CN106085288A - A kind of environment-friendly type mounts paper-hanging and preparation method thereof - Google Patents
A kind of environment-friendly type mounts paper-hanging and preparation method thereof Download PDFInfo
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- CN106085288A CN106085288A CN201610595705.1A CN201610595705A CN106085288A CN 106085288 A CN106085288 A CN 106085288A CN 201610595705 A CN201610595705 A CN 201610595705A CN 106085288 A CN106085288 A CN 106085288A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/10—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paper (AREA)
Abstract
The present invention relates to a kind of environment-friendly type and mount paper-hanging and preparation method thereof.First add water in blender, then start stirring, be sequentially added into starch, drier, oxidant, Cui's agent, penetrating agent, stirring, stirs after adding sheet alkali, reacts 90 to 120 minutes, finally starting stirring, stirring after adding Borax and defoamer both can get environment-friendly type and mounts paper-hanging.The present invention oxidation by oxidant, on starch molecular chain, in addition to hydroxyl, adds the group such as carboxyl, carbonyl, improves the tack mounting paper-hanging, reduce spread；By adding penetrating agent, can make to mount paper-hanging rapid osmotic paper, destroy fiber；Can make to mount paper-hanging by addition catalyst and certainly crosslink formation three-dimensional-structure in moment, promote to mount paper-hanging quick-drying, improve bonding strength and the water repelling property of cardboard；Can be improved the rate of drying mounting paper-hanging by addition drier, enable to environment-friendly type by addition defoamer and mount paper-hanging not bubbles, beneficially gluing is uniform.
Description
Technical field
The present invention relates to a kind of glue, especially relate to a kind of environment-friendly type and mount paper-hanging and preparation method thereof.
Background technology
Electronic product currently on the market requires that to extranal packing box major part is all color case, and used by color case processing is all complete
Automatic laminating machine, in order to improve production efficiency, mounts paper-hanging quick-binding to be had performance.In the market mount paper glue
Water, in order to meet fast dry adhesive and low cost problem, be the most all be dissolved in water with corn starch after add Caustic soda gelatinizing formed gelatinizing
Glue, through the laminated bonding realizing ticker tape and hole paper of Paper-pasting machine.But this glue water content higher (about 68%), and
And water at normal temperature divides and is not easy to evaporate, the product water content after Paper-pasting machine is the highest, it is easy to occur that bonding degumming is existing
As.
In order to solve to bond degumming problem, market is all addition quick dry agent in mounting paper-hanging, improves moisture evaporation speed
Degree, improves the bonding quality of laminated cardboard, improves with this and mount paper production efficiency.Subject matter is: in order to improve moisture evaporation speed
Containing volatile material such as a large amount of formaldehyde in the quick dry agent spent and add, this allows for mounting paper-hanging in use can be to people
Body and environmental danger.
Chinese patent CN105602473A discloses a kind of environment-friendly type and mounts paper-hanging and preparation technology thereof, and environment-friendly type mounts paper glue
The composition of water comprises water, starch, alkali liquor and Borax, and the percentage by weight that wherein starch is shared in environment-friendly type mounts paper-hanging is to be situated between
In between 32% and 34%, alkali liquor percentage by weight shared by environment-friendly type mounts paper-hanging is between 6% and 8%, and Borax exists
It is between 0.5% and 2% that environment-friendly type mounts percentage by weight shared in paper-hanging.The water content of this glue is used more at present
The water content mounting paper-hanging low, it is to avoid occur degumming problem, simultaneously this composition mounting paper-hanging do not contain formaldehyde or other
Volatilizer.
Chinese patent CN103214981A discloses a kind of compound method mounting paper-hanging, concretely comprises the following steps: first to stirring
Bucket adds 40～60 kg of water, adds 20～30 kilograms of rapid-curing cutback Semen Maydis rubber powders, stirs；Add 2～4 kilograms of content
The sheet alkali of 95%～99%, sheet alkali is first with 6～8 kg of water dilutions；Then adding 0.5～0.8 kilogram of Borax, Borax is put into by water dilute
In the sheet aqueous slkali released, it is allowed to stir 10～15 minutes in adding agitator after dissolving；25～35 are added in the most backward agitator
Milliliter stops agent, stirs and can use.It is bonding the most firm to any paper that what this inventive method configured mounts paper-hanging.
Above-mentioned two parts of patents are all conventional starch, sheet alkali, Borax and the compositions of water, although environmental-protecting performance can reach to want
Ask, but its tack, spread, water-resistance etc. all remain to be further improved.
Summary of the invention
Defect that the purpose of the present invention is contemplated to overcome above-mentioned prior art to exist and provide a kind of environment-friendly type to mount paper glue
Water and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of environment-friendly type mounts paper-hanging, is made up of the raw material of following components and weight portion: starch: 100～200, water:
600～800, drier: 50～100, oxidant: 5～10, Cui's agent: 1～5, Borax: 5～10, defoamer: 0.1～3, sheet
Alkali: 10～20, penetrating agent: 1～5.
One or more in corn starch, tapioca, potato starch or wheaten starch of described starch are mixed
Compound.
The described drier mixture of one or more in calcium carbonate, silicon dioxide, triple superphosphate or bentonite.
Described oxidant is selected from Ammonium persulfate., potassium peroxydisulfate or the mixture of one or more of hydrogen peroxide.
The described catalyst mixture of one or more in boric acid, zirconium carbonate ammonium or potassium zirconium carbonate.
The described defoamer mixture of one or more in dimethicone, higher alcohols or polyether-modified silicon.
Described penetrating agent is selected from NPE (TX-10), fatty alcohol-polyoxyethylene ether (AEO-09), poly-second
The mixture of one or more in glycol or polypropylene glycol.
Described environment-friendly type mounts the preparation method of paper-hanging, first adds water in blender, then starts stirring, in order
Add starch, drier, oxidant, Cui's agent, penetrating agent, stir 5-10 minute, stir after adding sheet alkali 3-5 minute and stop stirring
Mixing, react 90 to 120 minutes, finally start stirring, after adding Borax and defoamer, stirring both can get environment-friendly type in 3-10 minute
Mount paper-hanging.
Described environment-friendly type is mounted paper-hanging and is applicable to gluing machine gluing, manually mounts hole machine and automatically mount hole machine gluing.
By the oxidation of oxidant, on starch molecular chain, in addition to hydroxyl, add the group such as carboxyl, carbonyl, improve
Mount the tack of paper-hanging, reduce spread, beneficially rapid draing；By adding penetrating agent, can make to mount paper-hanging quick
Infiltration paper, destroys fiber；Can make to mount paper-hanging by addition catalyst and certainly crosslink formation three-dimensional-structure in moment,
Promote to mount paper-hanging quick-drying, meanwhile, also can crosslink reaction with the group on paper fiber, thus improve bonding strength and cardboard
Water repelling property；The rate of drying mounting paper-hanging can be improved by addition drier, enable to environmental protection by adding defoamer
Paper-hanging not bubbles mounted by type, and beneficially gluing is uniform, it is possible to keep paper card not bend, be unlikely to deform.
Compared with prior art, advantages of the present invention and having the beneficial effects that:
1, it is primary raw material with corn starch or tapioca, replaces polyvinyl alcohol and vinyl acetate Virgin's milk glue in print
The application of brush factory, environmental-protecting performance is greatly improved.
2, during paper-hanging is mounted in preparation, add oxidant and starch molecule is aoxidized, make to increase on starch molecular chain
The group such as carboxyl, carbonyl, improves the tack mounting paper-hanging, it is possible to reduce the spread of laminating, beneficially rapid draing.
3, mount addition penetrating agent in paper-hanging, can make to mount paper-hanging and penetrate in paper, destroy fiber, improve laminating strong
Degree.
4, can make to mount paper-hanging by addition catalyst and crosslink formation three-dimensional-structure from moment, promote to mount
Paper-hanging is quick-drying, meanwhile, also can crosslink reaction with the group on paper fiber, thus improve the water resistant of bonding strength and cardboard
Performance.
5, can improve and mount the rate of drying of paper-hanging by adding drier.
6, the present invention is mainly composed of starch and water, and the additive of selection mostly is the chemical substance that environmental-protecting performance is excellent, makes
Paper-hanging good environmental protection must be mounted.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Mount factory formula and the technique of paper-hanging.
1000 kilograms of finished product glue: formula and technique
1: tap water: 769
2: tapioca: 130 kilograms
3: drier (calcium carbonate): 70 kilograms
4: hydrogen peroxide: 8 kilograms
5: Cui's agent (boric acid): 1.5 kilograms
6: Borax: 6 kilograms
7: defoamer (dimethicone): 0.5 kilogram
8: sheet alkali: 13 kilograms
9: penetrating agent (NPE): 2.
Technique: first add water in blender, then starts stirring, is sequentially added into starch, drier, oxidant, Cui
Agent, penetrating agent, stir 6 minutes, stirs 4 minutes and stops stirring, react 100 minutes, finally start stirring, add after adding sheet alkali
After entering Borax and defoamer, stirring both can get environment-friendly type for 5 minutes and mounted paper-hanging.
Embodiment 2
A kind of environment-friendly type mounts paper-hanging, is made up of the raw material of following components and weight portion: starch (corn starch): 100,
Water: 600, drier (silicon dioxide): 50, oxidant (Ammonium persulfate .): 5, Cui's agent (boric acid): 1, Borax: 5, defoamer (two
Methyl-silicone oil): 0.1, sheet alkali: 10, penetrating agent (fatty alcohol-polyoxyethylene ether): 1.
Environment-friendly type mounts the preparation method of paper-hanging, first adds water in blender, then starts stirring, is sequentially added into shallow lake
Powder, drier, oxidant, Cui's agent, penetrating agent, stir 5 minutes, stirs 3 minutes and stops stirring, react 90 points after adding sheet alkali
Clock, finally starts stirring, and after adding Borax and defoamer, stirring both can get environment-friendly type for 3 minutes and mounted paper-hanging.
Environment-friendly type obtained by the present embodiment is mounted paper-hanging and is applicable to gluing machine gluing, manually mounts hole machine and automatically mount hole
Machine gluing, greatly reduces with glue quantity, mounts, with this, the cardboard that paper-hanging posts, and bonding force is strong, and resistance to water is good, under water
Within 72 hours, do not disengage (five layers), cardboard can be kept not bend, be unlikely to deform simultaneously.
Embodiment 3
A kind of environment-friendly type mounts paper-hanging, is made up of the raw material of following components and weight portion: starch (potato starch):
150, water: 700, drier (triple superphosphate): 80, oxidant (potassium peroxydisulfate): 8, Cui's agent (zirconium carbonate ammonium): 3, Borax: 8, froth breaking
Agent (higher alcohols): 1, sheet alkali: 15, penetrating agent (Polyethylene Glycol): 3.
Environment-friendly type mounts the preparation method of paper-hanging, first adds water in blender, then starts stirring, is sequentially added into shallow lake
Powder, drier, oxidant, Cui's agent, penetrating agent, stir 8 minutes, stirs 4 minutes and stops stirring, react 110 after adding sheet alkali
Minute, finally start stirring, after adding Borax and defoamer, stirring both can get environment-friendly type for 6 minutes and mounted paper-hanging.
Environment-friendly type obtained by the present embodiment is mounted paper-hanging and is applicable to gluing machine gluing, manually mounts hole machine and automatically mount hole
Machine gluing, greatly reduces with glue quantity, mounts, with this, the cardboard that paper-hanging posts, and bonding force is strong, and resistance to water is good, under water
Within 72 hours, do not disengage (five layers), cardboard can be kept not bend, be unlikely to deform simultaneously.
Embodiment 4
A kind of environment-friendly type mounts paper-hanging, is made up of the raw material of following components and weight portion: starch (wheaten starch): 200,
Water: 800, drier (bentonite): 100, oxidant (hydrogen peroxide): 10, Cui's agent (potassium zirconium carbonate): 5, Borax: 10, defoamer
(polyether-modified silicon): 3, sheet alkali: 10～20, penetrating agent (polypropylene glycol): 5.
Environment-friendly type mounts the preparation method of paper-hanging, first adds water in blender, then starts stirring, is sequentially added into shallow lake
Powder, drier, oxidant, Cui's agent, penetrating agent, stir 10 minutes, stirs 5 minutes and stops stirring, react 120 after adding sheet alkali
Minute, finally start stirring, after adding Borax and defoamer, stirring both can get environment-friendly type for 10 minutes and mounted paper-hanging.
Environment-friendly type obtained by the present embodiment is mounted paper-hanging and is applicable to gluing machine gluing, manually mounts hole machine and automatically mount hole
Machine gluing, greatly reduces with glue quantity, mounts, with this, the cardboard that paper-hanging posts, and bonding force is strong, and resistance to water is good, under water
Within 72 hours, do not disengage (five layers), cardboard can be kept not bend, be unlikely to deform simultaneously.
The above-mentioned description to embodiment is to be understood that for ease of those skilled in the art and use invention.
These embodiments obviously easily can be made various amendment by person skilled in the art, and described herein typically
Principle is applied in other embodiments without through performing creative labour.Therefore, the invention is not restricted to above-described embodiment, ability
Field technique personnel should be the present invention's according to the announcement of the present invention, the improvement made without departing from scope and amendment
Within protection domain.
Claims (8)
1. an environment-friendly type mounts paper-hanging, it is characterised in that be made up of the raw material of following components and weight portion:
Starch: 100～200,
Water: 600～800,
Drier: 50～100,
Oxidant: 5～10,
Cui's agent: 1～5,
Borax: 5～10,
Defoamer: 0.1～3,
Sheet alkali: 10～20,
Penetrating agent: 1～5.
A kind of environment-friendly type the most according to claim 1 mounts paper-hanging, it is characterised in that described starch forms sediment selected from Semen Maydis
One or more mixture in powder, tapioca, potato starch or wheaten starch.
A kind of environment-friendly type the most according to claim 1 mounts paper-hanging, it is characterised in that described drier is selected from carbonic acid
The mixture of one or more in calcium, silicon dioxide, triple superphosphate or bentonite.
A kind of environment-friendly type the most according to claim 1 mounts paper-hanging, it is characterised in that described oxidant is selected from persulfuric acid
The mixture of one or more of ammonium, potassium peroxydisulfate or hydrogen peroxide.
A kind of environment-friendly type the most according to claim 1 mounts paper-hanging, it is characterised in that described catalyst selected from boric acid,
The mixture of one or more in zirconium carbonate ammonium or potassium zirconium carbonate.
A kind of environment-friendly type the most according to claim 1 mounts paper-hanging, it is characterised in that described defoamer is selected from dimethyl
The mixture of one or more in silicone oil, higher alcohols or polyether-modified silicon.
A kind of environment-friendly type the most according to claim 1 mounts paper-hanging, it is characterised in that described penetrating agent is selected from nonyl phenol
The mixture of one or more in polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol or polypropylene glycol.
8. the environment-friendly type as according to any one of claim 1-7 mounts the preparation method of paper-hanging, it is characterised in that first will
Water adds in blender, then starts stirring, is sequentially added into starch, drier, oxidant, Cui's agent, penetrating agent, stirs 5-
10 minutes, add to stir after sheet alkali 3-5 minute and stop stirring, react 90 to 120 minutes, finally start stirring, add Borax and
After defoamer, stirring both can get environment-friendly type for 3-10 minute and mounted paper-hanging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610595705.1A CN106085288A (en) | 2016-07-26 | 2016-07-26 | A kind of environment-friendly type mounts paper-hanging and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610595705.1A CN106085288A (en) | 2016-07-26 | 2016-07-26 | A kind of environment-friendly type mounts paper-hanging and preparation method thereof |
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| CN106085288A true CN106085288A (en) | 2016-11-09 |
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| CN201610595705.1A Pending CN106085288A (en) | 2016-07-26 | 2016-07-26 | A kind of environment-friendly type mounts paper-hanging and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107268333A (en) * | 2017-08-07 | 2017-10-20 | 安徽凤凰松包装有限公司 | A kind of corrugated paper starch enhancer |
| CN107936868A (en) * | 2017-11-07 | 2018-04-20 | 湖南鸿江包装有限公司 | A kind of high-intensity packing bag production special environment friendly glue and its preparation process |
| CN111117520A (en) * | 2020-01-06 | 2020-05-08 | 济南远达彩印包装有限公司 | Low-permeability paper laminating glue and preparation method thereof |
| CN111559121A (en) * | 2020-04-23 | 2020-08-21 | 华龙日清纸品(许昌)有限公司 | Production method of corrugated case |
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| CN101343513A (en) * | 2008-08-13 | 2009-01-14 | 河南省新斗彩印刷有限公司 | Corn starch adhesive agent |
| CN103214981A (en) * | 2013-03-20 | 2013-07-24 | 湖南凌华印务有限责任公司 | Preparation method of paper pasting glue |
| CN105602473A (en) * | 2016-02-25 | 2016-05-25 | 华励包装（惠州）有限公司 | Environmentally-friendly paper pasting glue and preparation process thereof |
-
2016
- 2016-07-26 CN CN201610595705.1A patent/CN106085288A/en active Pending
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| CN101343513A (en) * | 2008-08-13 | 2009-01-14 | 河南省新斗彩印刷有限公司 | Corn starch adhesive agent |
| CN103214981A (en) * | 2013-03-20 | 2013-07-24 | 湖南凌华印务有限责任公司 | Preparation method of paper pasting glue |
| CN105602473A (en) * | 2016-02-25 | 2016-05-25 | 华励包装（惠州）有限公司 | Environmentally-friendly paper pasting glue and preparation process thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107268333A (en) * | 2017-08-07 | 2017-10-20 | 安徽凤凰松包装有限公司 | A kind of corrugated paper starch enhancer |
| CN107936868A (en) * | 2017-11-07 | 2018-04-20 | 湖南鸿江包装有限公司 | A kind of high-intensity packing bag production special environment friendly glue and its preparation process |
| CN111117520A (en) * | 2020-01-06 | 2020-05-08 | 济南远达彩印包装有限公司 | Low-permeability paper laminating glue and preparation method thereof |
| CN111559121A (en) * | 2020-04-23 | 2020-08-21 | 华龙日清纸品(许昌)有限公司 | Production method of corrugated case |
| CN111559121B (en) * | 2020-04-23 | 2022-02-22 | 许昌华龙日清纸品有限公司 | Production method of corrugated case |
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Application publication date: 20161109 |
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