CN103811098B - 用于太阳能电池电极的糊剂组合物以及使用其制造的电极 - Google Patents
用于太阳能电池电极的糊剂组合物以及使用其制造的电极 Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims abstract description 63
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract description 14
- 229910003069 TeO2 Inorganic materials 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims description 29
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 8
- UPWOEMHINGJHOB-UHFFFAOYSA-N cobalt(III) oxide Inorganic materials O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 239000010948 rhodium Substances 0.000 claims description 6
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229910052681 coesite Inorganic materials 0.000 claims description 5
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229910052682 stishovite Inorganic materials 0.000 claims description 5
- 229910052905 tridymite Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
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- 239000012963 UV stabilizer Substances 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
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- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- ZJRWDIJRKKXMNW-UHFFFAOYSA-N carbonic acid;cobalt Chemical compound [Co].OC(O)=O ZJRWDIJRKKXMNW-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910000001 cobalt(II) carbonate Inorganic materials 0.000 claims description 3
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- 239000007822 coupling agent Substances 0.000 claims description 3
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- 229910052741 iridium Inorganic materials 0.000 claims description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 3
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
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- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
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- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 claims description 3
- LAJZODKXOMJMPK-UHFFFAOYSA-N tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 claims description 3
- 239000013008 thixotropic agent Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
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- 239000010937 tungsten Substances 0.000 claims description 3
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- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- LNNWKAUHKIHCKO-UHFFFAOYSA-N dioxotin;oxo(oxoindiganyloxy)indigane Chemical compound O=[Sn]=O.O=[In]O[In]=O LNNWKAUHKIHCKO-UHFFFAOYSA-N 0.000 claims 1
- 230000006641 stabilisation Effects 0.000 claims 1
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- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
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- 150000003624 transition metals Chemical class 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
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- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
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- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
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- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Photovoltaic Devices (AREA)
Abstract
Description
PbO | SiO2 | TeO2 | Bi2O3 | P2O5 | Li2O | ZnO | NiO | WO3 | Co2O3 | |
实施例1 | 40.00 | 5.00 | 22.00 | 20.00 | 0.00 | 3.00 | 0.00 | 10.00 | 0.00 | 0.00 |
实施例2 | 40.00 | 5.00 | 22.00 | 20.00 | 0.00 | 3.00 | 0.00 | 0.00 | 10.00 | 0.00 |
实施例3 | 40.00 | 5.00 | 22.00 | 20.00 | 0.00 | 3.00 | 0.00 | 0.00 | 0.00 | 10.00 |
实施例4 | 45.00 | 0.00 | 27.00 | 20.00 | 1.00 | 2.00 | 0.00 | 5.00 | 0.00 | 0.00 |
实施例5 | 45.00 | 0.00 | 27.00 | 20.00 | 1.00 | 2.00 | 0.00 | 0.00 | 5.00 | 0.00 |
实施例6 | 45.00 | 0.00 | 27.00 | 20.00 | 1.00 | 2.00 | 0.00 | 0.00 | 0.00 | 5.00 |
实施例7 | 15.00 | 0.00 | 30.00 | 40.00 | 0.00 | 0.00 | 5.00 | 0.00 | 10.00 | 0.00 |
实施例8 | 40.00 | 5.00 | 30.00 | 10.00 | 0.00 | 0.00 | 5.00 | 0.00 | 10.00 | 0.00 |
实施例9 | 15.00 | 0.00 | 30.00 | 40.00 | 0.00 | 0.00 | 5.00 | 10.00 | 0.00 | 0.00 |
实施例10 | 15.00 | 0.00 | 30.00 | 40.00 | 0.00 | 0.00 | 5.00 | 0.00 | 0.00 | 10.00 |
实施例11 | 10.00 | 0.00 | 30.00 | 40.00 | 0.00 | 0.00 | 5.00 | 0.00 | 15.00 | 0.00 |
实施例12 | 10.00 | 0.00 | 30.00 | 40.00 | 0.00 | 0.00 | 15.00 | 0.00 | 5.00 | 0.00 |
比较实施例1 | 65.00 | 10.00 | 22.00 | 0.00 | 0.00 | 3.00 | 0.00 | 0.00 | 0.00 | 0.00 |
比较实施例2 | 40.00 | 0.00 | 57.00 | 0.00 | 0.00 | 3.00 | 0.00 | 0.00 | 0.00 | 0.00 |
比较实施例3 | 40.00 | 5.00 | 22.00 | 20.00 | 0.00 | 3.00 | 10.00 | 0.00 | 0.00 | 0.00 |
效率(%) | |
实施例1 | 16.35 |
实施例2 | 16.88 |
实施例3 | 16.15 |
实施例4 | 16.38 |
实施例5 | 16.55 |
实施例6 | 16.64 |
实施例7 | 16.06 |
实施例8 | 16.26 |
实施例9 | 16.32 |
实施例10 | 16.27 |
实施例11 | 16.22 |
实施例12 | 16.29 |
比较实施例1 | 10.89 |
比较实施例2 | 14.5 |
比较实施例3 | 12.78 |
Claims (13)
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CN104118992A (zh) * | 2014-07-22 | 2014-10-29 | 江苏欧耐尔新型材料有限公司 | 用于太阳能高方阻浆料的玻璃粉及其制备方法 |
CN106716549B (zh) * | 2014-11-10 | 2020-03-24 | 株式会社村田制作所 | 玻璃陶瓷、锂离子导体、电池、电子装置及电极的制造方法 |
JP2018506152A (ja) | 2015-02-04 | 2018-03-01 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 導電性ペースト組成物およびそれによって製造された半導体デバイス |
TWI532062B (zh) * | 2015-04-27 | 2016-05-01 | Giga Solar Materials Corp | Conductive pulp and a method of manufacturing the same |
JP6580383B2 (ja) * | 2015-06-17 | 2019-09-25 | ナミックス株式会社 | 導電性ペースト、太陽電池及び太陽電池の製造方法 |
KR101706539B1 (ko) * | 2015-09-16 | 2017-02-15 | 주식회사 휘닉스소재 | 태양 전지 전극 형성용 유리 프릿 조성물, 이를 사용하여 형성된 태양 전지용 전극, 및 상기 전극을 포함하는 태양 전지 |
KR101693840B1 (ko) * | 2015-10-05 | 2017-01-09 | 대주전자재료 주식회사 | 태양전지 전면전극용 페이스트 조성물 및 이를 이용한 태양전지 |
KR20170064570A (ko) * | 2015-10-31 | 2017-06-12 | 엘에스니꼬동제련 주식회사 | 태양전지용 전극 페이스트 및 이를 사용하여 제조된 태양전지 |
KR102007863B1 (ko) * | 2015-10-31 | 2019-08-06 | 엘에스니꼬동제련 주식회사 | 태양전지용 전극 페이스트 및 이를 사용하여 제조된 태양전지 |
KR20170066716A (ko) * | 2015-10-31 | 2017-06-15 | 엘에스니꼬동제련 주식회사 | 태양전지용 전극 페이스트 및 이를 사용하여 제조된 태양전지 |
KR20170141559A (ko) * | 2016-06-15 | 2017-12-26 | 삼성에스디아이 주식회사 | 태양전지 전극 형성용 조성물 및 이로부터 제조된 전극 |
JP6714275B2 (ja) * | 2016-08-23 | 2020-06-24 | ナミックス株式会社 | 導電性ペースト及び太陽電池 |
KR20180046809A (ko) * | 2016-10-28 | 2018-05-09 | 삼성에스디아이 주식회사 | 태양전지용 핑거 전극의 제조방법 |
KR101853417B1 (ko) * | 2016-11-24 | 2018-05-02 | 엘에스니꼬동제련 주식회사 | 태양전지 전극용 도전성 페이스트 조성물 및 이를 사용하여 제조된 전극을 포함하는 태양전지 |
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CN107216041B (zh) * | 2017-05-04 | 2020-09-25 | 无锡帝科电子材料股份有限公司 | 用于制备太阳能电池电极的玻璃粉料、包括其的糊剂组合物、太阳能电池电极及太阳能电池 |
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KR20140062573A (ko) | 2014-05-26 |
CN103811098A (zh) | 2014-05-21 |
TWI546824B (zh) | 2016-08-21 |
DE102013111563B4 (de) | 2019-06-27 |
KR101600652B1 (ko) | 2016-03-07 |
DE102013111563A1 (de) | 2014-05-15 |
US20140131629A1 (en) | 2014-05-15 |
US8968607B2 (en) | 2015-03-03 |
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