CN107488420A - A kind of resistance to production method for freezing white glue with vinyl of waterproof - Google Patents
A kind of resistance to production method for freezing white glue with vinyl of waterproof Download PDFInfo
- Publication number
- CN107488420A CN107488420A CN201710832501.XA CN201710832501A CN107488420A CN 107488420 A CN107488420 A CN 107488420A CN 201710832501 A CN201710832501 A CN 201710832501A CN 107488420 A CN107488420 A CN 107488420A
- Authority
- CN
- China
- Prior art keywords
- dibutyl phthalate
- vinyl
- resistance
- add
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F118/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F118/02—Esters of monocarboxylic acids
- C08F118/04—Vinyl esters
- C08F118/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention discloses a kind of resistance to production method for freezing white glue with vinyl of waterproof.Dibutyl phthalate is mixed with octanol, stirring makes its dissolving, standby;Add water toward the reactor of jacketed, be heated to 60 80 DEG C and add polyvinyl alcohol under agitation, be warming up to 90 DEG C of insulations to being completely dissolved;Cold water is injected into the chuck of reactor, liquid in kettle is cooled to 66-69 DEG C, adds vinylacetate under agitation;The octanol solution of dibutyl phthalate is added into reactor, ammonium persulfate is added and stirs evenly, mixed 12 hours at 66 69 DEG C, the vinylacetate white glue with vinyl of thick white is produced, with vial or plastic bottle packing.A kind of resistance to production method for freezing white glue with vinyl of waterproof of the present invention, improves the production technology of white latex, adds modifying agent, obtain the modified latex not being gelled under low temperature, its water resistance, heat resistance and freexing tolerance are significantly increased than white latex.
Description
Technical field
The present invention relates to a kind of resistance to production method for freezing white glue with vinyl of waterproof, belong to white glue with vinyl technical field.
Background technology
White glue with vinyl is that purposes is most wide, dosage is maximum, one of water soluble adhesive with the longest history, is by vinyl acetate list
Body initiator effect under aggregated reaction prepared by a kind of thermoplastic adhesives.It is normal temperature solidified, solidification is very fast, bonding is strong
Degree is higher, and adhesive linkage has preferable toughness and durability and non-aging.
But be easily gelled under present conventional white glue with vinyl low temperature, and water resistance and heat resistance are poor.
The content of the invention
In view of this, the invention provides a kind of resistance to production method for freezing white glue with vinyl of waterproof, the life of white latex is improved
Production. art, the addition material component such as modifying agent, obtains the modified latex not being gelled under low temperature, its water resistance, heat resistance and resistance to
Jelly property is significantly increased than white latex.
The present invention solves above-mentioned technical problem by following technological means, a kind of resistance to production method for freezing white glue with vinyl of waterproof,
It is following steps:
(1) dibutyl phthalate is mixed with octanol, stirring make its dissolving, it is standby, dibutyl phthalate with
The mass ratio of octanol is 3:1;
(2) add water toward the reactor of jacketed, be heated to 60-80 DEG C and add polyvinyl alcohol under agitation, be warming up to 90 DEG C
To being completely dissolved, the dibutyl phthalate of addition and the mass ratio of polyvinyl alcohol, water are 3 for insulation:4:47.9;
(3) cold water is injected into the chuck of reactor, liquid in kettle is cooled to 66-69 DEG C, add acetic acid under agitation
Vinyl acetate, the vinylacetate of addition and the mass ratio of dibutyl phthalate are 44:3;
(4) toward the octanol solution of addition dibutyl phthalate in reactor, add ammonium persulfate and stir evenly, in 66-
1-2 hours are mixed at 69 DEG C, produce the vinylacetate white glue with vinyl of thick white, with vial or plastic bottle packing, addition
The mass ratio of ammonium persulfate and dibutyl phthalate is 0.1:3.
When step (1) dibutyl phthalate mixes with octanol, the temperature of stirring and dissolving is 50-60 DEG C.
In the step (4), it is 500-700r/min to add after ammonium persulfate the speed mixed.
The present invention has very strong cohesive force, and initial viscosity to porous material such as timber, paper, cotton, leather, ceramics etc.
It is higher, can cold curing, and curing rate is fast, and glued membrane is transparent, does not pollute adherend, and is easy to process, and is scattered using water
Medium, do not burn, without toxic gas, free from environmental pollution, safety nuisance free, for the thick liquid of one-component, use ratio
More convenient, the glued membrane after solidification has certain toughness, resistance to diluted alkaline, diluted acid, and oil resistivity is also fine.
The white glue with vinyl of the present invention, it is cheap.The product make primary bond base-material with vinyl acetate, polyvinyl alcohol, using wink
Between be made into soap emulsion process preparation technology, its outward appearance is milky, is a kind of stronger composite white latex of cohesive force.The product system
Standby technique is simple, and production cost is low, and has the resistance to jelly function of waterproof.
The beneficial effects of the invention are as follows:(1) white glue with vinyl has normal temperature cure, solidification is very fast, adhesive strength is higher, adhesive linkage
Series of advantages with preferable toughness and durability and non-aging grade.It can be widely applied to be bonded paper products (wallpaper),
Also the adhesive of water-repellent paint and timber can be made.
(2) it is safe to use, nontoxic, non-ignitable, easy to clean, the normal temperature cure, to timber, paper using water as dispersant
There is good adhesion with fabric, glue-joint strength is high, the glue-line water white transparency after solidification, good toughness, does not pollute bonded object.
(3) modifying agent of the binders such as phenolic resin, Lauxite can also be made, for manufacturing Polyvinyl acetate latex paint
Deng.
(4) good emulsion stability, Storage period is up to more than half a year.Therefore, printing bookbinding and furniture system be can be widely used in
Make, the bonding as paper, timber, cloth, leather, ceramics etc..
Embodiment
Below with reference to specific embodiment, the present invention is described in detail, a kind of resistance to jelly white glue with vinyl of waterproof of the present embodiment
Production method, it is following steps:
(1) dibutyl phthalate is mixed with octanol, stirring make its dissolving, it is standby, dibutyl phthalate with
The mass ratio of octanol is 3:1;
(2) add water toward the reactor of jacketed, be heated to 60-80 DEG C and add polyvinyl alcohol under agitation, be warming up to 90 DEG C
To being completely dissolved, the dibutyl phthalate of addition and the mass ratio of polyvinyl alcohol, water are 3 for insulation:4:47.9;
(3) cold water is injected into the chuck of reactor, liquid in kettle is cooled to 66-69 DEG C, add acetic acid under agitation
Vinyl acetate, the vinylacetate of addition and the mass ratio of dibutyl phthalate are 44:3;
(4) toward the octanol solution of addition dibutyl phthalate in reactor, add ammonium persulfate and stir evenly, in 66-
1-2 hours are mixed at 69 DEG C, produce the vinylacetate white glue with vinyl of thick white, with vial or plastic bottle packing, addition
The mass ratio of ammonium persulfate and dibutyl phthalate is 0.1:3.
When step (1) dibutyl phthalate mixes with octanol, the temperature of stirring and dissolving is 50-60 DEG C.
In the step (4), it is 500-700r/min to add after ammonium persulfate the speed mixed.
Embodiment 1
A kind of resistance to production method for freezing white glue with vinyl of waterproof, it is following steps:
(1) dibutyl phthalate is mixed with octanol, stirring make its dissolving, it is standby, dibutyl phthalate with
The mass ratio of octanol is 3:1;
(2) add water toward the reactor of jacketed, be heated to 75 DEG C and add polyvinyl alcohol under agitation, be warming up to 90 DEG C of insulations
To being completely dissolved, the dibutyl phthalate of addition and the mass ratio of polyvinyl alcohol, water are 3:4:47.9;
(3) cold water is injected into the chuck of reactor, liquid in kettle is cooled to 67 DEG C, add vinyl acetate under agitation
Ester, the vinylacetate of addition and the mass ratio of dibutyl phthalate are 44:3;
(4) toward the octanol solution of addition dibutyl phthalate in reactor, add ammonium persulfate and stir evenly, at 67 DEG C
Lower mixing 1.5 hours, the vinylacetate white glue with vinyl of thick white is produced, with vial or plastic bottle packing, the over cure of addition
The mass ratio of sour ammonium and dibutyl phthalate is 0.1:3.
When step (1) dibutyl phthalate mixes with octanol, the temperature of stirring and dissolving is 55 DEG C.
In the step (4), it is 600r/min to add after ammonium persulfate the speed mixed.
Embodiment 2
A kind of resistance to production method for freezing white glue with vinyl of waterproof, it is following steps:
(1) dibutyl phthalate is mixed with octanol, stirring make its dissolving, it is standby, dibutyl phthalate with
The mass ratio of octanol is 3:1;
(2) add water toward the reactor of jacketed, be heated to 71 DEG C and add polyvinyl alcohol under agitation, be warming up to 90 DEG C of insulations
To being completely dissolved, the dibutyl phthalate of addition and the mass ratio of polyvinyl alcohol, water are 3:4:47.9;
(3) cold water is injected into the chuck of reactor, liquid in kettle is cooled to 68 DEG C, add vinyl acetate under agitation
Ester, the vinylacetate of addition and the mass ratio of dibutyl phthalate are 44:3;
(4) toward the octanol solution of addition dibutyl phthalate in reactor, add ammonium persulfate and stir evenly, at 66 DEG C
Lower mixing 1.3 hours, the vinylacetate white glue with vinyl of thick white is produced, with vial or plastic bottle packing, the over cure of addition
The mass ratio of sour ammonium and dibutyl phthalate is 0.1:3.
When step (1) dibutyl phthalate mixes with octanol, the temperature of stirring and dissolving is 58 DEG C.
In the step (4), it is 650r/min to add after ammonium persulfate the speed mixed.
Embodiment 3
A kind of resistance to production method for freezing white glue with vinyl of waterproof, it is following steps:
(1) dibutyl phthalate is mixed with octanol, stirring make its dissolving, it is standby, dibutyl phthalate with
The mass ratio of octanol is 3:1;
(2) add water toward the reactor of jacketed, be heated to 70 DEG C and add polyvinyl alcohol under agitation, be warming up to 90 DEG C of insulations
To being completely dissolved, the dibutyl phthalate of addition and the mass ratio of polyvinyl alcohol, water are 3:4:47.9;
(3) cold water is injected into the chuck of reactor, liquid in kettle is cooled to 68 DEG C, add vinyl acetate under agitation
Ester, the vinylacetate of addition and the mass ratio of dibutyl phthalate are 44:3;
(4) toward the octanol solution of addition dibutyl phthalate in reactor, add ammonium persulfate and stir evenly, at 69 DEG C
Lower mixing 1.5 hours, the vinylacetate white glue with vinyl of thick white is produced, with vial or plastic bottle packing, the over cure of addition
The mass ratio of sour ammonium and dibutyl phthalate is 0.1:3.
When step (1) dibutyl phthalate mixes with octanol, the temperature of stirring and dissolving is 60 DEG C.
In the step (4), it is 500r/min to add after ammonium persulfate the speed mixed.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of technical solution of the present invention, it all should cover at this
Among the right of invention.
Claims (3)
1. the resistance to production method for freezing white glue with vinyl of a kind of waterproof, it is characterised in that be following steps:
(1) dibutyl phthalate is mixed with octanol, stirring makes its dissolving, standby, dibutyl phthalate and octanol
Mass ratio be 3:1;
(2) add water toward the reactor of jacketed, be heated to 60-80 DEG C and add polyvinyl alcohol under agitation, be warming up to 90 DEG C of insulations
To being completely dissolved, the dibutyl phthalate of addition and the mass ratio of polyvinyl alcohol, water are 3:4:47.9;
(3) cold water is injected into the chuck of reactor, liquid in kettle is cooled to 66-69 DEG C, add vinyl acetate under agitation
Ester, the vinylacetate of addition and the mass ratio of dibutyl phthalate are 44:3;
(4) toward the octanol solution of addition dibutyl phthalate in reactor, add ammonium persulfate and stir evenly, at 66-69 DEG C
Lower mixing 1-2 hours, the vinylacetate white glue with vinyl of thick white is produced, with vial or plastic bottle packing, the over cure of addition
The mass ratio of sour ammonium and dibutyl phthalate is 0.1:3.
A kind of 2. resistance to production method for freezing white glue with vinyl of waterproof according to claim 1, it is characterised in that:The step (1)
When dibutyl phthalate mixes with octanol, the temperature of stirring and dissolving is 50-60 DEG C.
A kind of 3. resistance to production method for freezing white glue with vinyl of waterproof according to claim 1, it is characterised in that:The step (4)
In, it is 500-700r/min to add after ammonium persulfate the speed mixed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710832501.XA CN107488420A (en) | 2017-09-15 | 2017-09-15 | A kind of resistance to production method for freezing white glue with vinyl of waterproof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710832501.XA CN107488420A (en) | 2017-09-15 | 2017-09-15 | A kind of resistance to production method for freezing white glue with vinyl of waterproof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107488420A true CN107488420A (en) | 2017-12-19 |
Family
ID=60651827
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710832501.XA Pending CN107488420A (en) | 2017-09-15 | 2017-09-15 | A kind of resistance to production method for freezing white glue with vinyl of waterproof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107488420A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110437775A (en) * | 2019-08-08 | 2019-11-12 | 东莞市顺威粘合剂有限公司 | Surfactant-free white glue with vinyl |
CN111662659A (en) * | 2020-07-24 | 2020-09-15 | 安徽大松树脂有限公司 | Preparation method of graphene heating floor tile bonding adhesive |
CN113416453A (en) * | 2021-07-09 | 2021-09-21 | 宋志旭 | Glue solution and mixing solution for ancient mural holographic copying compound sleeve mineral pigment drawing |
CN113635701A (en) * | 2021-08-09 | 2021-11-12 | 宋志旭 | Drawing technique on ancient mural holographic copying substrate material |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102250564A (en) * | 2010-12-21 | 2011-11-23 | 刘青 | Manufacture method of white latex |
CN104629633A (en) * | 2015-01-28 | 2015-05-20 | 海安县紫石涂料有限公司 | Water-resistant white latex |
CN104650778A (en) * | 2015-01-28 | 2015-05-27 | 海安县中丽化工材料有限公司 | Environment-friendly white latex |
CN104672391A (en) * | 2015-01-28 | 2015-06-03 | 海安县紫石涂料有限公司 | Method for preparing water-resistant white emulsion |
-
2017
- 2017-09-15 CN CN201710832501.XA patent/CN107488420A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102250564A (en) * | 2010-12-21 | 2011-11-23 | 刘青 | Manufacture method of white latex |
CN104629633A (en) * | 2015-01-28 | 2015-05-20 | 海安县紫石涂料有限公司 | Water-resistant white latex |
CN104650778A (en) * | 2015-01-28 | 2015-05-27 | 海安县中丽化工材料有限公司 | Environment-friendly white latex |
CN104672391A (en) * | 2015-01-28 | 2015-06-03 | 海安县紫石涂料有限公司 | Method for preparing water-resistant white emulsion |
Non-Patent Citations (1)
Title |
---|
陈三斌: "《240种实用化工产品配方与制造》", 30 September 1993, 金盾出版社 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110437775A (en) * | 2019-08-08 | 2019-11-12 | 东莞市顺威粘合剂有限公司 | Surfactant-free white glue with vinyl |
CN111662659A (en) * | 2020-07-24 | 2020-09-15 | 安徽大松树脂有限公司 | Preparation method of graphene heating floor tile bonding adhesive |
CN113416453A (en) * | 2021-07-09 | 2021-09-21 | 宋志旭 | Glue solution and mixing solution for ancient mural holographic copying compound sleeve mineral pigment drawing |
CN113635701A (en) * | 2021-08-09 | 2021-11-12 | 宋志旭 | Drawing technique on ancient mural holographic copying substrate material |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102433087B (en) | High-temperature-resistant paper-plastic laminating adhesive and preparation method thereof | |
CN107488420A (en) | A kind of resistance to production method for freezing white glue with vinyl of waterproof | |
CN101265398B (en) | Environment-friendly type white emulsion glue | |
CN101362929B (en) | Emulsion type adhesive for paper and plastics and preparation method thereof | |
CN106085289A (en) | Environment-friendly type corrugated board low temperature laminating starch adhesive and preparation method thereof | |
CN105176457B (en) | A kind of environment-friendly water-based adhesive | |
WO2009074006A1 (en) | An adhesive, preparation and use thereof | |
CN101880349B (en) | Cross linking type methyl acrylate and vinyl acetate emulsion and preparation method thereof | |
CN106634720B (en) | A kind of water-fast glue bond of paper products of room temperature quickstick and preparation method thereof | |
CN102086371B (en) | Method for preparing antiseptic soy protein adhesive | |
CN102453455A (en) | Environment-friendly emulsion paint used for glued board | |
CN105440982B (en) | Packing box used and wood-leather base material used environmentally-friendly aqueous binder | |
CN104004478A (en) | Method for fabricating acidolysis acetylated starch adhesive and application of acidolysis acetylated starch adhesive | |
CN108251047A (en) | A kind of preparation method of compound type starch adhesive | |
CN102838769B (en) | Preparation method of moisture absorption packaging film | |
CN104356975A (en) | Preparation method of modified starch adhesive | |
CN102533182A (en) | Method for preparing starch-based water-resistant adhesive for corrugated board production | |
CN103881634A (en) | Urea-formaldehyde resin adhesive and preparation method thereof | |
CN109456707A (en) | A kind of adhesive for corrugated board bonding | |
CN104164203A (en) | White latex for leatherworking and preparation method thereof | |
CN103333645B (en) | Formaldehyde-free polyvinyl acetate wood adhesive and preparation method thereof | |
CN103351831B (en) | A kind of plastics binder and preparation method thereof | |
CN101851475B (en) | Preparation method of energy-saving, environment-protecting and sag-resistant water-based instant adhesive | |
CN101979452B (en) | Method for preparing waterproof adhesive for corrugated paper production | |
CN107805484A (en) | A kind of preparation method of wood materials starch adhesive |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171219 |