CN107083122A - A kind of nanometer internal wall fungicidal paint and preparation method thereof - Google Patents
A kind of nanometer internal wall fungicidal paint and preparation method thereof Download PDFInfo
- Publication number
- CN107083122A CN107083122A CN201710472251.3A CN201710472251A CN107083122A CN 107083122 A CN107083122 A CN 107083122A CN 201710472251 A CN201710472251 A CN 201710472251A CN 107083122 A CN107083122 A CN 107083122A
- Authority
- CN
- China
- Prior art keywords
- internal wall
- parts
- fungicidal paint
- nanometer internal
- nanometer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0831—Gold
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses a kind of nanometer internal wall fungicidal paint and preparation method thereof.The raw material of the nanometer internal wall fungicidal paint includes by weight：15~30 parts of polymer emulsion, 5~10 parts of cationic block copolymers, 1~5 part of alcohol organic solvent, 1~3 part of nano titanium oxide, 0.1~0.5 part of nanogold, modified 0.1~0.2 part of sodium disilicate, 0.1~0.3 part of Ricinate, 15~18 parts of powdered whiting, 0.2~0.4 part of defoamer, 10~20 parts of water.The nanometer internal wall fungicidal paint of the present invention be it is a kind of there is excellent water resistance energy, the environmental protection coating material of wash-resistant property, be chronically exposed in air and do not ftracture, do not fall off, and with stronger bactericidal effect, it is adaptable to the decorations of indoor wall.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of nanometer internal wall fungicidal paint and preparation method thereof.
Background technology
With social progress and the raising of living standards of the people, various coating can particularly meet specific industry domain requirement
Functional paint demand it is increasing, its pollution of contained organic matter to environment is increasingly severe.The quality of coating quality
Directly influence the class and the market competitiveness of the products such as automobile, building materials, instrument and meter, electronic product, ship, aircraft, the world
In the range of requirement also more and more higher to environmental protection, each state all throwing huge fund and carrying out the research and development of environment-friendly type coating.
Construction wall decoration coating directly embodies and influenceed household as an important major class in decorate home material
The effect and function of decoration.In the last few years, market was to tend to multi-functional, high added value and superior to the demand of such product.
Therefore, according to the difference in functionality and feature of coating, there are automatically cleaning pollution resistance, scrubbing resistance row, against weather and quality persistent
Multifunctional nano composite exterior wall coating is received by the market, and just progressively turns into a kind of important leading products system in coating industry
Row.
Interior wall coating water resistance used at present is bad, bond strength is not good, and coating can be caused by causing to clean for a long time
Come off, and existing coating also generally existing the problem of antibacterial term of validity is short.Therefore, a kind of water resistance how is prepared
The problem of good, bond strength height and the good coating of anti-microbial property are current urgent need to resolve.
The content of the invention
In view of this, the invention provides a kind of nanometer internal wall fungicidal paint and preparation method thereof, its have it is water-fastness, from
The good advantage of cleaning, antipollution, anti-microbial property.
The present invention, which is adopted the following technical scheme that, realizes above-mentioned purpose：
The invention provides a kind of nanometer internal wall fungicidal paint, its raw material includes by weight：Polymer emulsion 15~30
Part, 5~10 parts of cationic block copolymers, 1~5 part of alcohol organic solvent, 1~3 part of nano titanium oxide, nanogold 0.1~
0.5 part, modified 0.1~0.2 part of sodium disilicate, 0.1~0.3 part of Ricinate, 15~18 parts of powdered whiting, defoamer
0.2~0.4 part, 10~20 parts of water.
It is preferred that, nanometer internal wall fungicidal paint of the invention, its raw material is made up of following components by weight：Polymer breast
15~30 parts of liquid, 5~10 parts of cationic block copolymers, 1~5 part of alcohol organic solvent, 1~3 part of nano titanium oxide, nanometer
0.1~0.5 part of gold, modified 0.1~0.2 part of sodium disilicate, 0.1~0.3 part of Ricinate, 15~18 parts of powdered whiting,
0.2~0.4 part of defoamer, 10~20 parts of water.
Wherein, described polymer emulsion is preferably styrene-acrylic emulsion.
Wherein, described cationic block copolymers are preferably the cationic block containing methyl methacrylate block
Copolymer, more preferably methyl methacrylate-[2- (methacryloxypropyl) ethyl] trimethyl ammonium chloride block polymer, i.e.,
P(MMA)-b-P(METEA).The present invention further preferably uses following three kinds of block copolymers：P(MMA)20-b-P(METEA)10、P
(MMA)20-b-P(METEA)20、P(MMA)20-b-P(METEA)30。
Wherein, described alcohol organic solvent is preferably ethanol and/or methanol.
Wherein, the particle diameter of described nano titanium oxide is preferably 20~40nm.
Wherein, the particle diameter of described nanogold is preferably 10~20nm.
Wherein, described defoamer is preferably defoamer CF-16.
Wherein, described Ricinate is preferably dispersant SN-5040.
Wherein, described modification sodium disilicate can use the product of commercialization, and commercial disignation is MDS, is purchased from the prosperous profit in Hubei
Moral Chemical Co., Ltd., it is to be formed through waterglass addition coagent through specific technique productions.
The present invention, by adding the synergy of block copolymer and modified sodium disilicate, forms big point in interior wall coating
The spatial network of son, especially forms the composite coating of hybrid inorganic-organic, improves the water resistance and scrub resistance of film,
The adhesive force and hygroscopic capacity of film are greatly enhanced simultaneously；Nano titanium oxide and the association of nanogold by addition
Same-action improves the anti-microbial property of coating, and especially it is using above-mentioned macromolecular spatial network as carrier, the sterilization being consequently formed
Effect is more obvious.
Present invention also offers the preparation method of above-mentioned nanometer internal wall fungicidal paint, it comprises the steps：
Water, polymer emulsion, cationic block copolymers, alcohol organic solvent, Ricinate are added in agitator,
Nano titanium oxide, nanogold, modified sodium disilicate, powdered whiting, defoamer are added after stirring, it is agitated uniform
.
The positive effect that the present invention is obtained：The nanometer internal wall fungicidal paint of the present invention is a kind of with excellent water resistance
Energy, the environmental protection coating material of wash-resistant property, are chronically exposed in air and do not ftracture, do not fall off, and with stronger bactericidal effect, fit
Decorations for indoor wall.
Embodiment
Technical scheme is further illustrated with reference to specific embodiment.
Antibiotic rate is tested：
By 2mL floras suspension inoculation in 6 porocyte culture plates, sterilized water 2mL is added, as blank negative control group,
Its OD value is surveyed, OD is designated as0；2mL coating samples are added in 2mL floras suspension, are equally inoculated in 6 porocyte culture plates, it is ultraviolet
Its OD value is surveyed after light irradiation 96h, OD is designated as1；OD0With OD1Difference again divided by OD0Produce antibiotic rate.
Embodiment 1
Composition of raw materials is as shown in the table：
Wherein, polymer emulsion is styrene-acrylic emulsion；Cationic block copolymers are P (MMA)20-b-P(METEA)10；Alcohols
Organic solvent is ethanol；The particle diameter of nano titanium oxide is 20~40nm；The particle diameter of nanogold is 10~20nm；Defoamer is to disappear
Infusion CF-16；Ricinate is dispersant SN-5040；The commercial disignation of modified sodium disilicate is MDS, is purchased from the prosperous profit in Hubei
Moral Chemical Co., Ltd..
Preparation method：Water is added in agitator, it is polymer emulsion, cationic block copolymers, alcohol organic solvent, wet
Moisten dispersant, nano titanium oxide, nanogold, modified sodium disilicate, powdered whiting, defoamer added after stirring,
It is agitated uniform.
The performance for the nanometer internal wall fungicidal paint that the present embodiment is obtained is as shown in the table：
In coating due to quaternary ammonium salt, nano titanium oxide, nanogold synergy, can kill or suppress flora life
It is long, make coating that there is preferable antibacterial effect.
Embodiment 2
Composition of raw materials is as shown in the table：
| Sequence number | Title material | Parts by weight |
| 1 | Polymer emulsion | 24 |
| 2 | Cationic block copolymers | 7 |
| 3 | Alcohol organic solvent | 3 |
| 4 | Nano titanium oxide | 2 |
| 5 | Nanogold | 0.3 |
| 6 | Modified sodium disilicate | 0.2 |
| 7 | Ricinate | 0.2 |
| 8 | Powdered whiting | 16 |
| 9 | Defoamer | 0.3 |
| 10 | Water | 15 |
Wherein, polymer emulsion is styrene-acrylic emulsion；Cationic block copolymers are P (MMA)20-b-P(METEA)20；Alcohols
Organic solvent is methanol；The particle diameter of nano titanium oxide is 20~40nm；The particle diameter of nanogold is 10~20nm；Defoamer is to disappear
Infusion CF-16；Ricinate is dispersant SN-5040；The commercial disignation of modified sodium disilicate is MDS, is purchased from the prosperous profit in Hubei
Moral Chemical Co., Ltd..
Preparation method：Water is added in agitator, it is polymer emulsion, cationic block copolymers, alcohol organic solvent, wet
Moisten dispersant, nano titanium oxide, nanogold, modified sodium disilicate, powdered whiting, defoamer added after stirring,
It is agitated uniform.
The performance for the nanometer internal wall fungicidal paint that the present embodiment is obtained is as shown in the table：
In coating due to quaternary ammonium salt, nano titanium oxide, nanogold synergy, can kill or suppress flora life
It is long, make coating that there is preferable antibacterial effect.
Embodiment 3
Composition of raw materials is as shown in the table：
| Sequence number | Title material | Parts by weight |
| 1 | Polymer emulsion | 30 |
| 2 | Cationic block copolymers | 10 |
| 3 | Alcohol organic solvent | 5 |
| 4 | Nano titanium oxide | 3 |
| 5 | Nanogold | 0.5 |
| 6 | Modified sodium disilicate | 0.2 |
| 7 | Ricinate | 0.3 |
| 8 | Powdered whiting | 18 |
| 9 | Defoamer | 0.4 |
| 10 | Water | 20 |
Wherein, polymer emulsion is styrene-acrylic emulsion；Cationic block copolymers are P (MMA)20-b-P(METEA)30；Alcohols
Organic solvent is ethanol；The particle diameter of nano titanium oxide is 20~40nm；The particle diameter of nanogold is 10~20nm；Defoamer is to disappear
Infusion CF-16；Ricinate is dispersant SN-5040；The commercial disignation of modified sodium disilicate is MDS, is purchased from the prosperous profit in Hubei
Moral Chemical Co., Ltd..
Preparation method：Water is added in agitator, it is polymer emulsion, cationic block copolymers, alcohol organic solvent, wet
Moisten dispersant, nano titanium oxide, nanogold, modified sodium disilicate, powdered whiting, defoamer added after stirring,
It is agitated uniform.
The performance for the nanometer internal wall fungicidal paint that the present embodiment is obtained is as shown in the table：
In coating due to quaternary ammonium salt, nano titanium oxide, nanogold synergy, can kill or suppress flora life
It is long, make coating that there is preferable antibacterial effect.
Obviously, the explanation of above example is only intended to product, method and its core concept for helping to understand the present invention.Should
, under the premise without departing from the principles of the invention, can also be right for the those of ordinary skill of the technical field when pointing out
The present invention carries out some improvement and modification, and these are improved and modification is also fallen into the protection domain of the claims in the present invention.
Claims (10)
1. a kind of nanometer internal wall fungicidal paint, its raw material includes by weight：15~30 parts of polymer emulsion, cationic block is common
5~10 parts of polymers, 1~5 part of alcohol organic solvent, 1~3 part of nano titanium oxide, 0.1~0.5 part of nanogold, modified two silicic acid
0.1~0.2 part of sodium, 0.1~0.3 part of Ricinate, 15~18 parts of powdered whiting, 0.2~0.4 part of defoamer, water 10~
20 parts.
2. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that the original of described nanometer internal wall fungicidal paint
Material is made up of following components by weight：15~30 parts of polymer emulsion, 5~10 parts of cationic block copolymers, alcohols is organic
1~5 part of solvent, 1~3 part of nano titanium oxide, 0.1~0.5 part of nanogold, modified 0.1~0.2 part of sodium disilicate, moistening point
0.1~0.3 part of powder, 15~18 parts of powdered whiting, 0.2~0.4 part of defoamer, 10~20 parts of water.
3. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that described polymer emulsion is phenylpropyl alcohol breast
Liquid.
4. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that described cationic block copolymers be containing
There are the cationic block copolymers of methyl methacrylate block, preferably methyl methacrylate-[2- (methacryls
Oxygen) ethyl] trimethyl ammonium chloride block polymer.
5. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that described alcohol organic solvent is ethanol
And/or methanol.
6. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that the particle diameter of described nano titanium oxide is
20~40nm.
7. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that the particle diameter of described nanogold is 10~
20nm。
8. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that described defoamer is defoamer CF-16.
9. nanometer internal wall fungicidal paint as claimed in claim 1, it is characterised in that described Ricinate is dispersant
SN-5040。
10. a kind of preparation method of such as nanometer internal wall fungicidal paint according to any one of claims 1 to 9, it includes following
Step：
Water, polymer emulsion, cationic block copolymers, alcohol organic solvent, Ricinate, stirring are added in agitator
Nano titanium oxide, nanogold, modified sodium disilicate, powdered whiting, defoamer are added after uniform, it is agitated to be uniformly
Can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710472251.3A CN107083122A (en) | 2017-06-20 | 2017-06-20 | A kind of nanometer internal wall fungicidal paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710472251.3A CN107083122A (en) | 2017-06-20 | 2017-06-20 | A kind of nanometer internal wall fungicidal paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107083122A true CN107083122A (en) | 2017-08-22 |
Family
ID=59605879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710472251.3A Pending CN107083122A (en) | 2017-06-20 | 2017-06-20 | A kind of nanometer internal wall fungicidal paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107083122A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343441A (en) * | 2019-08-14 | 2019-10-18 | 炫杰复合材料（上海）有限公司 | A kind of water negative ion coating and preparation method thereof |
| CN113480900A (en) * | 2021-05-28 | 2021-10-08 | 深圳市能驭生态化工科技有限公司 | Daily light source sterilization and disinfection water-based transparent coating and preparation method thereof |
| CN113861498A (en) * | 2021-09-17 | 2021-12-31 | 刘轩彤 | Stain-resistant flame-retardant building outer wall and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1583907A (en) * | 2004-06-14 | 2005-02-23 | 深圳清华大学研究院 | Multifuntional green environmental protection nanometer titania coating and preparing method thereof |
| CN1616559A (en) * | 2004-09-24 | 2005-05-18 | 深圳清华大学研究院 | Nano metal silver antibiotic paint and its preparing method |
| CN101338101A (en) * | 2008-08-14 | 2009-01-07 | 广州市星冠化工涂料有限公司 | Nanometer interior wall coating g |
| CN102329539A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Interior wall coating and preparation method thereof |
| CN102443324A (en) * | 2010-10-07 | 2012-05-09 | 艾永平 | Interior and exterior wall paint and production method thereof |
-
2017
- 2017-06-20 CN CN201710472251.3A patent/CN107083122A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1583907A (en) * | 2004-06-14 | 2005-02-23 | 深圳清华大学研究院 | Multifuntional green environmental protection nanometer titania coating and preparing method thereof |
| CN1616559A (en) * | 2004-09-24 | 2005-05-18 | 深圳清华大学研究院 | Nano metal silver antibiotic paint and its preparing method |
| CN101338101A (en) * | 2008-08-14 | 2009-01-07 | 广州市星冠化工涂料有限公司 | Nanometer interior wall coating g |
| CN102443324A (en) * | 2010-10-07 | 2012-05-09 | 艾永平 | Interior and exterior wall paint and production method thereof |
| CN102329539A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Interior wall coating and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张文福 等: "《现代消毒学新技术与应用》", 31 July 2013, 军事医学科学出版社 * |
| 赵玥: "TiO_2基抗菌自清洁涂料的制备及性能研究", 《化工新型材料》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343441A (en) * | 2019-08-14 | 2019-10-18 | 炫杰复合材料（上海）有限公司 | A kind of water negative ion coating and preparation method thereof |
| CN110343441B (en) * | 2019-08-14 | 2021-03-26 | 炫杰复合材料（上海）有限公司 | Water-based negative ion coating and preparation method thereof |
| CN113480900A (en) * | 2021-05-28 | 2021-10-08 | 深圳市能驭生态化工科技有限公司 | Daily light source sterilization and disinfection water-based transparent coating and preparation method thereof |
| CN113861498A (en) * | 2021-09-17 | 2021-12-31 | 刘轩彤 | Stain-resistant flame-retardant building outer wall and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109735154B (en) | Long-acting antibacterial agent, long-acting antibacterial agent with immediate effect and preparation method thereof | |
| CN101250376B (en) | Silicone exterior wall paint and preparation method thereof | |
| CN103937351B (en) | A kind of wallpaper basement membrane and preparation method thereof | |
| CN103483883B (en) | A kind of High-performance silica sol inorganic exterior coating | |
| CN105838158B (en) | Mould proof diatom ooze coating of spot-resistant and preparation method thereof | |
| CN103642347B (en) | A kind of ecological diatom coating and preparation method thereof | |
| CN107083122A (en) | A kind of nanometer internal wall fungicidal paint and preparation method thereof | |
| CN104673033B (en) | A kind of inorganic aqueous metallic paint and preparation method thereof | |
| CN105017906B (en) | A kind of colorful sealing wax of water-water and preparation method thereof | |
| CN104743972A (en) | Indoor inorganic dry powder building coating capable of automatically regulating humidity | |
| CN102229771A (en) | Diatomaceous earth active paint and preparation method thereof | |
| CN108034295A (en) | A kind of inorganic environment-friendly interior wall mould proof antibacterial paint | |
| KR101052608B1 (en) | Aqueous paints for humidity controlling and deodorizing activity in the room | |
| CN106116271A (en) | Interior wall coating kieselguhr wall material with purification function and preparation method thereof | |
| CN106752590A (en) | A kind of anti-formaldehyde novolac of aqueous wooden ware and preparation method thereof | |
| CN105440817A (en) | Preparation method of unlimited-color multifunctional antistatic aqueous coating | |
| CN113136127B (en) | Antiviral healthy plant water paint and preparation method thereof | |
| CN107474646A (en) | A kind of photo-catalytic coating and preparation method thereof | |
| CN105273544A (en) | Water-based fluorescent paint and preparation method thereof | |
| CN104910784A (en) | Coating material which is special for wallpaper and provided with indoor air purification function | |
| CN105331230A (en) | Environment-friendly waterproof coating and preparation method thereof | |
| CN108102489A (en) | A kind of Environmental Protective Water-paint and preparation method thereof | |
| CN104497663A (en) | Antibacterial latex paint | |
| JP6764889B2 (en) | Antibacterial and antifungal paint, algae-proof paint, antibacterial and antifungal member manufacturing method, and algae-proof member manufacturing method | |
| CN111423783A (en) | Antibacterial odor-removing water-based environment-friendly building coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170822 |
|
| RJ01 | Rejection of invention patent application after publication |