CN106545142B - A kind of flexible clay facing tile with air-cleaning function - Google Patents
A kind of flexible clay facing tile with air-cleaning function Download PDFInfo
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- CN106545142B CN106545142B CN201611122846.8A CN201611122846A CN106545142B CN 106545142 B CN106545142 B CN 106545142B CN 201611122846 A CN201611122846 A CN 201611122846A CN 106545142 B CN106545142 B CN 106545142B
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5041—Titanium oxide or titanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses a kind of flexible clay facing tiles with air-cleaning function, it is made of flexible clay facing tile and automatic cleaning coating.The composition of the automatic cleaning coating are as follows: 20~40 parts of modified acrylate emulsion, nano-TiO215~35 parts of the hydrosol, Nano-meter SiO_2215~35 parts of the hydrosol；The composition of the flexible clay facing tile are as follows: 8~15 parts of lotion, 5~10 parts of kaolin, 15~25 parts of heavy calcium carbonate, 5~20 parts of cement, 5~15 parts of negative ion powder, 40~50 parts of quartz sand, 0.1~1 part of inorganic pigment and 10~20 parts of water.The flexible clay facing tile preparation method is simple, energy conservation and environmental protection, and the long-acting sustained release anion of flexible clay facing tile energy being prepared passes through nano-TiO in coating to effectively adsorb tiny particles content, peculiar smell and the toxic gas in air2Photocatalysis decompose peculiar smell and toxic gas, and coating has excellent automatic cleaning action, is a kind of ecological architectural material with air-cleaning function and decoration functions.
Description
Technical field
The present invention relates to new decorative material for building technical field more particularly to a kind of flexibilities with air-cleaning function
Tapestry brick.
Background technique
Haze is the mixture of mist and haze, and when morning and evening humidity is big, the ingredient of mist is more.Humidity hour on daytime, haze occupy the main force,
Relative humidity is between 80% to 90%.Wherein mist is natural weather phenomenon, the steam generative forces of heaven and earth in air.Although using dust as solidifying
Tuberculosis, but it is overall nontoxic；It is low that the core substance of haze is suspended in substances, the relative air humidities such as cigarette, dust in air
In 80%, yellowish.Gas can be directly entered and be adhered in human body lower respiratory tract and the lobe of the lung, have injury to human health.
The formation of haze weather is mainly artificial environmental pollution, and along with temperature is low, wind is small etc., natural conditions lead to pollutant not
Easily diffusion.Haze increasingly influenced the life of this people in recent years, especially will affect people in haze environment for a long time
The health of the people.
Negative ion powder is the principle that human use's nature generates anion, and artificial synthesized or proportion one kind is compound
Mineral, typically tourmaline powder+lanthanide series or rare earth element, wherein the ratio of rare earth element greatly exceeds electricity
Gas mountain flour, rare earth have accounted for 60% or more.It is the effective means with germ and purification air is killed that anion, which is identified,.Its machine
After reason essentially consists in anion in conjunction with bacterium, so that bacterium is generated the change of structure or the transfer of energy, lead to bacterial death, most
Final decline is sunken to ground.Medical research shows in air that electronegative particle increases oxygen content in blood, be conducive to blood oxygen conveying,
It absorbs and utilizes, have and promote human metabolism, improve human immunological competence, enhance human muscle energy, it is flat to adjust body function
The effect of weighing apparatus.According to textual criticism, for anion to 7 systems of human body, nearly more than 30 kinds of diseases have inhibition, alleviation and auxiliary therapeutic action,
Especially the health-care effect of human body is become apparent.
Research has shown that anion has the effect of preventing haze well, and Chinese patent 201510193947.3 discloses
A kind of anion is to improve existing cement or pitch composite material bearing capacity except haze road material and preparation method thereof
On the basis of, a kind of polymer composite safely, effectively, persistently, convenient, healthy is provided.Composite technology and common
Pitch composite material mixed phase is same, 100/cm of anion number static state3, dynamically in 600/cm3More than.In its manufacturing process
The release anionic additive formulated by natural minerals is added, due to anionic additive nano-pore adsorption mechanism, variable valency metal
The principles of work and power such as the mechanism of action, permanent electrode mechanism, antibacterial bacteriostatic, using can be released in health-care environment protection type composite material of the present invention
Put anion, emitting far-infrared, electromagnetic radiation resistant, by the combined processes such as electrical neutralization, physical absorption, chemical reaction come
It reaches to decrease or even eliminate " vehicle exhaust " and " photochemical pollution ", keeps the health of human body.
Chinese patent 201610208980.3 discloses a kind of haze anion bamboo charcoal spinning mask, preparation bear from
Sub- bamboo charcoal spin filter layer generates anion, charge effect of the PM2.5 in anion by the pyroelectricity and piezoelectricity of tourmaline
Lower absorption, aggregation, sedimentation, using the hole of bamboo charcoal prosperity, huge specific surface area and extremely strong adsorption capacity come to PM2.5 into
Row sedimentation removal, purifies the air of oral-nasal perimeter, forms one layer of separation layer, to achieve the effect that anti-haze.It is produced by the present invention
Haze anion bamboo charcoal spinning mask gas permeability is splendid, removes thoroughly to deleterious particle in PM2.5 and air, cleaning week
Phase is short, and service life is long.
Flexible clay facing tile, also known as bright and beautiful clay (brocade: rich in color, clay: fine and glossy clay).It is with color modified inorganic mineral powder
Material is primary raw material, adds a small amount of water soluble polymer, flexible light by having made of specific technique
Matter building decoration, this respect are different from porcelain tendre, are the alternative materials of ideal traditional decoration building materials porcelain face brick, are suitable for coagulation
The energy conservation of the various newly-built walls such as soil, building block, external thermal insulation system and existing building is transformed with facing.
Flexible clay facing tile can be combined with the various External Thermal Insulation Technology for External used on the market at present, without changing exterior wall
The original technology way of external thermal insulation is directly pasted in outer thermal-insulating and anti-cracking protective layer.Compared to traditional porcelain face brick outer heat preservation system
Way, flexible clay facing tile have three advantages:
First is that safe and reliable from heavy and light, system, avoid due to porcelain face brick and the warm and humid shear stress of protective facing it is big and
The risk fallen；
Second is that steam permeability is extremely strong, waterproofness is again splendid, had not only overcome rainwater and has penetrated into exterior insulation within the walls, but also has prevented
Freeze thawing damage occurs for condensed water；
Third is that the arrangement of reinforcement quantity of structure foundation wall can be reduced, exterior insulation way is simplified, simplifies surface brick adherence process, not only
50% or more work efficiency can be improved, and comprehensive cost reduces by 30% or more, remarkable in economical benefits.
Compared to other same type of material, flexible clay facing tile has two big advantages: first is that water repellent and steam permeability are good, generically
It says, is exactly liquid water into not going, vaporous water can come out, it can be ensured that entire wall has respiratory.Second is that at flexible clay facing tile
Glue is not returned under hot environment, does not return white after brew 96 hours in 85 DEG C or more of hot water and can still be restored to the original state, automatically cleaning
Ability is strong, and the punching of wind water can be bright and clean as fresh.
Chinese patent 201110313406.1 discloses a kind of multi-functional environment-protection building coating, by weight by following components
Composition: 25-60 parts of filler；30-60 parts of ordor removing lotion；1-5 parts of negative ion powder；5-10 parts of fire retardant；20-35 parts of water, auxiliary agent 2-
5 parts；Wherein, the filler includes 0.5~2 part of wood fibre (80-200 mesh), 10~20 parts of diatomite (80-180 mesh), aperture
5~15 parts of expanded perlite (10-180 mesh).The present invention has the following advantages and effects: sound-absorbing effect is good；Air is purified, is adjusted
Humidity, a large amount of hole contained in film, internal surface area is big, can adsorb the toxic and harmful gas in air, while can be with
Adjust indoor air humidity；Dry- film density is low, has good energy-saving heat preserving performance；Easy construction: it when construction, can directly close
Overall beautiful coating is sprayed on lattice material.
Chinese patent 201110461072.2 discloses a kind of negative ion inorganic dry powder coating and preparation method thereof and construction
Technique.Negative ion inorganic dry powder coating is by a group major ingredient: latex powder, diatomite, silicate, negative ion powder, medical stone；Pair material: hydroxyl
Ethyl cellulose, fiber, titanium dioxide, attapulgite, quartz sand composition, by stirring at low speed mixing, filter screen filtration is made.This
The step of negative ion inorganic dry powder coating of invention applies feed liquid, batch wall and post-processing by construction pre-treatment, modulation is constructed.
The negative ion inorganic dry powder coating reduces the dosage of resin, reduces coating cost；Wherein diatomite has coating excellent
Different surface property, increase-volume, thickening and raising adhesive force, because it is with biggish pore volume, when film can be made to shorten dry
Between；And diatomite, medical stone can decompose indoor formaldehyde, have good environmental-protection function.Anion inorganic dry powder of the present invention
The preparation method and construction party simple process of coating, it is easy to operate, easily implement.
Chinese patent 201110313406.1 discloses a kind of multi-functional environment-protection building coating, by weight by following components
Composition: 25-60 parts of filler；30-60 parts of ordor removing lotion；1-5 parts of negative ion powder；5-10 parts of fire retardant；20-35 parts of water, auxiliary agent 2-
5 parts；Wherein, the filler includes 0.5~2 part of wood fibre (80-200 mesh), 10~20 parts of diatomite (80-180 mesh), aperture
5~15 parts of expanded perlite (10-180 mesh).The present invention has the following advantages and effects: sound-absorbing effect is good；Air is purified, is adjusted
Humidity, a large amount of hole contained in film, internal surface area is big, can adsorb the toxic and harmful gas in air, while can be with
Adjust indoor air humidity；Dry- film density is low, has good energy-saving heat preserving performance；Easy construction: it when construction, can directly close
Overall beautiful coating is sprayed on lattice material.
Chinese patent 201510143715.7 discloses a kind of negative ion ceramic glaze and prepares anion ceramics using it
The method of brick, wherein negative ion ceramic glaze each component are as follows: kaolin, potassium feldspar, nano-titanium dioxide, nanometer dravite
Powder, nanometer elbaite powder, praseodymium sesquioxide, water.Above-mentioned raw materials are fitted into 12~58h of ball milling in ball mill, by removing iron, mistake
Negative ion ceramic glaze is obtained after riddler's skill, applies above-mentioned glaze, glaze thickness to the ceramic body after drying with the mode of glaze spraying
0.35~0.55mm fires 2~8h at 1000~1280 DEG C of temperature, has obtained the anion glaze with health care, environment-friendly function
Face brick.The anion glazed tile is capable of releasing negative ion, increases the negative ion concentration of room air, plays improvement sleep, makes to breathe
Smooth, strengthen immunity makes that blood pressure is normal, purification blood and other effects.
Chinese patent 200410079022.8 discloses a kind of method for producing health ceramic brick capable of releasing negative ion, is making pottery
Nano composite negative ion powder is introduced in ceramic tile, formula composition is that elbaite accounts for 20~40%, dravite and accounts for 10~20%,
Nanometer Ti O2 accounts for 20~40%, other rare earth composite salts account for 5~12%, and nano composite negative ion powder is good with ceramic matrix
Good combines, and is burnt at 1080 DEG C~1200 DEG C of temperature through ceramic roller kiln, thus obtain have stablize release bear from
Glaze for glazed tile and that radiation performance is up to standard, the anion releasability of final products can reach health requirements, radiate performance
Equal Indexs measures are both needed to meet the health building materials of national building materials requirement standard.
But flexible clay facing tile on the market but be all only there is decoration function, and current people are in house decoraton at present
Requirement for indoor air quality is higher and higher, mostly there is the problems such as formaldehyde in the room especially just fitted up,
Therefore developing one kind not only has decoration functions, but also the face brick with air-cleaning function, can satisfy people for indoor and outdoor
The demand of air cleaning, and save trouble and labor.
Summary of the invention
In order to solve deficiency existing for existing building decoration materials, it is an object of that present invention to provide one kind to have air net
Change the flexible clay facing tile and preparation method thereof of function.
The technical solution adopted by the present invention is that:
Flexible clay facing tile with air-cleaning function of the invention is made of flexible clay facing tile and automatic cleaning coating:
The automatic cleaning coating is made of the raw material of following parts by weight: 20~40 parts of modified acrylate emulsion, being received
Rice TiO215~35 parts of the hydrosol, Nano-meter SiO_2215~35 parts of the hydrosol and 20~40 parts of water；
The flexible clay facing tile is made of the raw material of following parts by weight: 8~15 parts of lotion, 5~10 parts of kaolin, and weight
15~25 parts of matter Paris white, 5~20 parts of cement, 5~15 parts of negative ion powder, 40~50 parts of quartz sand, inorganic pigment 0.1~1
Part and 10~20 parts of water.
It is preferred that: the automatic cleaning coating of the flexible clay facing tile with air-cleaning function of the invention is by following parts by weight
Raw material composition: 30 parts of modified acrylate emulsion, nano-TiO225 parts of the hydrosol, Nano-meter SiO_2225 parts of the hydrosol；The flexibility
Tapestry brick is made of the raw material of following parts by weight: 10 parts of lotion, 8 parts of kaolin, and 20 parts of heavy calcium carbonate, 15 parts of cement,
10 parts of negative ion powder, 45 parts of quartz sand, 0.5 part of inorganic pigment and 15 parts of water.
The modified acrylate emulsion is self-crosslinking silicone modified acrylate emulsion or fluorin modified crylic acid ester lotion
One of, solid content is 40~60%.
The TiO2TiO in the hydrosol2Content is that 15~30%, pH is 6~8；The SiO2SiO in the hydrosol2Contain
It is 6~10 that amount, which is 20~30%, pH,.
The lotion is silicone acrylic emulsion, and solid content 50%, glass transition temperature is 5~30 DEG C.
The kaolin is washing or calcined kaolin, and partial size is 200~1250 mesh；The grain of the heavy calcium carbonate
Diameter is 0.5~3 μm.
The cement is portland cement, ordinary portland cement, portland slag cement, Portland pozzolana cement
And one of composite Portland cement.
The negative ion powder is made of the raw material of following parts by weight: 15~40 parts of tourmaline, 10~20 parts of neodymia,
Terbium sesquioxide or 15~30 parts of terbium peroxide, 10~30 parts of opal.
The partial size of the quartz sand is 50~400 mesh；The inorganic pigment is carbon black, titanium white, titan yellow, iron oxide
One or both of red, iron oxide yellow, barba hispanica, cadmium red, cadmium yellow.
Specific step is as follows for the preparation method of flexible clay facing tile with air-cleaning function of the invention:
(1) preparation of flexible clay facing tile:
Lotion, inorganic pigment and water are first weighed by weight, are stirred evenly, are obtained emulsion mixture；Then by weight
Kaolin, heavy calcium carbonate, cement, negative ion powder and quartz sand are weighed, is uniformly mixed, obtains powder mixture；Again by powder
Body mixture is added in emulsion mixture, is sufficiently stirred, and mortar is obtained；Finally above-mentioned mortar is poured into mold, one layer of laying
Alkali resistant glass fibre open weave cloth is put into drying 3~5 hours in 40~100 DEG C of baking ovens later, flexible clay facing tile is obtained after demoulding；
(2) coating treatment of flexible clay facing tile:
Under stirring, nano-TiO is separately added into modified acrylate emulsion by weight2It the hydrosol and receives
Rice SiO2Above-mentioned mixed glue solution is coated in flexible clay facing tile after mixing by the hydrosol and water by way of spray, brush or rolling
Surface, obtain the flexible clay facing tile with Air purification after dry.
The positive effect of the present invention is as follows:
1. using self-crosslinking silicone or fluorin modified crylic acid ester lotion as nano-TiO2And Nano-meter SiO_22Binder for film formation, have
Conducive to being combined into an entirety between coating and flexible clay facing tile.
2. self-crosslinking silicone or fluorin modified crylic acid ester, nano-TiO2And Nano-meter SiO_22The coating of formation has excellent resistant
Property, self-cleaning property and weatherability, can effectively protect flexible clay facing tile, extend its working life.
3. the nanoparticle in coating has great surface area, can be adsorbed by physisorption tiny in air
Particulate matter, while the long-term sustained release anion of negative ion powder energy in flexible clay facing tile, can adsorb the fine particle in air
Object, particulate matter are enriched in flexible clay facing tile coating surface, and the self-cleaning function through coating removes, and eliminate haze to realize
Function.
4. flexible clay facing tile can adsorb peculiar smell and toxic gas in air, and through receiving in coating by discharging anion
Rice TiO2Photocatalysis decomposed, so as to eliminate the peculiar smell and toxic gas in air.
It is inside and outside a kind of environmental protection with air-cleaning function 5. the preparation method of flexible clay facing tile is simple, energy conservation and environmental protection
Wall building decoration materials.
Specific embodiment
The following examples are a further detailed description of the invention.
Embodiment 1
Flexible clay facing tile with air-cleaning function of the invention is made of flexible clay facing tile and automatic cleaning coating:
The automatic cleaning coating is made of the raw material of following parts by weight: 40 parts of acrylate emulsion modified with organosiloxane, nanometer
TiO215 parts of the hydrosol, Nano-meter SiO_2235 parts of the hydrosol and 40 parts of water；
The flexible clay facing tile is made of the raw material of following parts by weight: the third cream of silicon that glass transition temperature is 5 DEG C
8 parts of liquid, 5 parts of the water-washed kaoline of 200 mesh, 0.5 μm 15 parts of heavy calcium carbonate, 20 parts of portland cement, 15 parts of negative ion powder,
50 50 parts of mesh quartz sands, 0.1 part of carbon black and 20 parts of water.
Above-mentioned negative ion powder is made of the raw material of following parts by weight: 20 parts of tourmaline, 25 parts of neodymia, three oxidations two
25 parts of terbium, 30 parts of opal.
Specific step is as follows for the preparation method of flexible clay facing tile with air-cleaning function of the invention:
(1) preparation of flexible clay facing tile:
Lotion, inorganic pigment and water are first weighed by weight, are stirred evenly, are obtained emulsion mixture；Then by weight
Kaolin, heavy calcium carbonate, cement, negative ion powder and quartz sand are weighed, is uniformly mixed, obtains powder mixture；Again by powder
Body mixture is added in emulsion mixture, is sufficiently stirred, and mortar is obtained；Finally above-mentioned mortar is poured into mold, one layer of laying
Alkali resistant glass fibre open weave cloth is put into baking oven later, 1 hour dry at 40 DEG C, 60 DEG C drying 3 hours, flexible decorations are obtained after demoulding
Face brick；
(2) coating treatment of flexible clay facing tile:
Under stirring, water, nano-TiO are separately added into modified acrylate emulsion by weight2The hydrosol and
Nano-meter SiO_22Above-mentioned mixed glue solution is coated in the surface of flexible clay facing tile after mixing by the hydrosol by spraying method, is done
The flexible clay facing tile with Air purification is obtained after dry.
Embodiment 2
Flexible clay facing tile with air-cleaning function of the invention is made of flexible clay facing tile and automatic cleaning coating:
The automatic cleaning coating is made of the raw material of following parts by weight: 30 parts of acrylate emulsion modified with organosiloxane, nanometer
TiO225 parts of the hydrosol, Nano-meter SiO_2225 parts of the hydrosol and 30 parts of water；
The flexible clay facing tile is made of the raw material of following parts by weight: the third cream of silicon that glass transition temperature is 10 DEG C
10 parts of liquid, 8 parts of the calcined kaolin of 325 mesh, 1 μm 25 parts of heavy calcium carbonate, 10 parts of ordinary portland cement, negative ion powder 5
Part, 100 40 parts of mesh quartz sands, 0.5 part of carbon black, 0.5 part of titan yellow and 10 parts of water.
Above-mentioned negative ion powder is made of the raw material of following parts by weight: 25 parts of tourmaline, 10 parts of neodymia, three oxidations two
40 parts of terbium, 25 parts of opal.
The preparation method is the same as that of Example 1, and floating coat is the surface that flexible clay facing tile is coated in by way of brush.
Embodiment 3
Flexible clay facing tile with air-cleaning function of the invention is made of flexible clay facing tile and automatic cleaning coating:
The automatic cleaning coating is made of the raw material of following parts by weight: 20 parts of acrylate emulsion modified with organosiloxane, nanometer
TiO235 parts of the hydrosol, Nano-meter SiO_2215 parts of the hydrosol and 20 parts of water；
The flexible clay facing tile is made of the raw material of following parts by weight: the third cream of silicon that glass transition temperature is 15 DEG C
12 parts of liquid, 6 parts of the water-washed kaoline of 400 mesh, 1.5 μm 20 parts of heavy calcium carbonate, 15 parts of portland slag cement, negative ion powder
10 parts, 150 45 parts of mesh quartz sands, 0.5 part of titanium white and 15 parts of water.
Above-mentioned negative ion powder is made of the raw material of following parts by weight: 30 parts of tourmaline, 15 parts of neodymia, seven oxidations four
20 parts of terbium, 35 parts of opal.
The preparation method is the same as that of Example 1, and floating coat is the surface that flexible clay facing tile is coated in by way of roller coating.
Embodiment 4
Flexible clay facing tile with air-cleaning function of the invention is made of flexible clay facing tile and automatic cleaning coating:
The automatic cleaning coating is made of the raw material of following parts by weight: 20 parts of fluorin modified crylic acid ester lotion, nanometer
TiO215 parts of the hydrosol, Nano-meter SiO_2235 parts of the hydrosol and 40 parts of water；
The flexible clay facing tile is made of the raw material of following parts by weight: the third cream of silicon that glass transition temperature is 20 DEG C
14 parts of liquid, 9 parts of the water-washed kaoline of 600 mesh, 2 μm 22 parts of heavy calcium carbonate, 8 parts of Portland pozzolana cement, anion
8 parts of powder, 200 40 parts of mesh quartz sands, 0.3 part of carbon black, 0.5 part of iron oxide red and 10 parts of water.
Above-mentioned negative ion powder is made of the raw material of following parts by weight: 35 parts of tourmaline, 30 parts of neodymia, seven oxidations four
25 parts of terbium, 10 parts of opal.
The preparation method is the same as that of Example 1.
Embodiment 5
Flexible clay facing tile with air-cleaning function of the invention is made of flexible clay facing tile and automatic cleaning coating:
The automatic cleaning coating is made of the raw material of following parts by weight: 30 parts of fluorin modified crylic acid ester lotion, nanometer
TiO225 parts of the hydrosol, Nano-meter SiO_2225 parts of the hydrosol and 30 parts of water；
The flexible clay facing tile is made of the raw material of following parts by weight: the third cream of silicon that glass transition temperature is 25 DEG C
9 parts of liquid, 800 10 parts of mesh calcined kaolins, 2.5 μm 16 parts of heavy calcium carbonate, 5 parts of composite Portland cement, negative ion powder 13
Part, 300 45 parts of mesh quartz sands, 0.8 part of cadmium yellow and 15 parts of water.
Above-mentioned negative ion powder is made of the raw material of following parts by weight: 40 parts of tourmaline, 20 parts of neodymia, three oxidations two
35 parts of terbium, 25 parts of opal.
Preparation method is the same as embodiment 2.
Embodiment 6
Flexible clay facing tile with air-cleaning function of the invention is made of flexible clay facing tile and automatic cleaning coating:
The automatic cleaning coating is made of the raw material of following parts by weight: 40 parts of fluorin modified crylic acid ester lotion, nanometer
TiO235 parts of the hydrosol, Nano-meter SiO_2215 parts of the hydrosol and 20 parts of water；
The flexible clay facing tile is made of the raw material of following parts by weight: the third cream of silicon that glass transition temperature is 30 DEG C
15 parts of liquid, 1,250 5 parts of mesh calcined kaolins, 3 μm 25 parts of heavy calcium carbonate, 17 parts of portland cement, 6 parts of negative ion powder, 400
50 parts of mesh quartz sand, 0.3 part of iron oxide yellow and 20 parts of water.
Above-mentioned negative ion powder is made of the raw material of following parts by weight: 25 parts of tourmaline, 20 parts of neodymia, seven oxidations four
15 parts of terbium, 40 parts of opal.
Preparation method is the same as embodiment 3.
Comparative example 1
The composition of the flexible clay facing tile of ordinary resin coating:
The resinous coat is made of the raw material of following parts by weight: 30 parts of acrylate emulsion modified with organosiloxane and water 30
Part；
The flexible clay facing tile is made of the raw material of following parts by weight: the third cream of silicon that glass transition temperature is 10 DEG C
10 parts of liquid, 325 8 parts of mesh calcined kaolins, 1 μm 25 parts of heavy calcium carbonate, 10 parts of ordinary portland cement, 100 mesh quartz sands
40 parts, 0.5 part of carbon black, 0.5 part of titan yellow and 10 parts of water.
Preparation method is the same as embodiment 2.
Sample prepared by the various embodiments described above and comparative example is tested as follows: surface contact angle test；By GB/
T3810.13-2006 measures pollution resistance；Anion-generating capacity is measured using static anion analyzer；PM2.5 concentration and formaldehyde
Assay is the interior progress in the confined space that area is 16 square metres, surrounding posts sample, originates PM2.5 concentration and first
Aldehyde is controlled as 100 μ g/m3And 0.2mg/m3, take air sample to be tested after 24 hours.
Nano-TiO is added from can be seen that in coating in 1 test result of table2And Nano-meter SiO_22Flexible facing can be significantly improved
The hydrophobicity and pollution resistance on brick surface；Embodiment 2 is compared with comparative example 1, by introducing nano-TiO in the coating2And nanometer
SiO2And negative ion powder is mixed in flexible clay facing tile, it can be seen that the flexible clay facing tile being prepared can be released effectively negative
Ion, while nano coating has biggish surface area, the two collective effect can effectively adsorb the PM2.5 particle in air
Formaldehyde in object, and absorption air, realizes air-cleaning function.
Table 1
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (8)
1. a kind of flexible clay facing tile with air-cleaning function, it is characterised in that: it is applied by flexible clay facing tile and automatically cleaning
Layer composition:
The automatic cleaning coating is made of the raw material of following parts by weight: 20~40 parts of modified acrylate emulsion, nano-TiO2
15~35 parts of the hydrosol, Nano-meter SiO_2215~35 parts of the hydrosol and 20~40 parts of water；The modified acrylate emulsion is certainly
It is crosslinked one of acrylate emulsion modified with organosiloxane or fluorin modified crylic acid ester lotion, solid content is 40~60%；
The flexible clay facing tile is made of the raw material of following parts by weight: 8~15 parts of lotion, 5~10 parts of kaolin, and heavy carbon
15~25 parts of sour calcium powder, 5~20 parts of cement, 5~15 parts of negative ion powder, 40~50 parts of quartz sand, 0.1~1 part of inorganic pigment and
10~20 parts of water；
The flexible clay facing tile the preparation method is as follows:
(1) preparation of flexible clay facing tile:
Lotion, inorganic pigment and water are first weighed by weight, are stirred evenly, are obtained emulsion mixture；Then it weighs by weight
Kaolin, heavy calcium carbonate, cement, negative ion powder and quartz sand are uniformly mixed, obtain powder mixture；Powder is mixed again
It closes object to be added in emulsion mixture, is sufficiently stirred, obtains mortar；Finally above-mentioned mortar is poured into mold, one layer of laying alkaline-resisting
Glass fiber reticular cloth is put into drying 3~5 hours in 40~100 DEG C of baking ovens later, flexible clay facing tile is obtained after demoulding；
(2) coating treatment of flexible clay facing tile:
Under stirring, nano-TiO is separately added into modified acrylate emulsion by weight2The hydrosol and Nano-meter SiO_22
Above-mentioned mixed glue solution is coated in the surface of flexible clay facing tile after mixing by the hydrosol by way of spray, brush or rolling, is done
The flexible clay facing tile with air-cleaning function is obtained after dry.
2. as described in claim 1 with the flexible clay facing tile of air-cleaning function, it is characterised in that: the automatically cleaning applies
Layer is made of the raw material of following parts by weight: 30 parts of modified acrylate emulsion, nano-TiO225 parts of the hydrosol, Nano-meter SiO_22Water
25 parts of colloidal sol and 30 parts of water；The flexible clay facing tile is made of the raw material of following parts by weight: 10 parts of lotion, 8 parts of kaolin,
20 parts of heavy calcium carbonate, 15 parts of cement, 10 parts of negative ion powder, 45 parts of quartz sand, 0.5 part of inorganic pigment and 15 parts of water.
3. as claimed in claim 1 or 2 with the flexible clay facing tile of air-cleaning function, it is characterised in that: the TiO2Water
TiO in colloidal sol2Content is that 15~30%, pH is 6~8；The SiO2SiO in the hydrosol2Content be 20~30%, pH be 6~
10。
4. as claimed in claim 1 or 2 with the flexible clay facing tile of air-cleaning function, it is characterised in that: the lotion
For silicone acrylic emulsion, solid content 50%, glass transition temperature is 5~30 DEG C.
5. as claimed in claim 1 or 2 with the flexible clay facing tile of air-cleaning function, it is characterised in that: the kaolinite
Soil is washing or calcined kaolin, and partial size is 200~1250 mesh；The partial size of the heavy calcium carbonate is 0.5~3 μm.
6. as claimed in claim 1 or 2 with the flexible clay facing tile of air-cleaning function, it is characterised in that: the cement is
In portland cement, ordinary portland cement, portland slag cement, Portland pozzolana cement and composite Portland cement
One kind.
7. as claimed in claim 1 or 2 with the flexible clay facing tile of air-cleaning function, it is characterised in that: it is described bear from
Sub- powder is made of the raw material of following parts by weight: 20~40 parts of tourmaline, 10~30 parts of neodymia, terbium sesquioxide or seven oxidations
Four 20~40 parts of terbiums, 10~40 parts of opal.
8. as claimed in claim 1 or 2 with the flexible clay facing tile of air-cleaning function, it is characterised in that: the quartz
The partial size of sand is 50~400 mesh；The inorganic pigment is carbon black, titanium white, titan yellow, iron oxide red, iron oxide yellow, barba hispanica, cadmium
One or both of red, cadmium yellow.
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| CN108895509A (en) * | 2018-09-14 | 2018-11-27 | 浙江帅康电气股份有限公司 | A kind of range hood and preparation method thereof of the permanent anion function of band |
| CN109626868B (en) * | 2018-12-05 | 2021-05-14 | 湖北万祺新型材料有限公司 | Porcelain-like coating and flexible stone-like facing brick |
| CN109437855B (en) * | 2019-01-14 | 2019-07-19 | 江西星东柔瓷建材有限公司 | A kind of preparation method of environmental protection porcelain tendre |
| CN111303678A (en) * | 2020-03-02 | 2020-06-19 | 关圣睿 | Anion powder for decoration material and preparation method and application thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005126561A (en) * | 2003-10-23 | 2005-05-19 | Dainichi Giken Kogyo Kk | Composition for multi-functional coating |
| CN1651351A (en) * | 2004-02-04 | 2005-08-10 | 黄宝林 | Nano-functional tile |
| CN101255049A (en) * | 2008-03-17 | 2008-09-03 | 石磊 | Flexible tapestry brick of external wall outer insulation system and production method thereof |
| CN101298378A (en) * | 2008-04-11 | 2008-11-05 | 北京迪百斯特科技发展有限公司 | Flexible ceramic-like tile and production process thereof |
| CN104250497A (en) * | 2014-09-26 | 2014-12-31 | 无锡七点建材有限公司 | Nano thermal insulation exterior wall paint and preparation method thereof |
| CN104559589A (en) * | 2013-10-25 | 2015-04-29 | 青岛德固建筑材料有限公司 | Nanometric and aqueous coating |
-
2016
- 2016-12-08 CN CN201611122846.8A patent/CN106545142B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005126561A (en) * | 2003-10-23 | 2005-05-19 | Dainichi Giken Kogyo Kk | Composition for multi-functional coating |
| CN1651351A (en) * | 2004-02-04 | 2005-08-10 | 黄宝林 | Nano-functional tile |
| CN101255049A (en) * | 2008-03-17 | 2008-09-03 | 石磊 | Flexible tapestry brick of external wall outer insulation system and production method thereof |
| CN101298378A (en) * | 2008-04-11 | 2008-11-05 | 北京迪百斯特科技发展有限公司 | Flexible ceramic-like tile and production process thereof |
| CN104559589A (en) * | 2013-10-25 | 2015-04-29 | 青岛德固建筑材料有限公司 | Nanometric and aqueous coating |
| CN104250497A (en) * | 2014-09-26 | 2014-12-31 | 无锡七点建材有限公司 | Nano thermal insulation exterior wall paint and preparation method thereof |
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