CN103739525B - 一种取代苯磺酰氯的制备方法 - Google Patents
一种取代苯磺酰氯的制备方法 Download PDFInfo
- Publication number
- CN103739525B CN103739525B CN201310742587.9A CN201310742587A CN103739525B CN 103739525 B CN103739525 B CN 103739525B CN 201310742587 A CN201310742587 A CN 201310742587A CN 103739525 B CN103739525 B CN 103739525B
- Authority
- CN
- China
- Prior art keywords
- chloride
- reaction
- preparation
- substituted
- substituted phenylsulfonyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- CSKNSYBAZOQPLR-UHFFFAOYSA-N benzenesulfonyl chloride Chemical class ClS(=O)(=O)C1=CC=CC=C1 CSKNSYBAZOQPLR-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000006243 chemical reaction Methods 0.000 claims abstract description 37
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000001263 acyl chlorides Chemical class 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 125000002490 anilino group Chemical class [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims abstract 5
- 239000000243 solution Substances 0.000 claims description 21
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 14
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- -1 nitro, methyl Chemical group 0.000 claims description 7
- 235000010288 sodium nitrite Nutrition 0.000 claims description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical group C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims description 5
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 5
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 239000001119 stannous chloride Substances 0.000 claims description 5
- 235000011150 stannous chloride Nutrition 0.000 claims description 5
- 239000000284 extract Substances 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 238000010025 steaming Methods 0.000 claims description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002699 waste material Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 17
- 239000012954 diazonium Substances 0.000 description 9
- 150000001989 diazonium salts Chemical class 0.000 description 9
- 150000001448 anilines Chemical class 0.000 description 8
- 230000035484 reaction time Effects 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 230000002363 herbicidal effect Effects 0.000 description 4
- 239000004009 herbicide Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229940100389 Sulfonylurea Drugs 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 125000006575 electron-withdrawing group Chemical group 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- DLEDOFVPSDKWEF-UHFFFAOYSA-N lithium butane Chemical compound [Li+].CCC[CH2-] DLEDOFVPSDKWEF-UHFFFAOYSA-N 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N n-Butyllithium Substances [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- 210000003739 neck Anatomy 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 1
- VVCAQQGQZZLRJK-UHFFFAOYSA-N 2-fluoro-6-(trifluoromethyl)benzenesulfonyl chloride Chemical compound FC1=CC=CC(C(F)(F)F)=C1S(Cl)(=O)=O VVCAQQGQZZLRJK-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- MCIGNPLOOOVZAG-UHFFFAOYSA-N [Cl].ClS(Cl)=O Chemical compound [Cl].ClS(Cl)=O MCIGNPLOOOVZAG-UHFFFAOYSA-N 0.000 description 1
- AHIBWURJLGCHAY-UHFFFAOYSA-N [S].C1=CC=CC=C1 Chemical class [S].C1=CC=CC=C1 AHIBWURJLGCHAY-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310742587.9A CN103739525B (zh) | 2013-12-30 | 2013-12-30 | 一种取代苯磺酰氯的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310742587.9A CN103739525B (zh) | 2013-12-30 | 2013-12-30 | 一种取代苯磺酰氯的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103739525A CN103739525A (zh) | 2014-04-23 |
CN103739525B true CN103739525B (zh) | 2016-05-25 |
Family
ID=50496614
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310742587.9A Active CN103739525B (zh) | 2013-12-30 | 2013-12-30 | 一种取代苯磺酰氯的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103739525B (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104961662B (zh) * | 2015-06-11 | 2017-05-03 | 湖南化工研究院有限公司 | 2‑氟‑6‑三氟甲基苯磺酰氯的制备方法 |
CN105218413A (zh) * | 2015-08-12 | 2016-01-06 | 诚达药业股份有限公司 | 制备芳香磺酸类化合物的方法 |
CN106916087B (zh) * | 2015-12-25 | 2018-08-14 | 沈阳化工研究院有限公司 | 一种2-氟-6-三氟甲基苯磺酰氯的合成方法 |
CN106478464B (zh) * | 2016-08-30 | 2018-06-05 | 黄河三角洲京博化工研究院有限公司 | 一种2-氟-6-三氟甲基苯磺酰氯的制备方法 |
CN107602566B (zh) * | 2017-09-26 | 2019-11-01 | 江苏省农用激素工程技术研究中心有限公司 | 双氟磺草胺中间体的合成方法 |
CN113194949B (zh) * | 2018-12-18 | 2024-05-31 | 株式会社D.西医疗法研究所 | 异喹啉磺酰氯酸加成盐和其制造方法 |
CN112759536A (zh) * | 2019-11-05 | 2021-05-07 | 常州锐博生物科技有限公司 | 取代的苯磺酰氯的制备方法 |
CN111574414A (zh) * | 2020-05-20 | 2020-08-25 | 上海毕得医药科技有限公司 | 一种4-溴-2-甲氧基苯磺酰氯的合成方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1443159A (zh) * | 2000-07-24 | 2003-09-17 | 拜尔作物科学有限公司 | 经取代的磺酰氨基甲基苯甲酸(衍生物)及其制备方法 |
CN103319489A (zh) * | 2013-07-12 | 2013-09-25 | 黑龙江大学 | 三唑并嘧啶磺酰胺化合物及合成方法和应用 |
CN103333120A (zh) * | 2013-06-22 | 2013-10-02 | 西南科技大学 | 甲基二磺隆的合成方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6433169B1 (en) * | 2000-09-26 | 2002-08-13 | Dow Agrosciences Llc | Process for the preparation of 2-alkoxy-6-trifluoromethyl-N-([1,2,4]triazolo[1,5-c]pyrimidin-2-yl) benzenesulfonamides |
EA015937B1 (ru) * | 2005-08-26 | 2011-12-30 | Мерк Сероно С.А. | Производные пиразина и их применение в качестве ингибиторов pi3k |
CN102336689A (zh) * | 2011-08-29 | 2012-02-01 | 天津市筠凯化工科技有限公司 | 4-氯-3-(三氟甲基)苯磺酰氯的制备及其精制方法 |
CN102603582A (zh) * | 2012-02-28 | 2012-07-25 | 王继龙 | 一种合成邻甲酸甲酯苯磺酰胺的方法 |
-
2013
- 2013-12-30 CN CN201310742587.9A patent/CN103739525B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1443159A (zh) * | 2000-07-24 | 2003-09-17 | 拜尔作物科学有限公司 | 经取代的磺酰氨基甲基苯甲酸(衍生物)及其制备方法 |
CN103333120A (zh) * | 2013-06-22 | 2013-10-02 | 西南科技大学 | 甲基二磺隆的合成方法 |
CN103319489A (zh) * | 2013-07-12 | 2013-09-25 | 黑龙江大学 | 三唑并嘧啶磺酰胺化合物及合成方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN103739525A (zh) | 2014-04-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103739525B (zh) | 一种取代苯磺酰氯的制备方法 | |
CN104447396B (zh) | 一种安息香肟衍生物及其制备方法 | |
CN105051009B (zh) | 用于制备酰亚胺基二硫酰化合物的方法 | |
CN105481744B (zh) | Co2/n2‑h2o2双重刺激响应型表面活性剂及其制备方法 | |
CN104945286A (zh) | 一种高纯度硫酸二酯的合成方法 | |
CN105348216A (zh) | 一种2-乙酰基噻唑的合成方法 | |
CN101195593A (zh) | 一种烷基苯磺酰氯的工业化生产方法 | |
CN103193611B (zh) | 一种间三氟甲基苯乙酮的合成方法 | |
CN102731321A (zh) | 一种2-甲基-4-(1,1,1,2,3,3,3-七氟-2-丙基)苯胺的制备方法 | |
CN102603721A (zh) | 一种异氰脲酸三缩水甘油酯的制备方法 | |
CN107043322A (zh) | 一种2,4,6‑三氟苯甲醛的制备方法 | |
CN104607251B (zh) | 含有混合价态Cu的框架化合物催化剂材料及其制备方法 | |
CN109232259A (zh) | 一种硝基苯乙酮的制备方法 | |
CN116003260B (zh) | 一种由尿素衍生物制备1-萘胺类化合物的方法及其预测模型 | |
CN103028356A (zh) | 一种室温下进行芳香杂环类锂卤交换反应的装置与方法 | |
CN106187814A (zh) | 一种分散染料重氮盐的合成方法 | |
CN102887530A (zh) | 一种氟化钾的生产工艺 | |
CN104817057A (zh) | 一种硫碘循环制氢系统的预混装置及硫碘循环制氢系统 | |
CN104072360A (zh) | 一种合成天然肉桂酸的方法 | |
CN103274944A (zh) | 氯甲酸甲酯的制备方法 | |
CN103351340B (zh) | 唑虫酰胺的新制备方法 | |
CN101735130A (zh) | 一种二甲基二硒的制备方法 | |
CN104774141A (zh) | 一种2-溴-9-芴酮的合成方法 | |
CN107602407A (zh) | 一种2‑溴‑4‑氟乙酰苯胺的合成方法 | |
CN111303073A (zh) | 利用苯并噻唑酮与2-卤代-n-甲基-n-苯基乙酰胺制备农药苯噻草胺的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Li Ying Inventor after: Li Chengkun Inventor after: Zhang Jianlin Inventor after: Mou Qingping Inventor after: Wu Wenlei Inventor after: Yao Gang Inventor after: Hou Xiaofeng Inventor after: Cheng Lunan Inventor before: Li Ying Inventor before: Zhang Jianlin Inventor before: Mou Qingping Inventor before: Wu Wenlei Inventor before: Yao Gang Inventor before: Hou Xiaofeng Inventor before: Cheng Lunan |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LI YING ZHANG JIANLIN MOU QINGPING WU WENLEI YAO GANG HOU XIAOFENG CHENG LUNAN TO: LI YING LI CHENGKUN ZHANG JIANLIN MOU QINGPING WU WENLEI YAO GANG HOU XIAOFENG CHENG LUNAN |
|
ASS | Succession or assignment of patent right |
Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: YELLOW RIVER DELTA JINGBO CHEMICAL RESEARCH INSTITUTE CO., LTD. Effective date: 20141204 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20141204 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Beijing Bo agricultural Polytron Technologies Inc Applicant after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Boxing Economic Development Zone, Binzhou, Shandong Applicant before: CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE Co.,Ltd. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Jingbo Agrochemical Technology Co., Ltd. of Jingbo Industrial Park, Chenhu Town, Boxing County, Binzhou City, Shandong Province Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder |
Address after: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee after: Shandong Jingbo Agrochemical Technology Co.,Ltd. Address before: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder |