CN109456707A - A kind of adhesive for corrugated board bonding - Google Patents
A kind of adhesive for corrugated board bonding Download PDFInfo
- Publication number
- CN109456707A CN109456707A CN201811466939.1A CN201811466939A CN109456707A CN 109456707 A CN109456707 A CN 109456707A CN 201811466939 A CN201811466939 A CN 201811466939A CN 109456707 A CN109456707 A CN 109456707A
- Authority
- CN
- China
- Prior art keywords
- adhesive
- corrugated board
- board bonding
- agent
- low temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The present invention is used for the adhesive of corrugated board bonding, and adhesive component and mass percent are as follows: cornstarch: 10%~15%；Wheaten starch: 5%~10%；Potato starch: 5%~10%；Glutinous rice flour 3%~8%；Modified compound protein 5%~10%；Vinylacetate 3%~8%；Melamine resin 3%~6%；Sodium hydroxide: 1%~2%；Water-soluble resin: 1%~3%；Dry filler material: 2%~3%；Thermoplastic resin: 1%~2%；Deionized water: surplus.Under the premise of guaranteeing waterproofness and viscosity, it can effectively enhance glue film flexibility, good waterproof performance, glue film flexibility, anti-corrosive properties and elasticity are excellent.To achieve the purpose that novel design, be formulated reasonable and good application effect.
Description
Technical field
The present invention relates to adhesive fields, and in particular to a kind of adhesive for corrugated board bonding.
Background technique
When prior art corrugated paper produces, the adhesive used is that gelatinous substance reacting condition occurs with starch and alkali,
Being formed has tack glue, excellent in view of making that adhesive is environmentally friendly, cheap, bond properties is high, curing time is short with starch etc.
Point is all made of this method in corrugated board industry and is bonded, but occurs a composition shallow lakes different with gelatinization point due to natural environmental-protective
Powder molecular structure difference.Although starch and its derivative, there is good cementability and film forming, be excellent natural resources glue
Glutinous agent, but its waterproofness is poor, and glue film flexibility, anti-corrosive properties and elasticity can not meet the demand developed at present.
Therefore, a kind of adhesive for corrugated paperboard that can overcome prior art difficulty how is researched and developed, is the related people of the industry
Member's technical problem urgently to be resolved.
Summary of the invention
In order to solve the above technical problems, we have proposed a kind of adhesive for corrugated board bonding, good waterproof performance,
Glue film flexibility, anti-corrosive properties and elasticity are excellent.
In order to achieve the above objectives, technical scheme is as follows:
A kind of adhesive for corrugated board bonding, adhesive component and mass percent are as follows:
Cornstarch: 10%~15%；
Wheaten starch: 5%~10%；
Potato starch: 5%~10%；
Glutinous rice flour 3%~8%；
Modified compound protein 5%~10%；
Vinylacetate 3%~8%；
Melamine resin 3%~6%；
Sodium hydroxide: 1%~2%；
Water-soluble resin: 1%~3%；
Dry filler material: 2%~3%；
Thermoplastic resin: 1%~2%；
Deionized water: surplus.
Preferably, the amount that 30% is taken out after the cornstarch, wheaten starch, potato starch and glutinous rice flour mixing, is mixed
Enter 15% pre-gelatinized starch or the former corn flour of pre- paste.
Preferably, ammonium persulfate 1%~2% is also contained in the low-temperature adhesive.
Preferably, borax 2%~4% is also contained in the low-temperature adhesive.
Preferably, nano silica 1%~3% is also contained in the low-temperature adhesive.
Preferably, calcined kaolin 1%~2% is also contained in the low-temperature adhesive.
Preferably, disproportionated rosin 1%~4% is also contained in the low-temperature adhesive.
Preferably, polyvinyl alcohol 1%~5% is also contained in the low-temperature adhesive.
Through the above technical solutions, the present invention is modified using ammonium persulfate, not only oxidation effectiveness is good, and modified compound egg
White, polyvinyl alcohol, vinylacetate, the molten effect of leaching of melamine resin are good, and product solid content is high, and stability is good, and
Cohesive force is strong, and rate of drying is fast, at low cost, and appearance is without precipitating, and not stratified, uniformity is good, and storage cycle is long；Modified compound protein
Not only viscosity is high, and ageing-resistant extremely excellent with waterproof, and not only elasticity is good after solidification, and flexility is excellent, it is corrosion-resistant with it is resistance to
Ageing properties are fabulous, and borax and modified compound protein synergistic effect can effectively improve glutinous rice flour, cornstarch, wheaten starch, horse
The crosslink density of bell sweet potato starch, product adhesion strength, waterproofness and antiseptic property are extremely excellent；And melamine resin can
Effective enhanced article water-resistance cooperates good fluidity with modified compound protein, the mixing with nano silica, calcined kaolin
Uniformity is good, not only can shorten drying time, can under the premise of guaranteeing waterproofness and viscosity with disproportionated rosin mating reaction
Effectively enhancing glue film flexibility, good waterproof performance, glue film flexibility, anti-corrosive properties and elasticity are excellent.To reached it is novel in design,
It is formulated reasonable and good application effect purpose.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
Below with reference to embodiment and specific embodiment, the present invention is described in further detail.
Embodiment 1.
A kind of adhesive for corrugated board bonding, adhesive component and mass percent are as follows:
Cornstarch: 10%；
Wheaten starch: 5%；
Potato starch: 5%；
Glutinous rice flour 3%；
Modified compound protein 5%；
Vinylacetate 3%；
Melamine resin 3%；
Sodium hydroxide: 1%；
Water-soluble resin: 1%；
Dry filler material: 2%；
Thermoplastic resin: 1%；
Ammonium persulfate: 1%；
Borax: 2%；
Nano silica: 1%；
Calcined kaolin: 1%；
Disproportionated rosin: 1%；
Polyvinyl alcohol: 1%；
Deionized water: surplus.
Wherein, 30% amount is taken out after above-mentioned cornstarch, wheaten starch, potato starch and glutinous rice flour mixing, then
It is mixed into 15% pre-gelatinized starch or the former corn flour of pre- paste.
Embodiment 2.
A kind of adhesive for corrugated board bonding, adhesive component and mass percent are as follows:
Cornstarch: 15%；
Wheaten starch: 10%；
Potato starch: 10%；
Glutinous rice flour: 8%；
Modified compound protein: 10%；
Vinylacetate: 8%；
Melamine resin: 6%；
Sodium hydroxide: 2%；
Water-soluble resin: 3%；
Dry filler material: 3%；
Thermoplastic resin: 2%；
Ammonium persulfate: 2%；
Borax: 4%；
Nano silica: 3%；
Calcined kaolin: 2%；
Disproportionated rosin: 4%；
Polyvinyl alcohol: 5%；
Deionized water: surplus.
Wherein, the amount that 30% is taken out after the cornstarch, wheaten starch, potato starch and glutinous rice flour mixing, is mixed into
15% pre-gelatinized starch or the former corn flour of pre- paste.
Embodiment 3.
A kind of adhesive for corrugated board bonding, adhesive component and mass percent are as follows:
Cornstarch: 13%；
Wheaten starch: 8%；
Potato starch: 8%；
Glutinous rice flour 5%；
Modified compound protein 8%；
Vinylacetate 5%；
Melamine resin 5%；
Sodium hydroxide: 1.5%；
Water-soluble resin: 2%；
Dry filler material: 2.5%；
Thermoplastic resin: 1.5%；
Ammonium persulfate: 1.5%；
Borax: 3%；
Nano silica: 2%；
Calcined kaolin: 1.5%；
Disproportionated rosin: 2.5%；
Polyvinyl alcohol: 3%；
Deionized water: surplus.
Wherein, the amount that 30% is taken out after the cornstarch, wheaten starch, potato starch and glutinous rice flour mixing, is mixed into
15% pre-gelatinized starch or the former corn flour of pre- paste.
Moisture quick-drying when low-temperature adhesive of the invention can promote first bonding force and solidification under gelatinization low-temperature condition, solidification
Modification temperature is low, low energy consumption, stability is high, energy-saving, promotes quality.The technical issues of solution is to promote gelatinization low-temperature condition
Under first bonding force and moisture quick-drying when solidification, solidify the fast binder of low modification temperature, low energy consumption, high stability, it is energy saving
Consumption reduction, promotes the quality of production corrugated paper, and the product quality of production has 30% or more in terms of physical property and flatness
Room for promotion, to achieve the purpose that novel design, be formulated reasonable and good application effect.
Above-described is only a kind of adhesive preferred embodiment for corrugated board bonding of the invention, should be referred to
Out, for those of ordinary skill in the art, without departing from the concept of the premise of the invention, can also make several
Modification and improvement, these are all within the scope of protection of the present invention.
Claims (8)
1. a kind of adhesive for corrugated board bonding, which is characterized in that
Its adhesive component and mass percent are as follows:
Cornstarch: 10%~15%；
Wheaten starch: 5%~10%；
Potato starch: 5%~10%；
Glutinous rice flour 3%~8%；
Modified compound protein 5%~10%；
Vinylacetate 3%~8%；
Melamine resin 3%~6%；
Sodium hydroxide: 1%~2%；
Water-soluble resin: 1%~3%；
Dry filler material: 2%~3%；
Thermoplastic resin: 1%~2%；
Deionized water: surplus.
2. a kind of adhesive for corrugated board bonding according to claim 1, which is characterized in that the corn forms sediment
The amount that 30% is taken out after powder, wheaten starch, potato starch and glutinous rice flour mixing, be mixed into 15% pre-gelatinized starch or pre- paste it is former
Corn flour.
3. a kind of adhesive for corrugated board bonding according to claim 1, which is characterized in that the low temperature adhesion
Also contain ammonium persulfate 1%~2% in agent.
4. a kind of adhesive for corrugated board bonding according to claim 1, which is characterized in that the low temperature adhesion
Also contain borax 2%~4% in agent.
5. a kind of adhesive for corrugated board bonding according to claim 1, which is characterized in that the low temperature adhesion
Also contain nano silica 1%~3% in agent.
6. a kind of adhesive for corrugated board bonding according to claim 1, which is characterized in that the low temperature adhesion
Also contain calcined kaolin 1%~2% in agent.
7. a kind of adhesive for corrugated board bonding according to claim 1, which is characterized in that the low temperature adhesion
Also contain disproportionated rosin 1%~4% in agent.
8. a kind of adhesive for corrugated board bonding according to claim 1, which is characterized in that the low temperature adhesion
Also contain polyvinyl alcohol 1%~5% in agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811466939.1A CN109456707A (en) | 2018-12-03 | 2018-12-03 | A kind of adhesive for corrugated board bonding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811466939.1A CN109456707A (en) | 2018-12-03 | 2018-12-03 | A kind of adhesive for corrugated board bonding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109456707A true CN109456707A (en) | 2019-03-12 |
Family
ID=65612287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811466939.1A Pending CN109456707A (en) | 2018-12-03 | 2018-12-03 | A kind of adhesive for corrugated board bonding |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109456707A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111777973A (en) * | 2020-07-08 | 2020-10-16 | 东莞市全泰纸品有限公司 | Glue for bonding corrugated paper and preparation method thereof |
| CN113861857A (en) * | 2021-10-14 | 2021-12-31 | 无锡欣盛包装材料科技有限公司 | Process for quickly and strongly bonding adhesive of paper product |
| CN115868621A (en) * | 2021-09-26 | 2023-03-31 | 安琪酵母股份有限公司 | Food adhesive and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011246510A (en) * | 2010-05-24 | 2011-12-08 | Yayoi Chemical Industry Co Ltd | Adhesive for floor material construction |
| CN103665288A (en) * | 2013-12-11 | 2014-03-26 | 广西大学 | Method for preparing wood adhesive using cassava starch hydrolyzed sugar |
| CN105802544A (en) * | 2016-05-25 | 2016-07-27 | 合肥东彩印刷科技有限公司 | Modified starch adhesive |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
-
2018
- 2018-12-03 CN CN201811466939.1A patent/CN109456707A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011246510A (en) * | 2010-05-24 | 2011-12-08 | Yayoi Chemical Industry Co Ltd | Adhesive for floor material construction |
| CN103665288A (en) * | 2013-12-11 | 2014-03-26 | 广西大学 | Method for preparing wood adhesive using cassava starch hydrolyzed sugar |
| CN105802544A (en) * | 2016-05-25 | 2016-07-27 | 合肥东彩印刷科技有限公司 | Modified starch adhesive |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 塔尔伯特: "《马铃薯生产与食品加工》", 30 January 2017, 上海科学技术出版社 * |
| 王靖哲等: "改性淀粉基木材用环保胶粘剂的合成研究 ", 《中国胶粘剂》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111777973A (en) * | 2020-07-08 | 2020-10-16 | 东莞市全泰纸品有限公司 | Glue for bonding corrugated paper and preparation method thereof |
| CN115868621A (en) * | 2021-09-26 | 2023-03-31 | 安琪酵母股份有限公司 | Food adhesive and application thereof |
| CN113861857A (en) * | 2021-10-14 | 2021-12-31 | 无锡欣盛包装材料科技有限公司 | Process for quickly and strongly bonding adhesive of paper product |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190312 |
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| RJ01 | Rejection of invention patent application after publication |