CN106085289A - Environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof - Google Patents
Environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106085289A CN106085289A CN201610595737.1A CN201610595737A CN106085289A CN 106085289 A CN106085289 A CN 106085289A CN 201610595737 A CN201610595737 A CN 201610595737A CN 106085289 A CN106085289 A CN 106085289A
- Authority
- CN
- China
- Prior art keywords
- starch
- low temperature
- adhesive
- environment
- corrugated board
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/10—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof, starch adhesive is made up of the raw material of following components and weight portion: starch: 15～30, water: 60～80, sodium hydroxide: 0.2～1, oxidant: 0.05～0.2, cross-linking agent: 0.1～0.5, tranquilizer: 0.1～0.5, drier: 2～10, reinforcing agent: 1～5, penetrating agent: 0.1～1.The present invention oxidation by oxidant, on starch molecular chain, in addition to hydroxyl, adds the group such as carboxyl, carbonyl, improves the tack of adhesive, reduce spread, beneficially rapid draing；By adding penetrating agent, adhesive rapid osmotic paper can be made, destroy fiber；Adhesive can be made from crosslinking formation three-dimensional-structure in moment by adding cross-linking agent and reinforcing agent, promote adhesive quick-drying, also can crosslink reaction with the group on paper fiber, thus improve the water repelling property of bonding strength and cardboard；The rate of drying of starch adhesive can be improved by adding drier, thus reduce the steam pressure of paper machine.
Description
Technical field
The present invention relates to a kind of starch adhesive, especially relate to a kind of environment-friendly type corrugated board low temperature laminating starch gluing
Agent and preparation method thereof.
Background technology
At present, the adhesive used by corrugated board production, mostly use starch adhesive, its raw material sources are extensive, glue
Technique is simple, substantially by water, starch, alkali, Borax, stabilizer, forms by certain proportioning, a definite sequence stirring reaction, but
Having that rate of drying is slow, speed is slow, water-resistance is poor in actual use, the corrugated board of production easily gets damp and feels like jelly, thus
Causing adhesion strength to decline, side pressure strength declines.Using common starch adhesive to produce corrugated board also has a comparison to dash forward
The shortcoming gone out is, required steam pressure is high, and energy consumption is big, and producing three ply board steam pressure needs 6～7 kilograms, five laminates
Steam pressure is up to 8～9 kilograms, and this energy-saving and emission-reduction policy existing with China runs in the opposite direction.
Chinese invention patent CN1438284, open a kind of one side and corrugated paper board production line water-resistant type amylum adhesive
And preparation method, it is characterized in water, starch, Borax, sodium hydroxide, melamine resin, phenolic resin, styrene-acrylic emulsion, pure
Acrylic emulsion stirring reaction forms；This adhesive described in invention has water-fast and humidity resistance, but, rate of drying phase during use
To relatively slow, paper machine steam pressure is high, and energy consumption is big.
Chinese invention patent 201010213557.5, discloses a kind of binding agent for high-strength waterproof corrugated cases, and this glues
In mixture, Ingredients Weight proportioning is: corn starch 15～25 parts, water 75～80 parts, sheet alkali 0.1～0.4 part, Borax 0.3～0.6
Part, Booster 0.5～1.2 parts, this adhesive water-tolerant described in invention, but, it is poor to there is component compatibility in adhesive, holds
Easily layering.
Summary of the invention
Defect that the purpose of the present invention is contemplated to overcome above-mentioned prior art to exist and a kind of environment-friendly type corrugated paper is provided
Plate low temperature laminating starch adhesive and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive, is made up of the raw material of following components and weight portion:
Starch: 15～30, water: 60～80, sodium hydroxide: 0.2～1, oxidant: 0.05～0.2, cross-linking agent: 0.1～0.5, stable
Agent: 0.1～0.5, drier: 2～10, reinforcing agent: 1～5, penetrating agent: 0.1～1.
One or more in corn starch, tapioca, potato starch or wheaten starch of described starch are mixed
Compound.
Described oxidant is selected from Ammonium persulfate., potassium peroxydisulfate or the mixture of one or more of hydrogen peroxide.
The described cross-linking agent mixture of one or more in Borax, boric acid, zirconium carbonate ammonium or potassium zirconium carbonate.
The described tranquilizer mixture of one or more in magnesium sulfate, magnesium chloride or citric acid.
The described drier mixture of one or more in calcium carbonate, silicon dioxide, triple superphosphate or bentonite.
Described reinforcing agent is selected from Lauxite, melamine resin, epoxy resin or polyurethane resin
Kind or several mixture.
Described penetrating agent is selected from NPE (TX-10), fatty alcohol-polyoxyethylene ether (AEO-09), poly-second
The mixture of one or more in glycol or polypropylene glycol.
The preparation method of described environment-friendly type corrugated board low temperature laminating starch adhesive, comprises the following steps:
The first step: by weight by starch 15～30 parts, water 60～80 parts mix homogeneously in a kettle., then heat to
40～45 DEG C, addition oxidant 0.05～0.2 part, react 30～60 minutes, obtain Oxytarch；
Second step: adding in above-mentioned Oxytarch by sodium hydroxide 0.2～1 part by weight, the viscosity of liquid is stuck with paste in detection, when
When viscosity reaches 15 seconds～35 seconds, add tranquilizer 0.1～0.5 part, cross-linking agent 0.1～0.5 part, drier 2～10 parts, strengthen
Agent 1～5 parts and penetrating agent 0.1～1 part, stir, prepare environment-friendly type corrugated board low temperature laminating starch adhesive.Its
In, viscosity uses and is coated with 4 glasss of mensuration.
The application process that described environment-friendly type corrugated board low temperature laminating starch adhesive is general: be transported to the paste of production line
In groove, by, on the upper paste roller coating stupefied peak of corrugated paper, heating up, gelatinizing, complete laminating.
By the oxidation of oxidant, on starch molecular chain, in addition to hydroxyl, add the group such as carboxyl, carbonyl, improve
The tack of adhesive, reduces spread, beneficially rapid draing；By adding penetrating agent, adhesive rapid osmotic can be made
Paper, destroys fiber；Adhesive can be made to crosslink formation build knot from moment by adding cross-linking agent and reinforcing agent
Structure, promotes adhesive quick-drying, meanwhile, also can crosslink reaction with the group on paper fiber, thus improve bonding strength and paper
The water repelling property of plate；The rate of drying of starch adhesive can be improved by adding drier, just can make starch with less heat
Stick with paste and be dried, thus reduce the steam pressure of paper machine.
Compared with prior art, advantages of the present invention and having the beneficial effects that:
1, during preparing adhesive, add oxidant and starch molecule is aoxidized, make to add on starch molecular chain
The group such as carboxyl, carbonyl, improves the tack of amylan, it is possible to reduce the spread of laminating, beneficially rapid draing.
2, adhesive adds penetrating agent, starch adhesive can be made to penetrate in paper, destroy fiber, improve laminating strong
Degree.
3, adhesive can be made to crosslink formation three-dimensional-structure from moment by addition cross-linking agent and reinforcing agent,
Promote adhesive quick-drying, meanwhile, also can crosslink reaction with the group on paper fiber, thus improve bonding strength and cardboard
Water repelling property.
4, the rate of drying of starch adhesive can be improved by adding drier, gelatinized corn starch just can be made with less heat to do
Dry, thus reduce the steam pressure of paper machine.
5, the present invention is mainly composed of starch and water, and the additive of selection mostly is the chemical substance that environmental-protecting performance is excellent, makes
Obtain corrugated board low temperature laminating starch adhesive good environmental protection.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
The basic preparation technology of each embodiment of the present invention is, starch and water, through metering, are added in reactor, fill by raw material
Divide stirring, be warming up to 40～45 DEG C, add oxidant, react 30～60 minutes, obtain Oxytarch, be subsequently adding hydroxide
Sodium, follows the tracks of the viscosity sticking with paste liquid, when viscosity reaches 15 seconds～35 seconds, adds tranquilizer, cross-linking agent, drier, reinforcing agent and oozes
Agent thoroughly, stirs, and prepares corrugated board low temperature laminating starch adhesive.
General application process: be transported in the paste groove of production line, by, on the upper paste roller coating stupefied peak of corrugated paper, heating up,
Gelatinizing, completes laminating.
In following example, viscosity all uses 4 glasss of mensuration of painting.
Embodiment 1
20 parts of (weight) starch and 70 parts of water (weight) are added in reactor, is sufficiently stirred for, is warming up to 40～45 DEG C, adds
Enter 0.1 part of (weight) hydrogen peroxide, react 45 minutes, obtain Oxytarch, be subsequently adding 0.9 part of (weight) sodium hydroxide, follow the tracks of
Stick with paste the viscosity of liquid, when viscosity reaches 20 seconds, add 0.5 part of (weight) magnesium sulfate, 0.5 part of (weight) Borax, 5 parts of (weight) carbon
Acid calcium, 2.5 parts of (weight) Lauxites and 0.5 part of (weight) TX-10, stir, obtain starch adhesive.
Application effect: this starch adhesive tack is strong, during the cardboard posted with this bonding agent, three ply board paper machine steam
Pressure is down to 5 kilograms from 7 kilograms, and five laminate paper machine steam pressures are down to 7 kilograms from 9 kilograms.
Embodiment 2
25 parts of (weight) starch and 65 parts of water (weight) are added in reactor, is sufficiently stirred for, is warming up to 40～45 DEG C, adds
Enter 0.05 part of (weight) sodium peroxydisulfate, react 30 minutes, obtain Oxytarch, be subsequently adding 0.95 part of (weight) sodium hydroxide,
Follow the tracks of the viscosity sticking with paste liquid, when viscosity reaches 25 seconds, add 0.75 part of (weight) magnesium sulfate, 0.75 part of (weight) boric acid, 4 parts
(weight) triple superphosphate, 3.5 parts of (weight) melamine resins and 0.5 part of (weight) AEO-09, stir, obtain amylan
Stick.
Application effect: this starch adhesive tack is strong, during the cardboard posted with this bonding agent, three ply board paper machine steam
Pressure is down to 4 kilograms from 7 kilograms, and five laminate paper machine steam pressures are down to 6 kilograms from 9 kilograms.
Embodiment 3
20 parts of (weight) starch and 60 parts of water (weight) are added in reactor, is sufficiently stirred for, is warming up to 40～45 DEG C, adds
Enter 0.1 part of (weight) potassium peroxydisulfate, react 60 minutes, obtain Oxytarch, be subsequently adding 0.9 part of (weight) sodium hydroxide, with
Track sticks with paste the viscosity of liquid, when viscosity reaches 30 seconds, adds 0.5 part of (weight) magnesium chloride, 0.5 part of (weight) boric acid, 5 parts (weight)
Calcium carbonate, 5 parts of (weight) bentonite, 2.5 parts of (weight) epoxy resin and 0.5 part of (weight) TX-10, stir, formed sediment
Arogel stick.
Application effect: this starch adhesive tack is strong, during the cardboard posted with this bonding agent, three ply board paper machine steam
Pressure is down to 3.5 kilograms from 7 kilograms, and five laminate paper machine steam pressures are down to 5 kilograms from 9 kilograms.
Embodiment 4
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive, is made up of the raw material of following components and weight portion:
Starch (tapioca): 15, water: 60, sodium hydroxide: 0.2, oxidant (Ammonium persulfate .): 0.05, cross-linking agent (boron
Sand): 0.1, tranquilizer (magnesium sulfate): 0.1, drier (calcium carbonate): 2, reinforcing agent (Lauxite): 1, penetrating agent (nonyl phenol
Polyoxyethylene ether): 0.1.
Preparation method, comprises the following steps:
The first step: by weight by starch 15 parts, 60 parts of water mix homogeneously in a kettle., then heat to 40 DEG C, add
Enter oxidant 0.05 part, react 30 minutes, obtain Oxytarch；
Second step: adding in above-mentioned Oxytarch by sodium hydroxide 0.2 part by weight, the viscosity of liquid is stuck with paste in detection, when viscous
When degree reaches 15 seconds, add tranquilizer 0.1 part, cross-linking agent 0.1 part, drier 2 parts, reinforcing agent 1 part and penetrating agent 0.1 part, stir
Mix uniformly, prepare environment-friendly type corrugated board low temperature laminating starch adhesive.
Application effect: this starch adhesive tack is strong, during the cardboard posted with this bonding agent, three ply board paper machine steam
Pressure is down to 3.5 kilograms from 7 kilograms, and five laminate paper machine steam pressures are down to 5.5 kilograms from 9 kilograms.
The application process that prepared environment-friendly type corrugated board low temperature laminating starch adhesive is general: be transported to the paste of production line
In groove, by, on the upper paste roller coating stupefied peak of corrugated paper, heating up, gelatinizing, complete laminating.
Embodiment 5
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive, is made up of the raw material of following components and weight portion:
Starch (potato starch): 20, water: 70, sodium hydroxide: 0.6, oxidant (potassium peroxydisulfate): 0.1, cross-linking agent (boron
Acid): 0.3, tranquilizer (magnesium chloride): 0.3, drier (silicon dioxide): 6, reinforcing agent (melamine resin): 3, infiltration
Agent (fatty alcohol-polyoxyethylene ether): 0.5.
Preparation method, comprises the following steps:
The first step: by weight by starch 20 parts, 70 parts of water mix homogeneously in a kettle., then heat to 43 DEG C, add
Enter oxidant 0.1 part, react 45 minutes, obtain Oxytarch；
Second step: adding in above-mentioned Oxytarch by sodium hydroxide 0.6 part by weight, the viscosity of liquid is stuck with paste in detection, when viscous
When degree reaches 25 seconds, add tranquilizer 0.3 part, cross-linking agent 0.3 part, drier 6 parts, reinforcing agent 3 parts and penetrating agent 0.5 part, stir
Mix uniformly, prepare environment-friendly type corrugated board low temperature laminating starch adhesive.
Application effect: this starch adhesive tack is strong, during the cardboard posted with this bonding agent, three ply board paper machine steam
Pressure is down to 4.5 kilograms from 7 kilograms, and five laminate paper machine steam pressures are down to 6.5 kilograms from 9 kilograms.
The application process that prepared environment-friendly type corrugated board low temperature laminating starch adhesive is general: be transported to the paste of production line
In groove, by, on the upper paste roller coating stupefied peak of corrugated paper, heating up, gelatinizing, complete laminating.
Embodiment 6
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive, is made up of the raw material of following components and weight portion:
Starch (wheaten starch): 30, water: 80, sodium hydroxide: 1, oxidant (hydrogen peroxide): 0.2, cross-linking agent (zirconium carbonate
Potassium): 0.5, tranquilizer (citric acid): 0.5, drier (bentonite): 10, reinforcing agent (polyurethane resin): 5, penetrating agent (poly-third
Glycol): 1.
Preparation method, comprises the following steps:
The first step: by weight by starch 30 parts, 80 parts of water mix homogeneously in a kettle., then heat to 45 DEG C, add
Enter oxidant 0.2 part, react 60 minutes, obtain Oxytarch；
Second step: adding in above-mentioned Oxytarch by sodium hydroxide 1 part by weight, the viscosity of liquid is stuck with paste in detection, works as viscosity
When reaching 35 seconds, adding tranquilizer 0.5 part, cross-linking agent 0.5 part, drier 10 parts, reinforcing agent 5 parts and penetrating agent 1 part, stirring is all
Even, prepare environment-friendly type corrugated board low temperature laminating starch adhesive.
Application effect: this starch adhesive tack is strong, during the cardboard posted with this bonding agent, three ply board paper machine steam
Pressure is down to 5 kilograms from 7 kilograms, and five laminate paper machine steam pressures are down to 7 kilograms from 9 kilograms.
The application process that prepared environment-friendly type corrugated board low temperature laminating starch adhesive is general: be transported to the paste of production line
In groove, by, on the upper paste roller coating stupefied peak of corrugated paper, heating up, gelatinizing, complete laminating.
The above-mentioned description to embodiment is to be understood that for ease of those skilled in the art and use invention.
These embodiments obviously easily can be made various amendment by person skilled in the art, and described herein typically
Principle is applied in other embodiments without through performing creative labour.Therefore, the invention is not restricted to above-described embodiment, ability
Field technique personnel should be the present invention's according to the announcement of the present invention, the improvement made without departing from scope and amendment
Within protection domain.
Claims (9)
1. environment-friendly type corrugated board low temperature laminating starch adhesive, it is characterised in that by following components and weight portion
Raw material is made:
Starch: 15～30,
Water: 60～80,
Sodium hydroxide: 0.2～1,
Oxidant: 0.05～0.2,
Cross-linking agent: 0.1～0.5,
Tranquilizer: 0.1～0.5,
Drier: 2～10,
Reinforcing agent: 1～5,
Penetrating agent: 0.1～1.
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive the most according to claim 1, it is characterised in that described
One or more mixture in corn starch, tapioca, potato starch or wheaten starch of starch.
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive the most according to claim 1, it is characterised in that described
Oxidant selected from Ammonium persulfate., potassium peroxydisulfate or the mixture of one or more of hydrogen peroxide.
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive the most according to claim 1, it is characterised in that described
The cross-linking agent mixture of one or more in Borax, boric acid, zirconium carbonate ammonium or potassium zirconium carbonate.
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive the most according to claim 1, it is characterised in that described
The tranquilizer mixture of one or more in magnesium sulfate, magnesium chloride or citric acid.
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive the most according to claim 1, it is characterised in that described
The drier mixture of one or more in calcium carbonate, silicon dioxide, triple superphosphate or bentonite.
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive the most according to claim 1, it is characterised in that described
The reinforcing agent one or more mixed in Lauxite, melamine resin, epoxy resin or polyurethane resin
Compound.
A kind of environment-friendly type corrugated board low temperature laminating starch adhesive the most according to claim 1, it is characterised in that described
Penetrating agent in NPE, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol or polypropylene glycol one or more
Mixture.
9. the preparation side of the environment-friendly type corrugated board low temperature laminating starch adhesive as according to any one of claim 1-8
Method, it is characterised in that the method comprises the following steps:
The first step: by weight by starch 15～30 parts, water 60～80 parts mix homogeneously in a kettle., then heat to 40～
45 DEG C, addition oxidant 0.05～0.2 part, react 30～60 minutes, obtain Oxytarch；
Second step: adding in above-mentioned Oxytarch by sodium hydroxide 0.2～1 part by weight, the viscosity of liquid is stuck with paste in detection, works as viscosity
When reaching 15 seconds～35 seconds, add tranquilizer 0.1～0.5 part, cross-linking agent 0.1～0.5 part, drier 2～10 parts, reinforcing agent 1
～5 parts and penetrating agent 0.1～1 part, stir, prepare environment-friendly type corrugated board low temperature laminating starch adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610595737.1A CN106085289A (en) | 2016-07-26 | 2016-07-26 | Environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610595737.1A CN106085289A (en) | 2016-07-26 | 2016-07-26 | Environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106085289A true CN106085289A (en) | 2016-11-09 |
Family
ID=57449606
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610595737.1A Pending CN106085289A (en) | 2016-07-26 | 2016-07-26 | Environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106085289A (en) |
Cited By (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753041A (en) * | 2016-12-15 | 2017-05-31 | 吴定财 | A kind of wood adhesive composition, preparation method and bonding wood method |
| CN106753036A (en) * | 2016-12-16 | 2017-05-31 | 山东叶华纸制品包装有限公司 | A kind of carton glue and preparation method thereof |
| CN106947410A (en) * | 2017-03-30 | 2017-07-14 | 宝艺新材料股份有限公司 | One kind is used for corrugated paper board production line low-temperature quick-drying type starch adhesive and preparation method thereof |
| CN106947411A (en) * | 2017-03-09 | 2017-07-14 | 玖龙包装（太仓）有限公司 | A kind of preparation technology of corrugated board glue |
| CN106987221A (en) * | 2017-04-05 | 2017-07-28 | 芜湖市广源包装科技有限公司 | A kind of high corrugated paper adhesive of initial adhesive force |
| CN107033807A (en) * | 2017-05-22 | 2017-08-11 | 句容市兴武包装有限公司 | A kind of water-fast corrugated board adhesive and preparation method thereof |
| CN107268333A (en) * | 2017-08-07 | 2017-10-20 | 安徽凤凰松包装有限公司 | A kind of corrugated paper starch enhancer |
| CN107815270A (en) * | 2017-11-01 | 2018-03-20 | 福建省文松彩印有限公司 | A kind of corrugated case making Aqueous Adhesives and preparation method thereof |
| CN107868627A (en) * | 2017-11-15 | 2018-04-03 | 上海鎏彩建材科技股份有限公司 | Timber industry vegetable adhesive and preparation method thereof |
| CN107936868A (en) * | 2017-11-07 | 2018-04-20 | 湖南鸿江包装有限公司 | A kind of high-intensity packing bag production special environment friendly glue and its preparation process |
| CN108034387A (en) * | 2017-12-07 | 2018-05-15 | 明光市永德包装有限公司 | A kind of bond for corrugated board preparation method of high stability |
| CN108130010A (en) * | 2017-12-07 | 2018-06-08 | 明光市永德包装有限公司 | A kind of corrugated paper adhesive of storage period length |
| CN108165232A (en) * | 2017-12-07 | 2018-06-15 | 明光市永德包装有限公司 | A kind of preparation method of corrugated board water-resistant adhesives |
| CN108165216A (en) * | 2017-12-07 | 2018-06-15 | 明光市永德包装有限公司 | A kind of high stability carton starch adhesive |
| CN108300379A (en) * | 2018-03-26 | 2018-07-20 | 诸城兴贸玉米开发有限公司 | A kind of water-resistant type environmental protection wall paper glue and its processing technology |
| CN108587514A (en) * | 2018-04-20 | 2018-09-28 | 裴文韬 | A kind of preparation method of multi-wall corrugated board mongolicum Turcz. with Modified Starch Adhesive |
| CN108864803A (en) * | 2018-03-30 | 2018-11-23 | 徐冬 | A kind of preparation method of opaquing fluid |
| CN108949062A (en) * | 2018-06-26 | 2018-12-07 | 淮安市冰青建设工程管理有限公司 | A kind of environment-friendly type starch adhesive |
| CN109252417A (en) * | 2018-08-27 | 2019-01-22 | 扬中市惠丰包装有限公司 | A kind of corrugation paper pulp and preparation method thereof with fire resistance characteristic |
| CN110041852A (en) * | 2019-05-15 | 2019-07-23 | 河南汇泉生物科技有限公司 | A kind of effective starch adhesive of spiral and preparation method thereof |
| CN110055011A (en) * | 2019-05-15 | 2019-07-26 | 河南汇泉生物科技有限公司 | A kind of paper cone starch adhesive and preparation method thereof |
| CN110105897A (en) * | 2019-05-16 | 2019-08-09 | 河南汇泉生物科技有限公司 | A kind of spiral adhesive tube and preparation method thereof |
| CN110105900A (en) * | 2019-05-16 | 2019-08-09 | 河南汇泉生物科技有限公司 | A kind of industrial paperboard starch adhesive and preparation method thereof |
| CN110257005A (en) * | 2019-07-23 | 2019-09-20 | 北京林业大学 | A kind of no aldehyde flour base adhesive and preparation method thereof |
| CN110272699A (en) * | 2019-07-23 | 2019-09-24 | 北京林业大学 | A kind of starch adhesive and preparation method thereof |
| CN110305604A (en) * | 2019-07-02 | 2019-10-08 | 广东新力德包装科技有限公司 | A kind of bond for corrugated board and preparation method thereof |
| CN110577809A (en) * | 2019-10-09 | 2019-12-17 | 四川长虹包装印务有限公司 | Corrugated board adhesive |
| CN110903407A (en) * | 2019-12-22 | 2020-03-24 | 南通通地生物技术有限公司 | Oxidized starch and preparation method thereof |
| CN112480843A (en) * | 2020-12-08 | 2021-03-12 | 浙江下沙荣成包装有限公司 | Adhesive and preparation method thereof |
| CN112663389A (en) * | 2020-12-17 | 2021-04-16 | 济南鑫丰源包装辅料有限公司 | Starch reinforcing agent for paper and application thereof |
| CN113265904A (en) * | 2021-05-26 | 2021-08-17 | 上海天赐包装材料有限公司 | Corrugated board and production process thereof |
| CN114311923A (en) * | 2022-03-08 | 2022-04-12 | 佛山市俊联纸品有限公司 | Moisture-proof corrugated board and production process thereof |
| CN117966518A (en) * | 2024-02-24 | 2024-05-03 | 东莞市益和纸制品有限公司 | Pressure-resistant anti-deformation corrugated board and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1438284A (en) * | 2003-02-28 | 2003-08-27 | 陈宝元 | Water-resisting starch binder for single-side machine and corrugated board production line and preparation method thereof |
| CN101857785A (en) * | 2010-06-30 | 2010-10-13 | 句容市兴文包装有限公司 | Bonding agent for high-strength waterproof corrugated cases |
| CN101967355A (en) * | 2010-09-29 | 2011-02-09 | 中山火炬职业技术学院 | Paper starch adhesive and preparation method thereof |
-
2016
- 2016-07-26 CN CN201610595737.1A patent/CN106085289A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1438284A (en) * | 2003-02-28 | 2003-08-27 | 陈宝元 | Water-resisting starch binder for single-side machine and corrugated board production line and preparation method thereof |
| CN101857785A (en) * | 2010-06-30 | 2010-10-13 | 句容市兴文包装有限公司 | Bonding agent for high-strength waterproof corrugated cases |
| CN101967355A (en) * | 2010-09-29 | 2011-02-09 | 中山火炬职业技术学院 | Paper starch adhesive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李子东等: "《胶黏剂助剂》", 28 February 2005, 化学工业出版社 * |
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753041B (en) * | 2016-12-15 | 2018-12-14 | 怀集县兴建木业有限公司 | A kind of wood adhesive composition, preparation method and bonding wood method |
| CN106753041A (en) * | 2016-12-15 | 2017-05-31 | 吴定财 | A kind of wood adhesive composition, preparation method and bonding wood method |
| CN106753036A (en) * | 2016-12-16 | 2017-05-31 | 山东叶华纸制品包装有限公司 | A kind of carton glue and preparation method thereof |
| CN106947411A (en) * | 2017-03-09 | 2017-07-14 | 玖龙包装（太仓）有限公司 | A kind of preparation technology of corrugated board glue |
| CN106947410A (en) * | 2017-03-30 | 2017-07-14 | 宝艺新材料股份有限公司 | One kind is used for corrugated paper board production line low-temperature quick-drying type starch adhesive and preparation method thereof |
| CN106947410B (en) * | 2017-03-30 | 2019-04-19 | 宝艺新材料股份有限公司 | One kind is for corrugated paper board production line low-temperature quick-drying type starch adhesive and preparation method thereof |
| CN106987221A (en) * | 2017-04-05 | 2017-07-28 | 芜湖市广源包装科技有限公司 | A kind of high corrugated paper adhesive of initial adhesive force |
| CN107033807A (en) * | 2017-05-22 | 2017-08-11 | 句容市兴武包装有限公司 | A kind of water-fast corrugated board adhesive and preparation method thereof |
| CN107268333A (en) * | 2017-08-07 | 2017-10-20 | 安徽凤凰松包装有限公司 | A kind of corrugated paper starch enhancer |
| CN107815270A (en) * | 2017-11-01 | 2018-03-20 | 福建省文松彩印有限公司 | A kind of corrugated case making Aqueous Adhesives and preparation method thereof |
| CN107936868A (en) * | 2017-11-07 | 2018-04-20 | 湖南鸿江包装有限公司 | A kind of high-intensity packing bag production special environment friendly glue and its preparation process |
| CN107868627A (en) * | 2017-11-15 | 2018-04-03 | 上海鎏彩建材科技股份有限公司 | Timber industry vegetable adhesive and preparation method thereof |
| CN108130010A (en) * | 2017-12-07 | 2018-06-08 | 明光市永德包装有限公司 | A kind of corrugated paper adhesive of storage period length |
| CN108165232A (en) * | 2017-12-07 | 2018-06-15 | 明光市永德包装有限公司 | A kind of preparation method of corrugated board water-resistant adhesives |
| CN108165216A (en) * | 2017-12-07 | 2018-06-15 | 明光市永德包装有限公司 | A kind of high stability carton starch adhesive |
| CN108034387A (en) * | 2017-12-07 | 2018-05-15 | 明光市永德包装有限公司 | A kind of bond for corrugated board preparation method of high stability |
| CN108300379A (en) * | 2018-03-26 | 2018-07-20 | 诸城兴贸玉米开发有限公司 | A kind of water-resistant type environmental protection wall paper glue and its processing technology |
| CN108864803A (en) * | 2018-03-30 | 2018-11-23 | 徐冬 | A kind of preparation method of opaquing fluid |
| CN108587514A (en) * | 2018-04-20 | 2018-09-28 | 裴文韬 | A kind of preparation method of multi-wall corrugated board mongolicum Turcz. with Modified Starch Adhesive |
| CN108949062A (en) * | 2018-06-26 | 2018-12-07 | 淮安市冰青建设工程管理有限公司 | A kind of environment-friendly type starch adhesive |
| CN109252417A (en) * | 2018-08-27 | 2019-01-22 | 扬中市惠丰包装有限公司 | A kind of corrugation paper pulp and preparation method thereof with fire resistance characteristic |
| CN110041852A (en) * | 2019-05-15 | 2019-07-23 | 河南汇泉生物科技有限公司 | A kind of effective starch adhesive of spiral and preparation method thereof |
| CN110055011A (en) * | 2019-05-15 | 2019-07-26 | 河南汇泉生物科技有限公司 | A kind of paper cone starch adhesive and preparation method thereof |
| CN110105897A (en) * | 2019-05-16 | 2019-08-09 | 河南汇泉生物科技有限公司 | A kind of spiral adhesive tube and preparation method thereof |
| CN110105900A (en) * | 2019-05-16 | 2019-08-09 | 河南汇泉生物科技有限公司 | A kind of industrial paperboard starch adhesive and preparation method thereof |
| CN110305604B (en) * | 2019-07-02 | 2020-09-29 | 广东新力德包装科技有限公司 | Adhesive for corrugated board and preparation method thereof |
| CN110305604A (en) * | 2019-07-02 | 2019-10-08 | 广东新力德包装科技有限公司 | A kind of bond for corrugated board and preparation method thereof |
| CN110272699A (en) * | 2019-07-23 | 2019-09-24 | 北京林业大学 | A kind of starch adhesive and preparation method thereof |
| CN110257005A (en) * | 2019-07-23 | 2019-09-20 | 北京林业大学 | A kind of no aldehyde flour base adhesive and preparation method thereof |
| CN110577809A (en) * | 2019-10-09 | 2019-12-17 | 四川长虹包装印务有限公司 | Corrugated board adhesive |
| CN110903407A (en) * | 2019-12-22 | 2020-03-24 | 南通通地生物技术有限公司 | Oxidized starch and preparation method thereof |
| CN112480843A (en) * | 2020-12-08 | 2021-03-12 | 浙江下沙荣成包装有限公司 | Adhesive and preparation method thereof |
| CN112663389A (en) * | 2020-12-17 | 2021-04-16 | 济南鑫丰源包装辅料有限公司 | Starch reinforcing agent for paper and application thereof |
| CN113265904A (en) * | 2021-05-26 | 2021-08-17 | 上海天赐包装材料有限公司 | Corrugated board and production process thereof |
| CN114311923A (en) * | 2022-03-08 | 2022-04-12 | 佛山市俊联纸品有限公司 | Moisture-proof corrugated board and production process thereof |
| CN114311923B (en) * | 2022-03-08 | 2022-05-31 | 佛山市俊联纸品有限公司 | Moisture-proof corrugated board and production process thereof |
| CN117966518A (en) * | 2024-02-24 | 2024-05-03 | 东莞市益和纸制品有限公司 | Pressure-resistant anti-deformation corrugated board and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106085289A (en) | Environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof | |
| CN101629019B (en) | Basic biomass synthetic resin and preparation method and application thereof | |
| CN104263252B (en) | A kind of egg white base based Wood Adhesives | |
| CN101892023B (en) | Aldehyde-free adhesive and preparation method thereof | |
| JP5164483B2 (en) | Eco-friendly cardboard adhesive | |
| CN1888002B (en) | Method for adhering woody product or decoration with polymer adhesive | |
| CN106634720B (en) | A kind of water-fast glue bond of paper products of room temperature quickstick and preparation method thereof | |
| CN105802544A (en) | Modified starch adhesive | |
| JP5049079B2 (en) | Starch-based water-resistant adhesive for corrugated board containing no formaldehyde | |
| CN101284981B (en) | Biogum adhesive and preparation method thereof | |
| CN102533182A (en) | Method for preparing starch-based water-resistant adhesive for corrugated board production | |
| CN106749936A (en) | Vinyl acetate binder and preparation method thereof | |
| CN107488420A (en) | A kind of resistance to production method for freezing white glue with vinyl of waterproof | |
| CN106866909A (en) | A kind of impregnating phenolic resin, Preparation Method And The Use | |
| CN106085288A (en) | A kind of environment-friendly type mounts paper-hanging and preparation method thereof | |
| CN105969245A (en) | Waterproof anti-corrosion starch adhesive with excellent flexibility | |
| CN103834357B (en) | Not aqueous wood sizing agent containing formaldehyde and preparation method thereof | |
| CN106065301A (en) | A kind of anti-gaping of joints hot pressing veneer overlay glue stick and preparation method | |
| CN106753065B (en) | A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production | |
| JP2009138128A (en) | Formaldehyde-free and water-resistant adhesive for corrugated cardboard | |
| CN105176458A (en) | Adhesive for starch modified vinyl acetate wooden veneer veneering and preparation method of adhesive | |
| CN104877627A (en) | Adhesive for buildings | |
| CN108624255A (en) | A kind of Corn Starch Glue and its preparation process | |
| JP5236925B2 (en) | Improved corrugated adhesive | |
| KR20180117930A (en) | Adhesive composition from natural materials for water proof plywood and its preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161109 |
|
| RJ01 | Rejection of invention patent application after publication |