CN103864349A - Multifunctional ecological inner wall coating material and preparation method thereof - Google Patents
Multifunctional ecological inner wall coating material and preparation method thereof Download PDFInfo
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- CN103864349A CN103864349A CN201410099990.9A CN201410099990A CN103864349A CN 103864349 A CN103864349 A CN 103864349A CN 201410099990 A CN201410099990 A CN 201410099990A CN 103864349 A CN103864349 A CN 103864349A
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- 239000000463 material Substances 0.000 title claims abstract description 61
- 238000000576 coating method Methods 0.000 title claims abstract description 45
- 239000011248 coating agent Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 39
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- 239000004576 sand Substances 0.000 claims abstract description 13
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 11
- 239000002131 composite material Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 238000013461 design Methods 0.000 claims abstract description 4
- 239000000049 pigment Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 13
- 239000004113 Sepiolite Substances 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 229910052624 sepiolite Inorganic materials 0.000 claims description 8
- 235000019355 sepiolite Nutrition 0.000 claims description 8
- 230000008719 thickening Effects 0.000 claims description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 7
- 241000276489 Merlangius merlangus Species 0.000 claims description 7
- 229910052599 brucite Inorganic materials 0.000 claims description 7
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- 238000007664 blowing Methods 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 230000003472 neutralizing effect Effects 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 229920002522 Wood fibre Polymers 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229920006243 acrylic copolymer Polymers 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- 238000005194 fractionation Methods 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- 229910001385 heavy metal Inorganic materials 0.000 claims description 2
- 239000004816 latex Substances 0.000 claims description 2
- 229920000126 latex Polymers 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- -1 polydimethylsiloxane Polymers 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 230000006870 function Effects 0.000 abstract description 12
- 230000001954 sterilising effect Effects 0.000 abstract description 4
- 150000002500 ions Chemical class 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 239000002086 nanomaterial Substances 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 239000012855 volatile organic compound Substances 0.000 abstract 4
- 238000007599 discharging Methods 0.000 abstract 2
- 238000004887 air purification Methods 0.000 abstract 1
- 230000001580 bacterial effect Effects 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 239000008204 material by function Substances 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 6
- 230000003115 biocidal effect Effects 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000000452 restraining effect Effects 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004958 brain cell Anatomy 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention provides a multifunctional ecological inner wall coating material and a preparation method thereof, and belongs to the field of coating materials. The inner wall coating material is prepared by mixing the following raw materials: de-ionized water, an emulsion, a liquid aid, titanium dioxide, low-VOC (volatile organic compound) color paste, a functional composite material, white sand and a powder aid. The preparation method comprises the following steps: (1) adding the de-ionized water and the emulsion into a reaction kettle, adding the liquid aid and titanium dioxide in sequence while stirring, dispersing for 15 minutes, and performing color mixing by the low-VOC color paste according to the color sample design requirements of customers; (2) adding the functional composite material, the powder aid and the white sand into a powder mixer, mixing for 10 minutes, and discharging for later use; (3) slowly adding the discharged powder in the step (2) into the reaction kettle while stirring, uniformly mixing, checking, discharging and packaging. The coating material comprises functional materials such as a low-VOC emulsion, an environment-friendly aid, a lead-free pigment, a biological sterilization material, a humidifying material and a nanomaterial, and has the functions of decoration, protection, humidification, energy conservation, bacterial inhibition and killing, air purification, negative ion release and the like.
Description
Technical field
The present invention relates to a kind of coating material, specifically a kind of thick coated type for household indoor wall has Multifunctional ecotype interior wall coating material of texture effect and preparation method thereof.
Background technology
Along with improving constantly of people's living standard, people's environment protection health consciousness obviously strengthens, requirement to living environment is also more and more higher, indoor wall has also proposed requirements at the higher level to atmospheric moisture with coating material except ornamental, atmospheric moisture is normally by regulating with air-conditioning and other Humidity regulating equipment at present, all belong to consumable electrode type equipment, adjust atmospheric moisture by materials for wall and greatly reduce energy consumption, meet energy-saving and cost-reducing principle; Simultaneously in Indoor Air, negative ion quantity also becomes one of unhealthful important measurement index, the negative ion that people recognize proper concn in air gradually to restraining and sterilizing bacteria, remove obnoxious flavour, purify air, promote the aspect such as activity of human body brain cell to have positive effect.
A lot of about the report of the sterilization for interior wall coating material and aldehydes removal functional paint aspect in recent years.Patent publication No. CN1170745A has reported a kind of coating material that utilizes biological antibiotic, this material have purify air, the effect such as antibacterial, anion releasing.Liu Chenglou etc. utilize diatomite, sepiolite powder and nanometer additive etc. to make inner-wall antibacterial humidity controlling coating to have anion releasing, antibacterial bacteriostatic, dispel the function such as obnoxious flavour, fresh air (modern coatings and application, 2008 11(8)).Zhang Liansong etc. utilize porous material absorption nano titanium oxide to be developed into a kind of interior wall powder coating, and this coating also has antibacterial bacteriostatic, purifies air, regulates the functions such as indoor air humidity (Chinese building material science and technology, 2005 14(2)).Be more than representative patent and achievement in research, no longer enumerate at this.
This series products majority adopts single biological antibiotic or single one physical chemism bacteriostasis antibiosis, its long-lasting being restricted aspect bacteriostasis antibiosis at present; Secondly, although this series products of part also meets current compulsory standard aspect environmental protection index in the past, be difficult to reach zero in some index as organic volatile (VOC); The 3rd, such invention material was also painted with master mainly with common putting down aspect decorative effect in the past, and coating thickness is less, and in unit wall area, contained humidity adjusting material total amount is inevitable less like this, so limited greatly the performance of humidity conditioning function; The 4th, such invention materials'use powder stuffing all consumed mining deposits in a large number as quartz mine, limestone mine etc. in the past, and these ore deposits all belong to Nonrenewable resources.More than be the problem to be solved in the present invention.
Summary of the invention
Technical assignment of the present invention is for the deficiencies in the prior art, and a kind of Multifunctional ecotype interior wall coating material and preparation method thereof is provided.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of Multifunctional ecotype interior wall coating material, is characterized in that, it is to be mixed by the raw material of following parts by weight:
Deionized water 5-15,
Emulsion 10-35,
Liquid type auxiliary agent 1-5,
Titanium dioxide 1-5,
Low VOC mill base 0.1-5
Functional material 5-15,
White sand 50-80,
Powder analog assistant 1-5.
Described emulsion is one or more the combination in low VOC Styrene And Chloroalkyl Acrylates copolymer emulsion, low VOC pure acrylic latex, low VOC ethylene-vinyl acetate copolymer emulsion, low VOC polyvinylacetate-acrylic copolymer emulsion.
Described liquid type auxiliary agent is the mixture of dispersion agent, defoamer, thickening material, neutralizing agent, frostproofer, and its blending ratio is dispersion agent/defoamer/thickening material/neutralizing agent/frostproofer=3/1.5/1.5/1/6.
Described dispersion agent is selected high-molecular-weight propylene acid copolymer dispersion agent, and defoamer is selected polydimethylsiloxane defoamer, and thickening material is selected agent for polyacrylic acid thickening, and neutralizing agent is selected 25% potassium hydroxide solution, and frostproofer is selected glycols oligopolymer.
Described titanium dioxide is commercially available Rutile type Titanium Dioxide or commercially available anatase thpe white powder.
Described low VOC mill base is the commercially available low VOC mill base product that does not contain the pigment of heavy metal.
Described functional material is made up of following material: sepiolite powder, oyster shell whiting, diatomite, brucite powder, nano zine oxide, nano titanium oxide, nano silicon, and its composition mass fraction and preparation technology are as follows:
1) composition massfraction:
Sepiolite powder 15-30,
Brucite powder 10-25,
Nano zine oxide 3-8,
Nano-titanium oxide 3-8,
Nano silicon oxide 3-8,
Diatomite 20-30,
Oyster shell whiting 20-40;
2) preparation technology: according to 1) in composition massfraction obtain described functional composite material herein after sepiolite powder, oyster shell whiting, diatomite, brucite powder, nano zine oxide, nano titanium oxide, nano silicon are dropped into powder mixer mixing 10-15min successively.
Described white sand is shell sand or Dali stone sand.
Described powder analog assistant is respectively any one in Vltra tears, wood fibre, lubricant, two or three combination.
The preparation method of above-mentioned Multifunctional ecotype interior wall coating material, this preparation method carries out according to following steps:
1) first deionized water, emulsion are added in reactor and under whipped state, add successively liquid type auxiliary agent, titanium dioxide, disperse to mix colours according to the low VOC mill base of client's design requirements tinctorial pattern after 15 minutes;
2) functional composite material, powder analog assistant, white sand are added in powder mixer mixed after 10 minutes blowing stand-by;
3) by step 2) in emit slowly to add under powder stirring state and in reactor, mix rear check, blowing packing.
Compared with prior art, the beneficial effect producing is a kind of Multifunctional ecotype interior wall coating material of the present invention and preparation method thereof:
Coating material of the present invention contains the functional type materials such as low VOC emulsion, environmental protection auxiliary agent, lead-free pigment, biological antibiotic material, humidity adjusting material, nano material, has the protection of decoration, energy-conservation, the restraining and sterilizing bacteria of damping, purifies air, the function such as anion releasing.
Embodiment
Further illustrate a kind of Multifunctional ecotype interior wall coating material of the present invention below in conjunction with embodiment 1-5, the formula of embodiment 1-5 is as follows: (table 1)
Above-described embodiment 1-5(table 1) in the preparation method of Multifunctional ecotype interior wall coating material, comprise the steps:
1) first deionized water, emulsion are added in reactor and under whipped state, add successively liquid type auxiliary agent, titanium dioxide, disperse to mix colours according to the low VOC mill base of client's design requirements tinctorial pattern after 15 minutes;
2) functional composite material, powder analog assistant, white sand are added in powder mixer mixed after 10 minutes blowing stand-by;
3) by step 2) in emit slowly to add under powder stirring state and in reactor, mix rear check, blowing packing.
Functional material in above-described embodiment 1-5, the formula of embodiment 1-7 is as follows: (table 2)
Above-described embodiment 1-7(table 2) in the preparation method of functional composite material:
After sepiolite powder, oyster shell whiting, diatomite, brucite powder, nano zine oxide, nano titanium oxide, nano silicon being dropped into powder mixer mixing 10-15min successively according to the composition massfraction in functional composite material (table 2), obtain described functional composite material herein.
Carry out related experiment for embodiment products obtained therefrom Multifunctional ecotype interior wall coating material below.
1) test for the relevant fundamental property (according to JG/T 24-2000) of Multifunctional ecotype interior wall coating material and coating germ resistance (according to JIS Z2801:2000), below table 3 are the performance test results of this invention product Multifunctional ecotype interior wall coating material.
The performance test results of table 3 Multifunctional ecotype interior wall coating material
2) test for coating humidity conditioning function and the function that purifies the air of a room.Testing program is as follows:
A) humidity conditioning function test: choose two adjacent same brick mix structure one-storey houses, wherein after the Multifunctional ecotype interior wall coating material maintenance of expires, in two houses, put into wet bulb thermometer, close door window simultaneously, carry out humidity conditioning function and air-cleaning function test, in uncoated Multifunctional ecotype interior wall coating material room, humidity is designated as Rh
blank, apply humidity in Multifunctional ecotype interior wall coating material room and be designated as Rh
be coated with, summer, day record data were in table 4.
The humidity data in table 4 summer day records result
Can find out by above data, in room, applying Multifunctional ecotype interior wall coating material can be within the specific limits to regulating indoor humidity.
B) function test that purifies the air of a room: will test A) in room in the afternoon 5:00 close door window simultaneously, two people walk out immediately room and close door after exhausting a cigarette simultaneously, next day, the morning, 8:30 opened door, entering in room uses sense of smell sense organ to contrast, the room smoke of uncoated Multifunctional ecotype interior wall coating material is still dense, and the smell in another room can be accepted.Also illustrate that by this experiment Multifunctional ecotype interior wall coating material has the function of purifying the air of a room.
Claims (10)
1. a Multifunctional ecotype interior wall coating material, is characterized in that, it is to be mixed by the raw material of following parts by weight:
Deionized water 5-15,
Emulsion 10-35,
Liquid type auxiliary agent 1-5,
Titanium dioxide 1-5,
Low VOC mill base 0.1-5
Functional material 5-15,
White sand 50-80,
Powder analog assistant 1-5.
2. a kind of Multifunctional ecotype interior wall coating material according to claim 1, it is characterized in that, described emulsion is one or more the combination in low VOC Styrene And Chloroalkyl Acrylates copolymer emulsion, low VOC pure acrylic latex, low VOC ethylene-vinyl acetate copolymer emulsion, low VOC polyvinylacetate-acrylic copolymer emulsion.
3. a kind of Multifunctional ecotype interior wall coating material according to claim 1, it is characterized in that, described liquid type auxiliary agent is the mixture of dispersion agent, defoamer, thickening material, neutralizing agent, frostproofer, and its blending ratio is dispersion agent/defoamer/thickening material/neutralizing agent/frostproofer=3/1.5/1.5/1/6.
4. a kind of Multifunctional ecotype interior wall coating material according to claim 3, it is characterized in that, described dispersion agent is selected high-molecular-weight propylene acid copolymer dispersion agent, defoamer is selected polydimethylsiloxane defoamer, thickening material is selected agent for polyacrylic acid thickening, neutralizing agent is selected 25% potassium hydroxide solution, and frostproofer is selected glycols oligopolymer.
5. a kind of Multifunctional ecotype interior wall coating material according to claim 1, is characterized in that, described titanium dioxide is commercially available Rutile type Titanium Dioxide or commercially available anatase thpe white powder.
6. a kind of Multifunctional ecotype interior wall coating material according to claim 1, is characterized in that, described low VOC mill base is the commercially available low VOC mill base product that does not contain the pigment of heavy metal.
7. a kind of Multifunctional ecotype interior wall coating material according to claim 1, it is characterized in that, described functional material is made up of following material: sepiolite powder, oyster shell whiting, diatomite, brucite powder, nano zine oxide, nano titanium oxide, nano silicon, and its composition mass fraction and preparation technology are as follows:
1) composition massfraction:
Sepiolite powder 15-30,
Brucite powder 10-25,
Nano zine oxide 3-8,
Nano-titanium oxide 3-8,
Nano silicon oxide 3-8,
Diatomite 20-30,
Oyster shell whiting 20-40;
2) preparation technology: according to 1) in composition massfraction obtain described functional composite material herein after sepiolite powder, oyster shell whiting, diatomite, brucite powder, nano zine oxide, nano titanium oxide, nano silicon are dropped into powder mixer mixing 10-15min successively.
8. a kind of Multifunctional ecotype interior wall coating material according to claim 1, is characterized in that, described white sand is shell sand or Dali stone sand.
9. a kind of Multifunctional ecotype interior wall coating material according to claim 1, is characterized in that, described powder analog assistant is respectively any one in Vltra tears, wood fibre, lubricant, two or three combination.
10. a preparation method for Multifunctional ecotype interior wall coating material as claimed in claim 1, is characterized in that, this preparation method carries out according to following steps:
1) first deionized water, emulsion are added in reactor and under whipped state, add successively liquid type auxiliary agent, titanium dioxide, disperse to mix colours according to the low VOC mill base of client's design requirements tinctorial pattern after 15 minutes;
2) functional composite material, powder analog assistant, white sand are added in powder mixer mixed after 10 minutes blowing stand-by;
3) by step 2) in emit slowly to add under powder stirring state and in reactor, mix rear check, blowing packing.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410099990.9A CN103864349B (en) | 2014-03-18 | 2014-03-18 | A kind of Multifunctional ecotype interior wall coating material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410099990.9A CN103864349B (en) | 2014-03-18 | 2014-03-18 | A kind of Multifunctional ecotype interior wall coating material and preparation method thereof |
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| CN103864349A true CN103864349A (en) | 2014-06-18 |
| CN103864349B CN103864349B (en) | 2016-09-14 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105541187A (en) * | 2015-12-18 | 2016-05-04 | 三棵树涂料股份有限公司 | Bright and beautiful-color real-stone-feeling paint and preparation method thereof |
| CN108610817A (en) * | 2017-01-05 | 2018-10-02 | 胡春宇 | Nana intelligent health powdery paints |
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| CN101348628A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Thick coating material purifying air and preparing method thereof |
| CN101481230A (en) * | 2008-11-18 | 2009-07-15 | 唐山长虹涂料有限公司 | Ceramic tile intimating construction coating and preparation thereof |
| CN101921501A (en) * | 2010-08-09 | 2010-12-22 | 江苏大象东亚制漆有限公司 | Nano coating additive and coating composite containing same |
| CN102604492A (en) * | 2012-03-14 | 2012-07-25 | 沈阳顺风新城建筑材料有限公司 | Preparation method of black sand primer paint assorted with ceramic tile simulated outer-wall coating |
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2014
- 2014-03-18 CN CN201410099990.9A patent/CN103864349B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348628A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Thick coating material purifying air and preparing method thereof |
| CN101481230A (en) * | 2008-11-18 | 2009-07-15 | 唐山长虹涂料有限公司 | Ceramic tile intimating construction coating and preparation thereof |
| CN101921501A (en) * | 2010-08-09 | 2010-12-22 | 江苏大象东亚制漆有限公司 | Nano coating additive and coating composite containing same |
| CN102604492A (en) * | 2012-03-14 | 2012-07-25 | 沈阳顺风新城建筑材料有限公司 | Preparation method of black sand primer paint assorted with ceramic tile simulated outer-wall coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105541187A (en) * | 2015-12-18 | 2016-05-04 | 三棵树涂料股份有限公司 | Bright and beautiful-color real-stone-feeling paint and preparation method thereof |
| CN105541187B (en) * | 2015-12-18 | 2017-12-08 | 三棵树涂料股份有限公司 | One kind has true mineral varnish of the gorgeous color of light and preparation method thereof |
| CN108610817A (en) * | 2017-01-05 | 2018-10-02 | 胡春宇 | Nana intelligent health powdery paints |
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| CN103864349B (en) | 2016-09-14 |
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Effective date of registration: 20190129 Address after: 266000 Level 102, 104, C1 Floor 1, Area C, Qingdao Institute of Industrial Technology, 17 Songyuan Road, Qingdao High-tech Zone, Shandong Province Patentee after: Qingdao Hai Fu Lai Safety Technology Co., Ltd. Address before: Room 102, Unit 4, Building 51, Shuiqingmuhua, Xinjiang, 216 Heilongjiang Road, Chengyang District, Qingdao City, Shandong Province Patentee before: Wang Xiangyang |