CN105802544A - Modified starch adhesive - Google Patents

Modified starch adhesive Download PDF

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Publication number
CN105802544A
CN105802544A CN201610369465.3A CN201610369465A CN105802544A CN 105802544 A CN105802544 A CN 105802544A CN 201610369465 A CN201610369465 A CN 201610369465A CN 105802544 A CN105802544 A CN 105802544A
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CN
China
Prior art keywords
parts
modified
starch adhesive
modified starch
borax
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610369465.3A
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Chinese (zh)
Inventor
唐述振
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEFEI DONGCAI PRINTING TECHNOLOGY Co Ltd
Original Assignee
HEFEI DONGCAI PRINTING TECHNOLOGY Co Ltd
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Filing date
Publication date
Application filed by HEFEI DONGCAI PRINTING TECHNOLOGY Co Ltd filed Critical HEFEI DONGCAI PRINTING TECHNOLOGY Co Ltd
Priority to CN201610369465.3A priority Critical patent/CN105802544A/en
Publication of CN105802544A publication Critical patent/CN105802544A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Abstract

The invention discloses a modified starch adhesive.The modified starch adhesive comprises, by weight, 5-15 parts of glutinous rice flour, 10-20 parts of corn starch, 20-40 parts of wheat starch, 10-20 parts of modified composite protein, 1-2 parts of ammonium persulfate, 2-6 parts of sodium hydroxide, 2-5 parts of borax, 1-3 parts of nano-silica, 1-2 parts of calcined kaolin, 1-4 parts of disproportionated rosin, 1-6 parts of polyvinyl alcohol, 5-15 parts of vinyl acetate, 5-10 parts of melamine formaldehyde resin and 50-120 parts of deionized water.The modified starch adhesive is good in waterproof performance and excellent in adhesive film toughness, corrosion resistance and elasticity.

Description

A kind of mongolicum Turcz. with Modified Starch Adhesive
Technical field
The present invention relates to adhesive technical field, particularly relate to a kind of mongolicum Turcz. with Modified Starch Adhesive.
Background technology
In the today emphasizing the strategy of sustainable development, along with the minimizing day by day of petroleum resources, with oil as raw material Chemical products will be replaced by reproducible natural high molecular substance.Based Wood Adhesives such as " three-aldehyde glues " is Synthesized by the monomer of non-renewable resources oil, thus domestic and international researcher is promoted competitively to seek " three aldehyde Glue " succedaneum, starch and derivant thereof have good cementability and film property, are excellent natural resources Adhesive, but its water proofing property is poor, and glued membrane pliability, anti-corrosive properties and elasticity can not meet the demand of development at present.
Summary of the invention
A kind of mongolicum Turcz. with Modified Starch Adhesive, goods good waterproof performance, glued membrane pliability, anti-corrosive properties and elastic excellence.
A kind of mongolicum Turcz. with Modified Starch Adhesive that the present invention proposes, its raw material includes by weight: glutinous rice flour 5-15 part, Corn starch 10-20 part, wheaten starch 20-40 part, modified compound protein 10-20 part, Ammonium persulfate. 1-2 Part, sodium hydroxide 2-6 part, Borax 2-5 part, nano silicon 1-3 part, calcined kaolin 1-2 part, Disproportionated rosin 1-4 part, polyvinyl alcohol 1-6 part, vinylacetate 5-15 part, melamine resin 5-10 Part, deionized water 50-120 part.
Preferably, modified compound protein uses following technique to prepare: by weight by 6-10 part prestox ring four Siloxanes, 0.1-0.5 part initiator DBSA, 0.5-1.2 part emulsifying agent alkylphenol-polyethenoxy Ether, 50-80 part deionized water mix and blend 20-50min, be warming up to 70-75 DEG C, adds 1-4 part hydroxide Potassium continues to stir 1-2h, regulation system pH to neutrality, nitrogen protection lower addition 2-6 part wheat gliadin, 10-20 part Semen arachidis hypogaeae albumen powder, 1-6 part silk fiber, 1-2 part allyltrimethoxysilanis, 0.2-1 part Potassium acid sulfite, 0.02-0.08 part potassium peroxydisulfate, 20-40 part natural emulsion mix and blend 40-100min, Add 0.2-3 part hydroxybutyric acid valeric acid copolyesters, 1-2 part poly-β-hydroxybutyric acid mixing and stirring, be warming up to 150-180 DEG C is continued stirring 20-50min, cooling, and regulation system pH, to neutral, obtains modified compound protein.
Preferably, modified compound protein, the weight ratio of Borax are 14-16:3-4.
Preferably, modified compound protein, the weight ratio of disproportionated rosin are 14-16:2-3.
Preferably, Borax, nano silicon, the weight ratio of calcined kaolin are 3-4:1.5-2:1.3-1.6.
Preferably, modified compound protein, polyvinyl alcohol, vinylacetate, the weight of melamine resin Amount ratio is 14-16:2-4:8-12:6-8.
Preferably, glutinous rice flour, corn starch, the weight ratio of wheaten starch are 10-13:12-15:30-34.
Preferably, described mongolicum Turcz. with Modified Starch Adhesive, its raw material includes by weight: glutinous rice flour 10-13 part, Corn starch 12-15 part, wheaten starch 30-34 part, modified compound protein 14-16 part, Ammonium persulfate. 1.2-1.5 Part, sodium hydroxide 3-4 part, Borax 3-4 part, nano silicon 1.5-2 part, calcined kaolin 1.3-1.6 Part, disproportionated rosin 2-3 part, polyvinyl alcohol 2-4 part, vinylacetate 8-12 part, melamino-formaldehyde tree Fat 6-8 part, deionized water 80-100 part.
Described mongolicum Turcz. with Modified Starch Adhesive uses following technique to prepare: by proportioning by glutinous rice flour, corn starch, Wheaten starch, deionized water, sodium hydroxide mix homogeneously, add Ammonium persulfate. stirring 20-40min, add Modified compound protein, Borax, nano silicon, calcined kaolin, disproportionated rosin, polyvinyl alcohol, vinegar Vinyl acetate mix homogeneously, adds melamine resin stirring 5-20min, obtains mongolicum Turcz. with Modified Starch Adhesive.
In the present invention, with glutinous rice flour, corn starch, wheaten starch major ingredient, after naoh treatment, Employing Ammonium persulfate. is modified, and not only oxidation effectiveness is good, and modified compound protein, polyvinyl alcohol, vinyl acetate Ester, melamine resin leaching molten effective, goods solid content is high, good stability, and cohesive force is strong, Rate of drying is fast, low cost, and outward appearance is without precipitation, and not stratified, uniformity is good, and storage cycle is long；Wherein, Modified compound protein not only viscosity is high, and ageing-resistant and waterproof extremely excellent, wherein wheat gliadin, flower Raw egg white lead, silk fiber through hydroxybutyric acid valeric acid copolyesters, poly-β-hydroxybutyric acid at prestox ring four silica Alkane, allyltrimethoxysilanis build space frame structure, can effectively accommodate glutinous rice flour, corn starch, Wheaten starch and Borax, nano silicon, calcined kaolin, not only good springiness after solidification, and pliability Can be excellent, corrosion-resistant fabulous with ageing-resistant performance, Borax and modified compound protein synergism, can effectively carry High glutinous rice flour, corn starch, the crosslink density of wheaten starch, goods adhesion strength, water proofing property and anti-corrosive properties Can be extremely excellent；And melamine resin can effectively strengthen goods water-resistance, join with modified compound protein Close good fluidity, good with the mixing uniformity of nano silicon, calcined kaolin, not only can shorten dry Time, with disproportionated rosin mating reaction, on the premise of ensureing water proofing property and viscosity, can effectively strengthen glued membrane Pliability.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of mongolicum Turcz. with Modified Starch Adhesive, its raw material includes by weight: glutinous rice flour 15 parts, corn starch 10 Part, wheaten starch 40 parts, modified compound protein 10 parts, Ammonium persulfate. 2 parts, sodium hydroxide 2 parts, boron 5 parts of sand, nano silicon 1 part, calcined kaolin 2 parts, disproportionated rosin 1 part, polyvinyl alcohol 6 parts, Vinylacetate 5 parts, melamine resin 10 parts, deionized water 50 parts.
Embodiment 2
A kind of mongolicum Turcz. with Modified Starch Adhesive, its raw material includes by weight: glutinous rice flour 5 parts, corn starch 20 parts, Wheaten starch 20 parts, modified compound protein 20 parts, Ammonium persulfate. 1 part, sodium hydroxide 6 parts, Borax 2 Part, nano silicon 3 parts, calcined kaolin 1 part, disproportionated rosin 4 parts, polyvinyl alcohol 1 part, vinegar Vinyl acetate 15 parts, melamine resin 5 parts, deionized water 120 parts.
Embodiment 3
A kind of mongolicum Turcz. with Modified Starch Adhesive, its raw material includes by weight: glutinous rice flour 13 parts, corn starch 12 Part, wheaten starch 34 parts, modified compound protein 14 parts, Ammonium persulfate. 1.5 parts, sodium hydroxide 3 parts, Borax 4 parts, nano silicon 1.5 parts, calcined kaolin 1.6 parts, disproportionated rosin 2 parts, polyethylene Alcohol 4 parts, vinylacetate 8 parts, melamine resin 8 parts, deionized water 80 parts.
Modified compound protein uses following technique to prepare: by weight by 10 parts of octamethylcy-clotetrasiloxanes, 0.1 Part initiator DBSA, 1.2 parts of emulsifying agent alkylphenol polyoxyethylene, 50 parts of deionized waters mix Close stirring 50min, be warming up to 70 DEG C, adds 4 parts of potassium hydroxide and continue stirring 1h, regulation system pH extremely in Property, nitrogen protection is lower add 6 portions of wheat gliadins, 10 parts of Semen arachidis hypogaeae albumen powder, 6 parts of silk fibers, 1 part Allyltrimethoxysilanis, 1 part of Potassium acid sulfite, 0.02 part of potassium peroxydisulfate, 40 parts of natural emulsion mixing Stirring 40min, adds 3 parts of hydroxybutyric acid valeric acid copolyesters, 1 part of poly-β-hydroxybutyric acid mixing and stirring, Being warming up to 180 DEG C and continue stirring 20min, cooling, regulation system pH, to neutral, obtains modified compound protein.
Embodiment 4
A kind of mongolicum Turcz. with Modified Starch Adhesive, its raw material includes by weight: glutinous rice flour 10-13 part, corn starch 15 parts, wheaten starch 30 parts, modified compound protein 16 parts, Ammonium persulfate. 1.2 parts, sodium hydroxide 4 parts, Borax 3 parts, nano silicon 2 parts, calcined kaolin 1.3 parts, disproportionated rosin 3 parts, polyvinyl alcohol 2 Part, vinylacetate 12 parts, melamine resin 6 parts, deionized water 100 parts.
Modified compound protein uses following technique to prepare: by weight by 6 parts of octamethylcy-clotetrasiloxanes, 0.5 Part initiator DBSA, 0.5 part of emulsifying agent alkylphenol polyoxyethylene, 80 parts of deionized waters mix Close stirring 20min, be warming up to 75 DEG C, adds 1 part of potassium hydroxide and continue stirring 2h, regulation system pH extremely in Property, nitrogen protection is lower add 2 portions of wheat gliadins, 20 parts of Semen arachidis hypogaeae albumen powder, 1 part of silk fiber, 2 parts Allyltrimethoxysilanis, 0.2 part of Potassium acid sulfite, 0.08 part of potassium peroxydisulfate, 20 parts of natural emulsions mix Close stirring 100min, add 0.2 part of hydroxybutyric acid valeric acid copolyesters, 2 parts of poly-β-hydroxybutyric acid mix and blends Uniformly, being warming up to 150 DEG C and continue stirring 50min, cooling, regulation system pH, to neutral, obtains modified multiple Hop protein.
Embodiment 5
A kind of mongolicum Turcz. with Modified Starch Adhesive, its raw material includes by weight: glutinous rice flour 12 parts, corn starch 13 Part, wheaten starch 32 parts, modified compound protein 15 parts, Ammonium persulfate. 1.35 parts, sodium hydroxide 3.8 parts, Borax 3.5 parts, nano silicon 1.8 parts, calcined kaolin 1.4 parts, disproportionated rosin 2.5 parts, poly- Vinyl alcohol 3 parts, vinylacetate 10 parts, melamine resin 7 parts, deionized water 90 parts.
Modified compound protein uses following technique to prepare: by weight by 8 parts of octamethylcy-clotetrasiloxanes, 0.3 Part initiator DBSA, 0.85 part of emulsifying agent alkylphenol polyoxyethylene, 70 parts of deionized waters mix Closing stirring 32min, be warming up to 73 DEG C, add 2 parts of potassium hydroxide and continue stirring 1.5h, regulation system pH is extremely Neutrality, nitrogen protection is lower add 4 portions of wheat gliadins, 14 parts of Semen arachidis hypogaeae albumen powder, 3 parts of silk fibers, 1.5 parts of allyltrimethoxysilanis, 0.6 part of Potassium acid sulfite, 0.06 part of potassium peroxydisulfate, 32 parts natural Latex mix and blend 80min, adds 1.5 parts of hydroxybutyric acid valeric acid copolyesters, 1.6 parts of poly-β-hydroxybutyric acids mix Conjunction stirs, and is warming up to 160 DEG C and continues stirring 32min, cooling, and regulation system pH, to neutral, obtains Modified compound protein.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention Within the scope of.

Claims (8)

1. a mongolicum Turcz. with Modified Starch Adhesive, it is characterised in that its raw material includes by weight: glutinous rice flour 5-15 Part, corn starch 10-20 part, wheaten starch 20-40 part, modified compound protein 10-20 part, persulfuric acid Ammonium 1-2 part, sodium hydroxide 2-6 part, Borax 2-5 part, nano silicon 1-3 part, calcined kaolin 1-2 part, disproportionated rosin 1-4 part, polyvinyl alcohol 1-6 part, vinylacetate 5-15 part, tripolycyanamide first Urea formaldehyde 5-10 part, deionized water 50-120 part.
Mongolicum Turcz. with Modified Starch Adhesive the most according to claim 1, it is characterised in that modified compound protein is adopted Prepare by following technique: by weight by 6-10 part octamethylcy-clotetrasiloxane, 0.1-0.5 part initiator ten The mixing of dialkyl benzene sulfonic acids, 0.5-1.2 part emulsifying agent alkylphenol polyoxyethylene, 50-80 part deionized water is stirred Mix 20-50min, be warming up to 70-75 DEG C, add 1-4 part potassium hydroxide and continue stirring 1-2h, regulation system PH is to neutral, and nitrogen protection is lower adds 2-6 part wheat gliadin, 10-20 part Semen arachidis hypogaeae albumen powder, 1-6 Part silk fiber, 1-2 part allyltrimethoxysilanis, 0.2-1 part Potassium acid sulfite, 0.02-0.08 part Potassium peroxydisulfate, 20-40 part natural emulsion mix and blend 40-100min, add 0.2-3 part hydroxybutyric acid valeric acid Copolyesters, 1-2 part poly-β-hydroxybutyric acid mixing and stirring, be warming up to 150-180 DEG C and continue stirring 20-50min, cooling, regulation system pH, to neutral, obtains modified compound protein.
Mongolicum Turcz. with Modified Starch Adhesive the most according to claim 1 and 2, it is characterised in that modified compound egg In vain, the weight ratio of Borax is 14-16:3-4.
4. according to the mongolicum Turcz. with Modified Starch Adhesive described in any one of claim 1-3, it is characterised in that modified multiple Hop protein, the weight ratio of disproportionated rosin are 14-16:2-3.
5. according to the mongolicum Turcz. with Modified Starch Adhesive described in any one of claim 1-4, it is characterised in that Borax, Nano silicon, the weight ratio of calcined kaolin are 3-4:1.5-2:1.3-1.6.
6. according to the mongolicum Turcz. with Modified Starch Adhesive described in any one of claim 1-5, it is characterised in that modified multiple Hop protein, polyvinyl alcohol, vinylacetate, the weight ratio of melamine resin are 14-16:2-4: 8-12:6-8.
7. according to the mongolicum Turcz. with Modified Starch Adhesive described in any one of claim 1-6, it is characterised in that glutinous rice flour, Corn starch, the weight ratio of wheaten starch are 10-13:12-15:30-34.
8. according to the mongolicum Turcz. with Modified Starch Adhesive described in any one of claim 1-7, it is characterised in that its raw material Include by weight: glutinous rice flour 10-13 part, corn starch 12-15 part, wheaten starch 30-34 part, change Property compound protein 14-16 part, Ammonium persulfate. 1.2-1.5 part, sodium hydroxide 3-4 part, Borax 3-4 part, Nano silicon 1.5-2 part, calcined kaolin 1.3-1.6 part, disproportionated rosin 2-3 part, polyvinyl alcohol 2-4 part, vinylacetate 8-12 part, melamine resin 6-8 part, deionized water 80-100 part.
CN201610369465.3A 2016-05-25 2016-05-25 Modified starch adhesive Pending CN105802544A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281111A (en) * 2016-08-29 2017-01-04 昆山鸣朋纸业有限公司 A kind of low-temperature adhesive for corrugated board bonding and processing technology thereof
CN106638159A (en) * 2016-11-29 2017-05-10 安徽索亚装饰材料有限公司 Temperature-resistant and flame-retardant PVC wallpaper
CN107083724A (en) * 2017-04-21 2017-08-22 周益铭 A kind of preparation method of paper pulp moulded packaging material
CN107201192A (en) * 2017-04-27 2017-09-26 深圳九州十里古镇文化旅游发展有限公司 A kind of ecological vegetable glue and preparation method thereof, application
CN107345120A (en) * 2017-06-14 2017-11-14 安徽友捷包装材料有限公司 A kind of Quick-drying type starch tackiness agent and preparation method thereof
CN108378604A (en) * 2018-04-29 2018-08-10 上海前引科技有限公司 A kind of environmental and ecological anion solid wood granule furniture-plates
CN108864983A (en) * 2018-07-02 2018-11-23 郭庆平 A kind of Environment-friendlyglue glue and preparation method thereof
CN109456707A (en) * 2018-12-03 2019-03-12 太仓适度纸业包装有限公司 A kind of adhesive for corrugated board bonding
CN111592831A (en) * 2019-02-20 2020-08-28 深圳市前海慧龙环保科技有限公司 Manufacturing process of low-temperature adhesive for bonding corrugated boards
CN111674099A (en) * 2020-06-17 2020-09-18 广东天元实业集团股份有限公司 Environment-friendly packaging bag and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1181406A (en) * 1996-10-31 1998-05-13 普雷马克Rwp控股公司 Adhesive for bonding decorative melamine treated paper to particle board
CN103275647A (en) * 2013-06-04 2013-09-04 伍淑华 Method for preparing modified quickly dried waterproof starch adhesive
CN103694489A (en) * 2013-12-10 2014-04-02 张亚丽 Method for modifying natural emulsion through pulullan-alcohol soluble protein

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1181406A (en) * 1996-10-31 1998-05-13 普雷马克Rwp控股公司 Adhesive for bonding decorative melamine treated paper to particle board
CN103275647A (en) * 2013-06-04 2013-09-04 伍淑华 Method for preparing modified quickly dried waterproof starch adhesive
CN103694489A (en) * 2013-12-10 2014-04-02 张亚丽 Method for modifying natural emulsion through pulullan-alcohol soluble protein

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281111A (en) * 2016-08-29 2017-01-04 昆山鸣朋纸业有限公司 A kind of low-temperature adhesive for corrugated board bonding and processing technology thereof
CN106638159A (en) * 2016-11-29 2017-05-10 安徽索亚装饰材料有限公司 Temperature-resistant and flame-retardant PVC wallpaper
CN106638159B (en) * 2016-11-29 2019-02-15 安徽索亚装饰材料有限公司 A kind of PVC wallpaper of heatproof flame-retardant
CN107083724A (en) * 2017-04-21 2017-08-22 周益铭 A kind of preparation method of paper pulp moulded packaging material
CN107083724B (en) * 2017-04-21 2018-08-03 宜兴市新天地包装制品有限公司 A kind of preparation method of paper pulp moulded packaging material
CN107201192A (en) * 2017-04-27 2017-09-26 深圳九州十里古镇文化旅游发展有限公司 A kind of ecological vegetable glue and preparation method thereof, application
CN107345120A (en) * 2017-06-14 2017-11-14 安徽友捷包装材料有限公司 A kind of Quick-drying type starch tackiness agent and preparation method thereof
CN108378604A (en) * 2018-04-29 2018-08-10 上海前引科技有限公司 A kind of environmental and ecological anion solid wood granule furniture-plates
CN108864983A (en) * 2018-07-02 2018-11-23 郭庆平 A kind of Environment-friendlyglue glue and preparation method thereof
CN109456707A (en) * 2018-12-03 2019-03-12 太仓适度纸业包装有限公司 A kind of adhesive for corrugated board bonding
CN111592831A (en) * 2019-02-20 2020-08-28 深圳市前海慧龙环保科技有限公司 Manufacturing process of low-temperature adhesive for bonding corrugated boards
CN111674099A (en) * 2020-06-17 2020-09-18 广东天元实业集团股份有限公司 Environment-friendly packaging bag and preparation method thereof

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Application publication date: 20160727