyl propenoate, vinylformic acid, N-methacrylic acid acid amides, after water heating for dissolving, add polyoxyethylene nonylphenol ether, sodium metabisulphite, Potassium Persulphate, under nitrogen gas sweet smell, at 40-70 ℃, react 120-220 minute, obtain product.
Embodiment 2
CALCIUM ACRYLATE tackiness agent of the present invention, it is characterized in that: by weight, by 90 parts of methyl acrylates, 350 parts of isobutyl acrylate, 150 parts of ethyl propenoates, 15 parts, vinylformic acid, 13 parts of N-methacrylic acid acid amides, 700 parts, water, 40 parts of polyoxyethylene nonylphenol ethers, 1 part of sodium metabisulphite, 1 part of composition of Potassium Persulphate, by methyl acrylate, isobutyl acrylate, ethyl propenoate, vinylformic acid, N-methacrylic acid acid amides, after water heating for dissolving, add polyoxyethylene nonylphenol ether, sodium metabisulphite, Potassium Persulphate, under nitrogen gas sweet smell, at 40-70 ℃, react 120-220 minute, obtain product.
Embodiment 3
CALCIUM ACRYLATE tackiness agent of the present invention, it is characterized in that: by weight, by 120 parts of methyl acrylates, 400 parts of isobutyl acrylate, 200 parts of ethyl propenoates, 20 parts, vinylformic acid, 30 parts of N-methacrylic acid acid amides, 880 parts, water, 60 parts of polyoxyethylene nonylphenol ethers, 5 parts of sodium metabisulphites, 5 parts of compositions of Potassium Persulphate, by methyl acrylate, isobutyl acrylate, ethyl propenoate, vinylformic acid, N-methacrylic acid acid amides, after water heating for dissolving, add polyoxyethylene nonylphenol ether, sodium metabisulphite, Potassium Persulphate, under nitrogen gas sweet smell, at 40-70 ℃, react 120-220 minute, obtain product.
Embodiment 4
CALCIUM ACRYLATE tackiness agent of the present invention, it is characterized in that: by weight, by 90 parts of methyl acrylates, 400 parts of isobutyl acrylate, 150 parts of ethyl propenoates, 20 parts, vinylformic acid, 13 parts of N-methacrylic acid acid amides, 700 parts, water, 60 parts of polyoxyethylene nonylphenol ethers, 1 part of sodium metabisulphite, 5 parts of compositions of Potassium Persulphate, by methyl acrylate, isobutyl acrylate, ethyl propenoate, vinylformic acid, N-methacrylic acid acid amides, after water heating for dissolving, add polyoxyethylene nonylphenol ether, sodium metabisulphite, Potassium Persulphate, under nitrogen gas sweet smell, at 40-70 ℃, react 120-220 minute, obtain product.
Embodiment 5
CALCIUM ACRYLATE tackiness agent of the present invention, it is characterized in that: by weight, by 120 parts of methyl acrylates, 350 parts of isobutyl acrylate, 200 parts of ethyl propenoates, 15 parts, vinylformic acid, 30 parts of N-methacrylic acid acid amides, 880 parts, water, 40 parts of polyoxyethylene nonylphenol ethers, 5 parts of sodium metabisulphites, 1 part of composition of Potassium Persulphate, by methyl acrylate, isobutyl acrylate, ethyl propenoate, vinylformic acid, N-methacrylic acid acid amides, after water heating for dissolving, add polyoxyethylene nonylphenol ether, sodium metabisulphite, Potassium Persulphate, under nitrogen gas sweet smell, at 40-70 ℃, react 120-220 minute, obtain product.
CALCIUM ACRYLATE tackiness agent of the present invention, product specification, quality: solid content is more than 80%, and its 1% solution pH value is 7.0-7.5; Viscosity 100-120 centipoise.

Claims (1)

1. a CALCIUM ACRYLATE tackiness agent, it is characterized in that: by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, water 700-880 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, Potassium Persulphate 1-5 part forms, by methyl acrylate, isobutyl acrylate, ethyl propenoate, vinylformic acid, N-methacrylic acid acid amides, after water heating for dissolving, add polyoxyethylene nonylphenol ether, sodium metabisulphite, Potassium Persulphate, under nitrogen gas sweet smell, at 40-70 ℃, react 120-220 minute, obtain product.
CN201310469063.7A 2013-10-10 2013-10-10 CALCIUM ACRYLATE tackiness agent Expired - Fee Related CN103525341B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310469063.7A CN103525341B (en) 2013-10-10 2013-10-10 CALCIUM ACRYLATE tackiness agent

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Application Number Priority Date Filing Date Title
CN201310469063.7A CN103525341B (en) 2013-10-10 2013-10-10 CALCIUM ACRYLATE tackiness agent

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CN103525341A true CN103525341A (en) 2014-01-22
CN103525341B CN103525341B (en) 2016-03-30

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103881626A (en) * 2014-03-20 2014-06-25 杨毅 Tricresyl phosphate heat-resisting acrylic acid adhesive
CN103881628A (en) * 2014-03-20 2014-06-25 杨毅 Decabromodiphenyl ether flame-retardant flocking adhesive

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1280159A (en) * 1999-07-09 2001-01-17 盐城冬阳化工有限公司 Method for low-temperature synthesizing water emulsion type flocking adhesive
CN101230244A (en) * 2008-02-29 2008-07-30 安徽大学 Self-seepage concrete crack repairing glue and method for making same
JP2011093956A (en) * 2009-10-27 2011-05-12 Lintec Corp Water-dispersed acrylic pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet, and method for producing the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1280159A (en) * 1999-07-09 2001-01-17 盐城冬阳化工有限公司 Method for low-temperature synthesizing water emulsion type flocking adhesive
CN101230244A (en) * 2008-02-29 2008-07-30 安徽大学 Self-seepage concrete crack repairing glue and method for making same
JP2011093956A (en) * 2009-10-27 2011-05-12 Lintec Corp Water-dispersed acrylic pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet, and method for producing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103881626A (en) * 2014-03-20 2014-06-25 杨毅 Tricresyl phosphate heat-resisting acrylic acid adhesive
CN103881628A (en) * 2014-03-20 2014-06-25 杨毅 Decabromodiphenyl ether flame-retardant flocking adhesive
CN103881628B (en) * 2014-03-20 2016-03-30 杨毅 The fire-retardant Flock Adhesive stick of decabromodiphynly oxide

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Address after: 542800 Garden Street, eight steps, the Guangxi Zhuang Autonomous Region, Hezhou 1-3

Patentee after: Yang Yi

Address before: 542800, No. 13 West Bay Street, Sai Wan Town, flat, Hezhou, the Guangxi Zhuang Autonomous Region

Patentee before: Yang Yi

TR01 Transfer of patent right

Effective date of registration: 20180821

Address after: 124000 Song Sheng Village 2111020090140207 (Park), Shuang Sheng street, Shuangtaizi District, Panjin, Liaoning.

Patentee after: Panjin Yi Li Kai Tai New Material Co. Ltd.

Address before: 542800 the Guangxi Zhuang Autonomous Region Hezhou eight step area Garden Street 1-3

Patentee before: Yang Yi

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160330

Termination date: 20191010

CF01 Termination of patent right due to non-payment of annual fee